Measurement of 34S/32S Ratios of NBS 120c and BCR 32 Phosphorites Using Purge and Trap EA‐IRMS Technology          下载免费PDF全文

François Fourel  François Martineau  Magali Seris  Christophe Lécuyer 《Geostandards and Geoanalytical Research》2015,39(1):47-53

Measurements of sulfur stable isotope ratios (³⁴S/³²S) have suffered from technical difficulties in analysing low‐S materials reducing their use despite their undeniable scientific interest. The measurement of ³⁴S/³²S ratios is a powerful tool for deciphering problems such as determining the sources of environmental pollutants, to detect adulteration, tracking the evolution of the redox state of the oceans and quantifying the role of the bacterial activity in sulfide minerals genesis. We have used a high‐precision method of sulfur isotope determination using a new type of elemental analyser based on ‘purge and trap’ technology. This new technique demonstrates the high quality of ³⁴S/³²S measurements for samples with S concentrations lower than 1% m/m. International calibrated references of diverse sulfur‐bearing materials were used to calibrate two low (< 1%) S‐bearing phosphorites used as compositional reference material for future use as isotopic references: BCR 32 and NBS 120c. δ³⁴S_CDT values of, respectively, 18.2‰ (1s = 0.3; n = 23) and 18.3‰ (1s = 0.4; n = 20) are proposed for these. Calibration of both phosphorites with international reference materials led to calculation of a mean standard error close to 0.4‰. The demonstration of a capability to reliably measure S isotope ratios in low‐S phosphate minerals or rocks opens up new fields of palaeoenvironmental reconstructions.  相似文献   

Scientific objectives for UV/visible astrophysics investigations: a summary of responsesby the community (2012)     

Paul A. Scowen  Mario R. Perez  Susan G. Neff  Dominic J. Benford 《Experimental Astronomy》2014,37(1):11-35

Following several recommendations presented by the Astrophysics Decadal Survey 2010 centered around the need to define “a future ultraviolet-optical space capability”, on 2012 May 25, NASA issued a Request for Information (RFI) seeking persuasive ultraviolet (UV) and visible wavelength astrophysics science investigations. The goal was to develop a cohesive and compelling set of science objectives that motivate and support the development of the next generation of ultraviolet/visible space astrophysics missions. Responses were due on 10 August 2012 when 34 submissions were received addressing a number of potential science drivers. A UV/visible Mission RFI Workshop was held on 2012 September 20 where each of these submissions was summarized and discussed in the context of each other. We present a scientific analysis of these submissions and presentations and the pursuant measurement capability needs, which could influence ultraviolet/visible technology development plans for the rest of this decade. We also describe the process and requirements leading to the inception of this community RFI, subsequent workshop and the expected evolution of these ideas and concepts for the remainder of this decade.  相似文献   

Variability of particulate (SS,POC) and dissolved (DOC,NO3) matter during storm events in the Alegria agricultural watershed          下载免费PDF全文

Itsasne Cerro  José Miguel Sanchez‐Perez  Estilita Ruiz‐Romera  Iñaki Antigüedad 《水文研究》2014,28(5):2855-2867

The temporal variability of suspended sediment, nitrates (NO₃) and dissolved (DOC) and particulate organic carbon concentrations was analysed in the Alegria agricultural watershed over a 2‐year period. Nine storm events were studied, including an exhaustive analysis of hydrometeorological conditions, quantification of fluxes, and concentration‐discharge hysteresis loop characterization. The overall aim was to study the variability in these components during storm events and determine the mechanisms (flow paths) affecting the trajectories, from the source to the stream. The forms, rotational patterns and trends of hysteretic loops were investigated, and relationships between hysteresis features and hydrological parameters were studied. The results revealed clear differences between particulate (suspended sediment, particulate organic carbon) and dissolved (DOC, NO₃) matter transport responses. Movement of the particulate matter was attributed to surface water, as reflected in clockwise hysteresis loops, whereas dissolved matter showed, in general, counterclockwise hysteresis loops, indicating a time delay in the arrival of solutes to the stream. This could be related to subsurface flow paths for DOC and a groundwater source for NO₃. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Variability of Quaternary glacial erosion rates – A global perspective with special reference to the Eastern Pyrenees     

Magali Delmas  Marc Calvet  Yanni Gunnell 《Quaternary Science Reviews》2009,28(5-6):484-498

