Drying of salt-contaminated masonry: MRI laboratory monitoring     

Teresa Diaz Gonçalves  Leo Pel  José Delgado Rodrigues 《Environmental Geology》2007,52(2):293-302

Drying of masonry specimens was monitored by means of a two-dimensional (2D) magnetic resonance imaging (MRI) technique. The external surfaces stayed wet for longer if NaCl was present instead of pure water only. This corroborates many practical observations that salts aggravate dampness in masonry. A slower evaporation process and not hygroscopicity was the cause. That suggests that salt-induced dampness may, in general, arise simply from changes in the drying process of masonry materials. That also implies that the height and depth at which crystallization occurs in walls may depend on the relative equilibrium humidity (RHeq) and other properties of salts that influence drying of porous materials. Evaporation rates of free surfaces of pure water and saturated NaCl solution were measured by a gravimetric technique. The results indicate that slow drying of salt-contaminated materials is not due only to the lower RHeq of salt solutions. The effective surface of evaporation is likely to be reduced perhaps due to blocking of pores by salt crystals. Final salt-distribution maps of the specimens show that: (a) salts may affect the inner materials of the masonry, even in evaporation-induced processes that lead crystallization to occur predominantly on the external surface; (b) distinct internal distribution patterns occur if masonry composition varies. Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.  相似文献   

Analysis of the mobilization of solid loads and heavy metals in runoff waters from granite quarries     

Enrique Peña González  Joaquín Suárez López  Jordi Delgado Martín  Alfredo Jácome Burgos  Jerónimo Puertas Agudo 《Environmental Geology》2006,50(6):823-834

The cutting operations of dimension stone at quarries produce a large amount of fines that, in turn, cause a negative environmental impact over local surface waters. This article presents a detailed analysis of the mobilized contamination associated with runoff waters in a large granite quarry (～200 ha) which is located in Porriño (Galicia, NW Spain), the most important production centre of dimension stone in Spain. There, an intensive monitoring survey was developed in order to characterize the hydrology of the system as well as the release and transport of pollutants. This was accomplished by means of different control sections for the flow and by the collection of 52 random water samples. Automatic samplers were also used to collect 192 water samples associated with runoff generated by significant rain events. For each of the samples collected, a wide battery of analytic determinations was performed, including solid loads, turbidity, organic pollution, nutrient and selected metals. Upon careful examination it has been possible to obtain different parameters related to the contamination control, like the “event mean concentration” (EMC), maximum concentrations and specific sediment loads. Moreover, a comprehensive statistical study including parameter correlation and cumulative probability analyses helped to understand the pollutant mobilization behaviour within the quarry system. It can be concluded that mobilized contamination shows the anomalous presence of some metals, whose concentrations are in excess when compared to the natural rock. This excess metal amount must be attributed to an anthropogenic source associated to mining and cutting operations.  相似文献   

Tectonic, sea-level, and climatic controls on Late Paleozoic sedimentation in the western basins of Argentina   总被引：2，自引：0，他引：2  

Carlos Limarino  Alfonsina Tripaldi  Sergio Marenssi  Luis Fauqu 《Journal of South American Earth Sciences》2006,22(3-4):205

