Partitioning of metals (Fe,Pb, Cu,Zn) in urban run‐off from the Kaikorai Valley,Dunedin, New Zealand     

Luke M. Mosley  Barrie M. Peake 《新西兰海洋与淡水研究杂志》2013,47(3):615-624

Urban run‐off from a catchment in Dunedin, New Zealand was sampled and chemically characterised (iron (Fe), lead (Pb), copper (Cu), zinc (Zn) in total and <0.4 (im fractions, suspended solids, nitrogen (N), phosphorus (P), dissolved organic carbon, major ions, pH) during base flows, and storm flows from five rainfall events. Fe and Pb were found to be predominantly particle‐associated (>0.4 μm) and their concentrations increased significantly at the beginning of storm run‐off. In contrast, the majority of Cu and Zn was found in the <0.4μm fraction before rainfall events but during the initial period of storm flows a significant proportion of Cu and Zn was also present in the >0.4 μm fraction. The results indicate that Cu and Zn may be more bio‐available, and more difficult to remove by storm‐water treatment, than Pb. The pH level and the concentration of major ions (Ca⁺², Na⁺, Mg⁺², K⁺), dissolved reactive phosphorus, and nitrate generally decreased during storm flows as a result of dilution by rainwater. Concentrations of total N and P often increased during the initial period of storm run‐off, which was likely because of wash‐off of particulate plant material.  相似文献   

Petroleum Geostatistics     

Dario Grana  Colin Daly 《Mathematical Geosciences》2017,49(4):439-440

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Clay‐coat diversity in marginal marine sediments     

Luke J. Wooldridge  Richard H. Worden  Joshua Griffiths  James E. P. Utley 《Sedimentology》2019,66(3):1118-1138

The specific mineralogy of clay grain coats controls the ability of the coat to inhibit quartz cementation in sandstones during prolonged burial and heating. How and why clay‐coat mineralogy varies across marginal marine systems is poorly understood, even though these eogenetic phenomena strongly influence subsequent mesodiagenesis and reservoir quality. The novel development of the ability to predict the distribution of clay‐coat mineralogy would represent an important development for sandstone reservoir quality prediction. In marginal marine sediments, clay minerals occur as grain‐coats, floccules, mud intraclasts, clay‐rich rock fragments or as dispersed material. However, the relationships between clay mineralogy, the amount of clay, and its distribution is poorly understood. This study focused on the Ravenglass Estuary, UK. The key aim was to develop and apply a novel methodology utilising scanning electron microscope – energy dispersive spectrometry, for the first time, on grain coats in modern sediments, to differentiate the clay‐coat mineral signature from that of the bulk sediment, and reveal the distribution of clay minerals across marginal marine sediments. The study showed that marginal marine sediments principally have their clay mineral assemblage present as clay‐coats on sand grains. These clay‐coats have a mixed clay mineralogy and are spatially heterogeneous across the range of marginal‐marine depositional environments. The study further showed that clay‐coat mineralogy is governed initially by the hydrologically‐controlled segregation of the clay minerals within inner estuarine depositional environments, and subsequently by the selective abrasive removal of specific clay mineral types during reworking and transport into the outer estuary and the marine environment. The highest relative abundance of grain‐coating chlorite was in sand‐flat and tidal‐bar depositional environments. The availability of an analogue data set, and an understanding of the controlling processes of clay‐coat mineralogy, offer crucial steps in building a predictive capability for clay‐coat derived elevated reservoir quality in deeply buried sandstones.  相似文献   

Paleomagnetic results from Permian rocks of the northern Saharan craton and motions of the Moroccan Meseta and Pangea     

