The determination of deep temperatures by means of the CO-CO2-H2-H2O geothermometer: an example using fumaroles in the Campi Flegrei,Italy. A comment     

Roberto Cioni  Luigi Marini 《Bulletin of Volcanology》1990,53(1):67-69

Three points raised in the paper by Tedesco and Sabroux (1987) are dealt with. (1) The inconsistency between the water partial pressure calculated by Tedesco and Sabroux (1987) and saturation pressure is due to the improper use of the water-gas-shift reaction as a geothermometer. In fact Tedesco and Sabroux (1987) do not take into account the distribution of gas species between the coexisting vapour and liquid phases. (2) The depth of the “steam reservoir” is evaluated by Tedesco and Sabroux (1987) in too simplistic a way. This matter should be treated with greater care owing to the high social impact of any consideration on the Phlegraean Fields system. (3) The reliability of carbon monoxide determination at the concentration level encountered at Solfatara depends on the collection method rather than on the gas-chromatographic technique.  相似文献   

The Double Solid Reactant Method for modeling the release of trace elements from dissolving solid phases: I. Outline and limitations     

Marina Accornero  Luigi Marini 《Environmental Geology》2008,55(8):1627-1635

A Double Solid Reactant Method was elaborated from a suggestion of Marini (Geological sequestration of carbon dioxide: Thermodynamics, kinetics, and reaction path modeling. Developments in Geochemistry, Elsevier, Amsterdam, 2007) to simulate the release of trace elements during the progressive dissolution of solid phases. The method is based on the definition, for each dissolving solid, of both an entity whose thermodynamic and kinetic properties are known (either a pure mineral or a solid mixture) and a special reactant, that is, a material of known stoichiometry and unknown thermodynamic and kinetic properties. The special reactant is utilised to take into account the concentrations of trace elements in the dissolving solid phase. In this communication, the influence of several trace elements on the ΔG _f ^o, ΔG _r ^o and log K of the minerals considered by Lelli et al. (Environ Geol, 2007) and Accornero and Marini (Geobasi, 2007a; Proceedings of IMWA symposium, Cagliari, 27–31 May 2007b) was evaluated assuming ideal mixing in the solid state. These effects were found to be negligible for albite and the leucite–latitic glass, limited for muscovites and chlorites, and slightly more important for apatites. These influences become progressively higher with increasing concentration of trace elements in these minerals. Based on these deviations in thermodynamic parameters, special reactants should not include oxide components with molar fractions higher than 0.003. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.

Luigi MariniEmail:

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FAOSTAT estimates of greenhouse gas emissions from biomass and peat fires     

Simone Rossi  Francesco N. Tubiello  Paolo Prosperi  Mirella Salvatore  Heather Jacobs  Riccardo Biancalani  Joanna I. House  Luigi Boschetti 《Climatic change》2016,135(3-4):699-711

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Erratum to: FAOSTAT estimates of greenhouse gas emissions from biomass and peat fires     

Simone Rossi  Francesco N. Tubiello  Paolo Prosperi  Mirella Salvatore  Heather Jacobs  Riccardo Biancalani  Joanna I. House  Luigi Boschetti 《Climatic change》2016,135(3-4):713-713

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The resolution sensitivity of the South Asian monsoon and Indo-Pacific in a global 0.35° AGCM     

Stephanie J. Johnson  Richard C. Levine  Andrew G. Turner  Gill M. Martin  Steven J. Woolnough  Reinhard Schiemann  Matthew S. Mizielinski  Malcolm J. Roberts  Pier Luigi Vidale  Marie-Estelle Demory  Jane Strachan 《Climate Dynamics》2016,46(3-4):807-831

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Elasticità e plasticità nella contrazione di volume di un solido isotropo sottoposto a pressione idrostatica     

Prof. Luigi Castoldi 《Pure and Applied Geophysics》1953,25(1):6-12

Riassunto Si prospetta una teoria della comprimibilità di un solido isotropo soggetto a pressione idrostatica, implicante il comportamento plastico ad elevate pressioni. Si ottiene in tal modo un accordo coi risultati sperimentali sensibilmente superiore a quello fin qui conseguito ritenendo il fenomeno di natura puramente elastica ed applicado ad esso la cosìddetta «approssimazione del second'ordine».

