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111.
In the Erlenbach stream, a pre‐alpine steep channel in Switzerland, sediment transport has been monitored for more than 25 years. Near the confluence with the main valley river, stream flow is monitored and sediment is collected in a retention basin with a capacity of about 2000 m3. The basin is surveyed at regular intervals and after large flood events. In addition, sediment transport has been continuously monitored with piezoelectric bedload impact and geophone sensors since 1986. In 2008–2009, the measuring system in the Erlenbach stream was enhanced by installing an automatic system to obtain bedload samples. Movable metal baskets are mounted on a rail at the downstream wall of the large check dam above the retention basin, and they can be moved automatically into the flow to take bedload transport samples. The wire mesh of the baskets has a spacing of 10 mm to sample all sediment particles coarser than this size (which is about the limiting grain size detected by the geophones). The upgraded measuring system permits to obtain bedload samples over short sampling periods and to measure the grain size distribution of the transported material and its variation over time and with discharge. The analysis of calibration relationships for the geophone measuring system confirms findings from very similar measurements which were performed until 1999 with piezoelectric bedload impact sensors; there is a linear relationship between impulse counts and bedload mass passing over the sensors. Findings from flume experiments are used to discuss the most important factors which affect the calibration of the geophone signal. The bedload transport rates as measured by the moving baskets are among the highest measured in natural streams, with values of the order of several kilograms per meter per second. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
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Rivers are important sources of freshwater and nutrients for the Mediterranean and Black Sea. We present a reconstruction of the spatial and temporal variability of these inputs since the early 1960s, based on a review of available data on water discharge, nutrient concentrations and climatic parameters. Our compilation indicates that Mediterranean rivers suffer from a significant reduction in freshwater discharge, contrary to rivers of the Black Sea, which do not have clear discharge trends. We estimate this reduction to be at least about 20% between 1960 and 2000. It mainly reflects recent climate change, and dam construction may have reduced discharge even further. A similar decrease can also be expected for the fluxes of dissolved silica (Si), strongly controlled by water discharge and potentially reduced by river damming as well. This contrasts with the fluxes of nitrogen (N) and phosphorus (P) in Mediterranean and Black Sea rivers, which were strongly enhanced by anthropogenic sources. Their total inputs to the Mediterranean Sea could have increased by a factor of >5. While N still remained at elevated levels in 2000, P only increased up to the 1980–1990s, and then rapidly dropped down to about the initial values of the 1960s. With respect to the marine primary production that can be supported by the riverine nutrient inputs, Mediterranean and the Black Sea rivers were mostly phosphorus limited during the study period. Their anthropogenic nutrient enrichment could only have had a fertilizing effect before the general decline of the P loads. When also considering Si as a limiting element, which is the case for siliceous primary producers such as diatoms, silica limitation may have become a widespread phenomenon in the Mediterranean rivers since the early 1980s. For the Black Sea rivers, this already started the late 1960s. Gross primary production sustained by rivers (PPR) represents only less than 2% of the gross production (PP) in the Mediterranean, and less than 5% in the Black Sea. Possible ecological impacts of the changing river inputs should therefore be visible only in productive coastal areas, such as the Gulf of Lions, where PPR can reach more than two thirds of PP. Reported ecosystem changes both in the Adriatic Sea and the Black Sea are concomitant with major changes in the reconstructed river inputs. Further work combining modelling and data collection is needed to test whether this may also have been the case for coastal ecosystems at other places in the Mediterranean and Black Sea.  相似文献   
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Fluxes of the heavy metals chromium (Cr), cobalt (Co), nickel (Ni), copper (Cu), lead (Pb), cadmium (Cd) and zinc (Zn) delivered by rivers to the Gulf of Lion (NW Mediterranean Sea) were estimated over a three year study of the River Rhone and its smaller tributaries. Most of the particulate metal fluxes (80–90%) delivered by these rivers occurred within a very short period of time (less than 12%), a typical trend for the Mediterranean environment, where highly contrasting hydrological regimes were observed over the year. Temporal and spatial variations in the fluxes of these particulate metals were driven by the fluxes in both water discharge and suspended particulate matter load. On the shelf, these particulate metal fluxes, largely arising from the Rhone watershed, were two to ten times more important than those resulting from atmospheric deposition. Co, Cr and Ni in the rivers and on the shelf surface sediments were mainly natural and associated with the finest particles. Cd and Phosphorus appeared to be associated with the silt fraction and to be enriched in the prodelta areas. Pb, Zn and Cu were more closely associated with the organic matter content and also showed enrichment in the organic rich prodeltaic sediments. Anthropogenic influences diminished offshore, except for Pb and Zn which could be supplied from the atmosphere by man-made aerosols. Although most of the metals tended to be enriched in the prodelta areas, these did not constitute a permanent sink due to resuspension processes affecting these shallow depths. A resuspension experiment conducted on sediment cores from the Rhone prodelta demonstrated that metal deposited on the surface layer, especially those associated with the organic matter, may be resuspended; this should be taken into account for a complete understanding of the biogeochemical cycle of these metals.  相似文献   
115.