Tectonic activity, sea-level changes, and the climate controlled sedimentation in Late Paleozoic basins of western Argentina. The role of each factor is investigated from the geologic record of the Río Blanco and Paganzo basins using three hierarchical orders of stratigraphic bounding surfaces. First-order surfaces correspond to regional unconformities, second-order ones to local unconformities with a lesser regional extent, and third-order surfaces represent locally extended sedimentary truncation. Using this methodology, the Carboniferous–Permian record of the Paganzo and Río Blanco basins may be divided into two megasequences, four sequences, and 12 stratigraphic sections. Megasequences are bounded by regional unconformities that result from tectonic events important enough to cause regional paleogeographic changes. Sequences are limited by minor regional extension surfaces related to local tectonic movements or significant sea-level falls. Finally, stratigraphic sections correspond to extended sedimentary truncations produced by transgressive events or major climatic changes. Sequence I is mainly composed of marine deposits divided into basal infill of the basin (Section 1) and Tournaisian–Visean transgressive deposits (Section 2). Sequence II is bounded by a sharp erosional surface and begins with coarse conglomerates (Section 3), followed by fluvial and shallow marine sedimentary rocks (Section 4) that pass upward into shales and diamictites (Section 5). The base of Sequence III is marked by an extended unconformity covered by Early Pennsylvanian glacial sedimentary rocks (Section 6) that represent the most important glacial event along the western margin of Gondwana. Postglacial deposits (Section 7) occur in the two basins and comprise both glaciolacustrine (eastern region) and transgressive marine (central and western regions) deposits. By the Moscovian–Kasimovian, fluvial sandstones and conglomerates were deposited in most of the Paganzo Basin (Section 8), while localized volcanic activity took place in the Río Blanco Basin. Near the end of the Carboniferous, an important transgression is recorded in the major part of the Río Blanco Basin (Section 9), reaching the westernmost portion area of the Paganzo Basin. Finally, Sequence IV shows important differences between the Paganzo and Río Blanco basins; fluvial red beds (Section 10), eolian sandstones (Section 11), and low-energy fluvial deposits (Section 12) prevailed in the Paganzo Basin whereas volcaniclastic sedimentation and volcanism dominated in the Río Blanco Basin. Thus, tectonic events, sea-level changes and climate exerted a strong and complex control on the evolution of the Río Blanco and Paganzo basins. The interaction of these allocyclic controls produced not only characteristic facies association patterns but also different kinds of stratigraphic bounding surfaces.  相似文献   

A MILP model for design of flotation circuits with bank/column and regrind/no regrind selection     

Luis A. Cisternas  David A. Méndez  Edelmira D. Gálvez  Rodrigo E. Jorquera 《International Journal of Mineral Processing》2006

A method for the design of flotation circuits is presented. The design problem is represented by several superstructures. The first superstructure represents separation tasks (STS), which include: feed processing superstructure (FPS), concentrate processing superstructure (CPS), and tail processing superstructure (TPS). The FPS commonly uses a single stage, i.e., rougher. The CPS represents the circuit needed to carry out the cleaner task, and the TPS represents the circuit needed to carry out the scavenger task. These superstructures are flow networks between several separation stages. In each separation stage two kinds of cells are allowed, bank and column. In several streams in the CPS and TPS, the incorporation of regrind mills is also included.  相似文献   

A recent,retrogressive, complex earthflow–earth slide at Cenes de la Vega,southern Spain     

Jesús Garrido  José Delgado 《Landslides》2013,10(1):83-89

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Unusual Emissions at Various Energies Prior to the Impulsive Phase of the Large Solar Flare and Coronal Mass Ejection of 4 November 2003     

Pierre Kaufmann  Gordon D. Holman  Yang Su  C. Guillermo Gimenez de?Castro  Emilia Correia  Luis O. T. Fernandes  Rodney V. de Souza  Adolfo Marun  Pablo Pereyra 《Solar physics》2012,279(2):465-475

The GOES X28 flare of 4 November 2003 was the largest ever recorded in its class. It produced the first evidence for two spectrally separated emission components, one at microwaves and the other in the THz range of frequencies. We analyzed the pre-flare phase of this large flare, twenty?minutes before the onset of the major impulsive burst. This period is characterized by unusual activity in X-rays, sub-THz frequencies, H??, and microwaves. The CME onset occurred before the onset of the large burst by about 6?min. It was preceded by pulsations of 3??C?5?s periods at sub-THz frequencies together with X-ray and microwave enhancements. The sub-THz pulsations faded out as impulsive bursts were detected at 100??C?300?keV and 7?GHz, close to the time of the first H?? brightening and the CME onset. The activities detected prior to and at the CME onset were located nearly 2?arcmin south of the following large flare, suggesting they were separate events. This unusual activity brings new clues to understanding the complex energy buildup mechanisms prior to the CME onset, occurring at a distinct location and well before the major flare that exploded afterwards.  相似文献   

