PM₁₀ and heavy metal measurements in an industrial area of southern Italy   总被引：1，自引：0，他引：1  

Maria Ragosta  Rosa Caggiano  Mariagrazia D'Emilio  Serena Sabia  Serena Trippetta  Maria Macchiato   《Atmospheric Research》2006,81(4):304-319

Atmospheric particulate concentrations and heavy metal content are measured from March to July 2001 at an industrial site located in a rural zone of the southern Italy. PM₁₀ samples are collected by a low-volume sampler and each sample is analysed by AAS techniques for its content of Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn. We measure also temperature, atmospheric pressure and relative humidity, and we collect anemometric data. The study purpose is the investigation of pollutant levels in an industrial area located in a rather unpolluted region and the characterization of the correlation structure among particulate concentrations, heavy metal content and local meteorological parameters. Data analysis is carried out by means of univariate and multivariate statistical methods. In the investigated period, the average value of PM₁₀ daily concentrations (24 μg Nm^− 3) does not exceed the national standard of 40 μg Nm^− 3 and only nine values are higher than the European daily limit value of 50 μg Nm^− 3. Particularly, the occurrence of two anomalous values (183 μg Nm^− 3 in 3 March and 94 μg Nm^− 3 in 22 June) seems to be related to no-local events as confirmed both by in situ data measured in the AQM network of Potenza city (about 10 km far from the study area) and by remote measurements performed in the same days. Regarding the heavy metal levels, we observe high levels of Cr (34 ng Nm^− 3), Ni (85 ng Nm^− 3) and Zn (214 ng Nm^− 3) in agreement with the local industrial source pattern. The multivariate analysis, carried out using meteorological parameters as exogenous variables, allow to evaluate the role of the different variables as driving factors of the correlation structure among the metals.  相似文献   

An Intercomparison of Large-Eddy Simulations of the Stable Boundary Layer   总被引：2，自引：27，他引：2  

Robert J. Beare  Malcolm K. Macvean  Albert A. M. Holtslag  Joan Cuxart  Igor Esau  Jean-Christophe Golaz  Maria A. Jimenez  Marat Khairoutdinov  Branko Kosovic  David Lewellen  Thomas S. Lund  Julie K. Lundquist  Anne Mccabe  Arnold F. Moene  Yign Noh  Siegfried Raasch  Peter Sullivan 《Boundary-Layer Meteorology》2006,118(2):247-272

Results are presented from the first intercomparison of large-eddy simulation (LES) models for the stable boundary layer (SBL), as part of the Global Energy and Water Cycle Experiment Atmospheric Boundary Layer Study initiative. A moderately stable case is used, based on Arctic observations. All models produce successful simulations, in as much as they generate resolved turbulence and reflect many of the results from local scaling theory and observations. Simulations performed at 1-m and 2-m resolution show only small changes in the mean profiles compared to coarser resolutions. Also, sensitivity to subgrid models for individual models highlights their importance in SBL simulation at moderate resolution (6.25 m). Stability functions are derived from the LES using typical mixing lengths used in numerical weather prediction (NWP) and climate models. The functions have smaller values than those used in NWP. There is also support for the use of K-profile similarity in parametrizations. Thus, the results provide improved understanding and motivate future developments of the parametrization of the SBL.  相似文献   

Evaluation of the Urban Tile in MOSES using Surface Energy Balance Observations     

M. J. Best  C. S. B. Grimmond  Maria Gabriella Villani 《Boundary-Layer Meteorology》2006,118(3):503-525

The UK Met Office has introduced a new scheme for its urban tile in MOSES 2.2 (Met Office Surface Exchange Scheme version 2.2), which is currently implemented within the operational Met Office weather forecasting model. Here, the performance of the urban tile is evaluated in two urban areas: the historic core of downtown Mexico City and a light industrial site in Vancouver, Canada. The sites differ in terms of building structures and mean building heights. In both cases vegetation cover is less than 5%. The evaluation is based on surface energy balance flux measurements conducted at approximately the blending height, which is the location where the surface scheme passes flux data into the atmospheric model. At both sites, MOSES 2.2 correctly simulates the net radiation, but there are discrepancies in the partitioning of turbulent and storage heat fluxes between predicted and observed values. Of the turbulent fluxes, latent heat fluxes were underpredicted by about one order of magnitude. Multiple model runs revealed MOSES 2.2 to be sensitive to changes in the canopy heat storage and in the ratio between the aerodynamic roughness length and that for heat transfer (temperature). Model performance was optimum with heat capacity values smaller than those generally considered for these sites. The results suggest that the current scheme is probably too simple, and that improvements may be obtained by increasing the complexity of the model.  相似文献   

