Considerations for conducting incubations to study the mechanisms of As release in reducing groundwater aquifers     

Kathleen A. Radloff  Anya R. Manning  Brian Mailloux  Yan Zheng  M. Moshiur Rahman  M. Rezaul Huq  Kazi M. Ahmed  Alexander van Geen 《Applied Geochemistry》2008

Microbial Fe reduction is widely believed to be the primary mechanism of As release from aquifer sands in Bangladesh, but alternative explanations have been proposed. Long-term incubation studies using natural aquifer material are one way to address such divergent views. This study addresses two issues related to this approach: (1) the need for suitable abiotic controls and (2) the spatial variability of the composition of aquifer sands. Four sterilization techniques were examined using orange-colored Pleistocene sediment from Bangladesh and artificial groundwater over 8 months. Acetate (10 mM) was added to sacrificial vials before sterilization using either (1) 25 kGy of gamma irradiation, (2) three 1-h autoclave cycles, (3) a single addition of an antibiotic mixture at 1× or (4) 10× the typical dose, and (5) a 10 mM addition of azide. The effectiveness of sterilization was evaluated using two indicators of microbial Fe reduction, changes in diffuse spectral reflectance and leachable Fe(II)/Fe ratios, as well as changes in P-extractable As concentrations in the solid phase. A low dose of antibiotics was ineffective after 70 days, whereas autoclaving significantly altered groundwater composition. Gamma irradiation, a high dose of antibiotics, and azide were effective for the duration of the experiment.  相似文献   

Radon transfer from groundwater used in showers to indoor air     

David S. Vinson  Ted R. Campbell  Avner Vengosh 《Applied Geochemistry》2008

Estimation of Rn transfer from water to indoor air based on multi-day measurements may underestimate alpha exposure that occurs at short time scales in confined spaces, such as from showering, in houses with high Rn activities in the water supply. In order to examine one such incremental increase in exposure, variations in Rn in water and indoor air in 18 houses with private wells in western North Carolina (USA) were investigated. Radon in well water ranged from 158 to 811 Bq L⁻¹ (median 239 Bq L⁻¹). After 20-min showers in bathrooms with closed doors, peak Rn in air increases (above background) ranged from 71 to 4420 Bq m⁻³ (median 1170 Bq m⁻³). Calculated transfer coefficients at the scale of a 40-min closed bathroom (20-min shower plus 20 min post-shower) are described by a lognormal distribution whose geometric mean exceeds the widely-used ∼10⁻⁴ whole-house transfer coefficient by about one order of magnitude. As short-lived decay products grow from shower-derived Rn, short-term alpha energy exposure occurs in bathrooms in addition to the exposure caused by Rn mixed throughout the volume of the house. Due to the increasing ratio of Rn decay products to Rn, alpha energy exposure is greatest several minutes after the shower is turned off. For a 7.2-min shower with 10 min of additional exposure before opening the door, a geometric mean 5.6% increase in exposure over the ∼10⁻⁴ whole-house transfer coefficient derived from longer measurement periods was estimated. In addition to Rn activity in water, short-term shower exposure to Rn progeny depends on exposure time, ventilation, attachment and deposition, among other variable factors that characterize individual houses and residents.  相似文献   

Sulfur isotopic study of sulfate in the aquifer of Costa de Hermosillo (Sonora,Mexico) in relation to upward intrusion of saline groundwater,irrigation pumping and land cultivation     

Anna Szynkiewicz  Miguel Rangel Medina  Magdalena Modelska  Rogelio Monreal  Lisa M. Pratt 《Applied Geochemistry》2008

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Coupled hydrogeological and reactive transport modelling of the Simpevarp area (Sweden)     

Jorge Molinero  Juan R. Raposo  Juan M. Galíndez  David Arcos  Jordi Guimerá 《Applied Geochemistry》2008

The Simpevarp area is one of the alternative sites being considered for the deep geological disposal of high level radioactive waste in Sweden. In this paper, a coupled regional groundwater flow and reactive solute transport model of the Simpevarp area is presented that integrates current hydrogeological and hydrochemical data of the area. The model simulates the current hydrochemical pattern of the groundwater system in the area. To that aim, a conceptual hydrochemical model was developed in order to represent the dominant chemical processes. Groundwater flow conditions were reproduced by taking into account fluid-density-dependent groundwater flow and regional hydrogeologic boundary conditions. Reactive solute transport calculations were performed on the basis of the velocity field so obtained. The model was calibrated and sensitivity analyses were carried out in order to investigate the effects of heterogeneities of hydraulic conductivity in the subsurface medium. Results provided by the reactive transport model are in good agreement with much of the measured hydrochemical data. This paper emphasizes the appropriateness of the use of reactive solute transport models when water-rock interaction reactions are involved, and demonstrates what powerful tools they are for the interpretation of hydrogeological and hydrochemical data from site geological repository characterization programs, by providing a qualitative framework for data analysis and testing of conceptual assumptions in a process-oriented approach.  相似文献   

Calibration of regional palaeohydrogeology and sensitivity analysis using hydrochemistry data in site investigations     

F.M.I. Hunter  L.J. Hartley  A. Hoch  C.P. Jackson  R. McCarthy  N. Marsic  B. Gylling 《Applied Geochemistry》2008

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First U–Pb SHRIMP age of the Hauterivian stage, Neuquén Basin, Argentina     

M. Beatriz Aguirre-Urreta  Pablo J. Pazos  Darío G. Lazo  C. Mark Fanning  Vanesa D. Litvak   《Journal of South American Earth Sciences》2008,26(1):91-99