Glaciers erode bedrock but are also efficient conveyors of debris supplied during a cycle of glaciation by processes other than basal erosion. In this dual capacity as both an eroding and a transporting agent lies the ambiguity of ‘glacial erosion’ as a geomorphic process, with implications for methods of measuring the removal of rock mass by glaciers in the geological past, and for interpreting what exactly the consequences have been on topography and elevation change. A global review of ～400 Quaternary glacial denudation rates estimated from five different measurement techniques provides values ranging between 10^?4 and 10 mm yr^?1. We investigate the causes of such wide variability by examining the respective influences of environmental setting and methodological bias. A reference frame chosen for assessing these issues is the Massif du Carlit (Pyrenees, France), where a quantified mass balance of the well preserved glacial, periglacial and paraglacial deposits was made possible by detailed geomorphological mapping and terrestrial cosmogenic nuclide dating of extant erosional and depositional landform sequences. Resulting age brackets helped to define three main episodes of ice-cap growth and decline, each characterized by a volume of debris and a mappable source area. Erosion rates were expressed in two ways: (i) as spatially averaged denudation rates (D) during the successive stages of glacial advance to the line of maximum ice extent (MIE), post-MIE ice recession, and Lateglacial cirque readvance, respectively; and (ii) as cirque-wall recession rates (R) where moraine facies criteria indicated a supraglacial provenance of debris. Results indicate low erosion (D ≈ 0.05 mm yr^?1) during the ice advance phase, probably because of thin or passive ice covering the low-gradient subglacial topography that occurs just above the late Pleistocene equilibrium line altitude (2.2–2.4 km). Erosion rates peaked (D ≈ 0.6 mm yr^?1 and R ≈ 2.4–4.5 mm yr^?1) during the main transition to ice-free conditions, when deglacial debuttressing promoted the rapid response of freshly exposed slope systems to new equilibrium conditions in the steep crest zone. Lateglacial D- and R-values declined to 0.2–0.3 mm yr^?1, with indications of spatially variable R controlled by lithology. In this environment glaciers overall behaved more as conveyors of debris supplied by supraglacial rock exposures in the mountain crest zone than as powerful modifiers of subglacial topography. This explains the widespread preservation of deep, in situ preglacial weathering profiles on relict Cenozoic land surfaces in the deglacierized part of the Eastern Pyrenees. When plotted on the global data set analyzed and discussed in the review, the East Pyrenean erosion rates stand out as being amongst the lowest on record.  相似文献   

Buried impact basins,the evolution of planetary surfaces and the Chicxulub multi‐ring crater     

Jaime Urrutia‐Fucugauchi  Ligia Perez‐Cruz 《Geology Today》2011,27(6):220-225

Impact craters are distinctive landforms on Moon, Mars, Venus and other bodies of the Solar System. In contrast, the Earth has few craters, due to the dynamic nature of the planet, where craters and other geological structures are destroyed, modified or covered. Planetary missions have also shown that in other worlds where craters are numerous and well preserved, the crater record has been modified, through the identification of buried structures. Studies of the concealed crater record have major implications for the crater‐size frequency distribution and crater‐counting chronologies. On Earth, Chicxulub is an example of a large multi‐ring buried basin. Its study provides clues for the investigation other planetary surfaces. In addition, geophysical surveys have unravelled its deep 3‐D structure, providing data and constraints for new planetary missions.  相似文献   

Sunken wood from the Vanuatu Islands: identification of wood substrates and preliminary description of associated fauna   总被引：1，自引：0，他引：1  

Marie Pailleret  Takuma Haga  Patricia Petit  Catherine Privé-Gill  Nima Saedlou  Françoise Gaill  & Magali Zbinden 《Marine Ecology》2007,28(1):233-241

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The western part of the Gulf of Cadiz: contour currents and turbidity currents interactions   总被引：2，自引：0，他引：2  

T. Mulder  P. Lecroart  V. Hanquiez  E. Marches  E. Gonthier  J.-C. Guedes  E. Thiébot  B. Jaaidi  N. Kenyon  M. Voisset  C. Perez  M. Sayago  Y. Fuchey  S. Bujan 《Geo-Marine Letters》2006,26(1):31-41