Biochronology and biochron boundaries: A real dilemma or a false problem? An example based on the Pleistocene large mammalian faunas from Italy     

Maria Rita Palombo  Raffaele Sardella 《Quaternary International》2007,160(1):30

Reconstructing the Neogene-Quaternary biostratigraphy in continental environments and recognising ‘boundaries’ between successive mammalian faunal complexes is a problematic task. The definition and application of biochronology has been often tainted by references to and inferences from biostratigraphy. Actually, the discontinuities in the continental sedimentary record, environmental conditions, taphonomic and sampling biases are responsible for the fact that the stratigraphical order of the lowest and highest occurrences of fossil remains (stratigraphic datum) does not necessarily reflect the temporal order of actual first/last appearances of taxa (palaeobiological events) in time. Nonetheless, the first/last appearance bioevents (recorded by lowest/highest occurrences of fossil remains in fossiliferous levels of different continental stratigraphical successions) have been the principal foundation for establishing the biochronological setting of continental mammal faunas. Therefore, from a theoretical point of view, ‘boundaries’ should be defined by the oldest and/or youngest ‘historical occurrence’ of one or more taxa. What about an operational approach?Some examples of the Italian faunas are presented, focusing on the transition from the Villafranchian to the Galerian and from the Galerian to the Aurelian Land-Mammal Ages. The results obtained indicate the difficulty of defining a stable scheme that can be applied for correlation by the international scientific community.  相似文献   

Cleats and their relation to geologic lineaments and coalbed methane potential in Pennsylvanian coals in Indiana   总被引：2，自引：0，他引：2  

Wilfrido Solano-Acosta  Maria Mastalerz  Arndt Schimmelmann 《International Journal of Coal Geology》2007,72(3-4):187-208

Cleats and fractures in Pennsylvanian coals in southwestern Indiana were described, statistically analyzed, and subsequently interpreted in terms of their origin, relation to geologic lineaments, and significance for coal permeability and coalbed gas generation and storage. These cleats can be interpreted as the result of superimposed endogenic and exogenic processes. Endogenic processes are associated with coalification (i.e., matrix dehydration and shrinkage), while exogenic processes are mainly associated with larger-scale phenomena, such as tectonic stress.At least two distinct generations of cleats were identified on the basis of field reconnaissance and microscopic study: a first generation of cleats that developed early on during coalification and a second generation that cuts through the previous one at an angle that mimics the orientation of the present-day stress field. The observed parallelism between early-formed cleats and mapped lineaments suggests a well-established tectonic control during early cleat formation. Authigenic minerals filling early cleats represent the vestiges of once open hydrologic regimes. The second generation of cleats is characterized by less prominent features (i.e., smaller apertures) with a much less pronounced occurrence of authigenic mineralization. Our findings suggest a multistage development of cleats that resulted from tectonic stress regimes that changed orientation during coalification and basin evolution.The coals studied are characterized by a macrocleat distribution similar to that of well-developed coalbed methane basins (e.g., Black Warrior Basin, Alabama). Scatter plots and regression analyses of meso- and microcleats reveal a power-law distribution between spacing and cleat aperture. The same distribution was observed for fractures at microscopic scale. Our observations suggest that microcleats enhance permeability by providing additional paths for migration of gas out of the coal matrix, in addition to providing access for methanogenic bacteria.The abundance, distribution, and orientation of cleats control coal fabric and are crucial features in all stages of coalbed gas operations (i.e., exploration and production). Understanding coal fabric is important for coal gas exploration as it may be related to groundwater migration and the occurrence of methanogenic bacteria, prerequisite to biogenic gas accumulations. Likewise, the distribution of cleats in coal also determines pathways for migration and accumulation of thermogenic gas generated during coalification.  相似文献   

