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221.
Abstract In this paper, a summary of the tectonic history of the Mirdita ophiolitic nappe, northern Albania, is proposed by geological and structural data. The Mirdita ophiolitic nappe includes a subophiolite mélange, the Rubik complex, overlain by two ophiolite units, referred to as the Western and Eastern units. Its history started in the Early Triassic with a rifting stage followed by a Middle to Late Triassic oceanic opening between the Adria and Eurasia continental margins. Subsequently, in Early Jurassic time, the oceanic basin was affected by convergence with the development of a subduction zone. The existence of this subduction zone is provided by the occurrence of the supra‐subduction‐zone‐related magmatic sequences found in both the Western and Eastern units of the Mirdita ophiolitic nappe. During the Middle Jurassic, continuous convergence resulted in the obduction of the oceanic lithosphere, in two different stages – the intraoceanic and marginal stages. The intraoceanic stage is characterized by the westward thrusting of a young and still hot section of oceanic lithosphere leading to the development of a metamorphic sole. In the Late Jurassic, the marginal stage developed by the emplacement of the ophiolitic nappe onto the continental margin. During this second stage, the emplacement of the ophiolites resulted in the development of the Rubik complex. In the Early Cretaceous, the final emplacement of the ophiolites was followed by the unconformable sedimentation of the Barremian–Senonian platform carbonate. From the Late Cretaceous to the Middle Miocene, the Mirdita ophiolitic nappe was translated westward during the progressive migration of the deformation front toward the Adria Plate. In the Middle to Late Miocene, a thinning of the whole nappe pile was achieved by extensional tectonics, while the compression was still active in the westernmost areas of the Adria Plate. On the whole, the Miocene deformations resulted in the uplift and exposition of the Mirdita ophiolites as observed today.  相似文献   
222.
The Gole Larghe Fault is an exhumed paleoseismic fault crosscutting the Adamello tonalites (Italian Southern Alps). Ambient conditions of faulting were 9–11 km in depth and 250–300 °C. In the study area the fault accommodates 1100 m of dextral strike-slip over a fault thickness of 550 m. Displacement is partitioned into three hierarchically different sets of discrete subparallel cataclastic horizons (faults1–2–3). Fault displacement is in the range of few centimeters (faults3) to a maximum of a few tens of meters in major faults1. Faults1–2 nucleated on pre-existing joints, whereas faults3 are newly generated fractures produced during slip along faults1–2. Each fault within the Gole Larghe Fault records the same evolution with development of indurated cataclasites precursory to pseudotachylyte production. Pseudotachylytes are usually generated at the host rock/cataclasite boundary and within cataclasites the mean clast size decreases getting closer to pseudotachylyte fault veins. Pseudotachylytes and cataclasites have a similar chemical composition which is enriched in Loss On Ignition, K, Rb, Ba, U and Fe3+ compared to host rock.We envision two models for the evolution of the Gole Larghe Fault. In both models synkinematic fluid–rock interaction along a fault causes fault hardening by precipitation of abundant K-feldspar+epidote (and minor chlorite) in the cataclasite matrix conducive to final production of pseudotachylyte. In the first model, induration occurs progressively by differential precipitation related to fabric evolution in cataclasites. In the second model, induration occurs abruptly dependent on the development of full connectivity within the fault network and to fluid reservoir. Whatever the model, the Gole Larghe Fault represents a strong fault, where hardening processes resulted in a low displacement/fault thickness ratio and contrast with many mature weak faults where localized repeated seismic slip along the same weak horizons yields high displacement/fault thickness ratios.  相似文献   
223.
224.
Interaction of heavy metals with clay minerals can dominate solid-solution reactions in soil, controlling the fate of the metals in the environment. In this study we used powdered and polarized extended X-ray absorption fine structure (EXAFS) spectroscopy and X-ray absorption near edge spectroscopy (XANES) to investigate Cu sorbed on Llano vermiculite and compare the results to reported Cu sorption mechanism on Wyoming (WY) smectite and reduced South African (SA) vermiculite. Analysis of the Cu K-edge spectra revealed that Cu sorbed on Llano vermiculite at high ionic strength (I) has the greatest degree of covalent bond character, followed by Cu sorbed on montmorillonite at high I, and Cu sorbed on reduced SA vermiculite at high I. Cu sorbed on clay minerals at low I has the least covalent character. EXAFS data from Cu sorbed Ca- and K-equilibrated Llano vermiculites showed the presence of a second-shell Al, Si, or Mg backscatterer at 3.02 Å. This distance is consistent with Cu sorbing via a corner-sharing monodentate or bidentate bond. Polarized XANES and EXAFS results revealed that the angle between the Cu atom and the mineral sorption sites is 68° with respect to the [001] direction. From the bond angle and the persistence of the second-shell backscatterer when the interlayer is collapsed (K-equilibration), we conclude that Cu adsorption on the Llano vermiculite is not occurring in the interlayer but rather Cu is adsorbing onto the edges of the vermiculite. Results from this research provide evidence that Cu forms inner-sphere and outer-sphere complexes on clay minerals, and does not form the vast multinuclear surface precipitates that have been observed for Co, Zn, and Ni.  相似文献   
225.