Recent multibeam bathymetry and acoustic imagery data provide a new understanding of the morphology of the western part of the Gulf of Cadiz. The gulf is under the influence of a strong current, the Mediterranean Outflow Water (MOW). This current is at the origin of the construction of the giant Contourite Depositional System. Canyons and valleys with erosive flanks are observed. Only the Portimao Canyon is presently connected to the continental shelf. Channels occur on the continental shelf but are presently disconnected from the deeper network of channels and valleys. Slumps are localized in steep slope areas. They are caused by oversteepening and overloading, sometimes probably associated with earthquake activity. Slumps transform sharply into turbidity currents, depositing turbidites on the floor of deep valleys. Interaction of the MOW and gravity currents is suggested by the filling of the incisions located on the drifts below the present seafloor, the shifting of valleys and canyons in the direction of the MOW flow inducing an unusual phenomenon of capture of submarine valleys.  相似文献   

The Local Tsunami Alert System [``SLAT']: A Computational Tool for the Integral Management of a Tsunami Emergency     

Ramirez  F. Jorge  Perez  P. Carlos 《Natural Hazards》2004,31(1):129-142

During a tsunami emergency numerous local authorities responsible for the security oflocal persons and businesses which function in the coastal zone are required to makecritical decisions within a very short time frame. It is known that the consequencesof the situation will depend on the quality and quantity of decisions which they makeor allow to occur at the critical time. Based on this concept, the Local System of Tsunami Alert (SLAT; Spanish) was developed. This is a computational tool designed for the automatic implementation of integral management for an emergency of this type.The System is able to immediately evaluate possible risks and determine thetype of alert represented (Red, Yellow, Green, Blue, and Celeste) if relevantdata such as coordinates of the epicenter, magnitude, date, and origin of theearthquake (>6.5° on the Richter scale) threatening the Pacific areknown. Other relevant data include location of the coastal or marine epicentreand the superficial hypocenter. The relevant data may now be obtained fromthe internet from international seismological services, and fed into the programto give the most probable time for arrival of the first wave train at a given pointof interest, whether this be a port, bathing area, generating plant, or coastal city.The program also gives the time required for the first wave train to arrive at agiven coast, and displays a menu of previously planned actions to be taken accordingto the type of alert. It also permits dissemination of a bulletin with critical data and action plans by fax or e-mail to scattered users as well as for storage on the computer disc. The system is designed in a way that the user always confirms with authorities that anevent has in fact been generated. On a local scale, the user is required to prepare an operative emergency plan of action to be followed by his company, community, or municipality, to be followed for each type of alert.The System permits carrying out test exercises with the users, as well as simulationof past events. Knowledge concerning past events permits understanding correctdesign of emergency action plans for mitigation of potential present and future events.This software is specifically designed for the Pacific Coast of South America, and isprepared in Spanish, with the intention of improving responses of inhabitants of coastalareas to the potential threat from tsunamis.  相似文献   

Seismic hazard reappraisal from combined structural geology, geomorphology and cosmic ray exposure dating analyses: the Eastern Precordillera thrust system (NW Argentina)   总被引：1，自引：0，他引：1  

L. L. Siame  O. Bellier  M. Sébrier  D. L. Bourlès  P. Leturmy  M. Perez  M. Araujo 《Geophysical Journal International》2002,150(1):241-260

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Exposure age chronology of the last glaciation in the eastern Pyrenees   总被引：2，自引：0，他引：2  

Magali Delmas  Yanni Gunnell  Régis Braucher  Didier Bourlès 《Quaternary Research》2008,69(2):231-241

We present a chronology of ice recession in the eastern Pyrenees based on in situ-produced ¹⁰Be data obtained from the Têt paleoglacier complex. The sampling strategy is based on the relative chronology provided by a detailed geomorphological map of glacial landforms. Results indicate that the last maximum ice advance occurred late (i.e., during Marine Isotope Stage 2) compared to the chronology currently established for the rest of the Pyrenees. Despite debatable evidence for a glacial readvance during the Oldest Dryas stade, ice-cap melt-out was rapid, residual cirque glaciers having disappeared by the Allerød interstade. This is consistent both with North Atlantic excursions established by the Greenland ice cores and paleoenvironmental data for the region. The rapid response of the east-Pyrenean ice cap to temperature variations is primarily linked to its small size compared to larger Pyrenean ice fields, to the dry Mediterranean climate, and to topography-related nonlinearities in which a small vertical rise in equilibrium line altitude generates a large change in ice mass. Possible sources of age uncertainty are discussed in the context of sampling design for single-nuclide (¹⁰Be) dating of landform sequences in formerly glaciated landscapes.  相似文献