Carbonate diagenesis of the upper Jurassic successions in the west of Binalud — Eastern Alborz (NE Iran)     

Ali Aghaei  Asadollah Mahboubi  Reza Moussavi Harami  Mahdi Nadjafi  Govind Joseph Chakrapani 《Journal of the Geological Society of India》2014,83(3):311-328

The upper Jurassic carbonate settings in Iran are widely exposed in north and northeastern parts. Five stratigraphic columns were selected in the north eastern Iran. Their thickness ranges from 330 to 500 m. The various diagenetic processes identified include, micritization, cementation, compaction (physical and chemical), dissolution, neomorphism, pyritization, hematitization, silicification and dolomitization, which affected these carbonates. Elemental and stable isotopes analysis indicated that these deposits have undergone both meteoric and burial diagenesis in a relatively open system with moderate water-rock interaction. The positive trend between trace elements and oxygen isotope depletion also support these burial conditions. Lighter δ^l8O values of the dolomite samples may be related to an increase in temperature during the burial, which correspond to coarser euhedral crystals. Relatively higher δ¹⁸O values in finer dolomite crystals indicate their formation at lower burial depths relative to coarser crystals. Petrographic evidences such as coarse euhedral crystals with bright and dull zonation prove this interpretation. Chert nodules also have lighter ¹⁸O values relative to carbonate host rock, thus indicating the influence of burial diagenetic processes in their formation. The average environmental palaeotemperature was estimated to be 26°C on the basis of oxygen isotope values of less altered lime-mudstones.  相似文献   

Geochemical peculiarities of the formation of the Novoshirokinskii gold-polymetallic deposit,Eastern Transbaikalia,Russia     

A. A. Ali  V. Yu. Prokofief  S. G. Kryazhev 《Moscow University Geology Bulletin》2014,69(2):72-78

The fluid inclusions in minerals and isotope composition of sulfur in sulfides and carbon and oxygen in carbonates are studied for the Novoshirokinskii gold-polymetallic deposit. The ore-forming fluids are characterized by the following physico-chemical and isotope-geochemical parameters: temperature of 290–100°C, salinity of 13–2.5 wt % NaCl-equiv., δ¹⁸O from +8 to 0‰, δ¹³C of 2.5 ± 0.5‰, and δ³⁴S of 10.5 ± 1.0‰. It is concluded that the Late Proterozoic-Early Cambrian carbonaceous-terrigenous and carbonate rocks were involved in the Late Jurassic ore-magmatic system.  相似文献   

Analytical solutions for one-dimensional advection–dispersion equation of the pollutant concentration     

Ali S Wadi  Mourad F Dimian  Fayez N Ibrahim 《Journal of Earth System Science》2014,123(6):1317-1324

We present simple analytical solutions for the unsteady advection–dispersion equations describing the pollutant concentration C(x, t) in one dimension. The solutions are obtained by using Laplace transformation technique. In this study we divided the river into two regions x ≤ 0 and x≥0 and the origin at x = 0. The variation of C(x, t) with the time t from t = 0 up to t → ∞ (the steady state case) is taken into account in our study. The special case for which the dispersion coefficient D = 0 is studied in detail. The parameters controlling the pollutant concentration along the river are determined.  相似文献   

Assessment of climate change impacts on rainfall using large scale climate variables and downscaling models – A case study     

Azadeh Ahmadi  Ali Moridi  Elham Kakaei Lafdani  Ghasem Kianpisheh 《Journal of Earth System Science》2014,123(7):1603-1618

Many of the applied techniques in water resources management can be directly or indirectly influenced by hydro-climatology predictions. In recent decades, utilizing the large scale climate variables as predictors of hydrological phenomena and downscaling numerical weather ensemble forecasts has revolutionized the long-lead predictions. In this study, two types of rainfall prediction models are developed to predict the rainfall of the Zayandehrood dam basin located in the central part of Iran. The first seasonal model is based on large scale climate signals data around the world. In order to determine the inputs of the seasonal rainfall prediction model, the correlation coefficient analysis and the new Gamma Test (GT) method are utilized. Comparison of modelling results shows that the Gamma test method improves the Nash–Sutcliffe efficiency coefficient of modelling performance as 8% and 10% for dry and wet seasons, respectively. In this study, Support Vector Machine (SVM) model for predicting rainfall in the region has been used and its results are compared with the benchmark models such as K-nearest neighbours (KNN) and Artificial Neural Network (ANN). The results show better performance of the SVM model at testing stage. In the second model, statistical downscaling model (SDSM) as a popular downscaling tool has been used. In this model, using the outputs from GCM, the rainfall of Zayandehrood dam is projected under two climate change scenarios. Most effective variables have been identified among 26 predictor variables. Comparison of the results of the two models shows that the developed SVM model has lesser errors in monthly rainfall estimation. The results show that the rainfall in the future wet periods are more than historical values and it is lower than historical values in the dry periods. The highest monthly uncertainty of future rainfall occurs in March and the lowest in July.  相似文献   

