Abrupt early Eocene global climatic change as a control of carbonate facies and diagenesis: a new record of the Palaeocene–Eocene Thermal Maximum in the Umm er Radhuma Formation,Saudi Arabia and Kuwait     

David A. Pollitt  Erik Anthonissen  Arthur H. Saller  Marcelle K. BouDagher‐Fadel  J. A. D. Dickson 《地学学报》2012,24(6):487-498

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Mineralogical attenuation for metallic remediation in a passive system for mine water treatment     

T. Maria Valente  M. Antunes  A. Sequeira Braga  M. I. Prudêncio  R. Marques  J. Pamplona 《Environmental Earth Sciences》2012,66(1):39-54

Passive systems with constructed wetlands have been consistently used to treat mine water from abandoned mines. Long-term and cost-effective remediation is a crucial expectation for these water treatment facilities. To achieve that, a complex chain of physical, chemical, biological, and mineralogical mechanisms for pollutants removal must be designed to simulate natural attenuation processes. This paper aims to present geochemical and mineralogical data obtained in a recently constructed passive system (from an abandoned mine, Jales, Northern Portugal). It shows the role of different solid materials in the retention of metals and arsenic, observed during the start-up period of the treatment plant. The mineralogical study focused on two types of materials: (1) the ochre-precipitates, formed as waste products from the neutralization process, and (2) the fine-grained minerals contained in the soil of the wetlands. The ochre-precipitates demonstrated to be poorly ordered iron-rich material, which gave rise to hematite upon artificial heating. The heating experiments also provided mineralogical evidence for the presence of an associated amorphous arsenic-rich compound. Chemical analysis on the freshly ochre-precipitates revealed high concentrations of arsenic (51,867 ppm) and metals, such as zinc (1,213 ppm) and manganese (821 ppm), indicating strong enrichment factors relative to the water from which they precipitate. Mineralogical data obtained in the soil of the wetlands indicate that chlorite, illite, chlorite–vermiculite and mica–vermiculite mixed-layers, vermiculite, kaolinite and goethite are concentrated in the fine-grained fractions (<20 and <2 μm). The chemical analyses show that high levels of arsenic (up to 3%) and metals are also retained in these fractions, which may be enhanced by the low degree of order of the clay minerals as suggested by an XRD study. The obtained results suggest that, although the treatment plant has been receiving water only since 2006, future performance will be strongly dependent on these identified mineralogical pollutant hosts.  相似文献   

Transition From Forearc Basin to Syn-Collisional Basin in Southern Tibet (Paleocene Cuojiangding Group): Implication to Timing of the India-Asia Initial Collision and of Yarlung Zangbo Ophiolite Emplacement     

HU Xiumian  WANG Jiangang  Marcelle BouDagher-Fadel  Eduardo Garzanti  WEI An 《《地质学报》英文版》2013,87(Z1):27-28

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The PMS δ Scuti star PDS2     

M. Marconi  V. Ripepi  S. Bernabei  A. Ruoppo  M. J. P. F. G. Monteiro  J. P. Marques  F. Palla  S. Leccia 《Astrophysics and Space Science》2010,328(1-2):109-111

The Herbig Ae star PDS2 was found to pulsate as a Pre-Main-Sequence delta Scuti star on the basis of R.E.M. telescope photometry. From the frequency analysis we have found four significant pulsation frequencies. We discuss these results and their interpretation through the adoption of nonradial pulsation models, deriving the first information on the intrinsic properties of this young star.  相似文献   

Amazonian floodplain water balance based on modelling and analyses of hydrologic and electrical conductivity data          下载免费PDF全文

Marie‐Paule Bonnet  Sébastien Pinel  Jérémie Garnier  Julie Bois  Géraldo Resende Boaventura  Patrick Seyler  David Motta Marques 《水文研究》2017,31(9):1702-1718

In the Amazon basin, floodplains form a complex mosaic of freshwater systems with differing morphologies, resulting in varied inundation patterns and heterogeneous chemical and ecological characteristics. In this study, we focused on the Janauacá floodplain, a medium‐sized system (786 km², including the local watershed) located along the Solimões River. Based on in situ and satellite observations acquired from November 2006 to November 2011, we computed water fluxes between the mainstream and the floodplain and examined the temporal dynamics of floodplain storage from river flooding, rainfall, runoff, and exchanges with groundwater through bank seepage for the 5 years from 2006 to 2011. The mainstream was the main input of water to the flooded area, accounting on average for 93% of total water inputs by the end of the water year. Direct precipitation and runoff from uplands contributed less than or equal to 5% and 10%, respectively. The seepage contribution was less than 1%. Model uncertainties, evaluated using Monte Carlo analysis of the input data and model parameters, showed that all water fluxes were relatively well constrained except for outflow through seepage, which had a standard deviation across simulations greater than 60%. The water balance computation was verified using electrical conductivity as an assumed non‐reactive tracer. Except during periods of very low water, the simulated and measured conductivities agreed well. Moreover, conductivity data analysis confirmed that the Janauacá system can be considered homogeneous in terms of electrical conductivity for filling percentages equal to or greater than 40% (i.e., when the water level is above 19.5 m, generally from April to August) but presented large heterogeneities during the rest of the hydrological cycle.  相似文献   