Global river discharge and water temperature under climate change   总被引:1,自引:0,他引:1  
Climate change will affect hydrologic and thermal regimes of rivers, having a direct impact on freshwater ecosystems and human water use. Here we assess the impact of climate change on global river flows and river water temperatures, and identify regions that might become more critical for freshwater ecosystems and water use sectors. We used a global physically based hydrological-water temperature modelling framework forced with an ensemble of bias-corrected general circulation model (GCM) output for both the SRES A2 and B1 emissions scenario. This resulted in global projections of daily river discharge and water temperature under future climate. Our results show an increase in the seasonality of river discharge (both increase in high flow and decrease in low flow) for about one-third of the global land surface area for 2071–2100 relative to 1971–2000. Global mean and high (95th percentile) river water temperatures are projected to increase on average by 0.8–1.6 (1.0–2.2) °C for the SRES B1–A2 scenario for 2071–2100 relative to 1971–2000. The largest water temperature increases are projected for the United States, Europe, eastern China, and parts of southern Africa and Australia. In these regions, the sensitivities are exacerbated by projected decreases in low flows (resulting in a reduced thermal capacity). For strongly seasonal rivers with highest water temperatures during the low flow period, up to 26% of the increases in high (95th percentile) water temperature can be attributed indirectly to low flow changes, and the largest fraction is attributable directly to increased atmospheric energy input. A combination of large increases in river temperature and decreases in low flows are projected for the southeastern United States, Europe, eastern China, southern Africa and southern Australia. These regions could potentially be affected by increased deterioration of water quality and freshwater habitats, and reduced water available for human uses such as thermoelectric power and drinking water production.  相似文献   
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The boron isotopic composition of zoned tourmaline in two metasediments from the island of Syros, determined by secondary-ion mass spectrometry (SIMS), reflects the sedimentary and metamorphic record of the rocks. Tourmaline from a silicate-bearing marble contains small (≤20 μm) detrital cores with highly variable δ 11B values (−10.7 to +3.6‰), pointing to a heterogeneous protolith derived from multiple sources. The sedimentary B isotopic record survived the entire metamorphic cycle with peak temperatures of ∼500°C. Prograde to peak metamorphic rims are homogeneous and similar among all analysed grains (δ 11B ≈ +0.9‰). The varying δ 11B values of detrital cores in the siliceous marble demonstrate that in situ B isotope analysis of tourmaline by SIMS is a potentially powerful tool for provenance studies not only in sediments but also in metasediments. A meta-tuffitic blueschist bears abundant tourmaline with dravitic cores of detrital or authigenic origin (δ 11B ≈ −3.3‰), and prograde to peak metamorphic overgrowth zones (−1.6‰). Fe-rich rims, formed during influx of B-bearing fluids under retrograde conditions, show strongly increasing δ 11B values (up to +7.7‰) towards the margins of the grains. The δ 11B values of metamorphic tourmaline from Syros, formed in mixed terrigenous–marine sediments, reflect the B signal blended from these two different sources, and was probably not altered by dehydration during subduction.  相似文献   
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The measurement of isotopic ratios provides a privileged insight both into nucleosynthesis and into the mechanisms operating in stellar envelopes, such as gravitational settling. In this article, we give a few examples of how isotopic ratios can be determined from high‐resolution, high‐quality stellar spectra. We consider examples of the lightest elements, H and He, for which the isotopic shifts are very large and easily measurable, and examples of heavier elements for which the determination of isotopic ratios is more difficult. The presence of 6Li in the stellar atmospheres causes a subtle extra depression in the red wing of the 7Li 670.7 nm doublet which can only be detected in spectra of the highest quality. But even with the best spectra, the derived 6Li abundance can only be as good as the synthetic spectra used for their interpretation. It is now known that 3D non‐LTE modelling of the lithium spectral line profiles is necessary to account properly for the intrinsic line asymmetry, which is produced by convective flows in the atmospheres of cool stars, and can mimic the presence of 6Li. We also discuss briefly the case of the carbon isotopic ratio in metal‐poor stars, and provide a new determination of the nickel isotopic ratios in the solar atmosphere. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
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