The activity of Hawaiian volcanoes during the years 1951–1956     

Gordon A. Macdonald 《Bulletin of Volcanology》1959,22(1):3-70

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Effect of wood waste dumping on organic matter in seawater and surficial sediments of Alberni Inlet,British Columbia     

Kazuo Iseki  Robie W. Macdonald  Chi Shing Wong 《Journal of Oceanography》1984,40(3):213-220

Distribution of particulate organic carbon (POC) and dissolved organic carbon (DOC) in seawater, and chemical composition of surficial sediments were studied in relation to pulpmill effluent and dumping of dredge spoil containing wood debris in Alberni Inlet, British Columbia, Canada. The maximum concentration of POC (377–584µg Cl^–1) was observed at the surface around the dumping area (5–7 km seaward of the inlet's head), and at the location immediately adjacent to the dump site POC was elevated throughout the water column (50 m). While POC tended to decrease in the surface layer for a distance of about 25km down-inlet, measureable effects of POC in the deeper water did not extend beyond 600m from the dump site. The dump site was conspicuous by the large maximum in C:N ratio (46.3). In contrast, DOC was observed to be highest (4.25mg Cl^–1) at the head of the inlet where pulpmill effluent was being discharged and a secondary maximum was found about 10km down-inlet from the dump site. The data suggest that a considerable proportion of the dredge spoil sinks rapidly near the dump site, probably within several hundred metres. Some of the spoil, perhaps low density wood debris may travel considerably further with the surface water where by leaching it may contribute to some extent to the surface DOC before sinking into deeper water.  相似文献   

The pathway and fate of the heavy metal mixture in Xiamen marine experiment enclosures     

Li Jinxi  Du Ronggui  Zhang Gongxun  C. S. Wong  R. W. Macdonal  W. K. Johnson 《海洋学报(英文版)》1990,9(3):389-403

The pathway and fate of heavy metals were studied in 10m3 enclosures at Xiamen Bay in 1985. The dissolved metals added are removed rather quickly during the first days, and their half-removal times ( t1/2) (d) are as follows: Pb 5. 4-5. 8, Hg 6. 7-14, Zn 11-22, Cu 16 - 29, and Cd 30-89. Zinc is transferred biologically to particles during phytoplankton bloom. The main Fate of added metals after 27 days is as follows; over 80% Cd and 60% Cu remain in dissolved phase, more than 60% Pb and 50% Hg transfer to settling settlement, while Zn is equally distributed in dissolved phase and settling settlement. The wall uptake is less than 2% of the total metals added. Organic materials play an essential role in the partition and the transfer of heavy metals in water column. Terrigenous and autochthonous particles show different affinities to different metals. Most heavy metals associate weakly with zooplankton. The Binding of Cd, Pb, Zn and Cu to the particles shows distinctive features related to the diagenetic  相似文献   

Contaminants in the arctic marine environment: priorities for protection   总被引：1，自引：0，他引：1  

Macdonald  R. W.; Bewers  J. M. 《ICES Journal of Marine Science》1996,53(3):537-563

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Fine scale study of a small overlapping spreading center system at 12°54′ N on the East Pacific Rise     

Lisa Antrim  Jean-Christophe Sempere  Ken C. Macdonald  E. N. Spiess 《Marine Geophysical Researches》1988,9(2):115-130

Overlapping spreading centers (OSCs) are a type of ridge axis discontinuity found along intermediate and fast spreading centers. The ridges at these locations overlap and curve towards each other. and are separated by an elongate overlap basin. A high resolution Deep-Tow survey was conducted over the 12°54 N OSC (offset 1.6 km) on the East Pacific Rise in order to study the structure of a small OSC on a fine scale. A detailed tectonic study and Deep-Tow 3-D magnetic inversion were performed on the data. Towards the tips of both limbs, the apparent age of lava flows increases, the density of exposed faults and fissures increases, and the axial graben loses definition and disappears. No active hydrothermal vents were detected in the area. These observations suggest that the magmatic budget steadily decreases along axis approaching and OSC, even where the offset is small. In contrast with OSCs which have a large offset (>5 km), the 3-D magnetic inversion solution for this OSC produced no evidence for highly magnetized areas near the tip of either spreading center.  相似文献   

