Spatial evolution of nitrogen and phosphorus loads along a small Mediterranean river: implication of bed sediments     

Marie‐George Tournoud  Jean‐Louis Perrin  Frdric Gimbert  Bernadette Picot 《水文研究》2005,19(18):3581-3592

This study addresses the spatial variations in water quality along the River Vène (France). The Vène drains a 67 km² rural basin, with a large karstic area, located in a Mediterranean context. A 1 day sampling campaign was conducted along the river, in winter low‐flow conditions (February 2003). Physico‐chemical parameters and water flow discharge were measured in situ during the sampling campaign. Water quality was evaluated by determining the concentrations of nitrogen and phosphorus in water and bed‐sediment samples. Nitrogen and phosphorus loads were evaluated taking into account the measured concentrations and discharge. The campaign included 18 sampling points and concerned the whole river from the spring to the outlet, plus the main inputs, i.e. sewage treatment works, main tributaries and karstic springs. The spatial evolution of nitrogen and phosphorus loads along the river allowed the significant role of point‐source inputs to be demonstrated. The decrease in nutrient loads along the river occurred mainly in specific reaches where fine sediments had accumulated. In these zones, phosphorus is trapped in the bed sediments in calcium‐bound phosphates due to precipitation processes. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Repeat Sampling and Coliform Bacteria Detection Rates in New Jersey Domestic Wells          下载免费PDF全文

Thomas B. Atherholt  Leo R. Korn  Judith B. Louis  Nicholas A. Procopio 《Ground Water Monitoring & Remediation》2015,35(2):70-80

In compliance with the New Jersey Private Well Testing Act, 78,546 wells (93,787 samples, including samples from 13,290 wells that were analyzed more than once) were analyzed for total coliform (TC) bacteria by one or more of 39 laboratories over a 10‐year period. Samples containing TC bacteria were further analyzed for the presence of either fecal coliform or E. coli (FC/EC) bacteria. The large population of wells sampled multiple times permitted a systematic study of the effect of repeat sampling on coliform bacteria detection rates. The detection rate increased with the number of times wells were sampled. In bedrock, TC bacteria were detected in 21% of the population of wells analyzed only once, 33% in the population sampled twice, and 43% in the population sampled three times. It was estimated that TC bacteria would be detected in 90% of all wells if each well was analyzed 10 times. For FC/EC bacteria, it was estimated that 21 and 68 samples, respectively, would be required to reach the 50% and 90% population detection rates. In the Coastal Plain (CP), many more samples would be required to achieve the same estimated population detection rates. The population detection rate estimates were also dependent on the type of method used, the pH of the well water, and the geologic formation in which wells were located. A single sample was not sufficient to detect coliform bacteria when present in well water.  相似文献   

Techniques to measure the dry aeolian deposition of dust in arid and semi‐arid landscapes: a comparative study in West Niger     

Dirk Goossens  Jean Louis Rajot 《地球表面变化过程与地形》2008,33(2):178-195

Seven techniques designed to measure the dry aeolian deposition of dust on a desert surface were tested during field experiments in Niger, central‐west Africa. Deposition fluxes were measured during eight periods of 3–4 days each. Experimental techniques tested were the MDCO (marble dust collector) method, the Frisbee method, the glass plate method (optical analysis of dust deposited on glass surfaces using particle imaging software), the soil surface method (deposition on a simulated desert floor) and the CAPYR (capteur pyramidal) method. Theoretical techniques tested were the inferential method and the combination method (gradient method extended with a deposition term for coarse dust particles). The results obtained by the MDCO, Frisbee, inferential and combination methods could be directly compared by converting the data to identical standard conditions (deposition on a water surface producing no resuspension). The results obtained by the other methods (glass plate, soil surface, CAPYR) were compared relatively. The study shows that the crude (unconverted) deposition fluxes of the five experimental techniques were similar, while the crude deposition fluxes calculated by the two theoretical techniques were substantially higher, of the order of four to five times as high as for the experimental techniques. Recalculation of the data to identical environmental conditions (the standard water surface) resulted in nearly identical deposition fluxes for the MDCO, Frisbee, inferential and combination techniques, although the latter two still had slightly higher values (but the differences remained small). The measurements illustrate the need to include a grain shape factor in theoretical dust deposition models. Without such a factor, theoretical models overestimate the deposition. The paper also discusses the advantages and disadvantages of the techniques tested. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Age and whole rock–glass compositions of proximal pyroclastics from the major explosive eruptions of Somma-Vesuvius: A review as a tool for distal tephrostratigraphy     