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Summary A theory of the comprimibility for isotropic solids, whith regard to their plastic properties, is proposed. Check whith experimental data furnishes more satisfactory results than current theory of second approximation.

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A semi-rigid connector for buoys and marine platforms     

Luigi Cavaleri 《Ocean Engineering》1980,7(3):447-455

A system is described which has the capability of maintaining two large structures apart, floating or submerged, but allowing their relative movements due to current, waves and wind.Such a system has been designed and built. The tests carried out show that the developed theory is correct within the specified limits of validity. A practical test in the sea has shown the efficiency of the system and suggested some possible improvements.Its main characteristics are simplicity, reliability and low cost.  相似文献   

Mesozoic exhumation history of the Grenvillian Oaxacan Complex,southern Mexico     

Fanis Abdullin  Luigi Solari  Jesús Sol  Carlos Ortega‐Obregn 《地学学报》2021,33(1):86-94

We present the first fission‐track results from the Grenvillian Oaxacan Complex, southern Mexico. Time–temperature modelling of the data indicates that two significant Mesozoic cooling episodes are recorded in the Oaxacan Complex and these are interpreted as resulting from exhumation. The older cooling event took place from the Late Triassic to Middle Jurassic and is possible linked to the break‐up of Pangea (including the initial opening of the Gulf of Mexico during the Jurassic). The younger exhumation period in the Early Cretaceous is contemporaneous with the final stages of rifting of the Gulf of Mexico. Key stratigraphic records also provide independent evidence for these exhumation episodes. In our view, both Mesozoic rapid exhumation events were controlled by the activity of the Caltepec Fault Zone and the Oaxaca Fault. Our data suggest that both these large fault systems have remained active since, at least, the Late Triassic.  相似文献   

Silicate liquid immiscibility in impact melts          下载免费PDF全文

Christopher Hamann  Agnese Fazio  Matthias Ebert  Lutz Hecht  Richard Wirth  Luigi Folco  Alex Deutsch  Wolf Uwe Reimold 《Meteoritics & planetary science》2018,53(8):1594-1632

We have investigated silicate emulsions in impact glasses and impact melt rocks from the Wabar (Saudi Arabia), Kamil (Egypt), Barringer (USA), and Tenoumer (Mauritania) impact structures, and in experimentally generated impact glasses and laser-generated glasses (MEMIN research unit) by scanning electron microscopy, electron microprobe analysis, and transmission electron microscopy. Textural evidence of silicate liquid immiscibility includes droplets of one glass disseminated in a chemically distinct glassy matrix; sharp phase boundaries (menisci) between the two glasses; deformation and coalescence of droplets; and occurrence of secondary, nanometer-sized quench droplets in Si-rich glasses. The compositions of the conjugate immiscible liquids (Si-rich and Fe-rich) are consistent with phase separation in two-liquid fields in the general system Fe₂SiO₄–KAlSi₃O₈–SiO₂–CaO–MgO–TiO₂–P₂O₅. Major-element partition coefficients are well correlated with the degree of polymerization (NBO/T) of the Si-rich melt: Fe, Ca, Mg, and Ti are concentrated in the poorly polymerized, Fe-rich melt, whereas K, Na, and Si prefer the highly polymerized, Si-rich melt. Partitioning of Al is less pronounced and depends on bulk melt composition. Thus, major element partitioning between the conjugate liquids closely follows trends known from tholeiitic basalts, lunar basalts, and experimental analogs. The characteristics of impact melt inhomogeneity produced by melt unmixing in a miscibility gap are then compared to impact melt inhomogeneity caused by incomplete homogenization of different (miscible or immiscible) impact melts that result from shock melting of different target lithologies from the crater's melt zone, which do not fully homogenize and equilibrate due to rapid quenching. By taking previous reports on silicate emulsions in impact glasses into account, it follows that silicate impact melts of variable composition, cooling rate, and crystallization history might readily unmix during cooling, thereby rendering silicate liquid immiscibility a much more common process in the evolution of impact melts than previously recognized.  相似文献   

Erratum to: Prediction of the thermodynamic properties of metal–arsenate and metal–arsenite aqueous complexes to high temperatures and pressures and some geological consequences     

Luigi Marini  Marina Accornero 《Environmental Earth Sciences》2010,59(7):1601-1606

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