Distribution,characteristics and potential impacts of chromophoric dissolved organic matter (CDOM) in Hudson Strait and Hudson Bay,Canada     

Mats A. Granskog  Robie W. Macdonald  C.-J. Mundy  David G. Barber 《Continental Shelf Research》2007

The characteristics of chromophoric dissolved organic matter (CDOM) were studied in Hudson Bay and Hudson Strait in the Canadian Arctic. Hudson Bay receives a disproportionately large influx of river runoff. With high dissolved organic matter (DOM) concentrations in Arctic rivers the influence of CDOM on coastal and ocean systems can be significant, yet the distribution, characteristics and potential consequences of CDOM in these waters remain unknown. We collected 470 discrete water samples in offshore, coastal, estuarine and river waters in the region during September and October 2005. Mixing of CDOM appeared conservative with salinity, although regional differences exist due to variable DOM composition in the rivers discharging to the Bay and the presence of sea-ice melt, which has low CDOM concentrations and low salinity. There were higher concentrations of CDOM in Hudson Bay, especially in coastal waters with salinities <28$<28$, due to river runoff. Using CDOM composition of water masses as a tracer for the freshwater components revealed that river runoff is largely constrained to nearshore waters in Hudson Bay, while sea-ice melt is distributed more evenly in the Bay. Strong inshore–offshore gradients in the bio-optical properties of the surface waters in the Hudson Bay cause large variation in penetration of ultraviolet radiation and the photic depth within the bay, potentially controlling the vertical distribution of biomass and occurrence of deep chlorophyll maxima which are prevalent only in the more transparent offshore waters of the bay. The CDOM distribution and associated photoprocesses may influence the thermodynamics and stratification of the coastal waters, through trapping of radiant heating within the top few meters of the water column. Photoproduction of biologically labile substrates from CDOM could potentially stimulate the growth of biomass in Hudson Bay coastal waters. Further studies are needed to investigate the importance of terrestrial DOM in the Hudson Bay region, and the impact of hydroelectric development and climate change on these processes.  相似文献   

Hydrothermal alteration of a chevkinite-group mineral to a bastnäsite-(Ce)-ilmenite- columbite-(Fe) assemblage: interaction with a F-, CO2-rich fluid     

Ray Macdonald  Bogusław Bagiński  Pavel M. Kartashov  Dmitry Zozulya  Piotr Dzierżanowski  Petras Jokubauskas 《Mineralogy and Petrology》2015,109(6):659-678

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Alkane and PAH biomarkers as tracers of terrigenous organic carbon in Arctic Ocean sediments   总被引：2，自引：0，他引：2  

Mark B. Yunker  Robie W. Macdonald  Lloyd R. Snowdon  Brian R. Fowler 《Organic Geochemistry》2011,42(9):1109-1146

We present the first sedimentary biomarker study encompassing the entire Arctic Ocean. A large data set of organic markers for terrigenous, petroleum and combustion inputs [alkanes, hopanes and steranes, parent and alkyl polycyclic aromatic hydrocarbons (PAHs)] is examined for patterns in space and time using principal components analysis (PCA) and partial least squares (PLS). Biomarker patterns reveal the central Arctic Ocean basin sediments to be compositionally distinct from those of the Mackenzie River/Beaufort Sea and Barents Sea, but similar to those of the Laptev Sea. PAH distributions reflected in PAH ratios and PCA projections demonstrate that Arctic Ocean sediment is dominated by natural inputs to the extent that anthropogenic combustion PAHs are not significant. We find only modest changes between the glacial and post-glacial sediments for atmospherically transported hydrocarbon biomarkers, while particle associated biomarkers were captured strongly at basin edges during the glacial period, and much more evenly transported across basins during the post-glacial period. The orders of magnitude decreases in particle associated petrogenic alkanes and PAHs in central basins during glacial times, coupled with the uniformity of most petrogenic biomarker parameters for most basin and shelf locations, reflect a massive reduction in ice transport that makes the margins the most likely source of petrogenic material for the Pleistocene/Holocene central Arctic basins. The proximity of large coal deposits of various maturity levels along the Lena River, the overlap in PAH and biomarker composition of the Laptev Sea and surficial sediments from the central Arctic Ocean and the location of the Laptev Sea at the origin of the main Transpolar Drift all point to eroded coals from the Lena River/Laptev Sea as the likely source of petrogenic hydrocarbons to the central Arctic Ocean. The ubiquitous presence of allochthonous coal in Arctic Ocean surface sediments provides a major constraint on the use of petrogenic biomarkers to infer the presence of subsurface petroleum reserves.  相似文献   

