An automated precise Winkler titration for determining dissolved oxygen on board ship   总被引：1，自引：0，他引：1  

Ken Furuya  Kazutoshi Harada 《Journal of Oceanography》1995,51(3):375-383

An automated titration for the Winkler method is presented for measuring primary productivity in the ocean. The system is based on a microcomputer-controlled titration with potentiometric endpoint detection. By the use of 0.005-N sodium thiosulfate as a titrant and a program designed to shorten the time for measuring, the method achieves a precision of 0.04% coefficient of variation with a range of 0.01 to 0.10% for six replicates of samples at oxygen concentration of 70 to 250 M. It takes about four to five minutes to measure one sample.  相似文献   

Comparison of organotin accumulation in the masu salmon Oncorhynchus masou accompanying migratory histories     

Madoka Ohji  Takaomi Arai  Nobuyuki Miyazaki 《Estuarine, Coastal and Shelf Science》2007,72(4):721-731

In order to examine the accumulation pattern of organotin compounds (OTs) accompanying the migration pattern in diadromous fish, tributyltin (TBT) and triphenyltin (TPT) compounds and their derivatives were determined in the liver, muscle, gill, and ovary tissues of both sea-run and freshwater-resident masu salmon, which are of the same species, Oncorhynchus masou. Their migratory histories were estimated using strontium (Sr) and calcium (Ca) analysis in the otolith. A significant difference in the mean Sr:Ca ratio from the core to the edge of the otolith was found between sea-run and freshwater-resident masu salmon. The TBT concentration in the liver was significantly higher than that in the other tissues in both sea-run and freshwater-resident fishes. In sea-run masu salmon, the TBT concentrations in all tissues except for the ovary were significantly higher than in those of freshwater-resident individuals. In the sea-run type, the percentage of TBT was higher than that of the freshwater-resident type. The TPT concentration in the liver of the sea-run type was also significantly higher than that in the other tissues, while that in the gill of the freshwater-resident type was significantly higher than that in the other tissues except for the ovary. The TPT concentrations found in the liver and muscle of the sea-run type were significantly higher than those in the freshwater-resident type, whereas the values of the gill in the sea-run type were significantly lower than those in the freshwater-resident fish examined. The percentage of TPT in the sea-run type was higher than that of the freshwater-resident type. These results suggest that the sea-run O. masou has a higher ecological risk of TBT and TPT exposure than the freshwater-residents during their life history.  相似文献   

Silicon flux and distribution of biogenic silica in deep-sea sediments in the western North Pacific Ocean     

Yoko Shibamoto  Koh Harada 《Deep Sea Research Part I: Oceanographic Research Papers》2010,57(2):163-174

We investigated biogenic silica, several biological components, and silicate in pore-water in the abyssal sediment to determine silicon flux of western North Pacific during several cruises. The surficial sediment biogenic silica content was high at high latitudes with the boundary running along the Kuroshio Extension, and maximum values (exceeding 20%) were found in the Oyashio region. In the subtropical region to the south, most stations showed less than 5% biogenic silica content. This distribution pattern reflected primary production and ocean currents in the surface layer very well. Pore-water samples were collected from 4 stations along the east coast of Japan. The highest asymptotic silicic acid concentration (670 μmol L^?1) in pore-water was observed at the junction of Kuroshio and Oyashio, followed by samples from the Oyashio region. It is at the southern station that the lowest value (450 μmol L^?1) was observed, and the primary production is low under the influence of Kuroshio there. The diffusive flux followed the same geographic trend as the asymptotic silicic acid concentrations did, ranging 77–389 mmol m^?2 yr ^?1. Multiple sampling of pore-water was conducted throughout the year at one station at high latitude. The average annual biogenic silica rain flux observed using sediment traps was 373 mmol m^?2 yr^?1; the diffusive flux and burial flux at the sediment–water interface were 305 and 9 mmol m^?2 yr^?1, respectively. We concluded that most of the settling silica particles dissolved and diffused at the sediment–water interface and approximately 3% only were preserved in this area. In addition, the obvious time lag observed between the peak rain flux and the maximum diffusive flux suggested that primary production in the surface layer has a great influence on the sedimentation environment of abyssal western North Pacific. These transitions of Si flux at the sediment–water interface were considerably greater in northwestern North Pacific than in southwestern North Pacific. In addition, a station in the Philippine Sea indicated high biogenic silica content because of Ethmodiscus ooze, which are scattered randomly on the sea floor in the subtropical region.  相似文献   

