Intermediate Alkali-Alumino-silicate Aqueous Solutions Released by Deeply Subducted Continental Crust: Fluid Evolution in UHP OH-rich Topaz-Kyanite Quartzites from Donghai (Sulu, China)   总被引：3，自引：0，他引：3  

Frezzotti  Maria Luce; Ferrando  Simona; Dallai  Luigi; Compagnoni  Roberto 《Journal of Petrology》2007,48(6):1219-1241

Minerals, fluid inclusions and stable isotopes have been studiedin ultrahigh-pressure (UHP) OH-rich topaz–kyanite quartzitesfrom Hushan (west of Dongai), in southern Sulu (China). Thequartzites underwent a metamorphic evolution characterized bya peak stage (3·5 GPa and 730–820°C) with theanhydrous assemblage coesite + kyanite I, followed by an earlynear-isothermal decompression stage (2·9 GPa and 705–780°C)with growth of kyanite II, muscovite, and OH-rich topaz, andby decompression-cooling stages, represented by paragonite (1·9GPa and 700–780°C) and pyrophyllite (0·3 GPaand 400°C) on kyanite (I and II) and OH-rich topaz, respectively.These rocks may exhibit unusually low ¹⁸O and D values acquiredbefore undergoing UHP metamorphism. Five distinct fluid generationsare recognized. Type I: concentrated peak solutions rich inSi, Al, and alkalis, present within multiphase inclusions inkyanite I. Type II: CaCl₂-rich brines present during the growthof early retrograde OH-rich topaz. Type III, IV, and V: lateaqueous fluids of variable salinity, and rare CO₂ present duringamphibolite- and late greenschist-facies conditions. A numberof conclusions may be drawn from these relationships that havean effect on fluid evolution in deeply subducted continentalrocks. (1) At a pressure of about 3·5 GPa alkali–alumino-silicateaqueous solutions, with compositions intermediate between H₂Ofluid and melt (H₂O > 25 and 50 wt %) evolved from quartzites,probably generated by dehydration reactions. (2) During earlydecompression stages, at the transition from UHP to high-pressure(2·9 GPa) conditions, brines of external origin withhigher water contents (82 wt % H₂O) initiated the growth ofOH-rich topaz and muscovite. (3) The subsequent decompression,at P <2 GPa, was defined by a limited circulation of NaClaqueous fluids, and CO₂ infiltration. Overall, fluid inclusionsand stable isotopes highlight a metamorphic fluid–rockinteraction characterized by internally derived intermediateaqueous solutions at UHP, followed by infiltration of Cl-richbrines with higher water activities. KEY WORDS: ultrahigh-pressure metamorphism; OH-rich topaz; fluid inclusions; stable isotopes; supercritical liquids  相似文献   

An open dataset for landslides triggered by the 2016 Mw 7.8 Kaikōura earthquake,New Zealand     

Tanyaş  Hakan  Görüm  Tolga  Fadel  Islam  Yıldırım  Cengiz  Lombardo  Luigi 《Landslides》2022,19(6):1405-1420

On November 14, 2016, the northeastern South Island of New Zealand was hit by the magnitude Mw 7.8 Kaikōura earthquake, which is characterized by the most complex rupturing mechanism ever recorded. The widespread landslides triggered by the earthquake make this event a great case study to revisit our current knowledge of earthquake-triggered landslides in terms of factors controlling the spatial distribution of landslides and the rapid assessment of geographic areas affected by widespread landsliding. Although the spatial and size distributions of landslides have already been investigated in the literature, a polygon-based co-seismic landslide inventory with landslide size information is still not available as of June 2021. To address this issue and leverage this large landslide event, we mapped 14,233 landslides over a total area of approximately 14,000 km². We also identified 101 landslide dams and shared them all via an open-access repository. We examined the spatial distribution of co-seismic landslides in relation to lithologic units and seismic and morphometric characteristics. We analyzed the size statistics of these landslides in a comparative manner, by using the five largest co-seismic landslide inventories ever mapped (i.e., Chi-Chi, Denali, Wenchuan, Haiti, and Gorkha). We compared our inventory with respect to these five ones to answer the question of whether the landslides triggered by the 2016 Kaikōura earthquake are less numerous and/or share size characteristics similar to those of other strong co-seismic landslide events. Our findings show that the spatial distribution of the Kaikōura landslide event is not significantly different from those belonging to other extreme landslide events, but the average landslide size generated by the Kaikōura earthquake is relatively larger compared to some other large earthquakes (i.e., Wenchuan and Gorkha).

