A low δLi lower crustal component: Evidence from an alkalic intraplate volcanic series (Chaîne des Puys, French Massif Central)     

Cdric Hamelin  Hans-Michael Seitz  Jean-Alix Barrat  Laure Dosso  Ren C. Maury  Marc Chaussidon 《Chemical Geology》2009,266(3-4):205-217

The intraplate volcanic suite of the Chaîne des Puys (French Massif Central) shows a complete petrologic range, from alkali basalts to trachytes. The significant variations of trace elements and radiogenic isotopes along the series strongly support the occurrence of crustal assimilation associated with fractional crystallization (AFC). The least contaminated basalts are clearly related to a HIMU-type reservoir (²⁰⁶Pb/²⁰⁴Pb > 19.6; ⁸⁷Sr/⁸⁶Sr < 0.7037; ε_Nd > + 4). The behavior of radiogenic isotopes suggests that the most likely crustal contaminants are meta-sediments located in the lower crust.The Li isotopic compositions of the lavas range from high δ⁷Li (> + 7‰) in basalts to lighter values in more evolved lavas (down to δ⁷Li ≈ 0‰). The mantle component, expressed in the least evolved lavas, has a heavy Li isotopic signature, in good agreement with previous δ⁷Li measurements of OIB lavas with HIMU affinities. The evolution of Li isotopic compositions throughout the volcanic series is in agreement with the AFC model suggested by the Sr–Nd–Pb isotopic systems. Although the behavior of Li isotopes during assimilation processes is currently poorly constrained, our calculations suggest that at least a portion of the lower crust beneath the Chaîne des Puys is characterized by a light Li isotopic composition (δ⁷Li < − 5‰).  相似文献   

Regolith mass balance inferred from combined mineralogical, geochemical and geophysical studies: Mule Hole gneissic watershed, South India   总被引：3，自引：0，他引：3  

Jean-Jacques Braun  Marc Descloitres  Jean Riotte  Simon Fleury  Jean-Loup Boeglin  Eva Lacarce  M. Sekhar  M.S. Mohan Kumar  S. Subramanian  Bernard Dupré 《Geochimica et cosmochimica acta》2009,73(4):935-24

The aim of this study is to propose a method to assess the long-term chemical weathering mass balance for a regolith developed on a heterogeneous silicate substratum at the small experimental watershed scale by adopting a combined approach of geophysics, geochemistry and mineralogy. We initiated in 2003 a study of the steep climatic gradient and associated geomorphologic features of the edge of the rifted continental passive margin of the Karnataka Plateau, Peninsular India. In the transition sub-humid zone of this climatic gradient we have studied the pristine forested small watershed of Mule Hole (4.3 km²) mainly developed on gneissic substratum. Mineralogical, geochemical and geophysical investigations were carried out (i) in characteristic red soil profiles and (ii) in boreholes up to 60 m deep in order to take into account the effect of the weathering mantle roots. In addition, 12 Electrical Resistivity Tomography profiles (ERT), with an investigation depth of 30 m, were generated at the watershed scale to spatially characterize the information gathered in boreholes and soil profiles. The location of the ERT profiles is based on a previous electromagnetic survey, with an investigation depth of about 6 m. The soil cover thickness was inferred from the electromagnetic survey combined with a geological/pedological survey.Taking into account the parent rock heterogeneity, the degree of weathering of each of the regolith samples has been defined using both the mineralogical composition and the geochemical indices (Loss on Ignition, Weathering Index of Parker, Chemical Index of Alteration). Comparing these indices with electrical resistivity logs, it has been found that a value of 400 Ohm m delineates clearly the parent rocks and the weathered materials. Then the 12 inverted ERT profiles were constrained with this value after verifying the uncertainty due to the inversion procedure. Synthetic models based on the field data were used for this purpose. The estimated average regolith thickness at the watershed scale is 17.2 m, including 15.2 m of saprolite and 2 m of soil cover.Finally, using these estimations of the thicknesses, the long-term mass balance is calculated for the average gneiss-derived saprolite and red soil. In the saprolite, the open-system mass-transport function τ indicates that all the major elements except Ca are depleted. The chlorite and biotite crystals, the chief sources for Mg (95%), Fe (84%), Mn (86%) and K (57%, biotite only), are the first to undergo weathering and the oligoclase crystals are relatively intact within the saprolite with a loss of only 18%. The Ca accumulation can be attributed to the precipitation of CaCO₃ from the percolating solution due to the current and/or the paleoclimatic conditions. Overall, the most important losses occur for Si, Mg and Na with −286 × 10⁶ mol/ha (62% of the total mass loss), −67 × 10⁶ mol/ha (15% of the total mass loss) and −39 × 10⁶ mol/ha (9% of the total mass loss), respectively. Al, Fe and K account for 7%, 4% and 3% of the total mass loss, respectively. In the red soil profiles, the open-system mass-transport functions point out that all major elements except Mn are depleted. Most of the oligoclase crystals have broken down with a loss of 90%. The most important losses occur for Si, Na and Mg with −55 × 10⁶ mol/ha (47% of the total mass loss), −22 × 10⁶ mol/ha (19% of the total mass loss) and −16 × 10⁶ mol/ha (14% of the total mass loss), respectively. Ca, Al, K and Fe account for 8%, 6%, 4% and 2% of the total mass loss, respectively.Overall these findings confirm the immaturity of the saprolite at the watershed scale. The soil profiles are more evolved than saprolite but still contain primary minerals that can further undergo weathering and hence consume atmospheric CO₂.  相似文献   

