Environmental controls on stable isotope precipitation values over Mali and Niger,West Africa   总被引：2，自引：0，他引：2  

Alexandra Lutz  James M. Thomas  Anna Panorska 《Environmental Earth Sciences》2011,62(8):1749-1759

This study evaluated the effects of the environmental factors precipitation amount (P), temperature (T), and vapor pressure (V _p) on the stable isotope composition (δ) of precipitation and the excess-deuterium (d) parameter in Mali and Niger, West Africa. At both locations, δ values were greatly affected by seasonal climatic conditions and a statistically significant negative correlation was observed between δ and P. In Mali, a statistically significant negative correlation was also observed between δ and V _p. There was no statistically significant correlation between δ and T. Mean-weighting of δ values may be masking both dry-season and individual storm event precipitation phenomena, which are otherwise observed in arithmetically averaged δ values. Mean monthly d values for peak monsoonal months indicate that precipitation is first-fraction, gaining little recycled water on its journey inland from the Atlantic Ocean near the equator. Agreement between rainy-season precipitation and groundwater δ values, specifically peak monsoonal months, indicates that groundwater is being recharged by infiltration of current monsoonal rains and is not paleo-groundwater recharged under past climatic conditions. Similarity between rainy-season precipitation and groundwater d values provide another indication that monsoonal precipitation under current climatic conditions is the source of groundwater recharge. The knowledge that groundwater is recently recharged monsoonal rains, rather than paleo-groundwater, is important for evaluating groundwater sustainability and the effects that climate change will have on water resources. Understanding and predicting changes in precipitation amounts and intensities, which ultimately affect timing and amount of groundwater recharge, is critical for water resource management.  相似文献   

Origin and emplacement of the impact formations at Chicxulub,Mexico, as revealed by the ICDP deep drilling at Yaxcopoil‐1 and by numerical modeling     

Dieter Stffler  Natalya A. Artemieva  Boris A. Ivanov  Lutz Hecht  Thomas Kenkmann  Ralf Thomas Schmitt  Roald Alberto Tagle  Axel Wittmann 《Meteoritics & planetary science》2004,39(7):1035-1067

We present and interpret results of petrographic, mineralogical, and chemical analyses of the 1511 m deep ICDP Yaxcopoil‐1 (Yax‐1) drill core, with special emphasis on the impactite units. Using numerical model calculations of the formation, excavation, and dynamic modification of the Chicxulub crater, constrained by laboratory data, a model of the origin and emplacement of the impact formations of Yax‐1 and of the impact structure as a whole is derived. The lower part of Yax‐1 is formed by displaced Cretaceous target rocks (610 m thick), while the upper part comprises six suevite‐type allochthonous breccia units (100 m thick). From the texture and composition of these lithological units and from numerical model calculations, we were able to link the seven distinct impact‐induced units of Yax‐1 to the corresponding successive phases of the crater formation and modification, which are as follows: 1) transient cavity formation including displacement and deposition of Cretaceous “megablocks;” 2) ground surging and mixing of impact melt and lithic clasts at the base of the ejecta curtain and deposition of the lower suevite right after the formation of the transient cavity; 3) deposition of a thin veneer of melt on top of the lower suevite and lateral transport and brecciation of this melt toward the end of the collapse of the transient cavity (brecciated impact melt rock); 4) collapse of the ejecta plume and deposition of fall‐back material from the lower part of the ejecta plume to form the middle suevite near the end of the dynamic crater modification; 5) continued collapse of the ejecta plume and deposition of the upper suevite; 6) late phase of the collapse and deposition of the lower sorted suevite after interaction with the inward flowing atmosphere; 7) final phase of fall‐back from the highest part of the ejecta plume and settling of melt and solid particles through the reestablished atmosphere to form the upper sorted suevite; and 8) return of the ocean into the crater after some time and minor reworking of the uppermost suevite under aquatic conditions. Our results are compatible with: a) 180 km and 100 km for the diameters of the final crater and the transient cavity of Chicxulub, respectively, as previously proposed by several authors, and b) the interpretation of Chicxulub as a peak‐ring impact basin that is at the transition to a multi‐ring basin.  相似文献   

Chemical modification of projectile residues and target material in a MEMIN cratering experiment     

Matthias EBERT  Lutz HECHT  Alexander DEUTSCH  Thomas KENKMANN 《Meteoritics & planetary science》2013,48(1):134-149