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Chemical Analysis of Iron Meteorites Using a Hand‐Held X‐Ray Fluorescence Spectrometer          下载免费PDF全文

Maurizio Gemelli  Massimo D'Orazio  Luigi Folco 《Geostandards and Geoanalytical Research》2015,39(1):55-69

We evaluate the performance of a hand‐held XRF (HHXRF) spectrometer for the bulk analysis of iron meteorites. Analytical precision and accuracy were tested on metal alloy certified reference materials and iron meteorites of known chemical composition. With minimal sample preparation (i.e., flat or roughly polished surfaces) HHXRF allowed the precise and accurate determination of most elements heavier than Mg, with concentrations > 0.01% m/m in metal alloy CRMs, and of major elements Fe and Ni and minor elements Co, P and S (generally ranging from 0.1 to 1% m/m) in iron meteorites. In addition, multiple HHXRF spot analyses could be used to determine the bulk chemical composition of iron meteorites, which are often characterised by sulfide and phosphide accessory minerals. In particular, it was possible to estimate the P and S bulk contents, which are of critical importance for the petrogenesis and evolution of Fe‐Ni‐rich liquids and iron meteorites. This study thus validates HHXRF as a valuable tool for use in meteoritics, allowing the rapid, non‐destructive (a) identification of the extraterrestrial origin of metallic objects (i.e., archaeological artefacts); (b) preliminary chemical classification of iron meteorites; (c) identification of mislabelled/unlabelled specimens in museums and private collections and (d) bulk analysis of iron meteorites.  相似文献   

Tectonic role of ophiolite-bearing terranes in the development of the Southern Apennines orogenic belt     

Carmelo Monaco  Luigi Tortorici 《地学学报》1995,7(2):153-160

New data on ophiolite-bearing terranes of the Liguride Complex, together with some information on the terranes of the Sicilide Complex, result in a better understanding of the role and tectonic significance of these units in the construction of the Southern Apennines orogenic belt. The Liguride Complex is composed of two main tectonic units overlain by a thick turbiditic sequence of Late Oligocene-Middle Miocene age. The uppermost one (Frido Unit) is a polydeformed and polymetamorphosed sequence, composed of two tectonic subunits of shales and calc-schists, respectively, containing blocks of ophiolite, garnet gneiss, amphibolites and granitoids. This unit is thrust over the un-metamorphosed terranes (Calabro–Lucano Flysch Unit) consisting of a broken formation with blocks of Late Jurassic ophiolite and their sedimentary cover, Cretaceous-Eocene pelagic sediments and Late Oligocene volcaniclastic deposits. The Frido Unit underwent HP/LT metamorphism (P= 8–10 Kb; T= 400–500 °C) resulting in glaucophane and lawsonite assemblages in the ophiolitic rocks and aragonite in the meta-limestones and calc-schists, followed by greenschist fades metamorphism (P= 4 Kb; T= 300–350 °C). From a structural point of view units of the Liguride Complex comprise structures developed at different structural levels, indicating progressive non-coaxial deformation in response to tectonic transport towards the N-NE. The ophiolite-bearing terranes of the Liguride Complex can be considered as a remnant of an accretionary complex in which the Calabro Lucano Flysch Unit represents the toe of the wedge where frontal accretion processes occur and the Frido Unit is a deeper portion. Emplacement of the Frido Unit is explained as being due to formation of a deep duplex structure during the early stage of continental collision processes. The polarity of tectonic transport provides new evidence that the Liguride Complex represents a suture zone between the Apulian and the Calabrian blocks. The age of collision appears to be not older than late Oligocene. The allochtonous terranes of the Liguride and Sicilide Complexes, therefore, represent a complete accretionary wedge which records, first, subduction of the Neotethys ocean beneath the Calabrian (Europe) continental margin and, later, continental collision with the African block.  相似文献   

