The effect of halogens on Zr diffusion and zircon dissolution in hydrous metaluminous granitic melts   总被引：1，自引：0，他引：1  

Don R. Baker  Aida Conte  Carmela Freda  Luisa Ottolini 《Contributions to Mineralogy and Petrology》2002,142(6):666-678

Diffusion of Zr and zircon solubility in hydrous, containing approximately 4.5 wt% H₂O, metaluminous granitic melts with halogens, either 0.35 wt% Cl (LCl) or 1.2 wt% F (MRF), and in a halogen-free melt (LCO) were measured at 1.0 GPa and temperatures between 1,050 and 1,400 °C in a piston-cylinder apparatus using the zircon dissolution technique. Arrhenius equations for Zr diffusion in each hydrous melt composition are, for LCO with 4.4ǂ.4 wt% H₂O: % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavP1wzZbItLDhis9wBH5garm % Wu51MyVXgaruWqVvNCPvMCG4uz3bqee0evGueE0jxyaibaieYlf9ir % Veeu0dXdh9vqqj-hEeeu0xXdbba9ev6pc9fs0-rqaqpepmKs4qpepe % I8kaL8kuc9pgc9q8qqaq-dhH6hb9hs0dXdHu6deP0u0-vr0-vr0db8 % meaabaqaciGacaGaaeaabaWaaeaaeaaakeaacqWGebarcqGH9aqpcq % aIYaGmcqGGUaGlcqaI4aaocqaI4aaocqGHXcqScqaIWaamcqGGUaGl % cqaIWaamcqaIZaWmcqWG4baEcqaIXaqmcqaIWaamdaahaaWcbeqaai % abgkHiTiabiIda4aaakiGbcwgaLjabcIha4jabcchaWnaabmaabaWa % aSaaaeaacqGHsislcqaIXaqmcqaI0aancqaIWaamcqGGUaGlcqaIXa % qmcqGHXcqScqaIZaWmcqaIZaWmcqGGUaGlcqaI5aqoaeaacqWGsbGu % cqWGubavaaaacaGLOaGaayzkaaaaaa!571F! D = 2.88 ±0.03x10 ^{- 8} exp( [( - 140.1 ±33.9)/(RT)] )D = 2.88 \pm 0.03x10^{ - 8} \exp \left( {{{ - 140.1 \pm 33.9} \over {RT}}} \right) , for LCl with 4.5ǂ.5 wt% H₂O: % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavP1wzZbItLDhis9wBH5garm % Wu51MyVXgaruWqVvNCPvMCG4uz3bqee0evGueE0jxyaibaieYlf9ir % Veeu0dXdh9vqqj-hEeeu0xXdbba9ev6pc9fs0-rqaqpepmKs4qpepe % I8kaL8kuc9pgc9q8qqaq-dhH6hb9hs0dXdHu6deP0u0-vr0-vr0db8 % meaabaqaciGacaGaaeaabaWaaeaaeaaakeaacqWGebarcqGH9aqpcq % aIYaGmcqGGUaGlcqaIZaWmcqaIZaWmcqGHXcqScqaIWaamcqGGUaGl % cqaIWaamcqaI1aqncqWG4baEcqaIXaqmcqaIWaamdaahaaWcbeqaai % abgkHiTiabisda0aaakiGbcwgaLjabcIha4jabcchaWnaabmaabaWa % aSaaaeaacqGHsislcqaIYaGmcqaI1aqncqaI0aancqGGUaGlcqaI4a % aocqGHXcqScqaI2aGncqaI0aancqGGUaGlcqaIXaqmaeaacqWGsbGu % cqWGubavaaaacaGLOaGaayzkaaaaaa!5719! D = 2.33 ±0.05x10 ^{- 4} exp( [( - 254.8 ±64.1)/(RT)] )D = 2.33 \pm 0.05x10^{ - 4} \exp \left( {{{ - 254.8 \pm 64.1} \over {RT}}} \right) and for MRF