Abstract– In the context of the MEMIN project, a hypervelocity cratering experiment has been performed using a sphere of the iron meteorite Campo del Cielo as projectile accelerated to 4.56 km s^?1, and a block of Seeberger sandstone as target material. The ejecta, collected in a newly designed catcher, are represented by (1) weakly deformed, (2) highly deformed, and (3) highly shocked material. The latter shows shock‐metamorphic features such as planar deformation features (PDF) in quartz, formation of diaplectic quartz glass, partial melting of the sandstone, and partially molten projectile, mixed mechanically and chemically with target melt. During mixing of projectile and target melts, the Fe of the projectile is preferentially partitioned into target melt to a greater degree than Ni and Co yielding a Fe/Ni that is generally higher than Fe/Ni in the projectile. This fractionation results from the differing siderophile properties, specifically from differences in reactivity of Fe, Ni, and Co with oxygen during projectile‐target interaction. Projectile matter was also detected in shocked quartz grains. The average Fe/Ni of quartz with PDF (about 20) and of silica glasses (about 24) are in contrast to the average sandstone ratio (about 422), but resembles the Fe/Ni‐ratio of the projectile (about 14). We briefly discuss possible reasons of projectile melting and vaporization in the experiment, in which the calculated maximum shock pressure does not exceed 55 GPa.  相似文献   

Sustainability of groundwater in Mali,West Africa     

Alexandra Lutz  James M. Thomas  Greg Pohll  Mamadou Keita  W. Alan McKay 《Environmental Geology》2009,58(7):1441-1450

The following paper describes the goals and some preliminary work in the Bani sustainability study, an ongoing project in Mali, West Africa. Rural communities in Mali are increasingly relying on hand-pumps, which tap groundwater resources, as a means of obtaining potable water. The long-term sustainable yield of groundwater resources is not known but can be evaluated in sustainability study. In 2005, a groundwater sustainability study was established along the Bani River of Mali. The Bani study collected groundwater levels that were used in a conceptual groundwater flow model—the Bani model—to develop an understanding of current aquifer conditions and to make limited predictions of sustainability under various future scenarios. The Bani model showed the climatic parameters of recharge (derived from precipitation) and evapotranspiration to influence simulated groundwater levels and groundwater volume available, while increased pumping rates, due to population growth, showed little effect. When considered in the context of the actual Bani sustainability study area, the change in groundwater levels resulting from climatic parameters may have negative implications, especially during several consecutive years of decreased precipitation, such as drought, or if downward trends anticipated for precipitation continue.  相似文献   

Spatial distribution of polyfluoroalkyl compounds in dab (Limanda limanda) bile fluids from Iceland and the North Sea     

Lutz Ahrens  Ralf Ebinghaus 《Marine pollution bulletin》2010,60(1):145-7973

The spatial distribution of polyfluoroalkyl compounds (PFCs) was investigated in dab (Limanda limanda) bile fluids collected from Iceland and the North Sea. Concentrations of various PFCs, including perfluorinated sulfonates (C₄-C₆, C₈ PFSAs), perfluorinated carboxylic acids (C₉-C₁₄ PFCAs) and n-methyl perfluorooctane sulfonamidoethanol (MeFOSE), were quantified. Perfluorooctane sulfonate (PFOS) was the predominant compound with highest concentrations along the Danish and German coast (mean 9.36 ng/g wet weight (ww)). Significantly lower PFOS concentrations were found at the other sampling stations in the North Sea and Iceland (p < 0.01, t-test). Conversely, the spatial distribution of the PFCAs in Iceland and the North Sea was more uniform. The most abundant PFCA was perfluorononanoic acid (PFNA), while the mean concentration decreased with increasing chain length from 4.7 ng/g ww for PFNA to 0.04 ng/g ww for perfluorotetradecanoic acid (PFTeDA). Overall, the different spatial distribution of PFCs indicates different origin of sources and different transportation mechanism.  相似文献   