Isotopic fractionation of nitrogen and carbon in Paleoarchean cherts from Pilbara craton, Western Australia: Origin of N-depleted nitrogen     

Daniele L. Pinti  Ko Hashizume  Marc Massault 《Geochimica et cosmochimica acta》2009,73(13):3819-3848

Nitrogen and carbon isotopic compositions, together with mineralogy and trace element geochemistry, were studied in a few kerogen-rich Paleoarchean cherts, a barite and a dolomitic stromatolite belonging to the eastern (Dixon Island Formation) and western (Dresser and Strelley Pool Chert Formations; North Pole Dome and Marble Bar) terranes of Pilbara Craton, Western Australia. The aim of the study was to search for ¹⁵N-depleted isotopic signatures, often found in kerogens of this period, and explain the origin of these anomalies. Trace elements suggest silica precipitation by hydrothermal fluids as the main process of chert formation with a contamination from volcanoclastic detritus. This is supported by the occurrence of hydrothermal-derived minerals in the studied samples indicating precipitation temperatures up to 350 °C. Only a dolomitic stromatolite from Strelley Pool shows a superchondritic Y/Ho ratio of 72 and a positive Eu/Eu^* anomaly of 1.8, characteristic of chemical precipitates from the Archean seawater. The bulk δ¹³C vs. δ¹⁵N values measured in the cherts show a roughly positive co-variation, except for one sample from the North Pole (PI-85-00). The progressive enrichment in ¹⁵N and ¹³C from a pristine source having δ¹³C ? −36‰ and δ¹⁵N ? −4‰ is correlated with a progressive depletion in N content and to variations in Ba/La and Co/As ratios. These trends have been interpreted as a progressive hydrothermal alteration of the cherts by metamorphic fluids. Isotopic exchange at 350 °C between NH₄⁺_(rock) and N_2(fluid) may explain the isotopic and elemental composition of N in the studied cherts. However, we need to assume isotopic exchange at 350 °C between carbonate C and graphite to explain the large ¹³C enrichment recorded. Only sample PI-85-00 shows a large N loss (90%) with a positive δ¹⁵N value (+11‰), while C (up to 120 ppm and δ¹³C −38‰) seems to be unaffected. This pattern has been interpreted as the result of devolatilization and alteration (oxidation) of graphite by low-temperature fluids. The ¹⁵N-¹³C-depleted pristine source has δ ¹⁵N values from −7‰ to −4‰ and ⁴⁰Ar/³⁶Ar ratios from 30,000 to 60,000, compatible with an inorganic mantle N source, although the elemental abundance ratios N/C and ⁴⁰Ar/C are not exactly the same with the mantle source. The component alternatively could be explained by elemental fractionation from metabolic activity of chemolithoautotrophs and methanogens at the proximity to the hydrothermal vents. However, ambiguities between mantle vs organic sources of N subsist and need further experimental work to be fully elucidated.  相似文献   

Red giant stellar collisions in the Galactic Centre     

James E. Dale  Melvyn B. Davies  Ross P. Church  Marc Freitag 《Monthly notices of the Royal Astronomical Society》2009,393(3):1016-1033