An immersed boundary method for compressible multiphase flows: application to the dynamics of pyroclastic density currents     

Mattia de’ Michieli Vitturi  Tomaso Esposti Ongaro  Augusto Neri  Maria Vittoria Salvetti  François Beux 《Computational Geosciences》2007,11(3):183-198

  相似文献   

The geology of the Morro Velho gold deposit in the Archean Rio das Velhas greenstone belt, Quadrilátero Ferrífero, Brazil     

Diogenes Scipioni Vial  Ed DeWitt  Lydia Maria Lobato  Charles H. Thorman 《Ore Geology Reviews》2007,32(3-4):511

The Morro Velho gold deposit, Quadrilátero Ferrífero region, Minas Gerais, Brazil, is hosted by rocks at the base of the Archean Rio das Velhas greenstone belt. The deposit occurs within a thick carbonaceous phyllite package, containing intercalations of felsic and intermediate volcaniclastic rocks and dolomites. Considering the temporal and spatial association of the deposit with the Rio das Velhas orogeny, and location in close proximity to a major NNW-trending fault zone, it can be classified as an orogenic gold deposit. Hydrothermal activity was characterized by intense enrichment in alteration zones of carbonates, sulfides, chlorite, white mica±biotite, albite and quartz, as described in other Archean lode-type gold ores. Two types of ore occur in the deposit: dark gray quartz veins and sulfide-rich gold orebodies. The sulfide-rich orebodies range from disseminated concentrations of sulfide minerals to massive sulfide bodies. The sulfide assemblage comprises (by volume), on average, 74% pyrrhotite, 17% arsenopyrite, 8% pyrite and 1% chalcopyrite. The orebodies have a long axis parallel to the local stretching lineation, with continuity down the plunge of fold axis for at least 4.8 km. The group of rocks hosting the Morro Velho gold mineralization is locally referred to as lapa seca. These were isoclinally folded and metamorphosed prior to gold mineralization. The lapa seca and the orebodies it hosts are distributed in five main tight folds related to F1 (the best examples are the X, Main and South orebodies, in level 25), which are disrupted by NE- to E-striking shear zones. Textural features indicate that the sulfide mineralization postdated regional peak metamorphism, and that the massive sulfide ore has subsequently been neither metamorphosed nor deformed. Lead isotope ratios indicate a model age of 2.82 ± 0.05 Ga for both sulfide and gold mineralization. The lapa seca are interpreted as the results of a pre-gold alteration process and may be divided into carbonatic, micaceous and quartzose types. The carbonatic lapa seca is subdivided into gray and brown subtypes. Non-mineralized, gray carbonatic lapa seca forms the hanging wall to the orebodies, and is interpreted as the product of extreme CO₂ metasomatism during hydrothermal alteration. This dolomitic lapa seca ranges in composition from relatively pure limestone and dolomite to silty limestone and dolomite. The brown carbonatic and micaceous lapa secas are the host rocks to gold. These units are interpreted to correspond to the sheared and hydrothermal products of metamorphosed volcaniclastic and/or volcanic rocks of varying composition from dacitic to andesitic, forming various types of schists and phyllites. The high-grade, massive sulfide orebodies occur at the base of the gray carbonatic lapa seca. Both disseminated mineralization and quartz veins are hosted by micaceous lapa seca. The data are consistent with a model of epigenetic mineralization for the lapa seca, from a hydrothermal fluid derived in part from the Archean basement or older crust material.  相似文献   

Large debris avalanches and associated eruptions in the Holocene eruptive history of Shiveluch Volcano, Kamchatka, Russia     

Vera V. Ponomareva  Maria M. Pevzner  Ivan V. Melekestsev 《Bulletin of Volcanology》1998,59(7):490-505