Sampling soil water along the pF curve for δ2H and δ18O analysis     

Natalie Orlowski  Lutz Breuer 《水文研究》2020,34(25):4959-4972

Soil water stable isotopes are widely used across disciplines (e.g., hydrology, ecology, soil science, and biogeochemistry). However, the full potential of stables isotopes as a tool for characterizing the origin, flow path, transport processes and residence times of water in different eco-, hydro-, and geological compartments has not yet been exploited. This is mainly due to the large variety of different methods for pore water extraction. While recent work has shown that matric potential affects the equilibrium fractionation, little work has examined how different water retention characteristics might affect the sampled water isotopic composition. Here, we present a simple laboratory experiment with two well-studied standard soils differing in their physico-chemical properties (e.g., clayey loam and silty sand). Samples were sieved, oven-dried and spiked with water of known isotopic composition to full saturation. For investigating the effect of water retention characteristics on the extracted water isotopic composition, we used pressure extractors to sample isotopically labelled soil water along the pF curve. After pressure extraction, we further extracted the soil samples via cryogenic vacuum extraction. The null hypothesis guiding our work was that water held at different tensions shows the same isotopic composition. Our results showed that the sampled soil water differed isotopically from the introduced isotopic label over time and sequentially along the pF curve. Our and previous studies suggest caution in interpreting isotope results of extracted soil water and a need to better characterize processes that govern isotope fractionation with respect to soil water retention characteristics. In the future, knowledge about soil water retention characteristics with respect to soil water isotopic composition could be applied to predict soil water fractionation effects under natural and non-stationary conditions. In this regard, isotope retention characteristics as an analog to water retention characteristics have been proposed as a way forward since matric potential affects the equilibrium fractionation between the bound water and the water vapour.  相似文献   

The reaction of carbonates in contact with laser-generated,superheated silicate melts: Constraining impact metamorphism of carbonate-bearing target rocks     

Christopher Hamann  Saskia Bläsing  Lutz Hecht  Sebastian Schäffer  Alex Deutsch  Jens Osterholz  Bernd Lexow 《Meteoritics & planetary science》2018,53(8):1644-1686

We simulated entrainment of carbonates (calcite, dolomite) in silicate impact melts by 1-bar laser melting of silicate–carbonate composite targets, using sandstone, basalt, calcite marble, limestone, dolomite marble, and iron meteorite as starting materials. We demonstrate that carbonate assimilation by silicate melts of variable composition is extremely fast (seconds to minutes), resulting in contamination of silicate melts with carbonate-derived CaO and MgO and release of CO₂ at the silicate melt–carbonate interface. We identify several processes, i.e., (1) decomposition of carbonates releases CO₂ and produces residual oxides (CaO, MgO); (2) incorporation of residual oxides from proximally dissociating carbonates into silicate melts; (3) rapid back-reactions between residual CaO and CO₂ produce idiomorphic calcite crystallites and porous carbonate quench products; (4) high-temperature reactions between Ca-contaminated silicate melts and carbonates yield typical skarn minerals and residual oxide melts; (5) mixing and mingling between Ca- or Ca,Mg-contaminated and Ca- or Ca,Mg-normal silicate melts; (6) precipitation of Ca- or Ca,Mg-rich silicates from contaminated silicate melts upon quenching. Our experiments reproduce many textural and compositional features of typical impact melts originating from silicate–carbonate targets. They reinforce hypotheses that thermal decomposition of carbonates, rapid back-reactions between decomposition products, and incorporation of residual oxides into silicate impact melts are prevailing processes during impact melting of mixed silicate–carbonate targets. However, by comparing our results with previous studies and thermodynamic considerations on the phase diagrams of calcite and quartz, we envisage that carbonate impact melts are readily produced during adiabatic decompression from high shock pressure, but subsequently decompose due to heat influx from coexisting silicate impact melts or hot breccia components. Under certain circumstances, postshock conditions may favor production and conservation of carbonate impact melts. We conclude that the response of mixed carbonate–silicate targets to impact might involve melting and decomposition of carbonates, the dominant response being governed by a complex variety of factors.  相似文献   

The Erbisberg drilling 2011: Implications for the structure and postimpact evolution of the inner ring of the Ries impact crater     

Gernot Arp  Andreas Reimer  Klaus Simon  Sebastian Sturm  Jakob Wilk  Corina Kruppa  Lutz Hecht  Bent T. Hansen  Jean Pohl  Wolf Uwe Reimold  Thomas Kenkmann  Dietmar Jung 《Meteoritics & planetary science》2019,54(10):2448-2482