New constraints on the width of the zone of active faulting on the East Pacific Rise 8° 30′ N – 10° 00′ N from Sea Beam Bathymetry and SeaMARC II Side-scan Sonar     

Crowder  Lisa K.  Macdonald  Ken C. 《Marine Geophysical Researches》2000,21(6):513-527

Sea Beam bathymetry and SeaMARC II side-scan sonar data are used to constrain the width of the zone of active faulting (plate boundary zone) to be 90 km (0.8 Ma) wide along the East Pacific Rise 8° 30N – 10° 00N. Fault scarps, identified on the basis of contoured, shaded relief and slope intensity maps of bathymetry, are measured. These scarp measurements, used in conjunction with data from a separate near-axis study, show that both inward- and outward-facing fault scarps increase in height away from the ridge axis, reaching average heights of 100 m at 0.8±0.2 Ma, 45±10 km from the ridge axis. Beyond this distance, there is no significant increase in scarp height. Earlier studies had suggested that the width of the zone of active faulting for outward-dipping faults might be significantly narrower than for inward-dipping faults. A lower crustal decoupling zone between brittle crust and strong upper mantle is predicted to exist out to 20–200 km from the ridge based on previously published lithospheric models. Such a decoupling zone may explain why outward-dipping faults continue to be active as far off-axis as inward-dipping faults. If the width of the zone of active faulting is controlled by the width of a lower crustal decoupling zone, our observations predict an 90 km wide decoupling zone in the lower oceanic crust at this location.  相似文献   

Detailed study of the Brunhes/Matuyama reversal boundary on the east Pacific rise at 19°30′ S: Implications for crustal emplacement processes at an ultra fast spreading center     

Jean-Christophe Sempere  Ken C. Macdonald  Stephen P. Miller  Loren Shure 《Marine Geophysical Researches》1987,9(1):1-23

We have conducted the first detailed survey of the recording of a geomagnetic reversal at an ultra-fast spreading center. The survey straddles the Brunhes/Matuyama reversal boundary at 19°30 S on the east flank of the East Pacific Rise (EPR), which spreads at the half rate of 82 mm yr^-1. In the vicinity of the reversal boundary, we performed a three-dimensional inversion of the surface magnetic field and two-dimensional inversions of several near-bottom profiles including the effects of bathymetry. The surface inversion solution shows that the polarity transition is sharp and linear, and less than 3–4 km wide. These values constitute an upper bound because the interpretation of marine magnetic anomalies observed at the sea surface is limited to wavelengths greater than 3–4 km. The polarity transition width, which represents the distance over which 90% of the change in polarity occurs, is narrow (1.5–2.1 km) as measured on individual 2-D inversion profiles of near-bottom data. This suggests a crustal zone of accretion only 3.0–4.2 km wide. Our method offers little control on accretionary processes below layer 2B because the pillow and the dike layers in young oceanic crust are by far the most significant contributors to the generation of marine magnetic anomalies. The Deep-Tow instrument package was used to determine in situ the polarity of individual volcanoes and fault scarps in the same area. We were able to make 96 in situ polarity determinations which allowed us to locate the scafloor transition boundary which separates positively and negatively magnetized lava flows. The shift between the inversion transition boundary and the seafloor transition boundary can be used to obtain an estimate of the width of the neovolcanic zone of 4–10 km. This width is significantly larger than the present width of the neovolcanic zone at 19°30 S as documented from near-bottom bathymetric and photographic data (Bicknell et al., 1987), and also larger than the width of the neovolcanic zone at 21° N on the EPR as inferred by the three-dimensional inversion of near-bottom magnetic data (Macdonald et al., 1983). The eruption of positively magnetized lava flows over negatively magnetized crust from the numerous volcanoes present in the survey area and episodic flooding of the flanks of the ridge axis by extensive outpourings of lava erupting from a particularly robust magma chamber may result in a widened neovolcanic zone. We studied the relationship between spreading rate and polarity transition widths obtained from 2-D inversions of the near-bottom magnetic field over various spreading centers. The mean transition width corrected for the time necessary for the reversal to occur decreases with increasing spreading rate but our data set is still too sparse to draw firm conclusions from these observations. Perhaps more interesting is the fact that the range of the measured transition widths also decreases with spreading rate. In the light of these results, we propose a new model for the spreading rate dependency of polarity transition widths. At slow spreading centers, the zone of dike injection is narrow but the locus of crustal accretion is prone to small lateral shifts depending on the availability of magmatic sources, and the resulting polarity transition widths can be narrow or wide. At intermediate spreading centers, the zone of crustal accretion is narrow and does not shift laterally, which leads to narrower transition widths on the average than at slow spreading centers. An intermediate, or even a slow spreading center, may behave like a fast or hot-spot dominated ridge for short periods of time when its magmatic budget is increased due to melting events in the upper mantle. At fast spreading centers, the zone of dike injection is narrow, but the large magmatic budget of fast spreading centers may result in occasional extensive flows less than a few tens of meters thick from the axis and off-axis volcanic cones. These thin flows will not significantly contribute to the polarity transition widths, which remain narrow, but they may greatly increase the width of the neovolcanic zone. Finally the gabbro layer in the lower section of oceanic crust may also contribute to the observed polarity transition widths but this contribution will only become significant in older oceanic crust (50–100 m.y.).  相似文献   