Roberto Santacroce  Raffaello Cioni  Paola Marianelli  Alessandro Sbrana  Roberto Sulpizio  Giovanni Zanchetta  Douglas J. Donahue  Jean Louis Joron 《Journal of Volcanology and Geothermal Research》2008

A review of compositional data of the major explosive eruptions of Vesuvius is presented, comparing compositions (major elements) of whole rock with glass shards from the proximal deposits, hopefully useful for long-distance correlation. A critical review of published and new geochronological data is also provided. All available ¹⁴C ages are calibrated to give calendar ages useful for the reconstruction of the volcanological evolution of the volcanic complex. The pyroclastic deposits of the four major Plinian eruptions (22,000 yr cal BP “Pomici di Base”, 8900 yr cal BP “Mercato Pumice”, 4300 yr cal BP “Avellino Pumice”, and A.D. 79 “Pompeii Pumice”) are widely dispersed and allow a four-folded, Plinian to Plinian, stratigraphic division: 1. B–M (between Pomici di Base and Mercato); 2. M–A (between Mercato and Avellino); 3. A–P (between Avellino and Pompeii); 4. P–XX (from the Pompeii Pumice to the last erupted products of the XXth century). Within each interval, the age, lithologic and compositional features of pyroclastic deposits of major eruptions, potentially useful for tephrostratigraphic purposes on distal areas, are briefly discussed. The Vesuvius rocks are mostly high Potassic products, widely variable in terms of their silica saturation. They form three groups, different for both composition and age: 1. slightly undersaturated, older than Mercato eruption; 2. mildly undersaturated, from Mercato to Pompeii eruptions; 3. highly undersaturated, younger than Pompeii eruption. For whole rock analyses, the peculiar variations in contents of some major and trace elements as well as different trends in element/element ratios, allow a clear, unequivocal, easy diagnosis of the group they belong. Glass analyses show large compositional overlap between different groups, but selected element vs. element plots are distinctive for the three groups. The comparative analysis of glass and whole rock major element compositions provides reliable geochemical criteria helping in the recognition, frequently not obvious, of distal products from the different single eruptions.  相似文献   

Variability in the annual cycle of vertical particulate organic carbon export on Arctic shelves: Contrasting the Laptev Sea,Northern Baffin Bay and the Beaufort Sea     

Catherine Lalande  Alexandre Forest  David G. Barber  Yves Gratton  Louis Fortier 《Continental Shelf Research》2009

The ongoing regression of sea ice cover is expected to significantly affect the fate of organic carbon over the Arctic continental shelves. Long-term moored sediment traps were deployed in 2005–2006 in the Beaufort Sea, Northern Baffin Bay and the Laptev Sea to compare the annual variability of POC fluxes and to evaluate the factors regulating the annual cycle of carbon export over these continental shelves. Annual POC fluxes at 200 m ranged from 1.6 to 5.9 g C m⁻² yr⁻¹ with the highest export in Northern Baffin Bay and the lowest export over the Mackenzie Shelf in the Beaufort Sea. Each annual cycle exhibited an increase in POC export a few weeks before, during, or immediately following sea ice melt, but showed different patterns over the remainder of the cycle. Enhanced primary production, discharge of the Lena River, and resuspension events contributed to periods of elevated POC export over the Laptev Sea slope. High POC fluxes in Northern Baffin Bay reflected periods of elevated primary production in the North Water polynya. In the Beaufort Sea sediment resuspension contributed to most of the large export events. Our results suggest that the outer shelf of the Laptev Sea will likely sustain the largest increase in POC export in the next few years due to the large reduction in ice cover and the possible increase in the Lena River discharge. The large differences in forcing among the regions investigated reinforce the importance of monitoring POC fluxes in the different oceanographic regimes that characterize the Arctic shelves to assess the response of the Arctic Ocean carbon cycle to interannual variability and climate change.  相似文献   

A New Data-Space Inversion Procedure for Efficient Uncertainty Quantification in Subsurface Flow Problems     