We show that collisions with stellar-mass black holes can partially explain the absence of bright giant stars in the Galactic Centre, first noted by Genzel et al. We show that the missing objects are low-mass giants and asymptotic giant branch stars in the range  1–3 M_⊙  . Using detailed stellar evolution calculations, we find that to prevent these objects from evolving to become visible in the depleted K bands, we require that they suffer collisions on the red giant branch, and we calculate the fractional envelope mass losses required. Using a combination of smoothed particle hydrodynamic calculations, restricted three-body analysis and Monte Carlo simulations, we compute the expected collision rates between giants and black holes, and between giants and main-sequence stars in the Galactic Centre. We show that collisions can plausibly explain the missing giants in the  10.5 < K < 12  band. However, depleting the brighter  ( K < 10.5)  objects out to the required radius would require a large population of black hole impactors which would in turn deplete the  10.5 < K < 12  giants in a region much larger than is observed. We conclude that collisions with stellar-mass black holes cannot account for the depletion of the very brightest giants, and we use our results to place limits on the population of stellar-mass black holes in the Galactic Centre.  相似文献   

Characterization and quantification of inorganic constituents of tropical peats and organic-rich deposits from Tasek Bera (Peninsular Malaysia): implications for coals     

Raphael A. J. Wüst  Colin R. Ward  R. Marc Bustin  Michelle I. Hawke 《International Journal of Coal Geology》2002,49(4)

Since the Carboniferous, tropical latitudes have been the site of formation of many economic coal deposits, most of which have a restricted range of mineralogical composition as a result of their depositional environment, climatic conditions, and diagenesis. Mineralogical and microscopic investigations of tropical peats from Tasek Bera, Peninsular Malaysia, were performed in order to better understand some of these factors controlling the nature, distribution and association of inorganic matter in peat-forming environments. Distribution and nature of the inorganic fraction of peat deposits give insight into the weathering conditions and detrital input into the mire system. Because the inorganic composition of peat deposits is determined by plant communities, height of water table, and climate, the results of the quantitative and qualitative analysis can be used to reconstruct palaeoclimatic conditions.Tasek Bera is a peat-accumulating basin in humid tropical Malaysia with organic deposits of low- to high-ash yield and thus representative of many ancient peat-forming environments. Clay minerals dominate the mineralogical composition of the peat and organic-rich sediments, while quartz and clays dominate the underlying siliciclastic deposits. Kaolinite is the most abundant clay mineral in the organic deposits with minor amounts of illite and vermiculite. Particle size analyses indicate that >50% of the inorganic detrital fraction is <2 μm. Most detrital quartz grains range in size from fine silt to fine sand. The fine sand fraction accounts for a maximum of 5 wt.% of the inorganic constituents. In addition, abundant biogenic and non-biogenic, Al- and Si-rich amorphous matter occur. In the ombrotrophic (low-nutrient) environment, biogenic inorganic material contributes up to >75% of the ash constituents. As a consequence, the vegetational communities make an important contribution to the inorganic and overall ash composition of peats and coals. The ash content of the often inundated peat consists on average of 10% opaline silica from diatoms and sponge spicules, while the ash of the top deposits may have up to 50% biogenic silica. Hence, Al- and Si-hydroxides and the opaline silica from diatoms and sponges represent a large repository of Al and Si, which may form the basis of mineral transformation, neoformation and alteration processes during coalification of the peat deposits. As a result, most coal deposits from paleotropical environments are anticipated to have little to no biogenic inorganic material but high amounts of secondary clays, such as kaolinite (detrital kaolinite, resilisified kaolinite, or desilisified gibbsite) or illite, and various amounts of detrital and authigenetic quartz.  相似文献   

(Pa/U)-(Th/U) of young mafic volcanic rocks from Nicaragua and Costa Rica and the influence of flux melting on U-series systematics of arc lavas     

Rebecca B. Thomas  Marc M. HirschmannHai Cheng  Mark K. ReaganR.Lawrence Edwards 《Geochimica et cosmochimica acta》2002,66(24):4287-4309

