Water source characterization through spatiotemporal patterns of major,minor and trace element stream concentrations in a complex,mesoscale German catchment     

Holger L. Fröhlich  Lutz Breuer  Hans‐Georg Frede  Johan A. Huisman  Kellie B. Vaché 《水文研究》2008,22(12):2028-2043

The link between spatiotemporal patterns of stream water chemistry and catchment characteristics for the mesoscale Dill catchment (692 km²) in Germany is explored to assess the catchment scale controls on water quality and to characterize water sources. In order to record the spatiotemporal pattern, ‘snapshot sampling’ was applied during low, mean and high flow, including 73 nested sites throughout the catchment. Water samples were analysed for the elements Li, B, Na, Mg, Al, K, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Rb, Sr, Mo, Ba, Pb and U using inductively‐coupled‐plasma mass spectrometry, and for electric conductivity and pH. Principle component analysis and hierarchical cluster analysis were used to find typical element associations and to group water samples according to their hydrochemical fingerprints. This revealed regional hydrochemical patterns of water quality which were subsequently related to catchment attributes to draw conclusions about the controls on stream chemistry. It was found that various lithologic signals and anthropogenic point source inputs controlled the base flow hydrochemistry. During increased flows, stream waters were diluted causing additional hydrochemical variability in response to heterogeneous precipitation inputs and differences in aquifer storage capacities. The hydrochemical patterns further displayed in‐stream mixing of waters. This implied, that stream waters could be apportioned to the identified water sources throughout the catchment. The basin‐wide hydrochemical variability has the potential to outrange the tracer signatures typically inferred in studies at the hillslope scale and is able to strongly influence the complexity of the catchment output. Both have to be considered for further catchment scale tracer and modelling work. Despite the likelihood of non‐conservative behaviour, the minor and trace elements enhanced the rather qualitative discrimination of the various groundwater types, as the major cations were strongly masked by point source inputs. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Improving seasonal matching in the STARS model by adaptation of the resampling technique     

Julia Lutz  Friedrich-Wilhelm Gerstengarbe 《Theoretical and Applied Climatology》2015,120(3-4):751-760

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Convex optimization under inequality constraints in rank-deficient systems     

Lutz Roese-Koerner  Wolf-Dieter Schuh 《Journal of Geodesy》2014,88(5):415-426

Many geodetic applications require the minimization of a convex objective function subject to some linear equality and/or inequality constraints. If a system is singular (e.g., a geodetic network without a defined datum) this results in a manifold of solutions. Most state-of-the-art algorithms for inequality constrained optimization (e.g., the Active-Set-Method or primal-dual Interior-Point-Methods) are either not able to deal with a rank-deficient objective function or yield only one of an infinite number of particular solutions. In this contribution, we develop a framework for the rigorous computation of a general solution of a rank-deficient problem with inequality constraints. We aim for the computation of a unique particular solution which fulfills predefined optimality criteria as well as for an adequate representation of the homogeneous solution including the constraints. Our theoretical findings are applied in a case study to determine optimal repetition numbers for a geodetic network to demonstrate the potential of the proposed framework.  相似文献   

Geochemical identification of projectiles in impact rocks     

Roald Tagle  Lutz Hecht 《Meteoritics & planetary science》2006,41(11):1721-1735

Abstract— The three major geochemical methods for impactor identification are evaluated with respect to their potential and limitations with regards to the precise detection and identification of meteoritic material in impactites. The identification of a projectile component in impactites can be achieved by determining certain isotopic and elemental ratios in contaminated impactites. The isotopic methods are based on Os and Cr isotopic ratios. Osmium isotopes are highly sensitive for the detection of minute amounts of extraterrestrial components of even <<0.05 wt% in impactites. However, this only holds true for target lithologies with almost no chemical signature of mantle material or young mantle‐derived mafic rocks. Furthermore, this method is not currently suitable for the precise identification of the projectile type. The Cr‐isotopic method requires the relatively highest projectile contamination (several wt%) in order to detect an extraterrestrial component, but may allow the identification of three different groups of extraterrestrial materials, ordinary chondrites, an enstatite chondrites, and differentiated achondrites. A significant advantage of this method is its independence of the target lithology and post‐impact alteration. The use of elemental ratios, including platinum group elements (PGE: Os, Ir, Ru, Pt, Rh, Pd), in combination with Ni and Cr represents a very powerful method for the detection and identification of projectiles in terrestrial and lunar impactites. For most projectile types, this method is almost independent of the target composition, especially if PGE ratios are considered. This holds true even in cases of terrestrial target lithologies with a high component of upper mantle material. The identification of the projectile is achieved by comparison of the “projectile elemental ratio” derived from the slope of the mixing line (target‐projectile) with the elemental ratio in the different types of possible projectiles (e.g., chondrites). However, this requires a set of impactite samples of various degree of projectile contamination.  相似文献   

A High-Resolution Solar Telescope Using Dark-Lens Diffractive Optics     

Cocks  F.H.  Watkins  S.A.  Walker  M.J.  Lutz  T.A.  Sussingham  J.C. 《Solar physics》2001,198(2):211-222

A telescope based upon dark-lens diffractive optics would be a uniquely new instrument for solar astronomy. The image formation process in such a telescope gives an intrinsically higher resolving power and a greatly reduced image intensity compared to that of refracting or reflecting optical systems of similar lens dimension. This low image intensity would be an advantage for solar observations made using a very large imaging element. After a brief overview of the history of solar instrument development, a quantitative evaluation of the dark-lens diffracting solar telescope concept is presented, showing the potential of this imaging method to meet or even to exceed the most demanding resolution goals currently being considered for future space-borne solar telescopes.  相似文献   

