Mantle and crustal processes in the magmatism of the Campania region: inferences from mineralogy, geochemistry, and Sr–Nd–O isotopes of young hybrid volcanics of the Ischia island (South Italy)     

Massimo D’Antonio  Sonia Tonarini  Ilenia Arienzo  Lucia Civetta  Luigi Dallai  Roberto Moretti  Giovanni Orsi  Mariachiara Andria  Alberto Trecalli 《Contributions to Mineralogy and Petrology》2013,165(6):1173-1194

Ischia, one active volcano of the Phlegraean Volcanic District, prone to very high risk, is dominated by a caldera formed 55 ka BP, followed by resurgence of the collapsed area. Over the past 3 ka, the activity extruded evolved potassic magmas; only a few low-energy explosive events were fed by less evolved magmas. A geochemical and Sr–Nd–O isotope investigation has been performed on minerals and glass from products of three of such eruptions, Molara, Vateliero, and Cava Nocelle (<2.6 ka BP). Data document strong mineralogical, geochemical, and isotopic heterogeneities likely resulting from mingling/mixing processes among mafic and felsic magmas that already fed the Ischia volcanism in the past. Detailed study on the most mafic magma has permitted to investigate its origin. The mantle sector below Ischia underwent subduction processes that modified its pristine chemical, isotopic, and redox conditions by addition of ≤1 % of sediment fluids/melts. Similar processes occurred from Southeast to Northwest along the Apennine compressive margin, with addition of up to 2.5 % of sediment-derived material. This is shown by volcanics with poorly variable, typical δ¹⁸O mantle values, and ⁸⁷Sr/⁸⁶Sr progressively increasing toward typical continental crust values. Multiple partial melting of this modified mantle generated distinct primary magmas that occasionally assimilated continental crust, acquiring more ¹⁸O than ⁸⁷Sr. At Ischia, 7 % of Hercynian granodiorite assimilation produced isotopically distinct, K-basaltic to latitic magmas. A SW–NE regional tectonic structure gave these magmas coming from large depth the opportunity to mingle/mix with felsic magmas stagnating in shallower reservoirs, eventually triggering explosive eruptions.  相似文献   

Characterization of the atmosphere above a site for millimeter wave astronomy     

Francesco Tony Nasir  Franco Buffa  Gian Luigi Deiana 《Experimental Astronomy》2011,29(3):207-225

The Sardinia Radio Telescope (SRT) is a challeging scientific project managed by the National Institute for Astrophysics (INAF), it is being developed at 30 km North of the city of Cagliari, Italy. The goal of the SRT project is to build a general purpose, fully steerable, 64 m diameter radio telescope, capable of operating with high efficiency in the centimeter and millimeter frequency range (0.3–100 GHz). In portions of this frequency range, especially towards the high end, astronomical observations can be heavily deteriorated by non-optimal atmospheric conditions, especially by water vapor content. The water molecule permanent electric dipole in fact, leads to pressure broadened rotational transitions around the 22.23 GHz spectral line. Furthermore, water vapor’s continuum absorption and emission may influence higher frequency observations too. To a lower degree, cloud liquid black body radiation can also affect centimeter and millimeter observations. In addition to this, inhomogeneities in water vapor distributions can cause signal phase errors which introduce a great amount of uncertainty to VLBI mode observations. The Astronomical Observatory of Cagliari (OA-CA) has obtained historical timeseries of radiosonde profiles conducted at the airport of Cagliari. Through the radiosonde measurements and an appropriate radiative transfer model, we have performed a statistical analysis of the SRT site’s atmosphere which accounts for atmospheric opacity at different frequencies, integrated water vapor (IWV), integrated liquid water (ILW) and cloud cover distributions during the year. This will help to investigate in which period of the year astronomical observations at different frequencies should be performed preferably. The results show that, at the SRT site, K-band astronomical observations are possible all year round, the median opacity at 22.23 GHz is 0.10 Np in the winter (Dec-Jan-Feb) and 0.16 Np in the summer (Jun-Jul-Aug). Integrated water vapor during winter months ranges, on average, between 7 and 15 mm. Cloud cover is usually not present for more than 36% of the time during the year. The atmospheric opacity study indicates that observations at higher frequencies (50–100 GHz) may be performed usefully: the median opacity at 100 GHz is usually below or equal to 0.2 Np in the period that ranges from January to April.  相似文献   

Seismic characterization of an abandoned mine site     

Diego Arosio  Laura Longoni  Monica Papini  Luigi Zanzi 《Acta Geophysica》2013,61(3):611-623

