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51.
Stijn Dhondt Quynh Le Xuan Hieu Vu Van Luc Hens 《Stochastic Environmental Research and Risk Assessment (SERRA)》2011,25(3):363-376
Traffic is an essential part of modern society and mobility is part of its socio-economic setting. However, signs of counter
productivity arise as the current mobility patterns substantially affect our health, including the consequences from traffic
accidents, air pollution—which causes even more victims than traffic accidents—and traffic-noise. The use of private motorised
vehicles also contributes to sedentarism, climate change and psychological effects. This paper reviews these mobility related
health effects and applies them to the situation in Hai Phong, a Vietnamese port-city in fast development and facing growing
mobility patterns. In his Master Plan the city developed a view on its development together with the transportation infrastructure
up to 2020. Together with the fast changing mobility patterns, such as a modal change from bicycles to motorcycles and cars,
this lead to an increase in motorized vehicles and non-negligible environmental health risks. Applying the methodology of
a Health Impact Assessment as used in previous studies the current health burden is estimated, focussing on particulate matter
(PM) and noise. For PM10 1287 deaths per year were calculated for the current situation, where the estimated number of deaths by 2020 doubled up to
2741. Hospital admissions due to PM10 raised from 44,954 now to 51,467 in 2020 and for PM2.5 the restricted-activity days were calculated, accounting for 852,352 per year. For noise only calculations for the current
state (2007) were performed. The total estimated DALYs due to noise was 4758. 相似文献
52.
Knowledge of the structural changes that particulate organic matter (POM) undergoes in natural systems is essential for determining its reactivity and fate. In the present study, we used advanced solid-state NMR techniques to investigate the chemical structures of sinking particulate matter collected at different depths as well as humic acids (HAs) extracted from these samples and underlying sediments from the Saguenay Fjord and the St. Lawrence Lower Estuary (Canada). Compared to bulk POM, HAs contain more non-polar alkyls, aromatics, and aromatic C-O, but less carbohydrates (or carbohydrate-like structures). In the two locations studied, the C and N contents of the samples (POM and HAs) decreased with depth and after deposition onto sediments, leaving N-poor but O-enriched HAs and suggesting the involvement of partial oxidation reactions during POM microbial degradation. Advanced NMR techniques revealed that, compared to the water-column HAs, sedimentary HAs contained more protonated aromatics, non-protonated aromatics, aromatic C-O, carbohydrates (excluding anomerics), anomerics, OCq, O-Cq-O, OCH, and OCH3 groups, but less non-polar alkyls, NCH, and mobile CH2 groups. These results are consistent with the relatively high reactivity of lipids and proteins or peptides. In contrast, carbohydrate-like structures were selectively preserved and appeared to be involved in substitution and copolymerization reactions. Some of these trends support the selective degradation (or selective preservation) theory. The results provide insights into mechanisms that likely contribute to the preservation of POM and the formation of molecules that escape characterization by traditional methods. Despite the depletion of non-polar alkyls with depth in HAs, a significant portion of their general structure survived and can be assigned to a model phospholipid. In addition, little changes in the connectivities of different functional groups were observed. Substituted and copolymerized carbohydrates and fused-ring aromatics detected in the present study likely represented an important part of molecularly uncharacterized components (MUC). 相似文献
53.
Mourad Essalhi Stanislas Sizaret Luc Barbanson Yan Chen France Lagroix François Demory José M. Nieto Reinaldo Sáez M. Ángeles Capitán 《Mineralium Deposita》2011,46(8):981-999
In the Rio Tinto district of the Iberian Pryrite Belt of South Spain, the weathering of massive sulfide bodies form iron caps,
i.e., true gossans and their subsequent alteration and re-sedimentation has resulted in iron terraces, i.e., displaced gossans.
To study the stucture and evolution of both types of gossans, magnetic investigations have been carried out with two foci:
(1) the characterisation and spatial distribution of magnetic fabrics in different mineralised settings, including massive
sulfides, gossans, and terraces, and (2) paleomagnetic dating. Hematite has been identified as the suceptibility carrier in
all sites and magnetic fabric investigation of four gossans reveals a vertical variation from top to bottom, with: (1) a horizontal
foliation refered to as “mature” fabric in the uppermost part of the primary gossans, (2) highly inclined or vertical foliation
interpreted as “immature” fabric between the uppermost and lowermost parts, and (3) a vertical foliation interpreted to be
inherited from Hercynian deformation in the lowermost part of the profiles. In terraces, a horizontal foliation dominates
and is interpreted to be a “sedimentary” fabric. Rock magnetic studies of gossan samples have identified goethite as the magnetic
remanence carrier for the low-temperature component, showing either a single direction close to the present Earth field (PEF)
direction or random directions. Maghemite, hematite, and occasionally magnetite are the remanence carriers for the stable
high-temperature component that is characterized by non PEF directions with both normal and reversed magnetic polarities.
