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171.
List of papers from other journals  相似文献   
172.
The Earth System Curator is a National Science Foundation sponsored project developing a metadata formalism for describing the digital resources used in climate simulations. The primary motivating observation of the project is that a simulation/model’s source code plus the configuration parameters required for a model run are a compact representation of the dataset generated when the model is executed. The end goal of the project is a convergence of models and data where both resources are accessed uniformly from a single registry. In this paper we review the current metadata landscape of the climate modeling community, present our work on developing a metadata formalism for describing climate models, and reflect on technical challenges we have faced that require new research in the area of Earth Science Informatics.  相似文献   
173.
A rock avalanche deposit was investigated in order to understand the chronological evolution of geological hazards and to evaluate the interaction of the triggering geodynamic processes in the valley Val Viola, Italian Alps. The deposit is situated west of the Alpe Dosdé, in a permafrost area with deep-seated gravitational deformations (DSGD) along a tectonic line. Based on its geomorphologic context, the rock avalanche was first interpreted as a result of slope stress release without exact timing. This hypothesis was tested by measuring the 10Be exposure date of quartz from one boulder from the rock avalanche. The age of 7430±460 years places the event in the early Holocene. The timing of the last deglaciation was constrained using the inner late glacial moraine of a moraine doublet in the valley Alpe Dosdé situated at an altitude between 2140 and 2120 m a.s.l. west of the rock avalanche. The 10Be concentrations of quartz yield minimum exposure ages of 11,480±670 and 10,850±820 years. Different proposals for potential triggering factors of the rock avalanche include (a) melting of the local valley glacier and slope stress release in the Val Viola, likely to play a minor role as trigger, because of the time delay between the deglaciation and the rock avalanche event. More likely are (b) enhanced crustal seismicity induced by post-glacial regional isostatic glacial rebound coupled with tectonic stress or/and (c) climate conditions with higher temperatures around 7430±460 years, resulting in an upwards movement of the permafrost limit and destabilization of the rock walls.  相似文献   
174.
A significant As anomaly has been reported in the literature for stream sediments and unlithified Quaternary deposits of the Pecora River valley in Southern Tuscany, extending from the “Colline Metallifere” pyrite-base metals district to the Tyrrhenian Sea. The As anomaly spreads over several square kilometers around a core that exceeds 500 ppm. Several source contributions (from natural to anthropogenic) have been invoked to explain the observed As distribution in the Pecora Valley, including the metal-working industry which was active in this area, particularly in Etrusco-Roman times and in the Middle Ages. In order to evaluate the contribution of ancient mining and metallurgical activities in the Pecora Valley to elevated As concentrations in the environment, a detailed mineralogical and geochemical survey of metallurgical slags and smelted ore minerals was undertaken from six different sites through the Pecora Valley: Poggio Butelli (Etrusco-Roman iron slags); Sata Creek, Arialla, Marsiliana, Forra and Cascata sites (all Medieval base metals slags). The As content of Etrusco-Roman slags is relatively low (few tens of ppm), whereas Medieval slags show variable, but higher amounts of base metals (±Ag) (ranging from tens to tens of thousands ppm) and As (up to 267 ppm, with average contents of about 40 ppm). Arsenic is mostly partitioned in sulfides disseminated through the glassy groundmass rather than in solid solution with the glassy matrix. Remnants of the ore used for base metal and Ag smelting during the Middle Ages had the highest As contents (up to about 1000 ppm).  相似文献   
175.
Whole-rock Nd and Sr isotopic compositions of the mafic-ultramafic complex near Finero demonstrate that the magma was derived from a depleted, perhaps MORB-type mantle reservoir. The Sm-Nd data for the Amphibole Peridotite unit can be interpreted as an isochron with an apparent age of 533 ± 20 Ma, which is consistent with a 207Pb/206Pb evaporation age of 549 ± 12 Ma of a single zircon grain from the Internal Gabbro unit. However, the interpretation of these apparent ages remains open to question. We therefore retain the alternative hypotheses that the intrusion occurred either about 533 or 270 Ma ago, the latter being the most likely age of emplacement of the much larger magma body near Balmuccia (Val Sesia). The implication of the older emplacement age (if correct) would be that the igneous complex may be related to the numerous amphibolite units, which are intercalated with the metapelites of the overlying Kinzigite Formation, and together with them may constitute an accretionary complex. In this case, the mafic-ultramafic complex itself might also be part of such an accretionary complex (as has been proposed for the Balmuccia peridotite).