Effective Hamiltonian for the D'Alembert Planetary Model Near a Spin/Orbit Resonance     

Luca Biasco  Luigi Chierchia 《Celestial Mechanics and Dynamical Astronomy》2002,83(1-4):223-237

The D'Alembert model for the spin/orbit problem in celestial mechanics is considered. Using a Hamiltonian formalism, it is shown that in a small neighborhood of a p:q spin/orbit resonance with (p,q) different from (1,1) and (2,1) the 'effective' D'Alembert Hamiltonian is a completely integrable system with phase space foliated by maximal invariant curves; instead, in a small neighborhood of a p:q spin/orbit resonance with (p,q) equal to (1,1) or (2,1) the 'effective' D'Alembert Hamiltonian has a phase portrait similar to that of the standard pendulum (elliptic and hyperbolic equilibria, separatrices, invariant curves of different homotopy). A fast averaging with respect to the 'mean anomaly' is also performed (by means of Nekhoroshev techniques) showing that, up to exponentially small terms, the resonant D'Alembert Hamiltonian is described by a two-degrees-of-freedom, properly degenerate Hamiltonian having the lowest order terms corresponding to the 'effective' Hamiltonian mentioned above.  相似文献   

Response of the bacterial community to in situ bioremediation of organic-rich sediments   总被引：8，自引：0，他引：8  

Vezzulli L  Pruzzo C  Fabiano M 《Marine pollution bulletin》2004,49(9-10):740-751

A field trial experiment was carried out to assess the potential of bioremediation for mobilisation of carbon in organic-rich sediments. Both bioaugmentation (bio-fixed microorganisms) and biostimulation (oxygen release compounds--ORC) protocols have been tested and the response of the bacterial community has been described to assess the baseline for bioremediation potential. Multifactorial ANOVA revealed that bioaugmentation protocol had an effect in stimulate mobilisation processes and significantly enhanced extra-cellular enzymatic activity rates. In contrast biostimulation treatment did not have an effect on mobilisation rates but contributed to enhance bacterial efficiency through a maximization of the bacterial production:enzymatic activity ratio. Average calculation of net mobilised carbon showed that 23% increase of mobilised pool was accounted for bioaugmentation in summer. Although biostimulation accounted for a smaller increase in mobilised carbon (<10%), the use of ORC resulted in an increased mineralisation and net carbon loss via respiration. Based on our results, a conceptual model for application of bioremediation to face the problem of sediment eutrophication is discussed.  相似文献   

Geochemical and O-isotope constraints on the evolution of lithospheric mantle in the Ross Sea rift area (Antarctica)     

Cristina?PerinelliEmail author  Pietro?Armienti  Luigi?Dallai 《Contributions to Mineralogy and Petrology》2006,151(3):245-266

Peridotite xenoliths found in Cenozoic alkali basalts of northern Victoria Land, Antarctica, vary from fertile spinel-lherzolite to harzburgite. They often contain glass-bearing pockets formed after primary pyroxenes and spinel. Few samples are composite and consist of depleted spinel lherzolite crosscut by amphibole veins and/or lherzolite in contact with poikilitic wehrlite. Peridotite xenoliths are characterized by negative Al₂O₃–Mg# and TiO₂–Mg# covariations of clino- and orthopyroxenes, low to intermediate HREE concentrations in clinopyroxene, negative Cr–Al trend in spinel, suggesting variable degrees of partial melting. Metasomatic overprint is evidenced by trace element enrichment in clinopyroxene and sporadic increase of Ti–Fe_tot. Preferential Nb, Zr, Sr enrichments in clinopyroxene associated with high Ti–Fe_tot contents constrain the metasomatic agent to be an alkaline basic melt. In composite xenoliths, clinopyroxene REE contents increase next to the veins suggesting metasomatic diffusion of incompatible element. Oxygen isotope data indicate disequilibrium conditions among clinopyroxene, olivine and orthopyroxene. The highest δ¹⁸O values are observed in minerals of the amphibole-bearing xenolith. The δ¹⁸O_cpx correlations with clinopyroxene modal abundance and geochemical parameters (e.g. Mg# and Cr#) suggest a possible influence of partial melting on oxygen isotope composition. Thermobarometric estimates define a geotherm of 80°C/GPa for the refractory lithosphere of NVL, in a pressure range between 1 and 2.5 GPa. Clinopyroxene microlites of melt pockets provide P–T data close to the anhydrous peridotite solidus and confirm that they originated from heating and decompression during transport in the host magma. All these geothermometric data constrain the mantle potential temperature to values of 1250–1350°C, consistent with the occurrence of mantle decompressional melting in a transtensive tectonic regime for the Ross Sea region.  相似文献   