Beyond the Fertile Crescent: Late Paleolithic and Neolithic Communities of the Jordanian Steppe. The Azraq Basin Project,Vol. 1. Andrew N. Garrard and Brian Byrd. 2013. Levant Supplementary Series 13, Oxbow Books,Oxford, 448 pp., B&W,ISBN 978‐1‐842‐17833‐1, £45 (hardcover)     

Danielle A. Macdonald 《Geoarchaeology》2015,30(5):452-453

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Spatial and temporal variability of flood seasonality in Wales     

Neil Macdonald  Ian D. Phillips  Gareth Mayle 《水文研究》2010,24(13):1806-1820

High‐magnitude floods across Europe within the last decade have resulted in the widespread reassessment of flood risk; this coupled with the introduction of the Water Framework Directive (2000) has increased the need for a detailed understanding of seasonal variability in flood magnitude and frequency. Mean day of flood (MDF) and flood seasonality were calculated for Wales using 30 years of gauged river‐flow records (1973–2002). Noticeable regional variations in timing and length of flood season are evident, with flooding occurring earlier in small catchments draining higher elevations in north and mid‐west Wales. Low‐altitude regions in West Wales exposed to westerly winds experience flooding during October–January, while large eastern draining catchments experience later flooding (January–February). In the northeast and mid‐east regions December–January months experience the greatest number of floods, while the southeast has a slightly longer flood season (December–February), with a noticeable increase in January floods. Patterns obtained from MDF data demonstrate their effectiveness and use in analysing regional patterns in flood seasonality, but catchment‐specific determinants, e.g. catchment wetness, size and precipitation regime are important factors in flood seasonality. Relatively strong correlations between precipitation and flood activity are evident in Wales, with a poorer relationship between flooding and weather types and the North Atlantic Oscillation (NAO). Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

TOWARDS AN ULTIMATE SOLUTION FOR BRITISH AERIAL TRIANGULATION     

A. S. Macdonald 《The Photogrammetric Record》1975,8(46):495-501

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Variations in the architecture of hydraulic‐jump bar complexes on non‐eroding beds     

Robert G. Macdonald  Jan Alexander  John C. Bacon  Mark J. Cooker 《Sedimentology》2013,60(5):1291-1312

Sediment accumulation downstream of hydraulic jumps can occur in many settings but the architectures of such deposits are poorly documented. Here, three flume runs were used to examine the influence of sediment grain size and transport rate on the characteristics of hydraulic‐jump unit bars. In one of these runs six hydraulic‐jump unit bars formed a hydraulic‐jump bar complex. In another, the same sediment was supplied more quickly and only two unit bars formed. In the third run with the same sediment supply rate, but different grain size, only one large unit bar formed. All unit bars developed in a similar way but their size and internal architecture differed; they all resulted from a reduction in sediment transport capacity at the transition from supercritical flow to subcritical flow in the hydraulic jump. After initial onset of sedimentation and unit bar formation, generation of subsequent unit bars may be: (i) related to small changes in sediment flux; and (ii) independent of changes in the hydraulic jump. Continued sedimentation caused changes from oscillating to weak hydraulic jumps and hydraulic‐jump unit bars formed in both circumstances. The flow of water and suspended sediment becomes shallower over the lee of the bar complex. This leads to flow acceleration and a return to supercritical flow conditions. In turn, a chain of such features can form and generate a chute and pool bed morphology. There is an inherent upper size limit to a hydraulic‐jump bar complex due to the changing flow conditions over the growing deposit as the water above it becomes shallower. There is also an amplitude minimum for the development of foresets and subsequent unit bar growth. Hydraulic‐jump unit bars have architectures that should be recognizable in the rock record and because their size is constrained by the flow conditions, their identification should be useful for interpreting palaeoenvironment.  相似文献   

