Tetrad effects in REE abundance patterns of chondrules from CM meteorites: Implications for aqueous alteration on the CM parent asteroid     

Mutsuo Inoue  Noboru Nakamura  Makoto Kimura 《Geochimica et cosmochimica acta》2009,73(17):5224-5239

Lanthanide tetrad effect in bulk chondrules from two moderately altered CM chondrites, Murchison and Yamato-793321 (Y-793321), are reported for the first time. Twenty-three chondrules were petrographically characterized and analyzed for 10 rare earth elements (REE) and other trace and major elements (Ba, Sr, Rb, K, Ca, Mg and Fe) using the precise isotope dilution technique. The results indicate systematic depletion (several times) of alkali and alkaline earths compared to CV and CO chondrules. Most of the porphyritic olivine (8 PO) and olivine-pyroxene (4 POP), porphyritic and radial pyroxene (2 PP, 1 RP), and granular olivine (1 GO) chondrules show a light-REE (L-REE) depleted, heavy-REE (H-REE) smoothly fractionated pattern composed of four (upward convex) segments possessing a relatively large negative Eu anomaly (CI-normalized La/Sm, Lu/Er and Eu/Eu* ratios = 0.3-1: Eu*, normal value). On the other hand, all barred-olivine (5 BO) chondrules, a few PO and POP indicate almost a flat L-REE pattern. In addition, regardless of their textural types, nearly half of the chondrules have a variable degree of Ce and Yb anomalies, and/or L/H-REE discontinuity, which is similar to CV and CO chondrules. The observed L- and H-convex REE patterns accompanied with the negative Eu anomaly is the first known case for chondrules as well as meteoritic materials, but have been previously reported for geological samples such as sedimentary rocks, late stage igneous and metamorphic rocks, and are explained as the lanthanide tetrad effect, which plausibly results from fluid-rock interaction. We suggest that the marked REE fractionations occurred by the selective incorporation of L-, H-REEs and Eu into alteration products in the matrix during alteration processes on the CM parent body, but that the gas/solid REE fractionation characteristics established in the nebula have basically remained unchanged. We suggest that the tetrad effects observed here represent a new index of physico-chemical conditions of fluid-rock interactions prevalent on the CM parent body.  相似文献   

Simultaneous measurements of compressional wave and shear wave velocities, Poisson's ratio, and Vp/Vs under deep crustal pressure and temperature conditions: Example of silicified pelitic schist from Ryoke Belt, Southwest Japan     

Yuki  Matsumoto  Masahiro  Ishikawa  Masaru  Terabayashi    Makoto  Arima 《Island Arc》2010,19(1):30-39

The ultrasonic technique for measuring travel times of compressional and shear waves using dual-mode transducers was adapted to a piston cylinder apparatus, allowing simultaneous measurements of travel times of compressional and shear waves of island arc samples under the high pressure and temperature conditions of island arcs. This method enables us to determine elastic properties and their pressure and temperature derivatives simultaneously. Furthermore, Vp/Vs can be directly determined from travel times of compressional and shear waves independently of length change due to compression or thermal expansion of rock samples under deep crustal conditions, providing more accurate Vp/Vs values than those determined from individual measurements of travel times of both elastic wave types using single-mode transducers. Experimental techniques and results are demonstrated using data on silicified pelitic schist from the Ryoke Belt to 0.6 GPa. The simultaneous measurement gives Vp  = 5.60 km/s, ∂ Vp /∂ P  = 0.090 (km/s)/GPa, Vs  = 3.37 km/s, ∂ Vs /∂ P  = 0.05 (km/s)/GPa, σ  = 0.216, and Vp / Vs  = 1.66 at ambient conditions. The temperature derivatives were constrained from fitting using linear functions of temperature, yielding ∂ Vp /∂ T  = −0.518 × 10⁻³ (km/s)/K and ∂ Vs /∂ T  = −0.182 × 10⁻³ (km/s)/K. Performing simultaneous measurements of travel times of compressional and shear waves using dual-mode transducers, it is possible to accurately determine Vp / Vs and Poisson's ratio of crustal minerals and rocks at deep crustal conditions to study the composition of the crustal interior, e.g. rock types and fluids below the hypocentral region of earthquakes or around bright spots.  相似文献   

Determination of transport rates in the Yellow River–Bohai Sea mixing zone via natural geochemical tracers     

Richard N. Peterson  William C. Burnett  Makoto Taniguchi  Jianyao Chen  Isaac R. Santos  Sambuddha Misra 《Continental Shelf Research》2008