Assessment of mixing between shallow and thermal waters using geochemical and environmental isotope tracers (N Portugal): a review and reinterpretation     

J.?M.?MarquesEmail author  C.?Matos  P.?M.?Carreira  J.?Espinha Marques  J.?Teixeira  H.?I.?Chaminé 《Environmental Earth Sciences》2014,72(7):2557-2567

Caldas de Moledo thermal (27–46 °C) spring and borehole waters issue in the region of the famous Port Wine vineyards, in the Douro River valley (Northern Portugal). The most abundant lithotypes are lower Cambrian metasedimentary rocks, Variscan granitoids and aplite-pegmatitic veins. The thermal waters are characterised by pH ≈ 9.0, TDS ranging from 200 to 350 mg/L, and belong to the HCO₃–Na facies indicating that the reservoir rock should be mainly granite. Since the local Spa is strongly dependent on water quality, the effects of mixing between local shallow cold groundwaters and deep thermal waters have been properly investigated. In the SO₄ ^2? (mg/L) versus δ¹⁸O (‰ vs. V-SMOW) diagram we can observe that some of the thermal springs show evidences of mixing (higher SO₄ ^2? concentrations) with local meteoric waters infiltrated at lower altitude sites (enriched δ¹⁸O signatures), showing the “altitude effect” in the isotopic composition of the recharge waters. Similar trends can be found in the K⁺, NO₃ ^?, Ca²⁺ and Na⁺ (mg/L) versus δ¹⁸O (‰ vs. V-SMOW) diagrams. It should be stated that SO₄ ^2?, K⁺ and Ca²⁺ are present in the fertilizers and fungicides used in the vineyards in the northern part of the country. Up to now, the thermal waters from boreholes used in the local Spa do not show evidences of mixing with shallow groundwaters contaminated with agrochemicals. The results obtained so far indicate that in the near future, special attention should be put on the possible occurrence of diffuse agricultural contamination (related to the Port Wine vineyards) in the thermal spring waters.  相似文献   

Apparent discrepancy in contamination history of a sub-tropical estuary evaluated through 210Pb profile and chronostratigraphical markers     

Marques AN  Monna F  da Silva Filho EV  Fernex FE  Fernando Lamego Simões Filho F 《Marine pollution bulletin》2006,52(5):532-539

Zn and Cd concentrations, stable lead isotopes and ²¹⁰Pb-derived chronology were determined in a sediment core sampled at Sepetiba Bay (South-eastern Brazil). During the last decades, the bay’s watershed has been modified by the increase of industrial activities and human interventions. In particular, Zn and Cd ore treatment plants were built near the coast in 1960 and 1970, respectively, and water has been diverted from the adjacent Paraíba do Sul River watershed since 1950. The core collected at shallow depth near the industrial area exhibits four successive events: (i) at 50 cm depth, a change in the ²⁰⁶Pb/²⁰⁷Pb ratio from about 1.162 to more than 1.18 might be the result of the São Francisco Channel opening and water diversion from Paraíba do Sul river; (ii) at 40 cm depth, Zn concentration starts to increase (up to 0.8 mg g⁻¹) (iii) above 30 cm depth, relatively high Cd concentrations (up to 1.6 μg g⁻¹) are observed and (iv) at 16 cm depth, change in unsupported ²¹⁰Pb slope is probably related to a waste dam built to prevent strong metal contamination in the bay. Sediment accumulation rates evaluated by Zn and Cd profiles used as time-markers are higher than those calculated from ²¹⁰Pb-based chronology models. Using the constant initial concentration (CIC) model both events are supposed to date back to about 1884 and 1902, respectively, while using the constant rate of supply (CRS) model it shifts to about 1925 and 1935. Such discrepancies are probably assigned to the fact that these models do not take into account site-specific local sedimentation dynamics. In the study area, particles deposition seems to be controlled by enrichment with unsupported ²¹⁰Pb transported by runoff from a mangrove flat bank. Chronology derived from a model that assumes an exponential increase of the initial ²¹⁰Pb activity fits well with the estimated rates obtained from historical events.  相似文献   

Integration of GIS and remote sensing for estimation of soil loss and prioritization of critical sub-catchments: a case study of Tapacurá catchment   总被引：1，自引：0，他引：1  