We present U, Th, and Pa isotope data for young lavas from Costa Rica and Nicaragua in the Central American arc. Thorium isotopic ratios for Costa Rica and Nicaragua differ dramatically: Costa Rican lavas are characterized by low (²³⁰Th/²³²Th) (1 to 1.2) and, for four out of five lavas, (²³⁰Th/²³⁸U) greater than unity. Nicaraguan lavas have high (²³⁰Th/²³²Th) (2.2 to 2.7) and, for five of six samples, (²³⁰Th/²³⁸U) less than unity. All lavas have (²³¹Pa/²³⁵U) greater than unity, with initial values ranging from 1.27 to 1.77, but those from Costa Rica have larger ²³¹Pa excesses. There is a broad positive correlation between (²³¹Pa/²³⁵U) and (²³⁰Th/²³⁸U) similar to the worldwide trend for arcs outlined by Pickett and Murrell (1997), although many of the Nicaraguan lavas skirt the high end of that trend. In greater detail, the Central American data appear to divide into separate high-(²³¹Pa/²³⁵U) and low-(²³¹Pa/²³⁵U) tiers. These tiers may be different because of either different residence times in the crust or different proportions of sedimentary components from the slab.Substantial (²³¹Pa/²³⁵U) excesses (>1.5) in both Costa Rica and Nicaragua require a melting process that allows for enhanced daughter (²³¹Pa) ingrowth. With increasing U addition, (²³¹Pa/²³⁰Th) increases in a manner that cannot be explained adequately by aging of fluid components before partial melting and eruption. Thus, either some ²³¹Pa is added from the slab, or melting-enhanced ²³¹Pa ingrowth is greater in sources that have experienced a larger amount of slab-derived flux and a higher extent of melting. These observations can be explained if regions that have undergone greater extents of fluxing and melting have experienced these processes over a longer time interval than those that have had little flux added and little melt extracted. We propose a flux-ingrowth melting model in which corner flow in the mantle wedge supplies fresh hot mantle into a zone of slab fluid addition. Partial melting occurs in response to this fluxing. We assume critical melting at low porosity (∼10⁻³), rapid fluid flux to the melting region, and rapid melt transport. Solid mantle traverses the melting region over 10⁵ to 10⁶ yr, thereby allowing ²³¹Pa and ²³⁰Th ingrowth from U retained in the residues of melt extraction. Magmas are aggregated from all parts of the melting regime, mixing melts from incipiently fluxed regions with those from sources that have experienced more extensive fluid addition, partial melting, and daughter nuclide ingrowth. With suitable assumptions about component addition from the slab, this flux-ingrowth model matches a wide range of U-series and trace element data from Costa Rican and Nicaraguan lavas, with required average extents of melting of ∼1 to 3% and 7 to 15%, respectively. Upwelling and/or extensive melt-rock reaction are not required to explain large (²³¹Pa/²³⁵U) excesses in Central America or other arcs. On Th isotope equiline plots, the model produces linear arrays that resemble isochrons but that have no age significance. Instead, these arrays are generated by mixing of melts from sources that have experienced fluid addition and partial melting over a range of time intervals, as seems likely in arc source regions. Finally, the flux-ingrowth model predicts considerable ²²⁶Ra excesses for integrated magmas. If we assume that ²²⁶Ra is added continuously with the slab-derived fluid, the model predicts large and increasing (²²⁶Ra/²³⁰Th) with increasing melting and slab-component addition, without requiring the addition of a distinct late fluid.  相似文献   

Non-numeric computation for high eccentricity orbits     

R. Sridharan  Marc L. Renard 《Celestial Mechanics and Dynamical Astronomy》1975,11(2):179-194

Geocentric orbits of large eccentricity (e=0.9 to 0.95) are significantly perturbed in cislunar space by the Sun and Moon. The time-history of the height of perigee, subsequent to launch, is particularly critical. The determination of ‘launch windows’ is mostly concerned with preventing the height of perigee from falling below its low initial value before the mission lifetime has elapsed. Between the extremes of high accuracy digital integration of the equations of motion and of using an approximate, but very fast, stability criteria method, this paper is concerned with the development of a method of intermediate complexity using non-numeric computation. The computer is used as the theory generator to generalize Lidov's theory using six osculating elements. Symbolic integration is completely automatized and the output is a set of condensed formulae well suited for repeated applications in launch window analysis. Examples of applications are given.  相似文献   

