Coupled thermal, hydraulic and geochemical evolution of pyritic tailings in unsaturated column experiments     

Patricia Acero  Carlos Ayora  Jesús Carrera 《Geochimica et cosmochimica acta》2007,71(22):5325-5338

The evolution of pore-water and the composition of solid phases in the vadose zone of pyritic tailings was studied by means of unsaturated column experiments. Several columns of water-saturated mine tailings were dried during 125 days under controlled laboratory conditions. The columns were dismantled at four successive drying stages and the evolution of pore-water, mineralogy, water content and temperature was characterized.Sulfide and aluminosilicate minerals present in the waste dissolved, releasing sulfate and other solutes (mainly Fe, Zn, Cu, Al, Mg and Ca) to the pore-water. Evaporation caused a crust of efflorescent, water-soluble sulfates to develop over the complete top surface of the columns and into the pores of the underlying waste material. This crust, which has also been identified in the field, changed the hydraulic properties of the tailings and produced a decrease in the evaporation rate of the columns. Moreover, these water-soluble precipitates (mainly rozenite, szomolnokite, halotrichite, hexahydrite, mirabilite and gypsum) acted as temporary sinks for Cd, Pb, Co and Ni, which could be released to the surface run-off or the groundwaters during rainfall events under field conditions.Pore-water evolution was determined not only by geochemical processes (dissolution of sulfides and aluminosilicates, precipitation of secondary phases) but also by thermal and hydraulic processes. Progressive dilution was observed in the lower part of the columns. Dilution was caused by the thermally driven vapor flux from the top of the column to its colder bottom and subsequent condensation therein. This process, which may also occur in tailings under sub-arid climate, played a key role on the evolution of pore-water with increasing drying.  相似文献   

Deconstructing the best case scenario: lessons from water politics in La Paz-El Alto, Bolivia     

Nina Laurie  Carlos Crespo 《Geoforum》2007,38(5):841-854

For nearly a decade the La Paz-El Alto concession in Bolivia was heralded by donor organizations, the state and the commercial water industry alike as an emblematic ‘pro-poor’ water concession under the private sector model. Managed by one of the largest water multinationals in the world (the French company Suez), the network was extended beyond the new connections required by the original ‘pro-poor’ contract, acclaimed as a pioneer of new pro-poor technologies and frequently disseminated internationally as an example of best practice. This paper analyses the La Paz-El Alto concession’s pro-poor image focusing on issues of social exclusion and network extension, contract negotiation, participation and transparency. It documents the rise of social protest about the concession and critiques the failure of neoliberal regulatory systems to promote accountability to the poor. In the context of the continued transnationalisation of the water industry the paper highlights the need for new mechanisms and delivery models to ensure greater national control over private companies and the development of a framework for international water governance.  相似文献   

Homogeneity of the Geochemical Reference Material BRP-1 (Paraná Basin Basalt) and Assessment of Minimum Mass     

Aloísio J.B. Cotta  Jacinta Enzweiler  Stephen A. Wilson  Carlos A. Pérez  Antonio J.R. Nardy  João H. Larizzatti 《Geostandards and Geoanalytical Research》2007,31(4):379-393

Reference materials (RM) are required for quantitative analyses and their successful use is associated with the degree of homogeneity, and the traceability and confidence limits of the values established by characterisation. During the production of a RM, the chemical characterisation can only commence after it has been demonstrated that the material has the required level of homogeneity. Here we describe the preparation of BRP-1, a proposed geochemical reference material, and the results of the tests to evaluate its degree of homogeneity between and within bottles. BRP-1 is the first of two geochemical RM being produced by Brazilian institutions in collaboration with the United States Geological Survey (USGS) and the International Association of Geoanalysts (IAG). Two test portions of twenty bottles of BRP-1 were analysed by wavelength dispersive-XRF spectrometry and major, minor and eighteen trace elements were determined. The results show that for most of the investigated elements, the units of BRP-1 were homogeneous at conditions approximately three times more rigorous than those strived for by the test of "sufficient homogeneity". Furthermore, the within bottle homogeneity of BRP-1 was evaluated using small beam (1 mm²) synchrotron radiation XRF spectrometry and, for comparison, the USGS reference materials BCR-2 and GSP-2 were also evaluated. From our data, it has been possible to assign representative minimum masses for some major constituents (1 mg) and for some trace elements (1-13 mg), except Zr in GSP-2, for which test portions of 74 mg are recommended.  相似文献   

Crustal attenuation in the Southern Andean retroarc (38°–39°30′ S) determined from tectonic and gravimetric studies: The Lonco-Luán asthenospheric anomaly     

Andrs Folguera  Antonio Introcaso  Mario Gimnez  Francisco Ruiz  Patricia Martinez  Cynthia Tunstall  Ezequiel García Morabito  Víctor A. Ramos 《Tectonophysics》2007,439(1-4):129-147