P. Morel  E. Irving  L. Daly  A. Moussine-Pouchkine 《Earth and Planetary Science Letters》1981,55(1):65-74

The characteristic magnetization of redbed samples from the upper part of the Série d'Abadla (probably Early Permian 31°N, 2.7°W) has a mean direction derived from 13 sites of D=129°, I=11°, k=59, α₉₅=6° and a corresponding south paleopole at 29°S, 60°E, A₉₅=5°. All directions have reversed polarity. The paleolatitude of the northern fringe of the Saharan craton was 6°±3°S, which is in excellent agreement with that for the Moroccan Meseta. Therefore, in all probability, there has been no paleolatitudinal displacement greater than about 500 km of the Moroccan Meseta relative to Africa since Permian time. Comparison of results from sedimentary rocks shows no evidence for relative rotation of the Moroccan Meseta since Permian time. Small apparent rotations are indicated by evidence from massive trachyandesite lavas from Morocco, but we argue that these could have arisen from the incomplete averaging of secular variation and uncertainties in estimates of paleohorizontal, rather than from true tectonic rotations. The combined latest Carboniferous/Early Permian paleopole for the Saharan craton and the Meseta differs form the path of apparent polar wandering for North America when the continents are assembled in Wegener's Pangea (Pangea A, in which northwest Africa is opposite North America). It is in reasonable agreement when the continents are assembled in the Pangea B configuration (northwest Africa opposite Europe).  相似文献   

HST Multicolor (255-1042 nm) Photometry of Saturn's Main Rings: I: Radial Profiles, Phase and Opening Angle Variations, and Regional Spectra     

Jeffrey N. CuzziRichard G. French  Luke Dones 《Icarus》2002,158(1):199-223

The main rings of Saturn were observed with the Planetary Camera of the WFPC2 instrument on the Hubble Space Telescope (HST) from September 1996 to December 2000 as the ring opening angle to Earth and Sun increased from 4° to 24°, with a spread of phase angles between 0.3° and 6° at each opening angle. The rings were routinely observed in the five HST wideband UBVRI filters (F336W, F439W, F555W, F675W, and F814W) and occasionally in the F255W, F785LP, and F1042M filters. The emphasis in this series of papers will be on radial color (implying compositional) variations. In this first paper we describe the analysis technique and calibration procedure, note revisions in a previously published Voyager ring color data analysis, and present new results based on over 100 HST images.In the 300-600 nm spectral range where the rings are red, the 555/336-nm ratio increases by about 14% as the phase angle increases from 0.3° to 6°. This effect, never reported previously for the rings, is significantly larger than the phase reddening which characterizes other icy objects, primarily because of the redness of the rings. However, there is no discernible tendency for color to vary with ring opening angle at a given phase angle, and there is no phase variation of color where the spectrum is flat. We infer from this combination of facts that multiple intraparticle scattering, either in a regolith or between facts of an unusually rough surface, is important in these geometries, but that multiple interparticle scattering in a vertically extended layer is not. Voyager color ratios at a phase angle of 14° are compatible with this trend, but calibration uncertainties prevent their use in quantitative modeling.Overall ring average spectra are compatible with those of earlier work within calibration uncertainties, but ring spectra vary noticeably with region. We refine and subdivide the regions previously defined by others. The variation seen between radial profiles of ratios between different wavelengths suggests the presence of multiple compositional components with different radial distributions. We present new radial profiles of far-UV color ratio (F336W/F255W) showing substantial global variations having a different radial structure than seen between 555 and 336 nm. We constrain radial variation in the strength of a putative 850-nm spectral feature to be at the percent level or less. There seem to be real variations in the shape of regional ring spectra between 800 and 1000 nm.  相似文献   

Wavelet and multitaper coherence methods for assessing the elastic thickness of the Irish Atlantic margin     

E. Daly  C. Brown  C. P. Stark  C. J. Ebinger 《Geophysical Journal International》2004,159(2):445-459

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Hydrology and dynamics of a polythermal (mostly cold) High Arctic glacier     

Robert G. Bingham  Peter W. Nienow  Martin J. Sharp  Luke Copland 《地球表面变化过程与地形》2006,31(12):1463-1479

To improve our understanding of the interactions between hydrology and dynamics in mostly cold glaciers (in which water flow is limited by thermal regime), we analyse short‐term (every two days) variations in glacier flow in the ablation zone of polythermal John Evans Glacier, High Arctic Canada. We monitor the spatial and temporal propagation of high‐velocity events, and examine their impacts upon supraglacial drainage processes and evolving subglacial drainage system structure. Each year, in response to the rapid establishment of supraglacial–subglacial drainage connections in the mid‐ablation zone, a ‘spring event’ of high horizontal surface velocities and high residual vertical motion propagates downglacier over two to four days from the mid‐ablation zone to the terminus. Subsequently, horizontal velocities fall relative to the spring event but remain higher than over winter, reflecting channelization of subglacial drainage but continued supraglacial meltwater forcing. Further transient high‐velocity events occur later in each melt season in response to melt‐induced rising supraglacial meltwater inputs to the glacier bed, but the dynamic response of the glacier contrasts with that recorded during the spring event, with the degree of spatial propagation a function of the degree to which the subglacial drainage system has become channelized. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Partially to fully saturated flow through smooth,clean, open fractures: qualitative experimental studies     

