New measurement technique for characterizing small extraterrestrial materials by X‐ray diffraction using the Gandolfi attachment     

Naoya Imae  Makoto Kimura 《Meteoritics & planetary science》2021,56(1):174-191

Identification and characterization of small extraterrestrial samples, such as small Antarctic meteorites <~1 cm, require the development of convenient laboratory‐based nondestructive analytical techniques using X‐ray diffraction (XRD). We explore the characterization criteria using an X‐ray diffractometer with a Gandolfi attachment using sub‐mm small fragments and powder aggregates for various kinds of stony meteorites and develop a new analytical technique. We primarily focus on olivine and pyroxene because they are the most abundant and important minerals for stony meteorite classification. A new calibration is performed to estimate the FeO content of the olivine in unequilibrated ordinary chondrites, which is useful for determining the meteorite chemical group irrespective of powder aggregate diameter but dependent on fragment grain diameter. This is because X‐ray intensity absorption is more effective for grains than for powders. Clinoenstatite (Cen) and orthoenstatite (Oen) were distinguished using the presence or absence of the isolated Oen 511 index peak. The method is also applied to other stony meteorites including carbonaceous chondrites and achondrites. The XRD results are consistent with studies based on polished sections involving textural observations by scanning microscope and chemical compositions of the constituent minerals. The new measurement technique presented here is convenient because of its use in air by the laboratory‐based X‐ray diffractometer, which makes it useful for the initial analyses of restricted extraterrestrial sample characterization.  相似文献   

Significance of stemflow in groundwater recharge. 1: Evaluation of the stemflow contribution to recharge using a mass balance approach     

Makoto Taniguchi  Maki Tsujimura  Tadashi Tanaka 《水文研究》1996,10(1):71-80

Stemflow was evaluated in a water balance and its contribution to groundwater recharge determined. Gross precipitation, throughfall and stemflow were measured for one year in a pine forest (Tsukuba, Japan) to determine each component of the water balance in the forest. Groundwater recharge rates by stemflow and throughfall were calculated from a mass balance method using chloride in subsurface waters. The stemflow in the water balance was relatively small when estimated as a value per canopy projected area of the tree in the forest. However, the results for the mass balance of chloride in subsurface waters indicated that it was impossible to disregard the stemflow in determining groundwater recharge. Although the ratio of stemflow to the net precipitation was small in the water balance, the effect of stemflow on groundwater recharge was relatively large.  相似文献   

Distinctive C isotopic signature distinguishes a novel sea ice biomarker in Arctic sediments and sediment traps     

Simon T. Belt  Guillaume Mass  Lindsay L. Vare  Steven J. Rowland  Michel Poulin  Marie-Alexandrine Sicre  Makoto Sampei  Louis Fortier 《Marine Chemistry》2008,112(3-4):158-167

A C₂₅ highly branched isoprenoid (HBI) monoene hydrocarbon, designated IP₂₅, has been proposed previously to originate from diatoms living in Arctic sea ice, while the presence of IP₂₅ in sediments has been suggested to be a proxy for the occurrence of former Arctic sea ice. Here, we show that the ¹³C isotopic composition of IP₂₅ in sea ice, in sediment trap material collected under sea ice, and in high latitude northern sediments, is distinctive (isotopically ‘heavy’) and distinguishable from that of organic matter of planktonic or terrigenous origin. Mean δ¹³C values for IP₂₅ were − 22.3 ± 0.4‰ (sea ice), − 19.6 ± 1.1‰ (sediment traps) and − 19.3 ± 2.3‰ (sediments). These measurements, therefore, support further the proposed use of IP₂₅ as an Arctic sea ice proxy.  相似文献   

Lagrangian observation of phytoplankton dynamics at an artificially enriched subsurface water in Sagami Bay,Japan     

Takako Masuda  Ken Furuya  Naoko Kohashi  Mitsuhide Sato  Shigenobu Takeda  Makoto Uchiyama  Naho Horimoto  Takashi Ishimaru 《Journal of Oceanography》2010,66(6):801-813

Phytoplankton dynamics in the lower euphotic zone were observed by tracking a subsurface water released at 20-m depth from Takumi, an artificial upwelling device. Takumi continually discharged seawater pumped up from a depth of 205 m: this water was mixed with 5-m depth water to adjust the density to that of 20-m depth water of Sagami Bay, Japan. The discharged water was pulse-labeled at Takumi with uranine and tracked for 63.9 h with a drifting buoy equipped with a drogue at 20-m depth. We present a simple model to estimate in situ phytoplankton net growth rates from temporal changes in phytoplankton abundance in the discharged water with correction for the influence of water exchange between the discharged water and neighboring layers. Lagrangian observation showed active growth of pico- and nanophytoplankton, especially cryptophytes and Synechococcus (Cyanobacteria), in the subsurface layer. In contrast, diatoms grew little in spite of micromolar concentrations of nutrients. The active growth of pico- and nanophytoplankton was in good agreement with shipboard serial dilution culture experiments. The low growth activity of diatoms was suggested to be related to low light availability in the subsurface layer.  相似文献