with 4.9ǂ.3 wt% H₂O: % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavP1wzZbItLDhis9wBH5garm % Wu51MyVXgaruWqVvNCPvMCG4uz3bqee0evGueE0jxyaibaieYlf9ir % Veeu0dXdh9vqqj-hEeeu0xXdbba9ev6pc9fs0-rqaqpepmKs4qpepe % I8kaL8kuc9pgc9q8qqaq-dhH6hb9hs0dXdHu6deP0u0-vr0-vr0db8 % meaabaqaciGacaGaaeaabaWaaeaaeaaakeaacqWGebarcqGH9aqpcq % aIYaGmcqGGUaGlcqaI1aqncqaI0aancqGHXcqScqaIWaamcqGGUaGl % cqaIWaamcqaIZaWmcqWG4baEcqaIXaqmcqaIWaamdaahaaWcbeqaai % abgkHiTiabiwda1aaakiGbcwgaLjabcIha4jabcchaWnaabmaabaWa % aSaaaeaacqGHsislcqaIYaGmcqaIYaGmcqaIZaWmcqGGUaGlcqaI4a % aocqGHXcqScqaIXaqmcqaI1aqncqGGUaGlcqaI1aqnaeaacqWGsbGu % cqWGubavaaaacaGLOaGaayzkaaaaaa!5715! D = 2.54 ±0.03x10 ^{- 5} exp( [( - 223.8 ±15.5)/(RT)] )D = 2.54 \pm 0.03x10^{ - 5} \exp \left( {{{ - 223.8 \pm 15.5} \over {RT}}} \right) . Solubilities determined by the dissolution technique were reversed for LCO +4.5ǂ.5 wt% H₂O by crystallization of a Zr-enriched glass of LCO composition at 1,200 and 1,050 °C at 1.0 GPa. The solubility data were used to calculate partition coefficients of Zr between zircon and hydrous melt, which are given by the following expressions: for LCO % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavP1wzZbItLDhis9wBH5garm % Wu51MyVXgaruWqVvNCPvMCG4uz3bqee0evGueE0jxyaibaieYlf9ir % Veeu0dXdh9vqqj-hEeeu0xXdbba9ev6pc9fs0-rqaqpepmKs4qpepe % I8kaL8kuc9pgc9q8qqaq-dhH6hb9hs0dXdHu6deP0u0-vr0-vr0db8 % meaabaqaciGacaGaaeaabaWaaeaaeaaakeaacyGGSbaBcqGGUbGBcq % WGebardaqhaaWcbaGaemOwaOLaemOCaihabaGaemOEaONaemyAaKMa % emOCaiNaem4yamMaem4Ba8MaemOBa4Maei4la8IaemyBa0Maemyzau % MaemiBaWMaemiDaqhaaOGaeyypa0JaeGymaeJaeiOla4IaeGOnayJa % eG4mamZaaeWaaeaadaWcaaqaaiabigdaXiabicdaWiabicdaWiabic % daWiabicdaWaqaaiabdsfaubaaaiaawIcacaGLPaaacqGHsislcqaI % 1aqncqGGUaGlcqaI4aaocqaI3aWnaaa!5924! lnD_Zr^zircon/melt = 1.63( [10000/(T)] ) - 5.87\ln D_{Zr}^{zircon/melt} = 1.63\left( {{{10000} \over T}} \right) - 5.87 , for LCl % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavP1wzZbItLDhis9wBH5garm % Wu51MyVXgaruWqVvNCPvMCG4uz3bqee0evGueE0jxyaibaieYlf9ir % Veeu0dXdh9vqqj-hEeeu0xXdbba9ev6pc9fs0-rqaqpepmKs4qpepe % I8kaL8kuc9pgc9q8qqaq-dhH6hb9hs0dXdHu6deP0u0-vr0-vr0db8 % meaabaqaciGacaGaaeaabaWaaeaaeaaakeaacyGGSbaBcqGGUbGBcq % WGebardaqhaaWcbaGaemOwaOLaemOCaihabaGaemOEaONaemyAaKMa % emOCaiNaem4yamMaem4Ba8MaemOBa4Maei4la8IaemyBa0Maemyzau % MaemiBaWMaemiDaqhaaOGaeyypa0JaeGymaeJaeiOla4IaeGinaqJa % eG4naCZaaeWaaeaadaWcaaqaaiabigdaXiabicdaWiabicdaWiabic % daWiabicdaWaqaaiabdsfaubaaaiaawIcacaGLPaaacqGHsislcqaI % 0aancqGGUaGlcqaI3aWncqaI1aqnaaa!5920! lnD_Zr^zircon/melt = 1.47( [10000/(T)] ) - 4.75\ln D_{Zr}^{zircon/melt} = 1.47\left( {{{10000} \over T}} \right) - 4.75 and, for MRF by % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavP1wzZbItLDhis9wBH5garm % Wu51MyVXgaruWqVvNCPvMCG4uz3bqee0evGueE0jxyaibaieYlf9ir % Veeu0dXdh9vqqj-hEeeu0xXdbba9ev6pc9fs0-rqaqpepmKs4qpepe % I8kaL8kuc9pgc9q8qqaq-dhH6hb9hs0dXdHu6deP0u0-vr0-vr0db8 % meaabaqaciGacaGaaeaabaWaaeaaeaaakeaacyGGSbaBcqGGUbGBcq % WGebardaqhaaWcbaGaemOwaOLaemOCaihabaGaemOEaONaemyAaKMa % emOCaiNaem4yamMaem4Ba8MaemOBa4Maei4la8IaemyBa0Maemyzau % MaemiBaWMaemiDaqhaaOGaeyypa0JaeGymaeJaeiOla4IaeGinaqJa % eG4naCZaaeWaaeaadaWcaaqaaiabigdaXiabicdaWiabicdaWiabic % daWiabicdaWaqaaiabdsfaubaaaiaawIcacaGLPaaacqGHsislcqaI % 0aancqGGUaGlcqaI5aqocqaIXaqmaaa!591C! lnD_Zr^zircon/melt = 1.47( [10000/(T)] ) - 4.91\ln D_{Zr}^{zircon/melt} = 1.47\left( {{{10000} \over T}} \right) - 4.91 . Experiments on the same compositions, but with water contents down to 0.5 wt%, demonstrated reductions in both the diffusion coefficient of Zr and zircon solubility in the melt. The addition of halogens at the concentration levels studied to metaluminous melts has a small effect on either the diffusion of Zr in the melt, or the solubility of zircon at all water concentrations and temperatures investigated. At 800 °C, the calculated diffusion coefficient of Zr is lowest in LCl, 9᎒^-17 m² s^-1, and is highest in LCO, 4᎒^-15 m² s^-1. Extrapolation of the halogen-free solubility data to a magmatic temperature of 800 °C yields solubilities of approximately one-third of those directly measured in similar compositions, predicted by earlier studies of zircon dissolution and based upon analyses of natural rocks. This discrepancy is attributed to the higher oxygen fugacity of the experiments of this study compared with previous studies and nature, and the effect of oxygen fugacity on the structural role of iron in the melt, which, in turn, affects zircon solubility, but does not significantly affect Zr diffusion.  相似文献   

