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21.
不整合运移通道类型及输导油气特征 总被引:12,自引:1,他引:11
在对不整合空间结构特征研究的基础上,提出了油气沿不整合运移的通道类型:宏观上,存在由不整合面之上底砾岩和不整合面之下半风化岩石两种高效运载层组合成的双运移通道型和单运移通道型两种通道类型;微观上,底砾岩连通孔隙、半风化岩石构造卸荷风化裂缝系统及溶蚀孔洞系统可作为油气运移的主要通道。通过对不整合面上、下岩石物性分析,认为半风化岩石“孔洞缝”系统较底砾岩连通孔隙有更高的输导油气的能力。研究结果表明,不同的运移通道类型具有不同的输导油气特征。在地史时期,构造裂缝系统和溶蚀孔洞系统一直是不整合输导油气的主要通道;对于软地层构成的不整合来说,开始应是卸荷、风化裂缝系统和底砾岩连通孔隙共同构成不整合输导油气的主要通道,当上覆沉积载荷达到一定程度后,主要是底砾岩连通孔隙起输导油气通道作用;对于脆硬地层构成的不整合来说,卸荷、风化裂缝系统和底砾岩连通孔隙一直是不整合输导油气的主要通道。 相似文献
22.
L. Moreno J. J. Durán M. A. Casermeiro J. R. Quintana Ma A. Fernández 《Environmental Geology》2008,54(3):465-477
Over a period of 4 years and 4 months, the geopurification installations at Dehesas de Guadix (Granada, Spain) were monitored
to determine the impact on soil and groundwater of the controlled discharge of urban wastewater, and also to identify the
best indicators of the entry of the recharged water into the aquifer. The installations are located in an area where the climate
is Mediterranean sub-arid, with an average precipitation of less than 287 mm/year, and a rate of evapotranspiration that is
almost three times greater. The system was controlled by determining the balance of majority nutrients and boron in the soil
and in the groundwater, both at the points affected directly by the wastewater discharge and at others. The quantity of mass
discharged was relatively large (COD 14,656 g/m2, NO3 85 g/m2, NO2 4 g/m2, NH4 2,425 g/m2, PO4 1,143 g/m2, K 1,531 g/m2, B 63 g/m2). It was observed that the elimination of nutrients within the soil (COD 97.5%, PO4 94.4%, K 59.17%, N
total 18.8%, B 12.69%) was very efficient except for the nitrogen, which nevertheless did not reach the groundwater, as it was
eliminated at deep levels of the unsaturated zone. Only 12.69% of the boron was removed, and appreciable, increasing amounts
of this element did reach the groundwater. Unexpectedly, none of the majority nutrients behaved as a reliable indicator of
the impact on groundwater; despite this, the boron and the bicarbonate did clearly reflect the arrival of the recharged water,
and are proposed as the best indicators. 相似文献
23.
Hydrogen sulfide (H2S) is known to catalyze thermochemical sulfate reduction (TSR) by hydrocarbons (HC), but the reaction mechanism remains unclear. To understand the mechanism of this catalytic reaction, a series of isothermal gold-tube hydrous pyrolysis experiments were conducted at 330 °C for 24 h under a constant confining pressure of 24.1 MPa. The reactants used were saturated HC (sulfur-free) and CaSO4 in the presence of variable H2S partial pressures at three different pH conditions. The experimental results showed that the in-situ pH of the aqueous solution (herein, in-situ pH refers to the calculated pH of aqueous solution under the experimental conditions) can significantly affect the rate of the TSR reaction. A substantial increase in the TSR reaction rate was recorded with a decrease in the in-situ pH value of the aqueous solution involved. A positive correlation between the rate of TSR and the initial partial pressure of H2S occurred under acidic conditions (at pH ∼3-3.5). However, sulfate reduction at pH ∼5.0 was undetectable even at high initial H2S concentrations. To investigate whether the reaction of H2S(aq) and occurs at pH ∼3, an additional series of isothermal hydrous pyrolysis experiments was conducted with CaSO4 and variable H2S partial pressures in the absence of HC at the same experimental temperature and pressure conditions. CaSO4 reduction was not measurable in the absence of paraffin even with high H2S pressure and acidic conditions. These experimental observations indicate that the formation of organosulfur intermediates from H2S reacting with hydrocarbons may play a significant role in sulfate reduction under our experimental conditions rather than the formation of elemental sulfur from H2S reacting with sulfate as has been suggested previously (Toland W. G. (1960) Oxidation of organic compounds with aqueous sulphate. J. Am. Chem. Soc.82, 1911-1916).Quantification of labile organosulfur compounds (LSC), such as thiols and sulfides, was performed on the products of the reaction of H2S and HC from a series of gold-tube non-isothermal hydrous pyrolysis experiments conducted at about pH 3 from 300 to 370 °C and a 0.1-°C/h heating rate. Incorporation of sulfur into HC resulted in an appreciable amount of thiol and sulfide formation. The rate of LSC formation positively correlated with the initial H2S pressure. Thus, we propose that the LSC produced from H2S reaction with HC are most likely the reactive intermediates for H2S initiation of sulfate reduction. We further propose a three-step reaction scheme of sulfate reduction by HC under reservoir conditions, and discuss the geological implications of our experimental findings with regard to the effect of formation water and oil chemistry, in particular LSC content. 相似文献
24.