No reliable conclusion can be yet be drawn on the timing of terrace magnetization due to the small number of samples. In gossans,
the polarity is reversed in the upper part and normal in the lower part. This vertical distribution with a negative reversal
test suggests remanence formation during two distinct periods. Remanence in the upper parts of the gossans is older than in
the lower parts, indicating that the alteration proceeded from top to bottom of the profiles. In the upper part, the older
age and the horizontal “mature” fabric is interpreted to be a high maturation stage of massive sulfides’ alteration. In the
lower part, the age is younger and the inherited “imature” vertical Hercynian fabric indicates a weak maturation stage. These
two distinct periods may reflect changes of paleoclimate, erosion, and/or tectonic motion. 相似文献
54.
This study investigates the isotopic composition (C, O, S and Sr) of carbonates, sulphates and sulphide cements in the rock
matrix and fracture fillings in geological formations of the Southeast basin of France, using core samples collected during
the Deep Geology of France programme (GPF Ardèche theme). The Southeast basin belongs to the Alpine Tethyan margin. It is
one of the thickest sedimentary basins in Europe, reaching upwards of 9 km in certain locations. The main fluid transfer from
the basin is related to the large Pb–Zn Mississippi Valley-type district along the southern margin of the Massif Central block.
A synthesis of the tectonic, mineralogical and petrographic investigations on the GPF boreholes shows that a major fluid circulation
event occurred across the Alpine margin of Tethys during the Early Jurassic (Hettangian–Bathonian). It produced a general
cementation of the rock porosity through precipitation of dolomite, sulphate and barite. Fracture fillings yield isotopic
signatures distinct from the matrix cements. Matrix cements have particular characteristics, i.e. δ34S and δ13C that agree with a marine origin. The δ34S values of Permo-Carboniferous to Triassic sulphides from fracture cements are interpreted as resulting from the thermo-chemical
reduction of sulphates. Fracture sulphates in the same geological formations yield δ34S values that define a relatively homogeneous end-member, whose composition is similar to sulphates in the Largentière Pb–Zn
ore deposit. The source of S is attributed to the Permo-Carboniferous succession. The borehole fracture fillings are attributed
to a major fluid circulation stage compatible with the Early Jurassic stage identified from the geological investigation of
the boreholes. The formation of the Largentière deposit is considered as resulting from the mixing of this Early Jurassic
fluid with continental hydrothermal fluids circulating in a basement horst, along its margin with the sedimentary basin. Other
Pb–Zn deposits may also be related to fluid migration along the basement/sedimentary cover interface in the eastern and western
parts of the Massif Central. This regional fluid circulation event may represent a geodynamic marker of the Jurassic extensional
phase. 相似文献
55.
The question being tackled in this study is to which extent grain rearrangement contributes to porosity reduction in very well sorted quartzose sands (ideal reservoir sands). A numerical model, RAMPAGE (an acronym of random packing generator), has been developed to address this long-standing problem. RAMPAGE represents a synthesis of various algorithms designed to simulate packing of equal-sized spheres, which have been used to represent ideal solids, liquids, and gases, as well as natural porous media. The results of RAMPAGE simulations compare favourably to theoretical and experimental data from various disciplines and allow delineation of the field of gravitationally stable random packing of equal-sized spheres in the 2-D state space of porosity (P) versus mean coordination number (N). Three end-member packing states have been identified: random loose packing (RLP: P = 45.4%, N = 5.2), random close packing (RCP: P = 36.3%, N = 7.0), and bridged random close packing (Bridged RCP: P = 39.5%, N = 5.2). Unlike previously proposed models, RAMPAGE can simulate the transition from RLP to any other point in the stability field. The RLP state is fully consistent with wet-packed porosities of synthetic sands with lognormal mass-size distributions reported in the literature. The much higher in-situ porosity values reported for modern (air-packed) sands are unlikely to be preserved at depth on geological time scales. Data on the relation between intergranular volume and burial depth indicate that the observed intergranular volume reduction in the upper ~ 800 m of the sediment column corresponds to the evolution of RLP to RCP, and is thus fully explained by non-destructive grain rearrangement. 相似文献
56.
Delphine Yeghicheyan Cécile Bossy Martine Bouhnik Le Coz Chantal Douchet Guy Granier Alexie Heimburger Francois Lacan Aurélie Lanzanova Tristan C. C. Rousseau Jean‐Luc Seidel Mickaël Tharaud Frédéric Candaudap Jérôme Chmeleff Christophe Cloquet Sophie Delpoux Marie Labatut Rémi Losno Catherine Pradoux Yann Sivry Jeroen E. Sonke 《Geostandards and Geoanalytical Research》2013,37(4):449-467
The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given. 相似文献
57.