Palynology of Lagoa dos Patos sediments,Rio Grande do Sul,Brazil     

Suzane Hilgert Cordeiro  Maria Luisa Lorscheitter 《Journal of Paleolimnology》1994,10(1):35-42

With the purpose of studying the vegetation and climatic changes in the last millenia of the Coastal Plain of Rio Grande do Sul, Brazil, a palynological study was made of the sediments of the northern part of Lagoa dos Patos lagoon. Twenty-four samples from a 2.26 m core taken at a depth of 7.70 m (30° 50 50 S and 50° 59 05 W) were collected.The analyses revealed marine transgression at 5170±120 years B.P., giving rise to local vegetation consisting chiefly of xerophytes and halophytes. Vegetation characteristic of a humid environment was present along adjacent portions of the Coastal Plain at this time. Transgression increased at about 4080±110 years B.P., when the greatest level of tidewater was reached. This coincided with the beginning of forest vegetation development along the inner portions of the Coastal Plain. These data suggest that marine transgression may have been a consequence of higher temperatures and more humidity. After 4000 years B.P., regression occurred, resulting in fresh waters characteristics in the northern portion of the lagoon. The development of forest vegetation began at this time.This is the fourth in a series of papers published in this issue on Paleolimnology in Southern South America. Dr. C. A. Fernández served as guest editor for these papers.  相似文献   

Strontium,SO42−/Cl− and Mg2+/Ca2+ ratios as tracers for the evolution of seawater into coastal aquifers: the example of Castell de Ferro aquifer (SE Spain)     

Pablo Pulido-Leboeuf  Antonio Pulido-Bosch  Maria Luisa Calvache  Ángela Vallejos  José Miguel Andreu 《Comptes Rendus Geoscience》2003,335(14):1039-1048

The strontium content and the SO₄^2?/Cl^? and Mg²⁺/Ca²⁺ ratios were used as natural tracers of the residence time of seawater intrusion into the Castell de Ferro aquifer. Analysis of these parameters indicated the existence of two principal flowpaths in the aquifer. The first flows through the eastern part of the aquifer, through the karstified Castell de Ferro massif; it accommodates a larger and more rapid flow, so that the residence time is shorter, leading to lower SO₄²⁺/Cl^? ratios, lower Sr²⁺ content and higher Mg²⁺/Ca²⁺ ratios. The second flowpath is in the western sector, and flows exclusively through alluvial deposits; the flow here is slower, particularly that flowing towards the sea. Thus the residence time of the water here will be longer and there is scant flushing of the intruded seawater; this is manifested in the high Sr²⁺ content, high SO₄²⁺/Cl^? and low Mg²⁺/Ca²⁺ ratios. To cite this article: P. Pulido-Leboeuf et al., C. R. Geoscience 335 (2003).  相似文献   

Effects of local site and building parameters on damage distribution in Angra do Heroísmo—Azores     

Paula Teves-Costa  Carlos S. Oliveira  M. Luisa Senos 《Soil Dynamics and Earthquake Engineering》2007,27(11):986-999

During the M_w=6.9 January 1, 1980 earthquake in the Azores, the damage distribution in the town of Angra do Heroísmo, in Terceira Island, had a non-homogeneous spatial character. In order to understand the observed pattern of damage a microtremor survey was carried out, using ambient vibrations, and the data were analysed with the J-Sesame software, following the H/V Nakamura methodology. The results are in good agreement with the surface geology and they show a good correlation with the observed damages. Two building surveys were performed, in 1980 on damage evaluation and in 2000 on characterization of few building parameters. With all these elements (surface geology type, soil peak frequency, building type, number of stories and damage level) for 2111 buildings it was possible to perform several interparameter analysis, which enabled the identification of indicators that could be used to improve the damage estimation for future events.  相似文献   

Chemical abundances and ionizing clusters of H ii regions in the LINER galaxy NGC 4258     

Angeles I. Díaz  Marcelo Castellanos  Elena Terlevich †  María Luisa García-Vargas 《Monthly notices of the Royal Astronomical Society》2000,318(2):462-474