An object-based approach for mapping forest structural types based on low-density LiDAR and multispectral imagery     

Luis Ángel Ruiz  Jorge Abel Recio  Pablo Crespo-Peremarch  Marta Sapena 《国际地球制图》2018,33(5):443-457

Mapping forest structure variables provides important information for the estimation of forest biomass, carbon stocks, pasture suitability or for wildfire risk prevention and control. The optimization of the prediction models of these variables requires an adequate stratification of the forest landscape in order to create specific models for each structural type or strata. This paper aims to propose and validate the use of an object-oriented classification methodology based on low-density LiDAR data (0.5 m^?2) available at national level, WorldView-2 and Sentinel-2 multispectral imagery to categorize Mediterranean forests in generic structural types. After preprocessing the data sets, the area was segmented using a multiresolution algorithm, features describing 3D vertical structure were extracted from LiDAR data and spectral and texture features from satellite images. Objects were classified after feature selection in the following structural classes: grasslands, shrubs, forest (without shrubs), mixed forest (trees and shrubs) and dense young forest. Four classification algorithms (C4.5 decision trees, random forest, k-nearest neighbour and support vector machine) were evaluated using cross-validation techniques. The results show that the integration of low-density LiDAR and multispectral imagery provide a set of complementary features that improve the results (90.75% overall accuracy), and the object-oriented classification techniques are efficient for stratification of Mediterranean forest areas in structural- and fuel-related categories. Further work will be focused on the creation and validation of a different prediction model adapted to the various strata.  相似文献   

Holocene environmental change on the Atlantic coast of NW Iberia as inferred from the Ponzos wetland sequence     

Luis Gómez-Orellana  Pablo Ramil-Rego  Javier Ferreiro da Costa  Castor Muñoz Sobrino 《Boreas: An International Journal of Quaternary Research》2021,50(4):1131-1145

The intertidal environment of the Ponzos beach (NW Iberian Peninsula) hosts a sedimentary sequence (including large wood fragments) deposited during the first half of the Holocene in a hygrophilous continental wetland. Pollen and macrofossil data alongside radiocarbon dating allow reconstruction of the changes that occurred during the Early and Middle Holocene in the landscape of the NW Iberia coastal lowlands, as well as the local wetland plant communities, in response to the climate variations and the eustatic sea-level oscillations. The sequence represents the evolution of a coastal wetland from its initial phases as a hygrophilous wetland towards the subsequent installation of a freshwater lagoon. Pollen data show the dominant role of Atlantic (mainly deciduous) woody taxa, the scarcity of conifers and the lack of Mediterranean elements in the coastal landscapes around the Ponzos site. The presence and abundance of some taxa such as deciduous Quercus, Castanea, Fagus, Tilia and Ulmus during the Early Holocene provides further support for the occurrence of glacial refuges in the Cantabrian-Atlantic area during the Last Glaciation. The diverse vegetation that characterizes the modern landscapes in this territory established later, spreading from these glacial reservoirs of biodiversity. In this sense, the notable and early presence of Fagus at the beginning of the Holocene, a tree also previously recorded during several phases of the Last Glacial Cycle on the NW Iberia coasts, is noteworthy. In addition, during the Early and Middle Holocene are recorded other trees that are currently extirpated as natural taxa in the area, such as Pinus, Tilia and Carpinus.  相似文献   

A combined structural and seasonal approach to assess wildfire susceptibility and hazard in summertime     

Bergonse  Rafaello  Oliveira  Sandra  Gonçalves  Ana  Nunes  Sílvia  da Câmara  Carlos  Zêzere  José Luis 《Natural Hazards》2021,106(3):2545-2573

Natural Hazards - Wildfire susceptibility and hazard models based on drivers that change only on a multiyear timescale are considered of a structural nature. They ignore specific short-term...  相似文献   