Internal Sm-Nd isochrons involving grt, cpx, plag and amph from the Internal Gabbro unit yield concordant ages of 231 ± 23, 226 ± 7, 223 ± 10, 214 ± 17, and 203 ± 13 Ma. These results confirm published evidence for a separate, regional heating event about 215 ± 15 Ma ago.

Initial Nd(533) values average +6.3 ± 0.4 for six samples of the Amphibole Peridotite unit and +6.0 ± 1.2 for ten samples of the External Gabbro unit. 87Sr/86Sr ratios require little or no age correction and range from 0.7026 to 0.7047 (with two outliers at 0.7053 and 0.7071). Strong correlations between 87Sr/86Sr and K2O and weaker correlations between initial Nd and K2O imply a comparatively minor (≤ 10%) contamination of the External Gabbro magma by crustal material and a later alteration by a crustal or seawater-derived fluid. These results contrast sharply with the isotopic composition (negative Nd and high 87Sr/86Sr values) of the associated mantle rocks, the Phlogopite Peridotite unit, which has been pervasively metasomatized by crustal fluids. This type of metasomatism and its isotopic signature are never seen in the magmatic complex. This evidence rules out any direct genetic relationship between the igneous complex and the mantle peridotite. The crust-mantle interaction is the opposite of that seen at Balmuccia, where the mantle peridotite is essentially ‘pristine’ and the magmatic body has been extensively contaminated by assimilation of crustal rocks.  相似文献   

176.
40Ar/39 Ar stepwise heating on one hydrothermal anhydrite and two partly hydrothermalized feldspars from a borehole in Vulcano volcano show that the initial trapped Ar does not have a constant isotopic composition. The constant 40Ar/36Ar ratio of the anhydrite, 306±3, is not a well-defined endmember for the two feldspars, which record a variety of fluid compositions. As the system is young (<100 ka), radiogenic Ar is much less than excess Ar.  相似文献   
177.
The central Campanian Plain is dominated by the structural depression of Acerra whose origin is tectonic, but may have been enlarged and further depressed after the eruption of the Campanian Ignimbrite (42-25 ka). The deposits of the Campanian Ignimbrite are possibly the results of multiple eruptions with huge pyroclastic deposits that covered all the Campanian Plain.The more recent activity of Vesuvius, Campi Flegrei and Procida occurred on the borders of Acerra depression and resulted from a reactivation of regional faults after the Campanian Ignimbrite cycle. The activity of Vesuvius produced the building of a stratovolcano mostly by effusive and plinian explosive eruptions. The Campi Flegrei area, on the contrary, was dominated by the eruption of the Neapolitan Yellow Tuff at 12 ka that produced a caldera collapse of the Gulf of Pozzuoli. The caldera formation controlled the emplacement of the recent activity of Campi Flegrei and the new volcanoes were formed only within the caldera or along its rim.  相似文献   
178.
The successful synthesis of nanoparticles of Fe-bearing kuramite, (Cu,Fe)3SnS4, is reported in this study. Nanocrystalline powders were obtained through a mild, environmentally friendly and scalable solvothermal approach, in a single run. The sample was the object of a multidisciplinary investigation, including X-ray diffraction and absorption, scanning electron microscopy and microanalysis, electron paramagnetic resonance, diffuse reflectance and Mössbauer spectroscopy as well as SQUID magnetometry. The nanoparticles consist of pure Fe-bearing kuramite, exhibiting tetragonal structure. The valence state of the metal cations was assessed to be Cu+, Sn4+ and Fe3+. The material presents a band gap value of 1.6 eV, which is fully compatible with solar cell applications. The uptake of Fe by nanokuramite opens a compositional field where the physical properties can be tuned. We thus foster the application of Fe-bearing nanokuramite for photovoltaics and energy storage purposes.  相似文献   
179.