The role of resource recycling     

Taneomi Harada 《Natural Resources Research》1993,2(3):247-255

Resource recycling reduces the amount of waste discharged into the global environment. The waste reduction achieved by thorough recycling is substantial. Recycling is thus an inseparable part of global environmental protection.We human beings have used mineral resources since the birth of our species. The quantities and increasingly complex forms in which mineral resources have been used at different times in our prehistory and history serve as indices of civilization's advancement. But on the eve of the 21st century, environmental pollution and global warming stemming from spiraling resource and energy consumption pose serious dilemmas for humanity. The rapidity with which our resource consumption has increased approximates exponential growth.The worsening condition of the earth's environment because of massive resource and energy consumption is the result of activity at many stages of production, from the mining of mineral resources to the manufacture of finished products; the culmination of the process is the disposal of products as waste after their use. As we shall see from examples given in this paper, efforts are being made to solve this problem through recycling; but in many areas the problems remain incompletely solved or unsolved altogether.  相似文献   

Chronic effects of tributyltin on the caprellid amphipod Caprella danilevskii   总被引：2，自引：0，他引：2  

Ohji M  Arai T  Miyazaki N 《Marine pollution bulletin》2003,46(10):1263-1272

In order to examine the biological effects by TBT exposure, experiments involving the exposure of five levels of TBT concentrations (0, 10, 100, 1000 and 10,000 ngl(-1)) were conducted on the caprellid amphipod Caprella danilevskii, over a generation after hatching. Marked delays in growth and molting during the early developmental stage and maturation were found in both 100 and 1000 ng TBTCl l(-1) concentrations in spite of the sex. All specimens died in 10,000 ng TBTCl l(-1) within 4 days after hatching. Inhibition of maturation and reproduction such as delaying in the achievement of maturity and a decrease in the number of juveniles hatched was apparent in 10 and 100 ng TBTCl l(-1) concentrations. Furthermore, brood loss, and failure in egg formation and hatching were observed as the TBT concentration became higher. No significant changes in sex ratio were seen at any of the TBT exposure levels during hatching and maturation in the present study. This phenomenon was different from a previous study in which the proportion of females was increased with an increase in TBT concentrations in the embryonic exposure experiment. This suggests that sex disturbance is induced during the embryonic stage of the species. A drastic decrease in survival rate was observed at 10 ng TBTCl l(-1) (25%) which corresponds to the mean level in coastal waters. Therefore, the present encountering ambient TBT concentration may influence populations of C. danilevskii in the coastal environment.  相似文献   

Latitudinal Distribution of CO2 Fugacity along 175°E in the North Pacific in 1992–1996     

Tomonori Watai  Koh Harada  Kouichi Gotoh  Shohei Murayama  Takakiyo Nakazawa 《Journal of Oceanography》1999,55(6):655-665

In order to examine latitudinal distribution and seasonal change of the surface oceanic fCO₂, we analyzed the data obtained in the North Pacific along 175°E during the NOPACCS cruises in spring and summer of 1992–1996. Except for around the equator where the fCO₂ was significantly affected by the upwelling of deep water, the latitudinal distribution of fCO₂ showed distinctive seasonal variation. In the spring, the fCO₂ decreased and then increased going southward with the minimum value of about 300 µatm around 35°N, while in the summer, the fCO₂ displayed high variability, showing minimum and maximum values at latitudes of around 44° and 35°N, respectively. It was also found that the fCO₂ was well correlated with the SST, but the relationship between the two was different for different hydrographic regions. In the subpolar gyre, the frontal regions between the Water-Mass Front and the Kuroshio bifurcation front, and between the Kuroshio bifurcation front and the Kuroshio Extension current, SST, DIC and TA influenced the seasonal fCO₂ change through seasonally-dependent biological activities and vertical mixing and stratification of seawater. In the central subtropical gyre and the North Equatorial current, the seasonal fCO₂ change was found to be produced basically by changes in SST and DIC. The summertime oceanic fCO₂ generally increased with time over the period covered by this study, but the increased rate was clearly higher than those expected from other measurements in the western North Pacific.  相似文献   