 Shiveluch Volcano, located in the Central Kamchatka Depression, has experienced multiple flank failures during its lifetime, most recently in 1964. The overlapping deposits of at least 13 large Holocene debris avalanches cover an area of approximately 200 km² of the southern sector of the volcano. Deposits of two debris avalanches associated with flank extrusive domes are, in addition, located on its western slope. The maximum travel distance of individual Holocene avalanches exceeds 20 km, and their volumes reach ∼3 km³. The deposits of most avalanches typically have a hummocky surface, are poorly sorted and graded, and contain angular heterogeneous rock fragments of various sizes surrounded by coarse to fine matrix. The deposits differ in color, indicating different sources on the edifice. Tephrochronological and radiocarbon dating of the avalanches shows that the first large Holocene avalanches were emplaced approximately 4530–4350 BC. From ∼2490 BC at least 13 avalanches occurred after intervals of 30–900 years. Six large avalanches were emplaced between 120 and 970 AD, with recurrence intervals of 30–340 years. All the debris avalanches were followed by eruptions that produced various types of pyroclastic deposits. Features of some surge deposits suggest that they might have originated as a result of directed blasts triggered by rockslides. Most avalanche deposits are composed of fresh andesitic rocks of extrusive domes, so the avalanches might have resulted from the high magma supply rate and the repetitive formation of the domes. No trace of the 1854 summit failure mentioned in historical records has been found beyond 8 km from the crater; perhaps witnesses exaggerated or misinterpreted the events. Received: 18 August 1997 / Accepted: 19 December 1997  相似文献   

The 200 mJy Subsample at 1.4 GHz     

Mercedes Esteves Filho  Maria João Marchã 《Astrophysics and Space Science》1998,261(1-4):259-260

  相似文献   

Low-degree partial melting trends recorded in upper mantle minerals     

Pierre Schiano  Bernard Bourdon  Robert Clocchiatti  Dominique Massare  Maria E. Varela  Yan Bottinga 《Earth and Planetary Science Letters》1998,160(3-4):537-550

The study of glass inclusions inside mantle minerals provides direct information about the chemistry of naturally occurring mantle-derived melts and the fine-scale complexity of the melting process responsible for their genesis. Minerals in a spinel lherzolite nodule from Grande Comore island contain glass inclusions which, after homogenization by heating, exhibit a continuous suite of chemical compositions clearly distinct from that of the host basanitic lava. The compositions range from silicic, with nepheline–olivine normative, 64 wt% SiO₂ and 11 wt% alkali oxides, to almost basaltic, with quartz normative, 50 wt% SiO₂ and 1–2 wt% alkali oxides. Within a single mineral phase, olivine, the inferred primary melt composition varies from 54 to 64 wt% SiO₂ for MgO content ranging from 8 to 0.8 wt%. An experimental study of the glass and fluid inclusions indicates that trapped melts represent liquids that are in equilibrium with their host phases at moderate temperature and pressure (T≈1230°C and P≈1.0 Gpa for melts trapped in olivine). Quantitative modelling of the compositional trends defined in the suite shows that all of the glasses are part of a cogenetic set of melts formed by fractional melting of spinel lherzolite, with F varying between 0.2 and 5%. The initial highly silicic, alkali-rich melts preserved in Mg-rich olivine become richer in FeO, MgO, CaO and Cr₂O₃ and poorer in SiO₂, K₂O, Na₂O, Al₂O₃ and Cl with increasing melt fractions, evolving toward the basaltic melts found in clinopyroxene. These results confirm the connection between glass inclusions inside mantle minerals and partial mantle melts, and indicate that primary melts with SiO₂ >60 wt%, alkali oxides >11%, FeO <1 wt% and MgO <1 wt% are generated during incipient melting of spinel peridotite. The composition of the primary melts is inferred to be dependent on pressure, and to reflect both the speciation of dissolved CO₂ and the effect of alkali oxides on the silica activity coefficient in the melt. At pressures around 1 GPa, low-degree melts are characterized by alkali and silica-rich compositions, with a limited effect of dissolved CO₂ and a decreased silica activity coefficient caused by the presence of alkali oxides, whereas at higher pressures alkali oxides form complexes with carbonates and, consequently, alkali-rich silica-poor melts will be generated.  相似文献