In light of the current problems facing the Yellow River and surrounding areas (e.g., periods of zero river discharge, increasing nitrate concentrations of the Bohai Sea), we examined the coastal mixing dynamics around the mouth of the Yellow River. Naturally occurring radium isotopes (²²³Ra, ²²⁴Ra, ²²⁶Ra, and ²²⁸Ra) and other geochemical tracers (Ba, Si, and salinity) were employed to determine river plume transport scales and rates. Barium and radium exhibit elevated concentrations within the salinity gradient where they are desorbed from particles via ion-exchange. Once they are added to the system, they decrease offshore from dilution with lower concentration Bohai Sea water, and in the case of ²²⁴Ra and ²²³Ra, by radioactive decay. Using radium “ages” to assess the dissolved material transport scales and rates proved to be a useful tool in this environment. The ages based on the ²²⁴Ra/²²⁸Ra activity ratio increased gradually until salinities reached ∼25 when they rapidly increased due to decreased mixing at higher salinities. Integrated net transport rates through the salinity front ranged from 1.4 to 1.6 cm/s and did not vary significantly with river discharge. Thus, tidal mixing appears to dominate in this system, at least over the range of discharges investigated (80–600 m³/s). Determining the temporal scale of flow across the coastal zone in this region is a valuable first step toward examining whether the Yellow River is contributing to the increasing inorganic nitrogen concentrations in the central Bohai Sea.  相似文献   

Comparison of Internal Structures of Marine Manganese Deposits of Hydrogenetic, Diagenetic and Hydrothermal Origins     

Yumi HAT TA  Makoto WATANABE  Kenichi HOSHINO  Akira USUI 《Resource Geology》1999,49(1):49-54

Abstract: Detailed microscopic observation, combined with X-ray diffraction and EPMA analyses of samples from marine manganese deposits of three different origins, suggests that characteristic internal structures are inherent in each manganse mineral; vernadite (δ–MnO₂), buserite (10Å–manganate) and todorokite (10Å–manganate).  相似文献   

Estimating the thickness of a faulted mechanical layer based on fault spacing: An example from Miyako‐jima Island,southern Ryukyu Arc,Japan     

Sumire Maeda  Makoto Otsubo  Daisuke Asahina  Yuki Furuno 《Island Arc》2020,29(1)

The thickness of the mechanical layer that hosts a group of faults can be estimated from the spacing of saturated faults (i.e. the constant spacing between faults when the fault system is fully developed and has attained its final fault density). We measured fault spacing for a group of saturated active normal faults on Miyako‐jima Island (southern Ryukyu Arc, Japan) and estimated the thickness of the faulted mechanical layer. The measured fault spacing is 1.30 ±0.14 km, and the thickness of the mechanical layer is < 3 km, which is the upper limit of the seismogenic zone. This faulted mechanical layer corresponds to a sedimentary layer in which earthquakes cannot occur. Results indicate that the shallow (< 3 km depth) normal faults on Miyako‐jima Island do not have the potential to cause medium‐size earthquakes as individual faults. The origin of the shallow normal faults might be related to the presence of a larger‐scale, deeper fault. The results indicate that fault spacing provides important information on the potential magnitude of earthquakes associated with active faults.  相似文献   

Mineral chemistry and petrogenesis of chromitites from the Khoy ophiolite complex,Northwestern Iran: Implications for aggregation of two ophiolites          下载免费PDF全文

Fatemeh Zaeimnia  Ali Kananian  Shoji Arai  Mirsaleh Mirmohammadi  Ali Imamalipour  Mohamed Zaki Khedr  Makoto Miura  Khadidja Abbou‐Kebir 《Island Arc》2017,26(6)

The Khoy ophiolitic complex in Northwestern Iran is a part of the Tethyan ophiolite belt, and is divided into two sections: the Eastern ophiolite in Qeshlaq and Kalavanes (Jurassic–Cretaceous) and the Western ophiolite in Barajouk, Chuchak and Hessar (Late Cretaceous). Our chromitites can be clearly classified into two groups: high‐Al chromitites (Cr# = 0.38–0.44) from the Eastern ophiolite, and high‐Cr chromitites (Cr# = 0.54–0.72) from the Western ophiolite. The chromian spinels in high‐Al chromitite include primary mineral inclusions mainly as Na‐bearing diopside and pargasite with subordinate rutile and their formation was probably related to reaction between a MORB (mid‐ocean‐ridge basalt)‐like melt with depleted harzburgite, possibly in a back‐arc setting. Their host harzburgites contain clinopyroxene with higher contents of Al₂O₃, Na₂O, Cr₂O₃, and TiO₂ relative to Western harzburgites and are possibly residue after moderate partial melting (~15 %) whereas the Western harzburgite is residue after high partial melting (~25 %). The chromian spinel in the Western Khoy chromitites contains inclusions such as clinopyroxene, olivine and platinum group mineral‐bearing sulfides. These Western chromitites were possibly formed at two stages during arc growth and are divided into the moderately high‐Cr# chromitites (Barajouk and Hessar) and the high‐Cr# chromitites (Chuchak A and C). The former crystallized from island‐arc‐tholeiite (IAT) melts during reaction with the host depleted harzburgites, whereas the latter crystallized from boninitic melts (second stage melt) during reaction with highly depleted harzburgite in a supra‐subduction‐zone environment. Based on the mineral chemistry of chromian spinels, pyroxenes, and mineral inclusions, the chromitites and the host peridotites from the Eastern and Western Khoy ophiolites were formed in a back‐arc basin and arc‐related setting, respectively. The Khoy ophiolitic complex is a tectonic aggregate of the two different ophiolites formed in two different tectonic settings at different ages.  相似文献   