Major- and trace-element contents and Sr–Nd isotope ratios were determined in albitite, albitized and unaltered late-Variscan granitoid samples from the world-class Na-feldspar deposits of central Sardinia, Italy. The albite deposit of high economic grade has geological, textural, and chemical features typical of metasomatic alteration affecting the host granitoids. Albitization, locally accompanied by chloritization and epidotization, was characterized by strong leaching of Mg, Fe, K, and geochemically similar trace elements, and by a significant increase of Na. Ca, and P were moderately leached in the most metasomatized rocks. Other major (Si, Ti, Ca) and trace elements (U, Th, Y, and Zr), along with light (LREE) and middle (MREE) rare-earth elements, behaved essentially immobile at the deposit scale. The Nd-isotope ratios (0.512098 to 0.512248) do not provide information on the emplacement age of the unaltered late-Variscan granitoids. On the other hand, their Sr-isotope ratios fit an errorchron of 274±29 Ma (1σ error), in fair agreement with all published ages of Sardinian Variscan granitoids. The very low Rb content of albitized rocks precludes application of the Rb–Sr radiometric system to determine the age of albitization. The Sm–Nd system is not applicable either, because the 143Nd/144Nd ratios of albitized rocks and unaltered granitoids overlap. The overlap confirms that Sm and Nd were substantially immobile during albitization. On the other hand, the measured 87Sr/86Sr ratios of the albitized rocks are appreciably lower than those of the unaltered host granitoids, whereas, their initial Sr-isotope ratios are higher. This seems to suggest that a) albitization was induced by non-magmatic fluids rich in radiogenic Sr, and b) albitization occurred shortly after the granitoid emplacement. This conclusion is supported by Nd isotopes, because unaltered granitoids and albitites fit the same reference isochron at 274 Ma. The fluids acquired radiogenic Sr by circulation through the Lower Paleozoic metasedimentary basement. Specifically, it is estimated that Sr supplied by the non-carbonatic basement represents about 22 wt% of total Sr in albitite.  相似文献   
226.
The marine sector surrounding Panarea Island (Aeolian Islands, South Italy) is affected by widespread submarine emissions of CO2 -rich gases and thermal water discharges which have been known since the Roman Age. On November 3rd, 2002 an anomalous degassing event affected the area, probably in response to a submarine explosion. The concentrations of minor reactive gases (CO, CH4 and H2) of samples collected in November and December, 2002 show drastic compositional changes when compared to previous samples collected from the same area in the 1980s. In particular the samples collected after the November 3rd phenomenon display relative increases in H2 and CO and a strong decrease in the CH4 contents, while other gas species show no significant change. The interaction of the original gas with seawater explains the variable contents of CO2, H2S, N2, Ar and He which characterize the different samples, but cannot explain the large variations of CO, CH4 and H2 which are instead compatible with changes in the redox, temperature and pressure conditions of the system. Two models, both implying an increasing input of magmatic fluids are compatible with the observed variations of minor reactive species. In the first one, the input of magmatic fluids drives the hydrothermal system towards atypical (more oxidizing) redox conditions, slowly pressurizing the system up to a critical state. In the second one, the hydrothermal system is flashed by the rising high-T volcanic fluid, suddenly released by a magmatic body at depth. The two models have different implications for volcanic surveillance and risk assessment: In the first case, the November 3rd event may represent both the culmination of a relatively slow process which caused the overpressurization of the hydrothermal system and the beginning of a new phase of quiescence. The possible evolution of the second model is unforeseeable because it is mainly related to the thermal, baric and compositional state of the deep magmatic system that is poorly known.  相似文献   
227.
