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81.
82.
The infrared complex permittivity functions of three varieties of maghemite, γ-Fe2O3, having different degrees of vacancy ordering, have been determined from their IR reflectance spectra, measured at near to normal incidence on pressed powder pellets. The optical constants therefrom obtained have been verified by using them in the simulation of the corresponding absorption spectra for KBr-diluted pellets, and these are in excellent agreement with the experimental spectra. All calculations are based on a procedure for the estimation of the effective dielectric function of a mixture, which incorporates percolation features, recently developed by the authors.  相似文献   
83.
The ability of the Maximum Entropy Spectral Estimate (MEM) to handle magnetotelluric signals was investigated. To this end simulations of naturally occurring signals and real data were spectral analyzed both by a standard FFT technique and by MEM. The method developed for the simulation of the time series, provides accurate amplitudes and phase, and turns out to be a good test procedure for spectral analysis methods, as they apply to MT signal processing. The final estimation of the apparent resistivity was better achieved by the FFT technique. Oscillations were observed in the estimation of the apparent resistivities by MEM.  相似文献   
84.
A regional gravity study of Honduras was performed as part of a major study of the geothermal resource potential of Honduras. This study was conducted by Los Alamos National Laboratory, in cooperation with the Honduras government. Regional offshore free-air and onshore Bouguer gravity maps, and residual/isostatic gravity maps of Honduras and surrounding regions were produced. From these data several regional crustal and upper mantle models were produced. These models pass through two local geothermal sites, Platanares and San Ignacio. The regional geologic and tectonic implications of the models and their relevance to the geothermal potential of Honduras and to six well known geothermal sites in particular are examined. No obvious regional structures observed in the gravity data can explain the thermal enhancement in general or the specific geothermal sites. More local tectonic or structural conditions must control the distribution of the thermally enhanced areas.  相似文献   
85.
Geophysical studies were carried out in Platanares in Western Honduras, as part of an investigation of the geothermal resource potential of Honduras by Los Alamos National Laboratory in cooperation with the Honduran government and the U.S. Geological Survey. Geological and geochemical studies later followed by exploratory bore-holes indicate this area of rugged topography has the best geothermal potential in Honduras. In order to better understand the geology of the area, gravity, audiomagnetotelluric and telluric surveys were carried out. The site is in a graben of Tertiary volcanics and Cretaceous red beds, with numerous hot springs along faults in the center of the graben. Gravity mapped the thickness of low-density tuffs and the position of associated normal faults. It also indicated the presence of persuasive, shallow, highly silicified, high-density tuffs and gravels. The electrical surveys mapped shallow, high-resistivity silicified zones and faults as low-resistivity zones. The red beds below the tuffs are considered to contain the geothermal reservoir, but their maximum thickness could not be determined by these surveys due to the lack of density contrast and the high surface electrical conductivities. Three geologic cross-sections constructed by others have been re-evaluated using gravity modeling and analysis of eletrical anomalies, showing general agreement but in detail significant differences.  相似文献   
86.
Large-scale conversion of tropical forests into pastures or annual crops will likely lead to changes in the local microclimate of those regions. Larger diurnal fluctuations of surface temperature and humidity deficit, increased surface runoff during rainy periods and decreased runoff during the dry season, and decreased soil moistrue are to be expected.It is likely that evapotranspiration will be reduced because of less available radiative energy at the canopy level since grass presents a higher albedo than forests, also because of the reduced availability of soil moisture at the rooting zone primarily during the dry season. Recent results from general circulation model (GCM) simulations of Amazonian deforestation seem to suggest that the equilibrium climate for a grassy vegetation in Amazonia would be one in which regional precipitation would be significantly reduced.Global climate changes probably will occur if there is a marked change in rainfall patterns in tropical forest regions as a result of deforestation. Besides that, biomass burning of tropical forests is likely adding CO2 into the atmosphere, thus contributing to the enhanced greenhouse warming.  相似文献   
87.