A high-resolution ion-microprobe (SHRIMP) U–Pb zircon age from a tuff layer intercalated in the ammonoid bearing sedimentary succession of the Neuquén Basin in Argentina provides a robust geochronologic date to add to the absolute ages and to improve the relative chronology of the Early Cretaceous Hauterivian stage. The tuff layer appears interbedded between shales of the upper member (Agua de la Mula) of the Agrio Formation within the Spitidiscus riccardii ammonoid zone (base of the Late Hauterivian) yielding a date of 132.5 ± 1.3 Ma. This date confirms and supports an accurate correlation between the ammonoid biostratigraphy of the Neuquén Basin with the Western Mediterranean Province of the Tethys during the Early Cretaceous and matches with the most recently published time scale. It also casts doubts on the validity of K–Ar ages on glauconite-grains recently reported from the Lower Cretaceous of the Vocontian Basin of France.  相似文献   

Drought and institutional adaptation in the Great Plains of Alberta and Saskatchewan, 1914–1939     

Gregory P. Marchildon  Suren Kulshreshtha  Elaine Wheaton  Dave Sauchyn 《Natural Hazards》2008,45(3):391-411

Agriculture in the southern Great Plains of Canada has been particularly vulnerable to prolonged episodes of drought. Using climate data and a precipitation minus potential evapotranspiration index, the extent of the region’s exposure to drought is examined. Between 1914 and 1917, the Dry Belt was particularly vulnerable to drought, whereas after 1928, a much larger region known as the Palliser Triangle covering most of southern Alberta and Saskatchewan was much more exposed to drought. These droughts provoked major institutional adaptation, in particular the establishment of the Special Areas Board by the Government of Alberta, and the creation of the Prairie Farm Rehabilitation Administration by the Government of Canada. Both organizations have proved to be relatively permanent public adaptations to the natural hazard of drought in the region. Moreover, these earlier experiences with prolonged drought as well as institution-building may be of value in helping the residents of the Palliser Triangle adapt to predicted climate changes in the future as well as anticipate some of the barriers to effective institutional adaptation.  相似文献   

Modeling households’ decisions on reconstruction of houses damaged by earthquakes––Japanese case study     

H. Sakakibara  H. Murakami  S. Esaki  D. Mori  H. Nakata 《Natural Hazards》2008,44(2):293-303

In this study, households’ decisions on reconstruction of damaged houses were modeled, using questionnaire data in Japan. Characteristics of households’ decisions were investigated using parameter estimation results. The effects of subsidizing policy were evaluated as follows. First, subsidy for rebuilding may be effective for the households whose houses were heavily damaged. Second, there is a possibility that subsidy accelerated rebuilding of houses by the households having children. Third, subsidy for rebuilding may not be effective for elderly people’s households and households in depopulated areas.  相似文献   

Flood hazard delineation combining geomorphological and hydrological methods: an example in the Northern Iberian Peninsula   总被引：2，自引：1，他引：1  

J. Lastra  E. Fernández  A. Díez-Herrero  J. Marquínez 《Natural Hazards》2008,45(2):277-293

Flood mapping requires the combination and integration of geomorphological and hydrological-hydraulic methods; however, despite this, there is very little scientific literature that compares and validates both methods. Two types of analysis are addressed in the present article. On the one hand, maps of flood plains have been elaborated using geomorphological evidence and historical flood data in the mountainous area of northwestern Spain, covering an area of more then 232 km² of floodplains. On the other hand, a hydrometeorological model has been developed (Clark semidistributed unit hydrograph) in the Sarria River basin (155 km², NW Spain). This basin is not gauged, hence the model was subjected to a goodness-of-fit test of its parameter (curve number) by means of Monte Carlo simulation. The peak flows obtained by means of the hydrological model were used for hydraulic modeling (one-phase, one-dimensional and steady flow) in a 4 km² urban stretch of the river bed. The delineation of surface areas affected by floods since 1918, as well as those analyzed subsequent to the geomorphological study, reveals a high degree of reliability in the delineation of the flooded areas with frequent recurrence intervals (<50 years). If we compare these flooded surface areas with the estimate obtained by the hydrological-hydraulic method we can see that the latter method overestimates the extent of the surface water by 144% for very frequent recurrence intervals (>10 years) and underestimates it as the recurrence interval increases, by up to 80% less floodplain for exceptional events (>500 years). Finally, a management map is put forth combining the most reliable results available by integrating both methods. Originally presented at the Sixth International Conference on Geomorphology.  相似文献   

Rain-induced debris and mudflow triggering factors assessment in the Santiago cordilleran foothills,Central Chile   总被引：1，自引：1，他引：0  

Sergio A. Sepúlveda  Cristóbal Padilla 《Natural Hazards》2008,47(2):201-215

Debris and mudflows are some of the main geological hazards in the mountain foothills of the Chilean capital city of Santiago. There, the risk of flows triggered in the basins of ravines that drain the range into the city increases with time due to the city growth. A multivariate statistical study based on the logistic regression method is presented. The model provides equations that allow the computation of combined meteorological triggering factors associated with a probability of rain-induced flow occurrence. Daily rainfall, accumulated rainfall and the snowfall level, traditionally considered as the relevant factors, are analysed for a 25-year period. The results show a strong relevance of the rainfall on the day of the flow event over the other factors. However, the relatively low probabilities returned for some real flow events suggest that the model does not capture all the significant variables and the problem is more complex than as it has been traditionally assumed, and further investigations are needed to develop predictive models of flow triggering.  相似文献