Overprinting porphyry‐type veinlets on the intrusive rocks and phreatomagmatic breccias in the Southwest prospect,southwestern Sto. Tomas II (Philex), Baguio District,Philippines     

Avriel Venis L. Cirineo  Akira Imai  Ryohei Takahashi  Redempta P. Baluda  Noel C. Oliveros  Victor B. Maglambayan  Roy Ronald C. Luis  Maria Lourdes M. Faustino  Jacky Almadin 《Resource Geology》2021,71(1):1-40

The Southwest prospect is located at the southwestern periphery of the Sto. Tomas II porphyry copper–gold deposit in the Baguio District, northwestern Luzon, Philippines. The Southwest prospect hosts a copper‐gold mineralization related to a complex of porphyry intrusions, breccia facies, and overlapping porphyry‐type veinlets emplaced within the basement Pugo metavolcanics rocks and conglomerates of the Zigzag Formation. The occurrences of porphyry‐type veinlets and potassic alteration hosted in the complex are thought to be indications of the presence of blind porphyry deposits within the Sto. Tomas II vicinity. The complex is composed of at least four broadly mineralogically similar dioritic intrusive rocks that vary in texture and alteration type and intensity. These intrusions were accompanied with at least five breccia facies that were formed by the explosive brecciation, induced by the magmatic–hydrothermal processes and phreatomagmatic activities during the emplacement of the various intrusions. Hydrothermal alteration assemblages consisting of potassic, chlorite–magnetite, propylitic and sericite–chlorite alteration, and contemporaneous veinlet types were developed on the host rocks. Elevated copper and gold grades correspond to (a) chalcopyrite–bornite assemblage in the potassic alteration in the syn‐mineralization early‐mineralization diorite (EMD) and contemporaneous veinlets and (b) chalcopyrite‐rich mineralization associated with the chalcopyrite–magnetite–chlorite–actinolite±sericite veinlets contemporaneous with the chlorite–magnetite alteration. Erratic remarkable concentrations of gold were also present in the late‐mineralization Late Diorite (LD). High X_Mg of calcic amphiboles (>0.60) in the intrusive rocks indicate that the magmas have been oxidizing since the early stages of crystallization, while a gap in the composition of Al between the rim and the cores of the calcic amphiboles in the EMD and LD indicate decompression at some point during the crystallization of these intrusive rocks. Fluid inclusion microthermometry suggests the trapping of immiscible fluids that formed the potassic alteration, associated ore mineralization, and sheeted quartz veinlets. The corresponding formation conditions of the shallower and deeper quartz veinlets were estimated at pressures of 50 and 30 MPa and temperatures of 554 and 436°C at depths of 1.9 and 1.1 km. Temperature data from the chlorite indicate that the chalcopyrite‐rich mineralization associated with the chlorite–magnetite alteration was formed at a much lower temperature (ca. 290°C) than the potassic alteration. Evidence from the vein offsetting matrix suggests multiple intrusions within the EMD, despite the K‐Ar ages of the potassic alteration in EMD and hornblende in the LD of about the same age at 3.5 ± 0.3 Ma. The K‐Ar age of the potassic alteration was likely to be thermally reset as a result of the overprinting hydrothermal alteration. The constrained K‐Ar ages also indicate earlier formed intrusive rocks in the Southwest prospect, possibly coeval to the earliest “dark diorite” intrusion in the Sto. Tomas II deposit. In addition, the range of δ³⁴S of sulfide minerals from +1.8‰ to +5.1‰ in the Southwest prospect closely overlaps with the rest of the porphyry copper and epithermal deposits in the Sto. Tomas II deposit and its vicinity. This indicates that the sulfides may have formed from a homogeneous source of the porphyry copper deposits and epithermal deposits in the Sto. Tomas II orebody and its vicinity. The evidence presented in this work proves that the porphyry copper‐type veinlets and the adjacent potassic alteration in the Southwest prospect are formed earlier and at a shallower level in contrast with the other porphyry deposits in the Baguio District.  相似文献