The near-surface rock structure that covers an abandoned marl mine nearby the village of Montevecchia (Italy) was investigated through a combination of seismic surveys. The methods selected for these investigations were refraction seismics and multichannel analysis of surface waves (MASW). A sort of transillumination experiment was also attempted. All the methods were successful and gave complementary information. Refraction seismics was used to characterize the upper low velocity layer and the second layer of the near-surface structure. The MASW method was necessary to assess the existence of a velocity inversion revealing the presence of a low velocity layer between the 2nd layer and a 4th high velocity layer covering the upper mine gallery. The transillumination experiment validated the presence of the 4th layer and gave an estimate of the average velocity that represents a lower boundary for the P-wave velocity within this layer. Both the refraction and transillumination data were analysed to derive average estimates of attenuation level and rock quality factor.  相似文献   

The behaviour of vernacular buildings in the 2012 Emilia earthquakes   总被引：2，自引：2，他引：0  

Luigi Sorrentino  Laura Liberatore  Domenico Liberatore  Renato Masiani 《Bulletin of Earthquake Engineering》2014,12(5):2367-2382

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Empirical prediction of the Pitzer’s interaction parameters for cationic Al species with both SiO_2(aq) and CO_2(aq): Implications for the geochemical modelling of very saline solutions     

Marina Accornero  Luigi Marini 《Applied Geochemistry》2009

The Pitzer’s interaction parameters, λ_N–M, involving the Mth cationic Al species Al³⁺ or AlOH²⁺ or AlO⁺ and the Nth neutral species SiO_2(aq) (at temperatures of 25–300 °C) or CO_2(aq) (at temperatures of 25–150 °C), have been evaluated through empirical linear relationships between λ_N–M and the surface electrostatic field of the ionic species of interest. These relationships have been obtained starting from the known λ_N–M for both SiO_2(aq) and CO_2(aq) with the main dissolved cations. The Pitzer’s interaction parameter thus estimated for the pair CO_2(aq)–Al³⁺ at 25 °C, 0.327, is 20–40% higher than the corresponding values obtained from CO₂ solubilities in concentrated solutions of AlCl₃, 0.272 ± 0.010 (2σ), and Al₂(SO₄)₃, 0.232 ± 0.002 (2σ), partly corroborating the empirical approach adopted in this study. To test the Pitzer’s interaction coefficients for cationic Al species with aqueous SiO₂, the log K values of the kaolinite dissolution reaction have been computed starting from available experimental data at 23–25 °C and ionic strengths of 0.0001–0.12 mol/kg adopting, alternatively, the Pitzer’s equations and the Debye–Hückel equation. A satisfactory agreement has been found between the log K values obtained through these two approaches, with maximum deviations of 0.11–0.12 log units. This good convergence of results is encouraging as it represents a necessary condition to prove the reliability of the Pitzer’s interaction coefficients estimated in this work. These results are a first step to take into account specific interactions among solutes in concentrated electrolyte solutions, such as those hosted in sedimentary basins or geothermal waters, for instance through the Pitzer’s equations. However, experimental or field data at higher ionic strengths are absolutely necessary to validate the reliability of the Pitzer’s interaction coefficients determined in this study.  相似文献   

The impact of dolomite and plagioclase weathering on the chemistry of shallow groundwaters circulating in a granodiorite-dominated catchment of the Sila Massif (Calabria,Southern Italy)     

Carmine Apollaro  Marina Accornero  Luigi Marini  Donatella Barca  Rosanna De Rosa 《Applied Geochemistry》2009

This work is aimed at investigating the weathering processes of the granodiorites cropping out in a small catchment of the Sila Massif. The mineral constituents in this granodiorite are plagioclase, often zoned with a Ca-rich core and a Na-rich rim, quartz, chlorite, K-feldspar, white mica and epidote. During this study, dolomite was discovered in local stream sediments, as separate monomineralic grains, probably resulting from erosion of veins cutting the crystalline rocks. Prevailing dissolution of foreign dolomite and a Ca-rich plagioclase is suggested by the Ca–Mg–HCO₃ chemical composition of local groundwaters and stream waters, which is rather unexpected for waters interacting with granitoid rocks. These qualitative observations are quantitatively confirmed by reaction path modelling of the weathering processes occurring in the study area, which was carried out using the EQ3/6 software package, version 8.0, and the Double Solid Reactant Method. Indeed, it was possible to ascertain that the release of both major dissolved constituents and several trace elements (Ba, Co, Cr, Fe, Mn, Ni, Pb, Sr, V and Zn), from rocks to waters, is chiefly controlled by the dissolution of foreign dolomite and the Ca-rich core of zoned plagioclases.  相似文献   

Biochemical and microbial features of shallow marine sediments along the Terra Nova Bay (Ross Sea,Antarctica)   总被引：1，自引：0，他引：1  

Franco Baldi  Davide Marchetto  Francesco Pini  Renato Fani  Luigi Michaud  Angelina Lo Giudice  Daniela Berto  Michele Giani 《Continental Shelf Research》2010