Richarde Marques da Silva  Suzana Maria Gico Lima Montenegro  Celso Augusto Guimar?es Santos 《Natural Hazards》2012,62(3):953-970

Mapping of erosion risk areas is an important tool for the planning of natural resources management, allowing researchers to propose the modification of land use properly and implement more sustainable long-term management strategies. The objective of this study was to assess and identify critical sub-catchments for soil conservation management using the USLE, GIS, and remote sensing techniques. The Tapacurá catchment is one of the planning units for water resource management of the Recife Metropolitan Region. Maps of the erosivity (R), erodibility (K), slope (LS), cover-management (C), and support practice (P) factors were derived from the climate database, digital elevation model, and soil and land-use maps. In order to validate the simulation process, total sediment delivery ratio was estimated. The results showed a mean sediment delivery ratio (SDR) of around 11.5?% and a calculated mean sediment yield of 0.108?t?ha^?1?year^?1, which is close to the observed one, 0.169?t?ha^?1?year^?1. The obtained soil loss map could be considered as a useful tool for environmental monitoring and water resources management. The methodology applied showed acceptable precision and allowed the identification of the most susceptible areas to soil erosion by water, constituting an important predictive tool for soil and environmental management in this region, which is highly relevant for the prediction of varying development scenarios for Tapacurá catchment. This approach can be applied to other areas for simple and reliable identification of critical areas of soil erosion in catchments.  相似文献   

Lacustrine sediments provide geochemical evidence of environmental change during the last millennium in southeastern Brazil     

Sonia Maria Barros de Oliveira  Soraya Elaine Marques Gouveia Saia  Luiz Carlos Ruiz Pessenda  Deborah Ines Teixeira Favaro 《Chemie der Erde / Geochemistry》2009,69(4):395-405

A 172 cm-long sediment core was collected from a small pristine lake situated within a centripetal drainage basin in a tropical karst environment (Ribeira River valley, southeastern Brazil) in order to investigate the paleoenvironmental record provided by the lacustrine geochemistry. Sediments derived from erosion of the surrounding cambisoils contain quartz, kaolinite, mica, chlorite and goethite. Accelerator mass spectroscopy (AMS) ¹⁴C dating provided the geochronological framework. Three major sedimentary units were identified based on the structure and color of the sediments: Unit III from 170 to140 cm (1030±60–730±60 yr BP), Unit II from 140 to 90 cm (730±60–360±60 yr BP) and Unit I from 90 to 0 cm (360±60–0 yr BP). Results of major and trace element concentrations were analysed through multivariate statistical techniques. Factor analysis provided three factors accounting for 72.4% of the total variance. F1 and F2 have high positive loadings from K, Ba, Cs, Rb, Sr, Sc, Th, light rare earth element (LREE), Fe, Cr, Ti, Zr, Hf and Ta, and high negative loadings from Mg, Co, Cu, Zn, Br and loss on ignition (LOI). F3, with positive loadings from V and non-metals As and Sb, accounts for a low percentage (9.7%) of the total variance, being therefore of little interpretative use. The profile distribution of F1 scores reveals negative values in Units I and III, and positive values in Unit II, meaning that K, Ba, Cs, Rb, Sr, Sc, Th, LREE, Fe, Cr, Ti, Zr, Hf and Ta are relatively more concentrated in Unit II, and Mg, Co, Cu, Zn and Br are relatively more abundant in Units I and III. The observed fluctuations in the geochemical composition of the sediments are consistent with slight variations of the erosion intensity in the catchment area as a possible response to variations of climatic conditions during the last millennium.  相似文献   

Environmental issues in urban groundwater systems: a multidisciplinary study of the Paranhos and Salgueiros spring waters,Porto (NW Portugal)   总被引：1，自引：1，他引：0  

Maria José Afonso  Helder I. Chaminé  José M. Marques  Paula M. Carreira  Laura Guimarães  Lúcia Guilhermino  Alberto Gomes  Paulo E. Fonseca  Ana Pires  Fernando Rocha 《Environmental Earth Sciences》2010,61(2):379-392

This study presents the results of a multidisciplinary approach, using hydrogeochemical, isotopic and ecotoxicological analyses, performed to assess the nature and suitability for use of Paranhos and Salgueiros spring waters (Porto city, NW Portugal). Based on the surface activities located along the course of the springs, 23 water samples were collected. All the samples were analysed for major element concentrations. The isotopic techniques employed included δ²H, δ¹⁸O and ³H. Standard acute bioassays with Daphnia magna were also performed. The hydrogeochemical analyses showed a nitrate and sulphate-enriched composition for these groundwaters, resulting mainly from urban drainage and sewer leakage. In the ecotoxicological analyses, no significant mortality was observed in any of the tests performed. The results obtained in this study suggest that Porto urban groundwater could be suitable for irrigation uses.  相似文献