The effects of wastewater effluent and river discharge on benthic heterotrophic production,organic biomass and respiration in marine coastal sediments     

B. Burd  T. Macdonald  S. Bertold 《Marine pollution bulletin》2013

We examine effects of high river particulate flux and municipal wastewater effluent on heterotrophic organic carbon cycling in coastal subtidal sediments. Heterotrophic production was a predictable (r² = 0.95) proportion (56%) of oxidized OC flux and strongly correlated with organic/inorganic flux. Consistent growth efficiencies (36%) occurred at all stations. Organic biomass was correlated with total, OC and buried OC fluxes, but not oxidized OC flux. Near the river, production was modest and biomass high, resulting in low P/B. Outfall deposition resulted in depleted biomass and high bacterial production, resulting in the highest P/B. These patterns explain why this region is production “saturated”. The δ¹⁵N in outfall effluent, sediments and dominant taxa provided insight into where, and which types of organisms feed directly on fresh outfall particulates, on older, refractory material buried in sediments, or utilize chemosynthetic symbiotic bacteria. Results are discussed in the context of declining bottom oxygen conditions along the coast.  相似文献   

Low Ozone Episodes at Amphitrite Point Marine Boundary Layer Observatory,British Columbia,Canada     

Ian McKendry  Eric Christensen  Corinne Schiller  Roxanne Vingarzan  Anne Marie Macdonald  Yimei Li 《大气与海洋》2014,52(3):271-280

At Amphitrite Point, ozone (O₃) mixing ratios are observed to drop steadily to 5–15?ppb over a period of 12 hours or less with a frequency approaching one event per week (with highest frequencies occurring in summer and fall). Analysis of 47 such O₃ depletion events reveals that low O₃ episodes are a predominantly nocturnal phenomenon associated with anticyclonic conditions characterized by light onshore or alongshore winds and an absence of fog and mist. Back-trajectories show air carried to the Amphitrite Point Observatory (APO) during depletion events remains in the marine boundary layer and is not brought to the surface from aloft. There is no strong correlation with other “criteria” pollutants (CO, NO_x, SO₂, PM_2.5) that might be indicative of a mechanism for O₃ destruction linked to human, terrestrial, or marine pollutant sources. However, CO₂ mixing ratios are observed to increase, coincident with O₃ depletion. Together, these results point to a natural marine boundary layer phenomenon in which O₃ destruction dominates O₃ production and/or replenishment by vertical mixing. While there are several candidate mechanisms, the conditions for O₃ depletion (and CO₂ buildup) to occur are set by meteorology and, in particular, development of a stable marine boundary layer in which vertical mixing is suppressed. Support for this interpretation is provided by simultaneous increases in CO₂ in the stable marine boundary that are indicative of an important role played by marine biogenic processes (respiration). Future research should be directed at elucidating the chemical mechanisms responsible for O₃ destruction in the coastal zone, which means that there would be a need for a much broader range of measurements at APO (including halogenated species) as well as offshore measurements of both chemical and marine boundary layer meteorological variables.  相似文献   

Fluorite stability in silicic magmas   总被引：6，自引：1，他引：5  

B.?ScailletEmail author  R.?Macdonald 《Contributions to Mineralogy and Petrology》2004,147(3):319-329

Recent experimental evidence is used to assess the conditions under which fluorite forms an early crystallising phase in silicic magmas. Fluorite solubility primarily depends on the (Na + K)/Al balance in the coexisting silicic melt, reaching a minimum in metaluminous melts. It can display reaction relationships with topaz and titanite, depending on changes in melt composition during crystallisation. An empirical model of fluorite stability in Ca-poor peralkaline rhyolite melts is derived and applied to selected rocks: At the F contents preserved in most silicic rocks, fluorite should normally appear late in the crystallisation sequence, in agreement with petrographic observations. During fluid-absent crustal anatexis, fluorite should melt at a relatively early stage and restitic fluorite is unlikely to persist during prolonged melting. Fluorite may, however, exert a decisive control on the alkali/alumina balance of sub-aluminous anatectic melts and it can affect the liquid line of descent of silicic magmas once extracted from source.Editorial responsibility: J. Hoefs  相似文献