The crystal chemistry of a ferroaxinite from Colebrook Hill, Rosebery district, Tasmania, Australia, was investigated by electron microprobe analysis in wavelength-dispersive mode, inductively coupled plasma–atomic emission spectroscopy (ICP–AES), 57Fe Mössbauer spectroscopy and single-crystal neutron diffraction at 293 K. The chemical formula obtained on the basis of the ICP–AES data is the following: \( ^{X1,X2} {\text{Ca}}_{4.03} \,^{Y} \left( {{\text{Mn}}_{0.42} {\text{Mg}}_{0.23} {\text{Fe}}^{2 + }_{1.39} } \right)_{\varSigma 2.04} \,^{Z1,Z2} \left( {{\text{Fe}}^{3 + }_{0.15} {\text{Al}}_{3.55} {\text{Ti}}_{0.12} } \right)_{\varSigma 3.82} \,^{T1,T2,T3,T4} \left( {{\text{Ti}}_{0.03} {\text{Si}}_{7.97} } \right)_{\varSigma 8} \,^{T5} {\text{B}}_{1.96} {\text{O}}_{30} \left( {\text{OH}} \right)_{2.18} \). The 57Fe Mössbauer spectrum shows unambiguously the occurrence of Fe2+ and Fe3+ in octahedral coordination only, with Fe2+/Fe3+ = 9:1. The neutron structure refinement provides a structure model in general agreement with the previous experimental findings: the tetrahedral T1, T2, T3 and T4 sites are fully occupied by Si, whereas the T5 site is fully occupied by B, with no evidence of Si at the T5, or Al or Fe3+ at the T1T5 sites. The structural and chemical data of this study suggest that the amount of B in ferroaxinite is that expected from the ideal stoichiometry: 2 a.p.f.u. (for 32 O). The atomic distribution among the X1, X2, Y, Z1 and Z2 sites obtained by neutron structure refinement is in good agreement with that based on the ICP–AES data. For the first time, an unambiguous localization of the H site is obtained, which forms a hydroxyl group with the oxygen atom at the O16 site as donor. The H-bonding scheme in axinite structure is now fully described: the O16H distance (corrected for riding motion effect) is 0.991(1) Å and an asymmetric bifurcated bonding configuration occurs, with O5 and O13 as acceptors [i.e. with O16···O5 = 3.096(1) Å, H···O5 = 2.450(1) Å and O16H···O5 = 123.9(1)°; O16···O13 = 2.777(1) Å, H···O13 = 1.914(1) Å and O16H···O13 = 146.9(1)°].  相似文献   
180.
The crystal structure and chemical composition of a crystal of (Mg14?x Cr x )(Si5?x Cr x )O24 (x ≈ 0.30) anhydrous Phase B (Anh-B) synthesized in the model system MgCr2O4–Mg2SiO4 at 12 GPa and 1600 °C have been investigated. The compound was found to be orthorhombic, space group Pmcb, with lattice parameters a = 5.900(1), b = 14.218(2), c = 10.029(2) Å, V = 841.3(2) Å3 and Z = 2. The structure was refined to R 1 = 0.065 using 1492 independent reflections. Chromium was found to substitute for both Mg at the M3 site (with a mean bond distance of 2.145 Å) and Si at the octahedral Si1 site (mean bond distance: 1.856 Å), according to the reaction Mg2+ + Si4+ = 2Cr3+. Such substitutions cause a reduction in the volume of the M3 site and an increase in the volume of the Si-dominant octahedron with respect to the values typically observed for pure Anh-B and Fe2+-bearing Anh-B. Taking into account that Cr3+ is not expected to be Jahn–Teller active, it appears that both the Cr3+–for–Mg and Cr3+–for–Si substitutions in the Anh-B structure decrease the distortion of the octahedra. Electron microprobe analysis gave the Mg13.66(8)Si4.70(6)Cr0.62(4)O24 stoichiometry for the studied phase. The successful synthesis of this phase provides new information for the possible mineral assemblages occurring in the Earth’s deep upper mantle and shed new light on the so-called X discontinuity that has been observed at 275–345 km depth in several subcontinental and subduction zone environments.  相似文献   
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