Investigation of faulting and abyssal hill formation on the flanks of the East Pacific Rise (21°N) using ALVIN     

Ken C. Macdonald  Bruce P. Luyendyk 《Marine Geophysical Researches》1985,7(4):515-535

A wealth of geologic information has been collected during studies of the Matuyama/Brunhes magnetic reversal boundary on the East Pacific Rise at 21°N. Five ALVIN and two CYANA dives, and a series of deep-tow traverses show that abyssal hills in this region of the Pacific are created near the spreading axis by inward dipping normal faulting and by back-tilting of these fault blocks. Outward dipping faults occur but are of less importance in the creation of relief. Tectonic disruption of the crust, particularly through tilting, is less pronounced than in the Atlantic. Small volcanoes approximately 50 m high and 400 m wide are common on the abyssal hills. A significant number of the volcanoes may have split apart at the spreading axis attesting to the narrowness of the crustal accretion zone on the East Pacific Rise. Active faulting is restricted to less than 10 to 12 km off-axis, although minor recent faulting may have been detected 23 km off-axis. Crustal sections exposed by faulting reveal that massive lava flows and sheet flows are common in the upper portion of oceanic layer two, but are less abundant than pillow lavas.  相似文献   

A 1998–1992 comparison of inorganic carbon and its transport across 24.5°N in the Atlantic     

A. M. Macdonald  M. O. Baringer  R. Wanninkhof  K. Lee  D. W. R. Wallace   《Deep Sea Research Part II: Topical Studies in Oceanography》2003,50(22-26):3041

In January and February 1998, when an unprecedented fourth repetition of the zonal hydrographic transect at 24.5°N in the Atlantic was undertaken, carbon measurements were obtained for the second time in less than a decade. The field of total carbon along this section is compared to that provided by 1992 cruise which followed a similar path (albeit in a different season). Consistent with the increase in atmospheric carbon levels, an increase in anthropogenic carbon concentrations of 8±3 μmolkg⁻¹ was found in the surface layers. Using an inverse analysis to determine estimates of absolute velocity, the flux of inorganic carbon across 24.5° is estimated to be −0.74±0.91 and −1.31±0.99 PgCyr⁻¹ southward in 1998 and 1992, respectively. Estimates of total inorganic carbon flux depend strongly upon the estimated mass transport, particularly of the Deep Western Boundary Current. The 1998 estimate reduces the large regional divergence in the meridional carbon transport suggested by previous studies and brings into question the idea that the tropical Atlantic constantly outgasses carbon, while the subpolar Atlantic sequesters it. Uncertainty in the carbon transports themselves, dominated by the uncertainty in the total mass transport estimates, are a hindrance to determining the “true” picture.The flux of anthropogenic carbon (C_ANTH) across the two transects is estimated as northward at 0.20±0.08 and 0.17±0.06 PgCyr⁻¹ for the 1998 and 1992 sections, respectively. The net transport of C_ANTH across 24.5°N is strongly affected by the difference in concentrations between the northward flowing shallow Florida Current and the mass balancing, interior return flow. The net northward transport of C_ANTH is opposite the net flow of total carbon and suggests, as has been found by others, that the pre-industrial southward transport of carbon within the Atlantic was stronger than it is today. Combining these flux results with estimates of atmospheric and riverine inorganic carbon input, it is determined that today's oceanic carbon system differs from the pre-industrial system in that today there is an uptake of anthropogenic carbon to the south that is advected northward and stored within the North Atlantic basin.  相似文献   