Significance of stemflow in groundwater recharge. 2: A cylindrical infiltration model for evaluating the stemflow contribution to groundwater recharge     

Tadashi Tanaka  Makoto Taniguchi  Maki Tsujimura 《水文研究》1996,10(1):81-88

A primary model for evaluating the effect of stemflow on groundwater recharge has been developed. The model, a cylindrical infiltration model (CI model), is based on the infiltration area of stemflow-induced water instead of canopy projected area for determining the stemflow inputs to the soil surface. The estimated ratio of recharge rate by stemflow to the total recharge rate determined with this model agrees closely with values obtained from the mass balance of chloride in subsurface waters. This primary model is considered to be useful for estimating the effect of stemflow on groundwater recharge.  相似文献   

Orbital evolution of giant comet-like objects     

Tsuko Nakamura  Makoto Yoshikawa 《Celestial Mechanics and Dynamical Astronomy》1993,57(1-2):113-121

We investigated by numerical integrations the long-term orbital evolution of four giant comets or comet-like objects. They are Chiron, P/Schwassmann-Wachmann 1 (SW1), Hidalgo, and 1992AD (5145), and their orbits were traced for 100–200 thousand years (kyr) toward both the past and the future. For each object, 13 orbits were calculated, one for the nominal orbital elements and other 12 with slightly modified elements based on the rms residual of the orbit determination and on the number of observations. As past studies indicate, their orbital evolution is found to be very chaotic, and thus can be described only in terms of probability. Plots of the semi-major axis (a) and perihelion distance (q) of the objects treated here seem to cross each other frequently, suggesting a possibility of their common evolutionary paths. About a half of all the calculated orbits showedq- ora-decreasing evolution. This indicates that, at least on the time scale in question, the giant comet-like objects are possibly on a dynamical track that can lead to capture from the outer solar system. We could hardly find the orbits with perihelia far outside the orbit of Saturn (q>15 AU). This is perhaps because the evolution of the orbits beyond Saturn is so slow that substantial orbital changes do not take place within 100–200 kyr.  相似文献   

A simple analytical model for the secular resonance ν6 in the asteroidal belt     

Makoto Yoshikawa 《Celestial Mechanics and Dynamical Astronomy》1987,40(3-4):233-272

When asteroids are in the secular resonance ₆, the variation of the eccentricity becomes very large. In this paper, the dynamics of this secular resonance ₆ is investigated by a simple analytical model, in which the third degree terms of the eccentricity and inclination are taken into account. The eccentricity variations of asteroids located near this resonance are represented clearly by the diagrams of equi-Hamiltonian curves on the plane of versuse ( the longitude of perihelion of asteroids and Saturn,e: the eccentricity of asteroids). These diagrams predict that the eccentricity of these asteroids suffers a large increase or decrease, and that the secular resonance argument librates about 0° and 180°. In order to confirm these predictions, numerical integrations are carried out over one million years. By these integrations, it is found that the eccentricity of secular resonant asteroids becomes more than 0.8, and that the libration about 0° also exists, as well as the libration about 180°. The strongly depopulated region in the asteroidal belt, which corresponds to the position of the secular resonance ₆, is also explained well by this analytical model.  相似文献   

GMS proton flux observation during February 1978     

Tsugunobu Nagai  Masaynki Kuwashima  Makoto Kawamura  Tsuyoshi Kohno 《Planetary and Space Science》1979,27(7):1035-1037

It is suggested that the drop out of the 1.2–4 MeV proton flux, observed by the geostationary satellite GMS, was due to the Earthward shift of the particle boundary in all local time. The particle boundary motions are associated with substorm activities.  相似文献