The western retroarc of the Southern Andes between 38° and 40° S is formed by a NNW-elongated ridge not associated with stacked thrust sheets. On the contrary, during the last 4–3 Ma this ridge was affected by extensional deformation, regional uplift and related folding on a very broad scale. Receiver function analysis shows that the drainage divide area and adjacent retroarc lie over an attenuated crust. Expected crustal thickness at these latitudes is around 38 km, whereas in this part of the retroarc the thickness is less than 32 km. The causes for such attenuation have been linked to a moderate steepening of the subducted Nazca plate beneath the South American plate, which is suggested by a westward shift and narrowing of the magmatic arc during the last 4 to 5 Ma. Gravimetric studies show that the upper plate did not react homogeneously to slab steepening, but ancient sutures and lithospheric discontinuities deeply buried under Mesozoic to Cenozoic sequences in the retroarc were locally reactivated. These processes resulted in an asthenospheric anomaly that correlates at the surface with the area of Pliocene to Quaternary doming, widespread extension and three radial troughs. Two of the troughs have accommodated substantial amounts of extension, but the third was probably aborted at an early stage. Moreover, the presence of an anomalous concentration of calderas and large volcanic centers over the proposed asthenospheric anomaly, and their age distribution, may indicate minor migration of the asthenospheric anomaly between 4 and 2 Ma through the western South American plate.  相似文献   

Structural framework and Mesozoic–Cenozoic evolution of Ponta Grossa Arch, Paraná Basin, southern Brazil     

Michael Strugale  Sidnei Pires Rostirolla  Fernando Mancini  Carlos Vieira Portela Filho  Francisco Jos Fonseca Ferreira  Rafael Corrêa de Freitas 《Journal of South American Earth Sciences》2007,24(2-4):203-227

  相似文献   

Occurrence and Resistance of Pathogenic Bacteria Along the Tietê River Downstream of São Paulo in Brazil     

Wolf-Rainer Abraham  Alexandre José Macedo  Luiz Humberto Gomes  Flavio C. A. Tavares 《洁净——土壤、空气、水》2007,35(4):339-347

The load of pathogenic bacteria, their fate and their dangerousness in the Tietê River were assessed along 100 km starting from the city of São Paulo, Brazil. The data were compared with those from two German rivers. High loads of pathogens were found in the Tietê River near the city of São Paulo (Escherichia coli O157:H7, Shigella flexneri, and Shigella boydii), which were absent 30 km downstream of São Paulo. The antibiotic resistances observed in the Tietê river were rather low and decreased after the major input in São Paulo to significantly lower levels about 30 km downstream. While the Brazilian isolates were more susceptible for ampicillin than the German ones, the reverse was observed for gentamycin. For optimal control of infections in humans critical areas where these bacteria survived longer and their elimination mechanisms should be identified as well as the extent and the origin of antibiotic resistance should be determined.  相似文献   

Mock 2dF and SDSS galaxy redshift surveys   总被引：1，自引：0，他引：1  

Shaun Cole  Steve Hatton  David H. Weinberg  & Carlos S. Frenk 《Monthly notices of the Royal Astronomical Society》1998,300(4):945-966

  相似文献   

A model that helps explain Sr-isotope disequilibrium between feldspar phenocrysts and melt in large-volume silicic magma systems     

Wendell A. Duffield  Joaquin Ruiz   《Journal of Volcanology and Geothermal Research》1998,87(1-4)

Feldspar phenocrysts of silicic volcanic rocks are commonly in Sr-isotopic disequilibrium with groundmass. In some cases the feldspar is more radiogenic, and in others it is less radiogenic. Several explanations have been published previously, but none of these is able to accommodate both senses of disequilibrium. We present a model by which either more- or less-radiogenic feldspar (or even both within a single eruptive unit) can originate. The model requires a magma body open to interaction with biotite- and feldspar-bearing wall rock. Magma is incrementally contaminated as wall rock melts incongruently. Biotite preferentially melts first, followed by feldspar. Such melting behavior, which is supported by both field and experimental studies, first contaminates magma with a relatively radiogenic addition, followed by a less-radiogenic addition. Feldspar phenocrysts lag behind melt (groundmass of volcanic rock) in incorporating the influx of contaminant, thus resulting in Sr-isotopic disequilibrium between the crystals and melt. The sense of disequilibrium recorded in a volcanic rock depends on when eruption quenches the contamination process. This model is testable by isotopic fingerprinting of individual feldspar crystals. For a given set of geologic boundary conditions, specific core-to-rim Sr-isotopic profiles are expectable. Moreover, phenocrysts that nucleate at different times during the contamination process should record different and predictable parts of the history. Initial results of Sr-isotopic fingerprinting of sanidine phenocrysts from the Taylor Creek Rhyolite are consistent with the model. More tests of the model are desirable.  相似文献   

