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81.
Geochemistry and environmental tracers were used to understand groundwater resources, recharge processes, and potential sources of contamination in the Rio Actopan Basin, Veracruz State, Mexico. Total dissolved solids are lower in wells and springs located in the basin uplands compared with those closer to the coast, likely associated with rock/water interaction. Geochemical results also indicate some saltwater intrusion near the coast and increased nitrate near urban centers. Stable isotopes show that precipitation is the source of recharge to the groundwater system. Interestingly, some high-elevation springs are more isotopically enriched than average annual precipitation at higher elevations, indicating preferential recharge during the drier but cooler winter months when evapotranspiration is reduced. In contrast, groundwater below 1,200 m elevation is more isotopically depleted than average precipitation, indicating recharge occurring at much higher elevation than the sampling site. Relatively cool recharge temperatures, derived from noble gas measurements at four sites (11–20 °C), also suggest higher elevation recharge. Environmental tracers indicate that groundwater residence time in the basin ranges from 12,000 years to modern. While this large range shows varying groundwater flowpaths and travel times, ages using different tracer methods (14C, 3H/3He, CFCs) were generally consistent. Comparing multiple tracers such as CFC-12 with CFC-113 indicates piston-flow to some discharge points, yet binary mixing of young and older groundwater at other points. In summary, groundwater within the Rio Actopan Basin watershed is relatively young (Holocene) and the majority of recharge occurs in the basin uplands and moves towards the coast.  相似文献   
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The conversion of subalpine forests into grasslands for pastoral use is a well-knownphenomenon, although for most mountain areas the timing of deforestation has not been determined. The presence of charcoal fragments in soil profiles affected by shallow landsliding enabled us to date the occurrence of fires and the periods of conversion ofsubalpine forest into grasslands in the Urbión Mountains, Iberian Range, Spain. We found that the treeline in the highest parts of the northwestern massifs of the Iberian Range(the Urbión, Demanda, Neila, and Cebollera massifs) is currently between 1500 and 1600 m a.s.l., probably because of pastoral use of the subalpine belt, whereas in the past it would have reached almost the highest divides(at approximately 2100–2200 m a.s.l.). The radiocarbon dates obtained indicate that the transformation of the subalpine belt occurred during the Late Neolithic, Chalcolithic, Bronze Age, Iron Age, and Middle Ages. Forest clearing was probably moderate during fires prior to the Middle Ages, as the small size of the sheep herds and the local character of the markets only required small clearings, and therefore more limited fires. Thus, it is likely that the forest recovered burnt areas in a few decades; this suggests the management of the forest and grasslands following a slash-andburn system. During the Middle and Modern Ages deforestation and grassland expansion affected most of the subalpine belt and coincided with the increasing prevalence of transhumance, as occurred in other mountains in the Iberian Peninsula(particularly the Pyrenees). Although the occurrence of shallow landslides following deforestation between the Neolithic and the Roman Period cannot be ruled out, the most extensive shallow landsliding processes would have occurred from the Middle Ages until recent times.  相似文献   
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The Tombador Formation exhibits depositional sequence boundaries placed at the base of extensive amalgamated fluvial sand sheets or at the base of alluvial fan conglomeratic successions that indicate basinward shifts of facies. The hierarchy system that applies to the Tombador Formation includes sequences of different orders, which are defined as follows: sequences associated with a particular tectonic setting are designated as ‘first order’ and are separated by first‐order sequence boundaries where changes in the tectonic setting are recorded; second‐order sequences represent the major subdivisions of a first‐order sequence and reflect cycles of change in stratal stacking pattern observed at 102 m scales (i.e., 200–300 m); changes in stratal stacking pattern at 101 m scales indicate third‐order sequences (i.e., 40–70 m); and changes in stratal stacking pattern at 100 m scales are assigned to the fourth order (i.e., 8–12 m). Changes in palaeogeography due to relative sea level changes are recorded at all hierarchical levels, with a magnitude that increases with the hierarchical rank. Thus, the Tombador Formation corresponds to one‐first‐order sequence, representing a distinct intracratonic sag basin fill in the polycyclic history of the Espinhaço Supergroup in Chapada Diamantina Basin. An angular unconformity separates fluvial‐estuarine to alluvial fan deposits and marks the second‐order boundary. Below the angular unconformity the third‐order sequences record fluvial to estuarine deposition. In contrast, above the angular unconformity these sequences exhibit continental alluvial successions composed conglomerates overlain by fluvial and eolian strata. Fourth‐order sequences are recognized within third‐order transgressive systems tract, and they exhibit distinct facies associations depending on their occurrence at estuarine or fluvial domains. At the estuarine domain, they are composed of tidal channel, tidal bar and overlying shoreface heterolithic strata. At the fluvial domain the sequences are formed of fluvial deposits bounded by fine‐grained or tidal influenced intervals. Fine grained intervals are the most reliable to map in fourth‐order sequences because of their broad laterally extensive sheet‐like external geometry. Therefore, they constitute fourth‐order sequence boundaries that, at the reservoir approach, constitute the most important horizontal heterogeneity and, hence, the preferable boundaries of production zones. The criteria applied to assign sequence hierarchies in the Tombador Formation are based on rock attributes, are easy to apply, and can be used as a baseline for the study of sequence stratigraphy in Precambrian and Phanerozoic basins placed in similar tectonic settings.  相似文献   
84.
The increase in heavy metal contamination in freshwater systems causes serious environmental problems in most industrialized countries, and the effort to find eco-friendly techniques for reducing water and sediment contamination is fundamental for environmental protection. Permeable barriers made of natural clays can be used as low-cost and eco-friendly materials for adsorbing heavy metals from water solution and thus reducing the sediment contamination. This study discusses the application of permeable barriers made of vermiculite clay for heavy metals remediation at the interface between water and sediments and investigates the possibility to increase their efficiency by loading the vermiculite surface with a microbial biofilm of Pseudomonas putida, which is well known to be a heavy metal accumulator. Some batch assays were performed to verify the uptake capacity of two systems and their adsorption kinetics, and the results indicated that the vermiculite bio-barrier system had a higher removal capacity than the vermiculite barrier (+34.4 and 22.8 % for Cu and Zn, respectively). Moreover, the presence of P. putida biofilm strongly contributed to fasten the kinetics of metals adsorption onto vermiculite sheets. In open-system conditions, the presence of a vermiculite barrier at the interface between water and sediment could reduce the sediment contamination up to 20 and 23 % for Cu and Zn, respectively, highlighting the efficiency of these eco-friendly materials for environmental applications. Nevertheless, the contribution of microbial biofilm in open-system setup should be optimized, and some important considerations about biofilm attachment in a continuous-flow system have been discussed.  相似文献   
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