Mrk 1014: an AGN-dominated ultraluminous infrared galaxy     

Th. Boller  L. C. Gallo  D. Lutz  E. Sturm 《Monthly notices of the Royal Astronomical Society》2002,336(4):1143-1146

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Comprehension and appropriateness of complex mobile pictographs for crisis communication     

Waidyanatha  Nuwan  Frommberger  Lutz 《Natural Hazards》2022,114(1):583-604

Natural Hazards - In crisis situations, illiterates and people with other linguistic challenges are unable to understand text messages to inform or be informed of a situation. Pictographic...  相似文献   

Calibration measurements on the DEPFET Detectors for the MIXS instrument on BepiColombo     

P. Majewski  F. Aschauer  S. Aschauer  A. Bähr  B. Bergbauer  M. Hilchenbach  M. Krumrey  C. Laubis  T. Lauf  P. Lechner  G. Lutz  F. Scholze  H. Soltau  A. Stefanescu  L. Strüder  J. Treis 《Experimental Astronomy》2014,37(3):525-538

The Mercury Imaging X-ray Spectrometer (MIXS) will be launched on board of the 5th ESA cornerstone mission BepiColombo. The two channel instrument MIXS is dedicated to the exploration of the elemental composition of the mercurian surface by imaging x-ray spectroscopy of the elemental fluorescence lines. One of the main scientific goals of MIXS is to provide spatially resolved elemental abundance maps of key rock-forming elements. MIXS will be the successor of the XRS instrument, which is currently orbiting Mercury on board of NASAs satellite MESSENGER. MIXS will provide unprecedented spectral and spatial resolution due to its innovative detector and optics concepts. The MIXS target energy band ranges from 0.5 to 7 keV and allows to directly access the Fe-L line at 0.7 keV, which was not accessible to previous missions. In addition, the high spectroscopic resolution of FWHM ≤ 200 eV at the reference energy of 1 keV after one year in Mercury orbit, allows to separate the x-ray fluorescence emission lines of important elements like Mg (1.25 keV) and Al (1.49 keV) without the need for any filter. The detectors for the energy and spatially resolved detection of x-rays for both channels are identical DEPFET (DEpleted P-channel FET) active pixel detectors. We report on the calibration of the MIXS flight and flight spare detector modules at the PTB (Physikalisch-Technische Bundesanstalt) beamlines at the BESSY II synchrotron radiation facility. Each detector was calibrated at least at 10 discrete energies in the energy range from 0.5 to 10 keV. The excellent spectroscopic performance of all three detector modules was verified.  相似文献   

Effects of catastrophic flooding on stream biogeochemistry in a headwater stream in Shenandoah National Park,USA     

K.S. Reinhardt  T. Furman 《水文研究》2008,22(18):3759-3771

This study examined the stream chemistry changes in Staunton River (a second‐order headwater stream with an average annual discharge 704 m³ ha^?1 yr^?1, Shenandoah National Park, Virginia) resulting from a catastrophic flood in June 1995. This flood, which followed after 800 mm of rain in a 4‐day period, caused large‐scale debris flows and complete scouring of riparian soils down to bedrock in the lower 2 km of the stream, and has been estimated to be a 1000‐year flood. The flood affected stream chemistry on both short‐ and long‐term time scales. The primary short‐term response was elevations in stream concentration of Ca²⁺, Mg²⁺, and K⁺ by 59%, 87%, and 49%, respectively, for 6 months immediately following the flood. The long‐term impact of decreased concentration of all base cations and SiO₂ during summer months (8% average) lasted about 2 years. At the episodic time scale, Ca²⁺, Mg²⁺, and K⁺ flushed from soil sources during pre‐flood storms while Na⁺ and SiO₂ diluted; these trends generally reversed during post‐flood storms for 2 years. Short‐term effects are attributed to the leaching of unconsolidated soil and upturned organic matter that clogged the streambed after the flood. The long‐term and superimposed episodic impacts may have resulted from the loss of riparian soils and vegetation in the flood. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Freshwater Ostracodes in Quaternary Permafrost Deposits in the Siberian Arctic     

Sebastian?WetterichEmail author  Lutz?Schirrmeister  Erika?Pietrzeniuk 《Journal of Paleolimnology》2005,34(3):363-376

Ostracode analysis was carried out on samples from ice-rich permafrost deposits obtained on the Bykovsky Peninsula (Laptev Sea). A composite profile was investigated that covers most of a 38-m thick permafrost sequence and corresponds to the last ca. 60 kyr of the Late Quaternary. The ostracode assemblages are similar to those known from European Quaternary lake deposits during cold stages. The ostracode habitats were small, shallow, cold, oligotrophic pools located in low centred ice wedge polygons or in small thermokarst depressions. In total, 15 taxa, representing 7 genera, were identified from 65 samples. The studied section is subdivided into six ostracode zones that correspond to Late Quaternary climatic and environmental stadial-interstadial variations established by other paleoenvironmental proxies: (1) cold and dry Zyrianian stadial (58–53 kyr BP); (2) warm and dry Karginian interstadial (48–34 kyr BP); (3) transition from the Karginian interstadial to the cold and dry Sartanian stadial (34–21 kyr BP); (4) transition from the Sartanian stadial to the warm and dry Late Pleistocene period, the Allerød (21–14 kyr BP); (5) transition from the Allerød to the warm and wet Middle Holocene (14–7 kyr BP); and (6) cool and wet Late Holocene (ca. 3 kyr BP). The abundance and diversity of the ostracodes will be used as an additional bioindicator for paleoenvironmental reconstructions of the Siberian Arctic.  相似文献