Shallow marine sediments were collected from seven stations (three of which located at Gerlache Inlet, two at Tethys Bay, one at Adelie Cove and one just beneath the Italian Research Base) along the Terra Nova Bay coast (Ross Sea, Antarctica). Their chemical, biochemical and microbiological properties were studied in order to provide further insights in the knowledge of this Antarctic benthic ecosystem. Overall, the organic carbon (OC) represented the major fraction of total carbon (TC) and displayed concentrations similar to or slightly lower than those previously measured in Antarctic bottom sediments. The biopolymeric carbon within OC ranged from 4.1% to 19.9% and showed a wide trophic range (65–834 μg g⁻¹ d.w.). Proteins (PRT) represented on average the main biochemical class contributing to labile organic carbon, followed by lipids (LIP) and carbohydrates (CHO). The activity of aminopeptidase, β-d-glucosidase, alkaline phosphatase and esterase was checked, giving the highest values at Tethys Bay and at the deepest water sediments. The principal component analysis, which was computed considering physical, chemical (elemental and biochemical sedimentary composition) and microbiological parameters (including bacterial abundance, ectoenzymatic activities, T-RFs richness and diversity indices), allowed to obtain two main clusters (“Tethys Bay” and “other stations”). Based on data obtained, two representative 16S rRNA clone libraries using samples from Tethys Bay and Gerlache Inlet were constructed. The sequences of 171 clones were compared to those available in public databases to determine their approximate phylogenetic affiliations. Both aerobic and anaerobic bacteria were disclosed, with the majority of them affiliated with the Gamma- and Deltaproteobacteria, Bacteroidetes and Acidobacteria. The occurrence of strictly anaerobic bacteria suggests that sediments might also undergo anoxic conditions that, in turn, could favor the accumulation of PRT in respect to CHO, assuming that fermentation of amino acids is slower than that of sugars from decomposing polysaccharides.  相似文献   

Disperse Two-Phase Flows,with Applications to Geophysical Problems     

Luigi C. Berselli  Matteo Cerminara  Traian Iliescu 《Pure and Applied Geophysics》2015,172(1):181-196

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Discussion on “Test on application of distributed fibre optic sensing technique into soil slope monitoring” by B.J. Wang, K. Li, B. Shi and G.Q. Wei     

Luciano Picarelli  Luigi Zeni 《Landslides》2009,6(4):361-363

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Propagation of P and S-waves in magmas with different crystal contents: Insights into the crystallinity of magmatic reservoirs     

Luca Caricchi  Luigi BurliniPeter Ulmer 《Journal of Volcanology and Geothermal Research》2008

Increasing amount of crystals tends to reduce the mobility of magmas and modifies its elastic characteristics (e.g. [Caricchi, L. et al., 2007. Non-Newtonian rheology of crystal-bearing magmas and implications for magma ascent dynamics. Earth and Planetary Science Letters, 264: 402–419.; Bagdassarov, N., Dingwell, D.B. and Webb, S.L., 1994. Viscoelasticity of crystal- and bubble-bearing rhyolite melts. Physics of the Earth and Planetary Interior, 83: 83–99.]). To quantify the effect of crystals on the elastic properties of magmas the propagation speed of shear and compressional waves have been measured at pressure and temperatures relevant for natural magmatic reservoirs. The measurements have been performed in aggregates at variable particle fractions (? = 0–0.7). The measurements were carried out at 200 MPa confining pressure and temperatures between 300 K and 1273 K (i.e. across the glass transition temperature (Tg) from glass to melt). The specimens were mixtures of a haplogranitic melt containing 5.25 wt.% H₂O and variable amounts of sub-spherical alumina particles. Additional experiments were carried out on a sample containing both, crystals and air bubbles. The temperature derivatives of the shear (dVs/dT) and compressional wave (dVp/dT) velocities for pure glass and samples with a crystal fraction of 0.5 are different below and above the glass transition temperature. For a crystal fraction 0.7, only dVp/dT changed above the Tg. In the presence of gas bubbles, Vp and Vs decrease constantly with increasing temperature. The bubble-bearing material yields a lower bulk modulus relative to its shear modulus. The propagation velocities of compressional and shear waves increase non-linearly with increasing crystal fraction with a prominent raise in the range 0.5 < ? < 0.7. The speed variations are only marginally related to the density increase due to the presence of crystals, but are dominantly related to the achievement of a continuous crystal framework. The experimental data set presented here can be utilized to estimate the relative proportions of crystals and melt present in a magmatic reservoir, which, in turn, is one of the fundamental parameters determining the mobility of magma and, consequently, exerting a prime control on the likelihood of an eruption from a sub-surficial magma reservoir.  相似文献