The 26 km diameter Nördlinger Ries is a complex impact structure with a ring structure that resembles a peak ring. A first research drilling through this “inner crystalline ring” of the Ries was performed at the Erbisberg hill (SW Ries) to better understand the internal structure and lithology of this feature, and possibly reveal impact‐induced hydrothermal alteration. The drill core intersected the slope of a 22 m thick postimpact travertine mound, before entering 42 m of blocks and breccias of crystalline rocks excavated from the Variscan basement at >500 m depth. Weakly shocked gneiss blocks that show that shock pressure did not exceed 5 GPa occur above polymict lithic breccias of shock stage Ia (10–20 GPa), with planar fractures and planar deformation features (PDFs) in quartz. Only a narrow zone at 49.20–50.00 m core depth exhibits strong mosaicism in feldspar and {102} PDFs in quartz, which are indicative of shock stage Ib (20–35 GPa). Finally, 2 m of brecciated Keuper sediments at the base of the section point to an inverse layering of strata. While reverse grading of clast sizes in lithic breccias and gneiss blocks is consistent with lateral transport, the absence of diaplectic glass and melt products argues against dynamic overthrusting of material from a collapsing central peak, as seen in the much larger Chicxulub structure. Indeed, weakly shocked gneiss blocks are rather of local provenance (i.e., the transient crater wall), whereas moderately shocked polymict lithic breccias with geochemical composition and ⁸⁷Sr/⁸⁶Sr signature similar to Ries suevite were derived from a position closer to the impact center. Thus, the inner ring of the Ries is formed by moderately shocked polymict lithic breccias likely injected into the transient crater wall during the excavation stage and weakly shocked gneiss blocks of the collapsing transient crater wall that were emplaced during the modification stage. While the presence of an overturned flap is not evident from the Erbisberg drilling, a survey of all drillings at or near the inner ring point to inverted strata throughout its outer limb. Whether the central ring of the Ries represents remains of a collapsed central peak remains to be shown. Postimpact hydrothermal alteration along the Erbisberg section comprises chloritization, sulfide veinlets, and strong carbonatization. In addition, a narrow zone in the lower parts of the polymict lithic breccia sequence shows a positive Eu anomaly in its carbonate phase. The surface expression of this hydrothermal activity, i.e., the travertine mound, comprises subaerial as well as subaquatic growth phases. Intercalated lake sediments equivalent to the early parts of the evolution of the central crater basin succession confirm a persistent impact‐generated hydrothermal activity, although for less time than previously suggested.  相似文献   

Silicate liquid immiscibility in impact melts          下载免费PDF全文

Christopher Hamann  Agnese Fazio  Matthias Ebert  Lutz Hecht  Richard Wirth  Luigi Folco  Alex Deutsch  Wolf Uwe Reimold 《Meteoritics & planetary science》2018,53(8):1594-1632

We have investigated silicate emulsions in impact glasses and impact melt rocks from the Wabar (Saudi Arabia), Kamil (Egypt), Barringer (USA), and Tenoumer (Mauritania) impact structures, and in experimentally generated impact glasses and laser-generated glasses (MEMIN research unit) by scanning electron microscopy, electron microprobe analysis, and transmission electron microscopy. Textural evidence of silicate liquid immiscibility includes droplets of one glass disseminated in a chemically distinct glassy matrix; sharp phase boundaries (menisci) between the two glasses; deformation and coalescence of droplets; and occurrence of secondary, nanometer-sized quench droplets in Si-rich glasses. The compositions of the conjugate immiscible liquids (Si-rich and Fe-rich) are consistent with phase separation in two-liquid fields in the general system Fe₂SiO₄–KAlSi₃O₈–SiO₂–CaO–MgO–TiO₂–P₂O₅. Major-element partition coefficients are well correlated with the degree of polymerization (NBO/T) of the Si-rich melt: Fe, Ca, Mg, and Ti are concentrated in the poorly polymerized, Fe-rich melt, whereas K, Na, and Si prefer the highly polymerized, Si-rich melt. Partitioning of Al is less pronounced and depends on bulk melt composition. Thus, major element partitioning between the conjugate liquids closely follows trends known from tholeiitic basalts, lunar basalts, and experimental analogs. The characteristics of impact melt inhomogeneity produced by melt unmixing in a miscibility gap are then compared to impact melt inhomogeneity caused by incomplete homogenization of different (miscible or immiscible) impact melts that result from shock melting of different target lithologies from the crater's melt zone, which do not fully homogenize and equilibrate due to rapid quenching. By taking previous reports on silicate emulsions in impact glasses into account, it follows that silicate impact melts of variable composition, cooling rate, and crystallization history might readily unmix during cooling, thereby rendering silicate liquid immiscibility a much more common process in the evolution of impact melts than previously recognized.  相似文献   

The value of instream stable water isotope and nitrate concentration data for calibrating a travel time-based water quality model     

A. Borriero  A. Musolff  R. Kumar  J. H. Fleckenstein  S. R. Lutz  T. V. Nguyen 《水文研究》2024,38(5):e15154

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