The effect of nitrogen limitation on cellular DMSP and DMS release in marine phytoplankton: climate feedback implications     

William G. Sunda  Rance Hardison  Ronald P. Kiene  Eva Bucciarelli  Hyakubun Harada 《Aquatic Sciences - Research Across Boundaries》2007,69(3):341-351

  相似文献   

Investigation of cutting methods for small samples of Hayabusa and future sample return missions     

Masayuki Uesugi  Ryo Noguchi  Tooru Matsumoto  Junya Matsuno  Takashi Nagano  Akira Tsuchiyama  Shigenori Harada  Kaori Yokoyama  Yoshiaki Yodo  Noboru Takeda  Toru Yada  Shogo Yakame  Yuzuru Karouji  Yukihiro Ishibashi  Masanao Abe  Tatsuaki Okada  Akio Fujimura  Mitsuru Ebihara  Fumio Kitajima  Keisuke Nagao  Tomoki Nakamura  Hiroshi Naraoka  Takaaki Noguchi  Ryuji Okazaki  Hisayoshi Yurimoto 《Meteoritics & planetary science》2014,49(7):1186-1201

We report the investigation of cutting methods for Hayabusa samples. The purpose of our study is to explore the possibility of applying multiple analyses to a single particle effectively. We investigated the cutting performance of a blade dicing saw, laser, focused ion beam (FIB), and physical breaking by microindenter. Cutting performance was examined by estimating the aspect ratio of the cut slit, i.e., depth over width of the slit. We also investigated the possible contamination and sample damage by cutting. The result of the investigation shows that we can cut the samples from <50 μm to 500 μm using those methods with aspect ratios from 10 to 20, although they would introduce some contamination or damage to the samples. Our investigations also provide an important basis for the analysis of samples obtained by future sample return missions.  相似文献   

Petromagnetic parameters of bottom sediments as indicators of the climatic and environmental changes in the central zone of the Sea of Okhotsk during the last 350 kyr     

M.I. Malakhov  S.A. Gorbarenko  G.Yu. Malakhova  N. Harada  Yu.P. Vasilenko  A.A. Bosin  E.L. Gol'dberg  A.N. Derkachev 《Russian Geology and Geophysics》2009,50(11):973-982

Bottom sediments from the central zone of the Sea of Okhotsk were preliminarily dated. The petromagnetic parameters of two groups of samples formed at cold and warm climatic stages were studied. Warm oxygen isotopic stages and substages were characterized by the coexistence of pseudo-single-domain allogenic magnetite and predominant magnetite and greigite (pyrrhotite) grains subject to biologic control. At cold stages, sediments containing a mixture of pseudo-single-domain and multidomain terrigenous magnetite particles accumulated. The petromagnetic curves agree with the normalized standard oxygen isotopic curve over the last 350 kyr of the column section.  相似文献   

Dilution of North Pacific Intermediate Water studied with chlorofluorocarbons     

Yutaka W. Watanabe  Koh Harada  Kimitoshi Ishikawa 《Journal of Oceanography》1995,51(2):133-144

Assessment was made of residual ratio of North Pacific Intermediate Water (NPIW) produced in subpolar region of the North Pacific using chlorofluorocarbons, CFC-11 and CFC-12 (CCl₃F and CCl₂F₂), along 175°E. NPIW on density horizons less than 26.80 remained more than 80% north of 30°N. It was suggested that new NPIW laterally spreads over the northern North Pacific without hardly being diluted by the surroundings. For density horizons greater than 26.80 north of 30°N, NPIW remained less than 60%. The difference in the residual ratio between <26.80 and >26.80 north of 30°N suggests that NPIW is produced on density horizons less than 26.80, which contacts the atmosphere in the subpolar region, and that NPIW is diluted by upwelling deep water on density horizons greater than 26.80 in high latitude of the North Pacific. NPIW on a density horizon of 26.80 remained about 50% south of 30°N. The decrease in the horizontal distribution of the residual ratio of NPIW suggests that half the new NPIW produced in the subpolar region is laterally spread over the North Pacific with the southward movement of NPIW.  相似文献