Study of ground subsidence in northwest Harris county using GPS,LiDAR, and InSAR techniques     

Shuhab D. Khan  Zheng Huang  Ayca Karacay 《Natural Hazards》2014,73(3):1143-1173

Subsidence has been affecting many cities around the world, such as Nagoya (Japan), Venice (Italy), San Joaquin Valley and Long Beach (California), and Houston (Texas). This phenomenon can be caused by natural processes and/or human activities, including but not limited to carbonate dissolution, extraction of material from mines, soil compaction, and fluid withdrawal. Surface deformation has been an ongoing problem in the Houston Metropolitan area because of the city’s location in a passive margin where faulting and subsidence are common. Most of the previous studies attributed the causes of the surface deformation to four major mechanisms: faulting, soil compaction, salt tectonics, and fluid withdrawal (groundwater withdrawal and hydrocarbon extraction). This work assessed the surface deformation in the greater Houston area and their possible relationship with fluid withdrawal. To achieve this goal, data from three complimentary remote sensing techniques Global Positioning System (GPS), Light Detection and Ranging (LiDAR), and Interferometric Synthetic Aperture Radar were used. GPS rates for the last 17 years show a change in surface deformation patterns. High rates of subsidence in the northwestern areas (up to ~4 cm/year) and signs of uplift in the southeast are observed (up to 2 mm\year). High rates of subsidence appear to be decreasing. Contrary to previous studies in which the location of subsidence appeared to be expanding toward the northwest, current results show that the area of subsidence is shrinking and migrating toward the northeast. Digital elevation model generated from airborne LiDAR, revealed changes between salt domes and their surrounding areas. The persistent scatterer interferometry was performed using twenty-five (25) European remote sensing-1/2 scenes. Rates of change in groundwater level and hydrocarbon production were calculated using data from 261 observation wells and 658 hydrocarbon wells. A water level decline of 4 m/year was found in area of highest subsidence, this area also show ~70 million m³/year of hydrocarbon extraction. This study found strong correlation between fluid withdrawals and subsidence. Therefore, both groundwater and hydrocarbon withdrawal in northwest Harris County are considered to be the major drivers of the surface deformation.  相似文献   

Assessments of Strength Anisotropy and Deformation Behavior of Banded Amphibolite Rocks   总被引：2，自引：0，他引：2  

Esamaldeen Ali  Wu Guang  Zhao zhiming  Jiang Weixue 《Geotechnical and Geological Engineering》2014,32(2):429-438

Assessment of strength anisotropy in transversely isotropic rocks has been one of the most challenging subjects in rock engineering. However, far too little attention has been paid to banded amphibolite rocks. This study aim to evaluate strength and deformation anisotropy behavior of banded amphibolite rocks. The dynamic mechanical tests including ultrasonic pulse test, uniaxial compressive strength, Brazilian test and deformability test were performed on drilled rock samples as a function of foliation plane angle (β = 0°, 30°, 60° and 90°). The results obtained have shown that the dynamic mechanical properties of amphibolite rocks have different values concerning banding plane. Compression and shear waves taken parallel to the foliation plane show highest values than those obtained in the other directions. Under uniaxial test, the banded amphibolite has a U-shaped anisotropy with maximum strength at β = 90° and minimum strength is obtained when β = 30°. Strength anisotropic index ranges between 0.96 and 1.47. It seems that the high range value of anisotropic index is mainly due to slight undulation of foliation planes, that being not perfectly straight. The results of elastic deformation test show that there is no clear dependence on microstructures characteristics of subtype-amphibolite rocks that controlling modulus “shape-anisotropy”. However, in this study, Young modulus values of amphibolite rocks with β follow both types of shape-anisotropy, “U-shape” and “decreased order-shaped”. Thus, this study recommended that further research be undertaken regarding the role of modulus “shape-anisotropy” within the same lithotype.  相似文献   

Sensitivity Analysis of Selected Input Parameters for an Advanced Constitutive Model     

L. Sebastian Bryson  Ali Salehian 《Geotechnical and Geological Engineering》2014,32(2):247-258

Experimental results and simulated behavior of a medium plasticity clay were compared to investigate the performance of an advanced soil constitutive model. The soil model employed for this study was the 3-SKH model. The performance of this model was compared to the performance of two other critical state models; the Cam Clay (CC) and Modified Cam Clay (MCC) models. In addition, the influences of some of the input parameters on the performance of the 3-SKH model were investigated by performing sensitivity analyses. The comparisons demonstrated that the CC model was able to predict normally consolidated compressive behavior of the remolded medium plasticity clay. The compression behavior of overconsolidated clay was better captured by both the 3-SKH and CC models. For extension behavior of the normally consolidated samples, the MCC model performed better than the CC and 3-SKH models in predicting the stress path. The 3-SKH model was found to be very sensitive to varying the exponent in the hardening function. In particular, a difference between the evaluated values as small as 0.01 had a noticeable effect on the predicted stress–strain values for the overconsolidated compression and extension samples.  相似文献   