Qisheng Ma 《Geochimica et cosmochimica acta》2008,72(22):5446-5456
Formation of the Carbon-13 (13C) and deuterium (D) doubly-substituted methane isotopologues (13CH3D) in natural gases is studied utilizing both first-principle quantum mechanism molecular calculation and direct FTIR laboratorial measurements of specifically synthesized high isotope concentration methane gas. For 13CH3D, the symmetrically breathing mode A0 emerges as IR-detectable attributed to the molecular symmetry lowering to C3v from Td of the non-isotopic methane (CH4), along with a large vibrational frequency shift from ∼3000 to ∼2250 cm−1. Our studies also indicate that the concentration of 13CH3D is dependent on the environmental temperature through isotope exchanges among methane isotopologues; and the Gibbs’ Free Energy difference due to Quantum Mechanics Zero-Point vibrational motions has the major contribution to this temperature dependency. Potential geologic applications of the 13CH3D measurement to natural gas exploration and assessments are also discussed. In order to detect the 13CH3D concentration change of each 50 °C in the natural gas system, a 10−9 resolution is desirable. Such a measurement could provide important add-on information to distinguish natural gas origin and distribution. 相似文献
25.
26.
Identifying China’s leading world city: a network approach 总被引:3,自引:0,他引:3
This paper reports our research on China’s world cities. Formal network analysis of air passenger linkages for recent years
among China’s most populous cities and among many of the world’s largest cities allows us to identify the country’s leading
world city from among the leading Mainland candidates, Beijing, Shanghai and Guangzhou. We theorize our findings about China’s
world cities in relation to both global forces (and China’s increasing entanglement with them) and the policies and actions
of the national state. We examine the national and global urban network through a longitudinal, two-level analysis of airline
passenger travel for four time points between about 1990 and 2005. We show that Beijing was China’s leading world city at
the beginning of the time period, a status it lost nationally in as early as 1995, and then globally 10 years later. On the
other hand Shanghai became China’s leading world city, and it acquired this status first nationally in 2000, and then globally
in 2005. The changing status of the Chinese capital corresponds to the country’s increasing involvement with the capitalist
world economy. Shanghai’s ascendance as the leading world city in China may indicate that global forces have come to play
an increasingly important role relative to that of the developmental state.
相似文献
Michael F. TimberlakeEmail: |
27.
28.
Li Miao Ruisong Xu Yueliang Ma Jinhong Xu Jie Wang Rui Cai Yu Chen 《Journal of Geochemical Exploration》2008,96(1):43-52
In the Hetai goldfield, Guangdong Province, China, samples including rocks, soils and leaves of four plants (Pinus massoniana, Rhodomyrms tomenlosa, D. linearis var. dichotoma and Embelia laeta) collected from the gold mineralization zone and the background area were analyzed for Au, Ag, Cu, Pb, Zn, Hg, As and physiological parameters. The objective of this investigation is to study the geochemical and biogeochemical characteristics of studied plants, aiming at biogeochemical methods in Au exploration. The goldfield region shows geochemical and biogeochemical anomalies. Abundances of Au in rocks, soils, plants and the leaf pigments in the mineralized area are much higher than those in the surrounding region. The plants display unhealthy physiological and ecological characteristics in the Hetai goldfield area. The cell structures of the goldfield plants were anomalous and aberrant, and there were many nano-metal particles diffused in mitochondria and chloroplasts. Macro- and microscopic evidences of the vegetation in the goldfield areas are distinctly different from the background regions. The strongly anomalies in responses to Au are profound in further geochemical and botanic exploration studies. 相似文献
29.
实验研究不同盐离子对水分子拉曼效应的影响 总被引:3,自引:0,他引:3
对流体包裹体中常见的几种盐水溶液进行了拉曼光谱分析.采用了频移参数描述水分子拉曼峰的形变强度,并讨论了频移参数与盐度之间的关系.实验分析结果表明,盐度越大,频移参数越大,水分子拉曼峰形变越大.对频移参数曲线斜率分析显示,盐类对水分子拉曼峰偏移程度影响的强弱顺序为NaCl>Na2SO4>NaHCO3>Na2CO3.讨论了不同阳离子和阴离子对水伸缩振动拉曼峰的影响,结果表明,高价阳离子的影响明显高于低价阳离子;而阴离子对水拉曼峰影响的强弱顺序初步确定为Cl-≈SO2-4->HCO-3>CO2-3≈NO-3. 相似文献
30.
运用源控含油气系统理论与综合分析技术,按成藏“层次分析”方法,通过对生、储、盖、圈(闭)静态要素及其内生、排、运、聚、散(失)动态过程的综合研究,对松辽盆地中央坳陷的三肇凹陷葡萄花油层成藏条件进行探讨,提出了以次级凹陷为中心、不同类型的油气聚集带紧邻并围绕次级凹陷最低部位呈环带状分布的大型凹陷内成藏模式,并进一步提出永乐次级凹陷中心及其三级聚油环带及徐家围子次级凹陷以西为"网式"运聚特征;在凹陷级成藏模式的指导下,通过对大面积密井网开发区综合解剖,提出三级构造带中单个的局部构造圈闭(群)、单个的(局部构造——)岩性圈闭(群)控油和成藏规律,为认识本区基本控油单元、油水分布规律、油气勘探及扩大新探区提供重要的理论依据。 相似文献