Wenyue Sun  Louis J. Durlofsky 《Mathematical Geosciences》2017,49(6):679-715

Uncertainty quantification for subsurface flow problems is typically accomplished through model-based inversion procedures in which multiple posterior (history-matched) geological models are generated and used for flow predictions. These procedures can be demanding computationally, however, and it is not always straightforward to maintain geological realism in the resulting history-matched models. In some applications, it is the flow predictions themselves (and the uncertainty associated with these predictions), rather than the posterior geological models, that are of primary interest. This is the motivation for the data-space inversion (DSI) procedure developed in this paper. In the DSI approach, an ensemble of prior model realizations, honoring prior geostatistical information and hard data at wells, are generated and then (flow) simulated. The resulting production data are assembled into data vectors that represent prior ‘realizations’ in the data space. Pattern-based mapping operations and principal component analysis are applied to transform non-Gaussian data variables into lower-dimensional variables that are closer to multivariate Gaussian. The data-space inversion is posed within a Bayesian framework, and a data-space randomized maximum likelihood method is introduced to sample the conditional distribution of data variables given observed data. Extensive numerical results are presented for two example cases involving oil–water flow in a bimodal channelized system and oil–water–gas flow in a Gaussian permeability system. For both cases, DSI results for uncertainty quantification (e.g., P10, P50, P90 posterior predictions) are compared with those obtained from a strict rejection sampling (RS) procedure. Close agreement between the DSI and RS results is consistently achieved, even when the (synthetic) true data to be matched fall near the edge of the prior distribution. Computational savings using DSI are very substantial in that RS requires \(O(10^5\)–\(10^6)\) flow simulations, in contrast to 500 for DSI, for the cases considered.  相似文献   

Ultraviolet irradiation of naphthalene in H2O ice: Implications for meteorites and biogenesis     

Max P. BERNSTEIN  Jason P. DWORKIN  Scott A. SANDFORD  Louis J. ALLAMANDOLA 《Meteoritics & planetary science》2001,36(3):351-358

Abstract— The polycyclic aromatic hydrocarbon (PAH) naphthalene was exposed to ultraviolet radiation in H₂O ice under astrophysical conditions, and the products were analyzed using infrared spectroscopy and high‐performance liquid chromatography. As we found in our earlier studies on the photoprocessing of coronene in H₂O ice, aromatic alcohols and ketones (quinones) were formed. The regiochemistry of the reactions is described and leads to specific predictions of the relative abundances of various oxidized naphthalenes that should exist in meteorites if interstellar ice photochemistry influenced their aromatic inventory. Since oxidized PAHs are present in carbon‐rich meteorites and interplanetary dust particles (IDPs), and ubiquitous in and fundamental to biochemistry, the delivery of such extraterrestrial molecules to the early Earth may have played a role in the origin and evolution of life.  相似文献   

Urban Planning in Hong Kong and Integration with the Pearl River Delta: A Historical Account of Local Development     

Louis?Augustin-JeanEmail author 《GeoJournal》2005,62(1-2):1-13

This paper shows the importance that urban planning plays in the development of Hong Kong. This leads to a reassessment of the role of the government, which is the sole proprietor of the land, in the economy – while it acknowledges the importance of market forces. The first part shows how, since 1945, Hong Kong authorities have been obliged to intervene more in urban planning and local development, despite their liberal ideology. The second part focuses on the interaction between government action and market forces, and their influence in this development. The third part deals with the question of the economic integration between Hong Kong and the Pearl River Delta (PRD) after China started its economics reforms in 1978. The deconcentration of Hong Kong industries to China was mainly due to market forces, but provided a new role for the government. This role is analyzed through its transportation policy – the domain with the most visible governmental intervention before and after 1997. It indicates the preference of the government to develop the territory rather than better integration with the PRD, because of the internal economic problems that may emerge from this integration. Nevertheless, for political and economic reasons, this integration is also seen as necessary. The future of Hong Kong’s economy lies in the answers the authorities will give to this dilemma.  相似文献   

Biological and Temporal Variations of Trace Element Concentrations in the Moss Species Scleropodium purum (Hedw.) Limpr.     

Sebastien Leblond  Sandrine Gombert  Jean Louis Colin  Remi Losno  Catherine Rausch De Traubenberg 《Journal of Atmospheric Chemistry》2004,49(1-3):95-110

Over a period of one year, the moss Scleropodium purum was sampled every two weeks in a French rural area to determine the levels of Li, Na, Al, Si, P, Ca, V, Mn, Fe, Zn, Ba, Hg, and Pb. The element distribution in the moss shoot was studied throughout the year. An apical bioconcentration was discovered for Na, P, Ca, Mn, and Zn, whereas higher levels were found in the basal fraction for Li, Al, Si, V, Fe, Ba, Hg, and Pb. A significant variation of element concentrations was observed during the sampling period. In the apical part Li, Al, Si, V, Fe, Ba, and Hg show maximum levels in the summer and minimum in the autumn. The same pattern was found with Ca and Mn in the whole plant, whereas Na showed opposite fluctuations.  相似文献   

Nondestructive imaging of small size voids at Akrotiri archaeological site, Thera Island, Greece, by seismic inversion techniques     

Filippos I. Louis  Roger A. Clark  Ioannis F. Louis  Costas C. Makropoulos   《Journal of Applied Geophysics》2005,57(4):306-326

  相似文献