Mixing processes in hydrothermal spring systems and implications for interpreting geochemical data: a case study in the Cappadocia region of Turkey     

Mustafa Afsin  Diana M. Allen  Dirk Kirste  U. Gokcen Durukan  Ali Gurel  Ozcan Oruc 《Hydrogeology Journal》2014,22(1):7-23

Mixing is a dominant hydrogeological process in the hydrothermal spring system in the Cappadocia region of Turkey. All springs emerge along faults, which have the potential to transmit waters rapidly from great depths. However, mixing with shallow meteoric waters within the flow system results in uncertainty in the interpretation of geochemical results. The chemical compositions of cold and warm springs and geothermal waters are varied, but overall there is a trend from Ca–HCO₃ dominated to Na–Cl dominated. There is little difference in the seasonal ionic compositions of the hot springs, suggesting the waters are sourced from a well-mixed reservoir. Based on δ¹⁸O and δ²H concentrations, all waters are of meteoric origin with evidence of temperature equilibration with carbonate rocks and evaporation. Seasonal isotopic variability indicates that only a small proportion of late spring and summer precipitation forms recharge and that fresh meteoric waters move rapidly into the flow system and mix with thermal waters at depth. ³H and percent modern carbon (pmC) values reflect progressively longer groundwater pathways from cold to geothermal waters; however, mixing processes and the very high dissolved inorganic carbon (DIC) of the water samples preclude the use of either isotope to gain any insight on actual groundwater ages.  相似文献   

Introducing a Comprehensive Data Reduction and Uncertainty Propagation Algorithm for U‐Th Geochronometry with Extraction Chromatography and Isotope Dilution MC‐ICP‐MS     

Ali Pourmand  François L. H. Tissot  Monica Arienzo  Arash Sharifi 《Geostandards and Geoanalytical Research》2014,38(2):129-148

We present an open‐source algorithm in Mathematica application (Wolfram Research) with a transparent data reduction and Monte Carlo simulation of systematic and random uncertainties for U‐Th geochronometry by multi‐collector ICP‐MS. Uranium and thorium were quantitatively separated from matrix elements through a single U/TEVA extraction chromatography step. A rigorous calibrator‐sample bracketing routine was adopted using CRM‐112A and IRMM‐035 standard solutions, doped with an IRMM‐3636a ²³³U/²³⁶U ‘double‐spike’ to account for instrumental mass bias and deviations of measured isotope ratios from certified values. The mean of ²³⁴U/²³⁸U and ²³⁰Th/²³²Th in the standard solutions varied within 0.42 and 0.25‰ (permil) of certified ratios, respectively, and were consistent with literature values within uncertainties. Based on multiple dissolutions with lithium metaborate flux fusion, U and Th concentrations in USGS BCR‐2 CRM were updated to 1739 ± 2 and 5987 ± 50 ng g^?1 (95% CI), respectively. The measurement reproducibility of our analytical technique was evaluated by analysing six aliquots of an in‐house reference material, prepared by homogenising a piece of speleothem (CC3A) from Cathedral Cave, Utah, which returned a mean age of 21483 ± 63 years (95% CI, 2.9‰). Replicate analysis of ten samples from CC3A was consistent with ages previously measured at the University of Minnesota by single‐collector ICP‐MS within uncertainties.  相似文献   

The formation of iron hydroxide coatings in an Emscher Marl: inverse reactive transport modeling of reactive surface area     

Ali Naderi Beni  Helge Stanjek  Christoph Clauser 《Environmental Earth Sciences》2014,71(2):763-771

The possible effects of iron oxide coatings on the reactive surface area of calcite in column experiments have been studied and then modeled numerically. A column with six compartments separated by teflon filters was packed with Emscher Marl (essentially calcite). The marl was initially mixed with corundum as an internal standard. Hydrochloric acid with pH 3 was percolated through the column for a given period, after which the mineralogical changes were quantified by X-ray diffraction ex-situ. Then, the column compartments were re-filled and again percolated with HCl. This procedure was repeated five times. The losses and gains of calcite in the column compartments provided the data basis for modeling the entire experiment with the reactive transport code TOUGHREACT using a kinetic rate law. The experimental results showed that during the first period, loss of calcite in the first compartment is about 50 % less than that determined from the theoretical analysis. This showed the entrance of acid into the higher compartments through preferential flow paths (wormholes) which was observed at the boundary between sample and cell wall. This pattern could also be verified by the relatively high Peclet and low Damköhler numbers, showing a strongly advection-dominant system. Apart from calcite dissolution, structural Fe²⁺ released from calcite oxidized and formed iron hydroxide (FeOOH) coatings along preferential fluid pathways. Despite specific assumptions such as using pure calcite in the model, a comparison between modeling results and lab observations is instructive. The simulated calcite change patterns in the most compartments are consistent with the experiments. Some discrepancies are noted in the last compartment, which may bring the attention to a need for model improvements.  相似文献