Comparison of the SFI peculiar velocities with the IRAS 1.2-Jy gravity field     

Luiz N. da Costa  Adi Nusser  Wolfram Freudling  Riccardo Giovanelli  Martha P. Haynes  John J. Salzer  & Gary Wegner 《Monthly notices of the Royal Astronomical Society》1998,299(2):425-432

We present a comparison between the peculiar velocity fields measured from a recently completed l -band Tully–Fisher survey of field spirals (SFI) and that derived from the IRAS 1.2-Jy redshift survey galaxy distribution. The analysis is based on the expansion of these data in redshift space using smooth orthonormal functions, and is performed using low- and high-resolution expansions, with an effective smoothing scale which increases almost linearly with redshift. The effective smoothing scales at 3000 km s⁻¹ are 1500 and 1000 km s⁻¹ for the low- and high-resolution filters. The agreement between the high- and low-resolution SFI velocity maps is excellent. The general features in the filtered SFI and IRAS velocity fields agree remarkably well within 6000 km s⁻¹. This good agreement between the fields allows us to determine the parameter β = Ω^0.6 / b , where Ω is the cosmological density parameter, and b is the linear biasing factor. From a likelihood analysis on the SFI and IRAS modes we find that β = 0.6 ± 0.1, independently of the resolution of the modal expansion. For this value of β, the residual fields for the two filters show no systematic variations within 6000 km s⁻¹. Most remarkable is the lack of any coherent, redshift-dependent dipole flow in the residual field.  相似文献   

Are the Venezuelan fault systems part of the southern Caribbean plate boundary?     

Carlos Schubert 《International Journal of Earth Sciences》1981,70(2):542-551

Three major fault systems have been recognized in Venezuela: the Oca, Boconó, and El Pilar fault zones. The Boconó-El Pilar system is an active, Late Pleistocene-Holocene fault system, which extends for over 1300 km between the Venezuela-Colombia border, through the Venezuelan Andes and along the northern Venezuelan coast, to the east of Trinidad. Recent tectonic evidence suggests that until the Late Tertiary or Early Quaternary, the Caribbean Plate-South America Plate boundary included the El Pilar and Oca fault systems. Since then, it has included the Boconó fault system. Right-lateral offset along these fault systems is not sufficient to derive the Caribbean Plate from Pacific crust; alternatively, the Caribbean Plate may have been a part of the South America Plate until comparatively recent geologic-time.

---

Zusammenfassung Drei wichtige Bruchsysteme sind in Venezuela festgestellt worden: die Oca, Boconé und El Pilar Bruchzonen. Das Boconó-El-Pilar-System ist ein aktives, Spätpleistozänes-Holozänes System, daß sich über mehr als 1300 km erstreckt, von der venezolanischkolumbianischen Grenze, durch die venezolanischen Anden und längs der nördlichen venezolanischen Küste, bis östlich von Trinidad. Rezente tektonische Daten lassen andeuten, daß bis zum Spättertiär oder Frühquartär, die Grenze zwischen der Karibischen Platte und der Südamerika-Platte die El Pilar- und Oca-Bruchsysteme einschloß. Später hat sie das Boconó-Bruchsystem eingeschlossen. Rechtsinnige Blattverschiebung an diesen Bruchsystemen ist nicht groß genug, um die Karibische Platte als ein Stück pazifischer Kruste zu betrachten; oder aber, die Karibische Platte war mit der Südamerika-Platte vereinigt bis zu einem relativ jungen geologischen Alter.

---

Resumen Se han establecido tres sistemas mayores de fallamiento en Venezuela: las zonas de falla de Oca, Boconó y El Pilar. El sistema de Boconó-El Pilar es un sistema de falla activo pleistoceno-holoceno, el cual se extiende por más de 1300 km entre la frontera colombo-venezolana, a traves de los Andes venezolanos y a lo largo de la costa norte de Venezuela, hasta más al este de Trinidad. Evidencias tectónicas recientes sugieren que hasta el Terciario Tardio o Cuatemario Temprano, el límite entre las Plaças del Caribe y de América del Sur incluía los sistemas de falla de Oca y El Pilar. Desde entonces incluye al sistema de falla de Boconó. El desplazamiento de rumbo hacia la derecha a lo largo de estos sistemas de fallamiento no es suficiente para derivar la Plaça del Caribe de la corteza pacifica; alternativamente, la Placa del Caribe puede haber sido parte de la Placa de América del Sur hasta una época geológica relativamente reciente.

---

: , ' El Pilar. - / , 1300 - , . , 1 Pilar. '. , , , , , .

---

---

Dedicated to the memory of John D. Weaver.  相似文献