J. Zender D. Berghmans D. S. Bloomfield C. Cabanas Parada I. Dammasch A. De Groof E. D’Huys M. Dominique P. Gallagher B. Giordanengo P. A. Higgins J.-F. Hochedez M. S. Yalim B. Nicula E. Pylyser L. Sanchez-Duarte G. Schwehm D. B. Seaton A. Stanger K. Stegen S. Willems 《Solar physics》2013,286(1):93-110
The PROBA2 Science Centre (P2SC) is a small-scale science operations centre supporting the Sun observation instruments onboard PROBA2: the EUV imager Sun Watcher using APS detectors and image Processing (SWAP) and Large-Yield Radiometer (LYRA). PROBA2 is one of ESA’s small, low-cost Projects for Onboard Autonomy (PROBA) and part of ESA’s In-Orbit Technology Demonstration Programme. The P2SC is hosted at the Royal Observatory of Belgium, co-located with both Principal Investigator teams. The P2SC tasks cover science planning, instrument commanding, instrument monitoring, data processing, support of outreach activities, and distribution of science data products. PROBA missions aim for a high degree of autonomy at mission and system level, including the science operations centre. The autonomy and flexibility of the P2SC is reached by a set of web-based interfaces allowing the operators as well as the instrument teams to monitor quasi-continuously the status of the operations, allowing a quick reaction to solar events. In addition, several new concepts are implemented at instrument, spacecraft, and ground-segment levels allowing a high degree of flexibility in the operations of the instruments. This article explains the key concepts of the P2SC, emphasising the automation and the flexibility achieved in the commanding as well as the data-processing chain. 相似文献
58.
Jae-Hun Park Kathleen A. Donohue D. Randolph Watts Luc Rainville 《Journal of Oceanography》2010,66(5):709-717
The distribution of deep near-inertial waves (NIWs) is investigated using data mainly from an array of 46 near-bottom acoustic
current meter sensors spanning a 600 km × 600 km region as part of the Kuroshio Extension System Study during 2004–2006. The
deep NIW distribution is interpreted in the context of both upper-layer and near-bottom mapped circulations. The wintertime-mean
mixed-layer NIW energy input, modeled from observed wind stress, has the same range of values north and south of the Kuroshio
Extension in this region. Yet, the wintertime-mean deep NIW energy distribution reveals a sharp factor-of-5 decrease from
north to south of the Kuroshio jet. This direct observational evidence shows that the Kuroshio Extension blocks the equatorward
propagation of NIWs. The NIW energy that does reach the sea floor within the subset of wintertime observations in the subtropical
gyre arrives with patchy spatial and temporal distribution. Elevated NIW energy in deep water is associated with anticyclones
in the deep barotropic flow and unassociated with upper layer eddies. 相似文献
59.
Els Verfaillie Steven Degraer Kristien Schelfaut Wouter Willems Vera Van Lancker 《Estuarine, Coastal and Shelf Science》2009
Mapping ecologically relevant zones in the marine environment has become increasingly important. Biological data are however often scarce and alternatives are being sought in optimal classifications of abiotic variables. The concept of ‘marine landscapes’ is based on a hierarchical classification of geological, hydrographic and other physical data. This approach is however subject to many assumptions and subjective decisions. 相似文献
60.
Leopoldo Franco Jimmy Geeraerts Riccardo Briganti Marc Willems Giorgio Bellotti Julien De Rouck 《Coastal Engineering》2009
The paper presents the comparison between the results of small-scale model tests and prototype measurements of wave overtopping at a rubble-mound breakwater. The specific structure investigated is the west breakwater of the yacht harbour of Rome at Ostia (Italy) and is characterized by a gentle seaward slope (1/4) and by a long, shallow foreshore. The laboratory tests firstly aimed at carefully reproducing two measured storms in which overtopping occurred and was measured. The tests have been carried out in two independent laboratories, in a wave flume and in a wave basin, hence using a two-dimensional (2-D) and a three-dimensional (3-D) setup. In the 2-D laboratory tests no overtopping occurred during the storm reproductions; in the 3-D case discharges five to ten times smaller than those observed in prototype have been measured. This indicates the existence of model and scale effects. These effects have been discussed on the basis of the results of several parametric tests, which have been carried out in both laboratories, in addition to the storm reproductions, varying wave and water level characteristics. Final comparison of all the performed tests with 86 prototype measurements still suggests the existence of scale and model effects that induce strong underestimation of overtopping discharge at small scale. The scale reproduction of wave breaking on the foreshore, together with the 3-D features of the prototype conditions and the absence of wind stress in the laboratory measurements, have been individuated as the main sources of scale and model effects. The paper also provides a comparison between the data and a largely used formula for wave overtopping discharges in the presence of structures similar to the one at hand. The suitable value of a roughness factor that appears in that formula is investigated and good agreement is found with other recent researches on rubble-mound breakwaters. 相似文献