The distributions of polycyclic alkanes were monitored in a Neocomian sequence (well 1-ESS-34) from the Espirito Santo Basin, southeast Brazil. The profiles included, apart from regular hopanes, significant concentrations of 18α(H), 28,30-bisnorhopane and subordinate amounts of gammacerane. Sterane concentrations, normally with hopane/sterane <5, were compatible with other geochemical data indicating a predominantly planktonic/microbial source of the deposited organic matter. Sample maturities ranged from very immature to the onset of oil generation, allowing biomarker distributions to be followed along a broad maturation range. The ability of certain molecular ratios (e.g. C27 17α(H)/17β(H)hopanes) to reflect a maturity sequence with depth in the closely-spaced strata of the immature upper levels (Jiquiá Stage) showed the value of molecular techniques over classical geochemical methods (e.g. vitrinite reflectance) for the study of immature sequences. The presence in the oils of southern Espirito Santo of 28,30-bisnorhopane, gammacerane and methyl steranes in similar concentrations as in extracts of the deepest levels of the 1-ESS-34 well qualify the Jiquia Stage as the probable source rock of oils accumulated in the basin.  相似文献   
88.
Geochemical Indicators of Intrinsic Bioremediation   总被引:19,自引:0,他引:19  
A detailed field investigation has been completed at a gasoline-contaminated aquifer near Rocky Point, NC, to examine possible indicators of intrinsic bioremediation and identify factors that may significantly influence the rate and extent of bioremediation. The dissolved plume of benzene, toluene, ethylbenzene, and xylene (BTEX) in ground water is naturally degrading. Toluene and o-xylene are most rapidly degraded followed by m-, p-xylene, and benzene. Ethylbenzene appears to degrade very slowly under anaerobic conditions present in the center of the plume. The rate and extent of biodegradation appears to be strongly influenced by the type and quantity of electron acceptors present in the aquifer. At the upgradient edge of the plume, nitrate, ferric iron, and oxygen are used as terminal electron acceptors during hydrocarbon biodegradation. The equivalent of 40 to 50 mg/I of hydrocarbon is degraded based on the increase in dissolved CO2 relative to background ground water. Immediately downgradient of the source area, sulfate and iron are the dominant electron acceptors. Toluene and o-xylene are rapidly removed in this region. Once the available oxygen, nitrate, and sulfate are consumed, biodegradation is limited and appears to be controlled by mixing and aerobic biodegradation at the plume fringes.  相似文献   
89.
The Bishop Tuff, a well known Quaternary high-silica rhyolite in east-central California, is widely considered the type example of a vertically and monotonically zoned pyroclastic deposit that represents zoning in the source magma reservoir, inverted during the process of pyroclastic emplacement. However, the deposit of plinian pumice, which forms the base of the Bishop Tuff and represents the initial 10% or so of all magma erupted during the event that produced the Bishop Tuff, contains features at odds with monotonie zoning for the reservoir. Relative to overlying ignimbrite, the plinian deposit contains a reversal in trace-element zoning. Moreover, the 87Sr/86Sr is significantly higher than that in overlying ignimbrite (about 0.7084 vs 0.7064), and melt inclusions trapped in quartz phenocrysts exhibit notable variability of trace-element concentrations, even within a single host crystal (e.g., U: 10.77 to 8.91 ppm).These data have been previously interpreted as due to processes of chemical fractionation and evolution operating within a magma system closed to chemical interactions with its roof rocks. For example, the reversal in trace-element zoning has been explained by the first-erupted magma being erupted from somewhat below the top of a monotonically zoned reservoir. However, we submit that the reversed zoning and other above-noted features can be explained equally well as consequences of minor assimilation of roof rocks into a magma reservoir that was erupted from the top down.The basal part of the Bishop Tuff exhibits extreme concentrations and depletions of trace elements, relative to the average composition of crustal rocks. For example, the upward decrease of Sr in the Bishop magma reservoir (downward decrease in the ignimbrite) results in concentrations as low as 2–4 ppm. Because of the attendant ‘chemical leverage’, assimilation of < 1 wt.% of Sierra Nevada batholith rocks typical of the area could readily reverse an ‘uncontaminated’ Sr (and other trace elements) trend of zoning and could also substantially raise 87Sr/86Sr. Small-scale trace-element variability in the uppermost part of the Bishop magma reservoir, as recorded by the above-mentioned melt inclusions, may simply reflect melt heterogeneity produced by the process of assimilation.  相似文献   
90.
Ti, Zr, Y and P, known to be chemically immobile elements during alteration and metamorphism, have been ploted in a set of diagrams in order to discriminative between calc-alkaline andesites from island arcs and continental margin. This method may be an appropiate procedure to help in the discrimination between ancient volcanics of both groups.  相似文献   
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