Luna 24 ferrobasalt as a low-Mg primary melt     

Marc Norman  Graham Ryder 《Earth, Moon, and Planets》1980,23(3):271-292

Luna 24 very-low titanium (VLT) ferrobasalts, metabasalts, brown glasses and impact melts form a tight compositional cluster with no gradation to other groupings postulated for the Luna 24 core components. This suggests that the Luna 24 VLT ferrobasalt was extruded as a liquid of its own composition and was not derived by fractional crystallization from a more magnesian parent in a surface flow. Furthermore, the characteristics of the core lithologies are not easily visualized as components of such a differentiated flow, e.g. brown glasses. Gravitative settling models purporting to demonstrate the validity of the flow differentiation model are merely permissive.Subsurface fractionation requires that plagioclase, not olivine, be the liquidus phase.The high-Mg component in the Luna 24 core can be constrained, though not identified, chemically, and it has neither the major element, trace element, isotopic, nor mineralogical characteristics required of a possible parent to the Luna 24 VLT ferrobasalt. Thus models of fractionation lack a physical expression of the less differentiated compositions, contrary to the belief that the high-Mg component in the core is the parent material.The Luna 24 VLT ferrobasalt is probably a primary low-Mg melt from a plagioclase-bearing source region, and may have undergone little or no fractionation prior to eruption. Such a model is compatible with, and suggested by, chemical and experimental data. Caution against postulating that all Mg-poor melts are fractionated products, based on terrestrial models, is advised. The terrestrial oceanic situation of primary melts with similar Mg/Fe is probably not valid for the Moon.  相似文献   

Echelle observations of C iii λ1909 and Si iii λ1892     

Allen  Marc S. 《Solar physics》1979,64(1):71-75

Profiles of C iii 1909 and Si iii 1892 obtained on and near the limb during the 1976 flight of the University of Hawaii echelle rocket spectrograph were reduced and analyzed to determine electron densities and mass motions. The electron pressure derived (N _eT_e 4 × 10¹⁵ cm^–3) agrees well with that determined by Cook and Nicolas (1979) from ATM data. Nonthermal velocities in the region of formation of Si iii 1892 on the disk were found to be 10–12 km s^–1, somewhat lower than the values obtained by Doschek et al. (1976), also from ATM spectra. However, velocities derived at and above the limb were in closer agreement, about 17 km s^–1.Geosciences Systems Department, Computer Sciences Corporation, 8728 Colesville Road, Silver Spring, Md. 20910, U.S.A.  相似文献   

A Survey of the Southwest Indian Ridge Axis Between Atlantis II Fracture Zone and the Indian Ocean Triple Junction: Regional Setting and Large Scale Segmentation   总被引：4，自引：0，他引：4  

Patriat  Philippe  Sauter  Daniel  Munschy  Marc  Parson  Lindsay 《Marine Geophysical Researches》1997,19(6):457-480

The study of very low-spreading ridges has become essential to ourunderstanding of the mid-oceanic ridge processes. The Southwest Indian Ridge(SWIR) , a major plate boundary of the world oceans, separating Africa fromAntarctica for more than 100 Ma, has such an ultra slow-spreadingrate. Its other characteristic is the fast lengthening of its axis at bothBouvet and Rodrigues triple junctions. A survey was carried out in thespring of 1993 to complete a multibeam bathymetric coverage of the axisbetween Atlantis II Fracture Zone (57° E) and the Rodrigues triplejunction (70° E). After a review of what is known about the geometry,structure and evolution of the SWIR, we present an analysis of the newalong-axis bathymetric data together with previously acquiredacross-axis profiles. Only three transform faults, represented byAtlantis II FZ, Novara FZ, and Melville FZ, offset this more than 1000 kmlong section of the SWIR, showing that the offsets are more generallyaccommodated by ridge obliquity and non-transform discontinuities. From comparison of the axial geometry, bathymetry, mantle Bouguer anomaly and central magnetic anomaly, three large sections (east of Melville FZ, between Melville FZ and about 65°30 E, and from there to the Rodrigues triple junction) can be distinguished. The central member, east of Melville FZ, does not resemble any other known mid-oceanic ridge section: the classical signs of the accretion (mantle Bouguer anomaly, central magnetic anomaly) are only observed over three very narrow and shallow axis sections. We also apply image processing techniques to the satellite gravity anomaly map of Smith and Sandwell (1995) to determine the off-axis characteristics of the Southwest Indian Ridge domain, more especially the location of the triple junction and discontinuities traces. We conclude that the large-scale segmentation of the axis has been inherited from the evolution of the Rodrigues triple junction.  相似文献