Brendon?R.?Jones  Luke?B.?Brouwers  Matthys?A.?DippenaarEmail author 《Hydrogeology Journal》2018,26(3):945-961

Fractures are both rough and irregular but can be expressed by a simple model concept of two smooth parallel plates and the associated cubic law governing discharge through saturated fractures. However, in natural conditions and in the intermediate vadose zone, these assumptions are likely violated. This paper presents a qualitative experimental study investigating the cubic law under variable saturation in initially dry free-draining discrete fractures. The study comprised flow visualisation experiments conducted on transparent replicas of smooth parallel plates with inlet conditions of constant pressure and differing flow rates over both vertical and horizontal inclination. Flow conditions were altered to investigate the influence of intermittent and continuous influx scenarios. Findings from this research proved, for instance, that saturated laminar flow is not likely achieved, especially in nonhorizontal fractures. In vertical fractures, preferential flow occupies the minority of cross-sectional area despite the water supply. Movement of water through the fractured vadose zone therefore becomes a matter of the continuity principle, whereby water should theoretically be transported downward at significantly higher flow rates given the very low degree of water saturation. Current techniques that aim to quantify discrete fracture flow, notably at partial saturation, are questionable. Inspired by the results of this study, it is therefore hypothetically improbable to achieve saturation in vertical fractures under free-draining wetting conditions. It does become possible under extremely excessive water inflows or when not free-draining; however, the converse is not true, as a wet vertical fracture can be drained.  相似文献   

Women,Gender Norms,and Natural Disasters in Bangladesh          下载免费PDF全文

Luke Juran  Jennifer Trivedi 《Geographical review》2015,105(4):601-611

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Nitrate sources and sinks in Elkhorn Slough,California: Results from long-term continuous in situ nitrate analyzers     

Thomas?P.?ChapinEmail author  Jane?M.?Caffrey  Hans?W.?Jannasch  Luke?J.?Coletti  John?C.?Haskins  Kenneth?S.?Johnson 《Estuaries and Coasts》2004,27(5):882-894

Nitrate and water quality parameters (temperature, salinity, dissolved oxygen, turbidity, and depth) were measured continuously with in situ NO₃ analyzers and water quality sondes at two sites in Elkhorn Slough in Central California. The Main Channel site near the mouth of Elkhorn Slough was sampled from February to September 2001. Azevedo Pond, a shallow tidal pond bordering agricultural fields further inland, was sampled from December 1999 to July 2001. Nitrate concentrations were recorded hourly while salinity, temperature, depth, oxygen, and turbidity were recorded every 30 min. Nitrate concentrations at the Main Channel site ranged from 5 to 65 μM. The propagation of an internal wave carrying water from ≈100 m depth up the Monterey Submarine Canyon and into the lower section of Elkhorn Slough on every rising tide was a major source of nitrate, accounting for 80–90% of the nitrogen load during the dry summer period. Nitrate concentrations in Azevedo Pond ranged from 0–20 μM during the dry summer months. Nitrate in Azevedo Pond increased to over 450 μM during a heavy winter precipitation event, and interannual variability driven by differences in precipitation was observed. At both sites, tidal cycling was the dominant forcing, often changing nitrate concentrations by 5-fold or more within a few hours. Water volume flux estimates were combined with observed nitrate concentrations to obtain nitrate fluxes. Nitrate flux calculations indicated a loss of 4 mmol NO₃ m^?2 d^?1 for the entire Elkhorn Slough and 1 mmol NO₃ m^?2 d^?1 at Azevedo Pond. These results suggested that the waters of Elkhorn Slough were not a major source of nitrate to Monterey Bay but actually a nitrate sink during the dry season. The limited winter data at the Main Channel site suggest that nitrate was exported from Elkhorn Slough during the wet season. Export of ammonium or dissolved organic nitrogen, which we did not monitor, may balance some or all of the NO₃ flux.  相似文献