意大利埃特纳火山的三维速度结构与地震活动性   总被引:2,自引:2,他引:0  
本文的研究工作,得到了埃特纳火山下面的一组新的三维速度模型。作者们用1980年以来地方性地震在永久和临时地震台网在4个或更多台记录到的1249次地震的P和S波,被选来作走时反演。选择了几种判别标志与参数化办法以显示其类似的基本特征。表明在火山的东南象限在浅层,有P波的高速分怖,它同布格重力高异常有密切关系。在该区存在低的Vp/Vs比值;沿着中央火山管道,分布有高速P波和高的Vp/Vs比值;建议该处存在有稠密的侵入的岩浆体,延伸到20千米左右的深度,该区附近有低速的P波速度。对震源的重新定位也显示出向外倾斜的易碎区,与中央火山管道延伸出一段P波高速异常区,位于中央火山口的附近。沿着中央火山口附近,有P波的低速区,它同次生的火山锥的分布有关,与部份熔融的深部岩浆库有联系。  相似文献   
228.
A two-dimensional analytical solution for stress, strain rate, and velocity is obtained for parallel-sided and wedge-shaped blocks with generalized viscous rheology (linearly viscous and power-law) deforming in plane strain. The main assumptions used in the derivation of the solution are that the material is incompressible, the longitudinal gradient in shear stress is much less than the vertical gradient of vertical normal stress, and the longitudinal strain rate varies linearly in the horizontal direction. Velocity boundary conditions are specified at the top of the block, and shear stress boundary conditions at the base of the block. In the one-dimensional case (where stress and strain rate do not vary in the longitudinal direction), the solution reduces to a well-known solution for the deformation of parallel-sided ice sheets [Nye, J. F. (1957) The distribution of stress and velocity in glaciers and ice sheets. Proceedings of the Royal Society of London A-239, 113–133]. The stress equilibrium for tapered wedges [Platt, J. P. (1986) Dynamics of orogenic wedges and the uplift of high-pressure metamorphic rocks. Geological Society of America Bulletin 97, 1037–1053] is a special case of the present stress solution. Implementation of the solution requires the subdivision of the wedge into vertical segments, and yields the tectonic normal and shear stresses that must be applied to the rear of a block with specified rheology in order to maintain a given longitudinal strain rate. The solution makes it possible to model deformation patterns analytically with longitudinally varying strain rate (including coeval compression and extension) and with vertical components of velocity reflecting the effects of underplating.  相似文献   
229.
Natural processes encountered in mining, hydrogeologic, environmental, etc. applications usually are poorly known because of scarcity of data over the area of interest. Therefore, stochastic estimation techniques are the tool of choice for a careful accounting of the heterogeneity and uncertainty involved. Within such a framework, a better utilization of all available data concerning the process of interest and all other natural processes related to it, is of primary importance. Because many natural processes show complicated spatial trends, the hypothesis of spatial homogeneity cannot be invoked always, and the more general theory of intrinsic spatial random fields should be employed. Efficient use of secondary information in terms of the intrinsic model requires that suitable permissibility criteria for the generalized covariances and cross-covariances are satisfied. A set of permissibility criteria are presented for the situation of two intrinsic random fields. These criteria are more general and comprehensive than the ones currently available in the geostatistical literature. A constrained least-square technique is implemented for the inference of the generalized covariance and cross-covariance parameters, and a synthetic example is used to illustrate the methodology. The numerical results show that the use of secondary information can lead to significant reductions in the estimation errors.  相似文献   
230.
High rates of coastal land loss in Louisiana have prompted efforts to maintain or restore coastal wetland habitats, and structural management of marsh hydrology is one of a number of approaches that has been adopted. The aim of this study was to determine the effect of hydrologic management measures on marsh-surface sediment deposition in the Mississippi deltaic plain. Four impoundments, ranging in size from 50 ha to 177 ha and similarly sized control sites were included in the study. At each site, marsh-surface sediment traps were collected approximately biweekly for 3.5 yr to measure changes in sediment deposition. There was no significant difference in sediment deposition between any of the impoundment and control sites during the premanagement period. The results show no significant difference in marsh-surface sediment deposition between management year 1992–1993 and management year 1994–1995, but management year 1993–1994 had significantly lower sediment deposition than either the first or the last year of the study. Management year 1992–1993 showed the highest sediment deposition when it was assessed across all basins, areas, and sites, and this high rate of deposition is accounted for by the impact of Hurricane Andrew. For all management years there were significant differences between impoundment and control sites, with control sites showing higher rates of marsh surface sediment deposition than impoundments. No clear pattern was identified concerning the influence of various types of hydrologic management on rates of sediment deposition. This reduction in sediment deposition indicated that the areas under management in this study are receiving insufficient inorganic sediment deposition to keep pace with sea-level rise.  相似文献   
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