We present long-slit observations in the optical and near-infrared of eight H  ii regions in the spiral galaxy NGC 4258. Six of the observed regions are located in the south-east inner spiral arms, and the other two are isolated in the northern outer arms. A detailed analysis of the physical conditions of the gas has been performed. For two of the regions, an electron temperature has been derived from the [S  iii ] λ 6312 line. For the rest, an empirical calibration based on the red and near-infrared sulphur lines has been used. The oxygen abundances derived by both methods are found to be significantly lower (by a factor of 2) than previously derived by using empirical calibrations based on the optical oxygen lines.
In the brightest region, 74C, the observation of a prominent feature caused by Wolf–Rayet (WR) stars provides an excellent constraint over some properties of the ionizing clusters. In the light of the current evolutionary synthesis models, no consistent solution is found to explain at the same time both the WR feature characteristics and the emission-line spectrum of this region. In principle, the presence of WR stars could lead to large temperature fluctuations and also to a hardening of the ionizing radiation. None of these effects is found in region 74C, for which the electron temperatures found from the [S  iii ] λ 6312 line and the Paschen discontinuity at 8200 Å are equal within the errors, and the effective temperature of the ionizing radiation is estimated at around 35 300 K.
Both more observations of confirmed high-metallicity regions and a finer metallicity grid for the evolutionary synthesis models are needed in order to understand the ionizing populations of H  ii regions.  相似文献   

Hybrid derivative-free extended Kalman filter for unknown lever arm estimation in tightly coupled DGPS/INS integration     

Yanrui Geng  Richard Deurloo  Luisa Bastos 《GPS Solutions》2011,15(2):181-191

Differential carrier phase observations from GPS (Global Positioning System) integrated with high-rate sensor measurements, such as those from an inertial navigation system (INS) or an inertial measurement unit (IMU), in a tightly coupled approach can guarantee continuous and precise geo-location information by bridging short outages in GPS and providing a solution even when less than four satellites are visible. However, to be efficient, the integration requires precise knowledge of the lever arm, i.e. the position vector of the GPS antenna relative to the IMU. A previously determined lever arm by direct measurement is not always available in real applications; therefore, an efficient automatic estimation method can be very useful. We propose a new hybrid derivative-free extended Kalman filter for the estimation of the unknown lever arm in tightly coupled GPS/INS integration. The new approach takes advantage of both the linear time propagation of the Kalman filter and the nonlinear measurement propagation of the derivative-free extended Kalman filter. Compared to the unscented Kalman filter, which in recent years is typically used as a superior alternative to the extended Kalman filter for nonlinear estimation, the virtue of the new Kalman filter is equal estimation accuracy at a significantly reduced computational burden. The performance of the new lever arm estimation method is assessed with simulated and real data. Simulations show that the proposed technique can estimate the unknown lever arm correctly provided that maneuvers with attitude changes are performed during initialization. Field test results confirm the effectiveness of the new method.  相似文献   

Overview of the Italian strong motion database ITACA 1.0   总被引：3，自引：2，他引：1  

Francesca Pacor  Roberto Paolucci  Lucia Luzi  Fabio Sabetta  Andrea Spinelli  Antonella Gorini  Mario Nicoletti  Sandro Marcucci  Luisa Filippi  Mauro Dolce 《Bulletin of Earthquake Engineering》2011,9(6):1723-1739

The Italian Strong Motion Database, ITACA, was developed within projects S6 and S4, funded in the framework of the agreements between the Italian Department of Civil Protection (Dipartimento della Protezione Civile, DPC) and the Istituto Nazionale di Geofisica e Vulcanologia (INGV), starting from 2005. The alpha version of the database was released in 2007 and subsequently upgraded to version 1.0 after: (i) including the most recent strong motion data (from 2005 to 2007) recorded in Italy, in addition to the 2008 Parma earthquake, M 5.4, and the M ≥  4.0, 2009 Abruzzo seismic events; (ii) processing the raw strong motion data using an updated procedure; (iii) increasing the number of stations with a measured shear wave velocity profile; (iv) improving the utilities to retrieve time series and ground motion parameters; (v) implementing a tool for selecting time series in agreement with design-response spectra; (vi) compiling detailed station reports containing miscellaneous information such as photo, maps and site parameters; (vii) developing procedures for the automatic generation of station reports and for the updating of the header files. After such improvements, ITACA 1.0 was published at the web site , in 2010. It presently contains 3,955 three-component waveforms, comprising the most complete catalogue of the Italian accelerometric records in the period 1972–2007 (3,562 records) and the strongest events in the period 2008–2009. Records were mainly acquired by DPC through its Accelerometric National Network (RAN) and, in few cases, by local networks and temporary stations or networks. This paper introduces the published version of the Italian Strong Motion database (ITACA version 1.0) together with main improvements and new functionalities.  相似文献   