Peralkaline syenite autoliths from Kilombe volcano, Kenya Rift Valley: Evidence for subvolcanic interaction with carbonatitic fluids     

Filippo Ridolfi  Alberto Renzulli  Ray Macdonald  Brian G.J. Upton 《Lithos》2006,91(1-4):373-392

Mineral chemistry, textures and geochemistry of syenite autoliths from Kilombe volcano indicate that they crystallized in the upper parts of a magma chamber from peralkaline trachytic magmas that compositionally straddle the alkali feldspar join in the “residuum system” (ne = 0–1.03; qz = 0–0.77). Mineral reaction and/or overgrowth processes were responsible for the replacement of (i) Mg–hedenbergite by aegirine–augite, Ca–aegirine and/or aegirine, (ii) fayalite by amphiboles, and (iii) magnetite by aenigmatite. Ti–magnetite in silica-saturated syenites generally shows ilmenite exsolution, partly promoted by circulating fluids.

By contrast, the Fe–Ti oxides in the silica-undersaturated (sodalite-bearing) syenites show no signs of deuteric alteration. These syenites were ejected shortly after completion of crystallization. Ilmenite–magnetite equilibria indicate fO₂ between − 19.5 and − 23.1 log units (T 679–578 °C), slightly below the FMQ buffer. The subsequent crystallization of aenigmatite and Na-rich pyroxenes suggests an increase in the oxidation state of the late-magmatic liquids and implies the influence of post-magmatic fluids.

Irrespective of silica saturation, the syenites can be divided into (1) “normal” syenites, characterized by Ce/Ce ratios between 0.83 and 0.99 and (2) Ce-anomalous syenites, showing distinct negative Ce-anomalies (Ce/Ce 0.77–0.24). “Normal” silica-saturated syenites evolved towards pantelleritic trachyte. The Ce-anomalous syenites are relatively depleted in Zr, Hf, Th, Nb and Ta but, with the exception of Ce, are significantly enriched in REE.

The silica-saturated syenites contain REE–fluorcarbonates (synchysite-bastnaesite series) with negative Ce-anomalies (Ce/Ce 0.4–0.8, mean 0.6), corroded monazite group minerals with LREE-rich patches, and hydrated, Fe- and P-rich phyllosilicates. Each of these is inferred to be of non-magmatic origin. Fractures in feldspars and pyroxenes contain Pb-, REE- and Mn-rich cryptocrystalline or amorphous material. The monazite minerals are characterized by the most prominent negative Ce-anomalies (Ce/Ce_mean = 0.5), and in the most altered and Ca-rich areas (depleted in REE), Ce/Ce is less than 0.2.

It is inferred that carbonatitic fluids rich in F, Na and lanthanides but depleted in Ce by fractional crystallization of cerian pyrochlore, percolated into the subvolcanic system and interacted with the syenites at the thermal boundary layers of the magma chamber, during and shortly after their crystallization.

Chevkinite–(Ce), pyrochlore, monazite and synchysite-bastnaesite, occurring as accessory minerals, have been found for the first time at Kilombe together with eudialyte, nacareniobsite–(Ce) and thorite. These latter represent new mineral occurrences in Kenya.  相似文献