Global change and relative sea level rise at Venice: what impact in term of flooding     

Laura Carbognin  Pietro Teatini  Alberto Tomasin  Luigi Tosi 《Climate Dynamics》2010,35(6):1039-1047

Relative sea level rise (RSLR) due to climate change and geodynamics represents the main threat for the survival of Venice, emerging today only 90 cm above the Northern Adriatic mean sea level (msl). The 25 cm RSLR occurred over the 20th century, consisting of about 12 cm of land subsidence and 13 cm of sea level rise, has increased the flood frequency by more than seven times with severe damages to the urban heritage. Reasonable forecasts of the RSLR expected to the century end must be investigated to assess the suitability of the Mo.S.E. project planned for the city safeguarding, i.e., the closure of the lagoon inlets by mobile barriers. Here we consider three RSLR scenarios as resulting from the past sea level rise recorded in the Northern Adriatic Sea, the IPCC mid-range A1B scenario, and the expected land subsidence. Available sea level measurements show that more than 5 decades are required to compute a meaningful eustatic trend, due to pseudo-cyclic 7–8 year long fluctuations. The period from 1890 to 2007 is characterized by an average rate of 0.12 ± 0.01 cm/year. We demonstrate that linear regression is the most suitable model to represent the eustatic process over these 117 year. Concerning subsidence, at present Venice is sinking due to natural causes at 0.05 cm/year. The RSLR is expected to range between 17 and 53 cm by 2100, and its repercussions in terms of flooding frequency are associated here to each scenario. In particular, the frequency of tides higher than 110 cm, i.e., the value above which the gates would close the lagoon to the sea, will increase from the nowadays 4 times per year to a range between 20 and 250. These projections provide a large spread of possible conditions concerning the survival of Venice, from a moderate nuisance to an intolerable aggression. Hence, complementary solutions to Mo.S.E. may well be investigated.  相似文献   

Theoretical Derivation of a Peak Particle Velocity–Distance Law for the Prediction of Vibrations from Blasting     

Luigi Sambuelli 《Rock Mechanics and Rock Engineering》2009,42(3):547-556

I would like to suggest a theoretical justification for the mathematical structure of some laws for predicting the maximum particle velocity vibration from blasting operations in the light of some basic notions of elastic and anelastic wave theory. Within this point of view, in dimensionally correct expressions, the terms pertaining to the rock, to the blast and to the seismic wave become evident and recognisable. A law is presented that can be used to forecast the maximum particle velocity on the basis of some blast design and rock parameters. Four tests of the proposed law performed with real data sets seem to confirm fairly well its reliability.  相似文献   

AVES: A high performance computer cluster array for the INTEGRAL satellite scientific data analysis     

Memmo Federici  Bruno Luigi Martino  Pietro Ubertini 《Experimental Astronomy》2012,34(1):105-121

In this paper we describe a new computing system array, designed, built and now used at the Space Astrophysics and Planetary Institute (IAPS) in Rome, Italy, for the INTEGRAL Space Observatory scientific data analysis. This new system has become necessary in order to reduce the processing time of the INTEGRAL data accumulated during the more than 9 years of in-orbit operation. In order to fulfill the scientific data analysis requirements with a moderately limited investment the starting approach has been to use a ??cluster?? array of commercial quad-CPU computers, featuring the extremely large scientific and calibration data archive on line.  相似文献