Magnetic classification of stony meteorites: 1. Ordinary chondrites     

Pierre ROCHETTE  Leonardo SAGNOTTI  Michle BOUROT‐DENISE  Guy CONSOLMAGNO  Luigi FOLCO  Jrme GATTACCECA  Maria Luisa OSETE  Lauri PESONEN 《Meteoritics & planetary science》2003,38(2):251-268

Abstract— We present a database of magnetic susceptibility measurements on 971 ordinary chondrites. It demonstrates that this parameter can be successfully used to characterize and classify ordinary chondrite meteorites. In ordinary chondrites, this rapid and non‐destructive measurement essentially determines the amount of metal in the sample, which occurs in a very narrow range for each chondrite class (though terrestrial weathering can result in a variable decrease in susceptibility, especially in finds). This technique is particularly useful not only for a rapid classification of new meteorites, but also as a check against curation errors in large collections (i.e., unweathered meteorites, the measured susceptibility of which lies outside the expected range, may well be misclassified or misidentified samples). Magnetic remanence, related to magnetic field measurements around asteroids, is also discussed.  相似文献   

Nondestructive spectroscopic and petrochemical investigations of Paleoarchean spherule layers from the ICDP drill core BARB5, Barberton Mountain Land,South Africa          下载免费PDF全文

Jörg Fritz  Roald Tagle  Luisa Ashworth  Ralf Thomas Schmitt  Axel Hofmann  Béatrice Luais  Phillip D. Harris  Desirée Hoehnel  Seda Özdemir  Tanja Mohr‐Westheide  Christian Koeberl 《Meteoritics & planetary science》2016,51(12):2441-2458

A Paleoarchean impact spherule‐bearing interval of the 763 m long International Continental Scientific Drilling Program (ICDP) drill core BARB5 from the lower Mapepe Formation of the Fig Tree Group, Barberton Mountain Land (South Africa) was investigated using nondestructive analytical techniques. The results of visual observation, infrared (IR) spectroscopic imaging, and micro‐X‐ray fluorescence (μXRF) of drill cores are presented. Petrographic and sedimentary features, as well as major and trace element compositions of lithologies from the micrometer to kilometer‐scale, assisted in the localization and characterization of eight spherule‐bearing intervals between 512.6 and 510.5 m depth. The spherule layers occur in a strongly deformed section between 517 and 503 m, and the rocks in the core above and below are clearly less disturbed. The μXRF element maps show that spherule layers have similar petrographic and geochemical characteristics but differences in (1) sorting of two types of spherules and (2) occurrence of primary minerals (Ni‐Cr spinel and zircon). We favor a single impact scenario followed by postimpact reworking, and subsequent alteration. The spherule layers are Al₂O₃‐rich and can be distinguished from the Al₂O₃‐poor marine sediments by distinct Al‐OH absorption features in the short wave infrared (SWIR) region of the electromagnetic spectrum. Infrared images can cover tens to hundreds of square meters of lithologies and, thus, may be used to search for Al‐OH‐rich spherule layers in Al₂O₃‐poor sediments, such as Eoarchean metasediments, where the textural characteristics of the spherule layers are obscured by metamorphism.  相似文献   

Simulated effect of soil depth and bedrock topography on near‐surface hydrologic response and slope stability     

Cristiano Lanni  Jeff McDonnell  Luisa Hopp  Riccardo Rigon 《地球表面变化过程与地形》2013,38(2):146-159

  相似文献