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51.
Trace elements contamination of agricultural soils affected by sulphide exploitation (Iberian Pyrite Belt,Sw Spain) 总被引:1,自引:0,他引:1
Agricultural soils of the Riotinto mining area (Iberian Pyrite Belt) have been studied to assess the degree of pollution by
trace elements as a consequence of the extraction and treatment of sulphides. Fifteen soil samples were collected and analysed
by ICP-OES and INAA for 51 elements. Chemical analyses showed an As–Cu–Pb–Zn association related with the mineralisation of
the Iberian Pyrite Belt. Concentrations were 19–994 mg kg−1 for As, 41–4,890 mg kg−1 for Pb, 95–897 mg kg−1 for Zn and of 27–1,160 mg kg−1 for Cu. Most of the samples displayed concentrations of these elements higher than the 90th percentile of the corresponding
geological dominium, which suggests an anthropogenic input besides the bedrock influence. Samples collected from sediments
were more contaminated than leptosols because they were polluted by leachates or by mining spills coming from the waste rock
piles. The weathering of the bedrock is responsible for high concentrations in Co, Cr and Ni, but an anthropogenic input,
such as wind-blown dust, seems to be indicative of the high content of As, Cu, Pb and Zn in leptosols. The metal partitioning
patterns show that most trace elements are associated with Fe amorphous oxy-hydroxides, or take part of the residual fraction.
According to the results obtained, the following mobility sequence is proposed for major and minor elements: Mn, Pb, Cd, > Zn,
Cu > Ni > As > Fe > Cr. The high mobility of Pb, Cu and Zn involve an environmental risk in this area, even in soils where
the concentrations are not so high. 相似文献
52.
Natural radioactivity in sediment of Wei River,China 总被引:1,自引:0,他引:1
The concentrations of natural radionuclides in sediment of Wei River of China were measured using γ-ray spectrometry with
the aim of estimating the radiation hazard as establishing a database for radioactivity levels of river sediment of China.
The activity concentrations of 226Ra, 232Th and 40K in sediment samples ranged from 10.4 to 39.9 Bq kg−1, 15.3 to 54.8 Bq kg−1 and 514.8 to 1,175.5 Bq kg−1, respectively. The concentrations of these radionuclides were compared with the typical world values and the average activities
of Chinese soil and Shaanxi soil. Radium equivalent activity (Raeq), external hazard index (H
ex) and representative level index (I
γr) were calculated for the samples to assess the radiation hazards arising due to the use of these sediment samples in the
construction of dwellings. All the sediment samples have Raeq lower than the limit of 370 Bq kg−1, H
ex less than unity and I
γr close to 1 Bq kg−1. The overall mean outdoor terrestrial gamma dose rate is 64.8 nGy h−1 and the corresponding outdoor annual effective dose is 0.079 mSv. None of the studied location is considered a radiological
risk and sediment can be safely used in construction. 相似文献
53.
J. L. Simón M. A. Soriano L. E. Arlegui J. Gracia C. L. Liesa A. Pocoví 《Environmental Geology》2008,53(5):1057-1065
Space and time variations of alluvial karst subsidence in the central Ebro Basin are analysed in trenches (paleodolines),
aerial photographs (historical dolines) and field surveys (present-day active dolines). The measured subsidence rates, as
well as a comparison between densities of paleodolines computed in randomly selected scan-lines and density of active dolines
computed in maps, suggest that present-day subsidence in favourable areas is more intense than that of Pleistocene times.
According to diachronic maps drawn from (a) different aerial photographs taken after 1946 and (b) field surveys on deformations
in urbanized areas, subsidence behaved as a nearly steady process while the whole area was used for agriculture. In contrast,
rapid changes (through periods of several tens of years) have occurred in urbanized areas, in which dolines expand their boundaries
through small marginal collapses, shifting sharply their sinking centres to neighbouring sites. These rapid changes do not
have an equivalent in observed paleodolines. 相似文献
54.
Gamma activity from the naturally occurring radionuclides namely, 226Ra, 232Th, the primordial radionuclide 40K was measured in the soil of Cuihua Mountain National Geological Park, China using γ-ray spectrometry technique. The mean
activity of 226Ra, 232Th and 40K were found to be 27.2 ± 6.5, 43.9 ± 6.2 and 653.1 ± 127.6 Bq kg−1, respectively. The concentrations of these radionuclides were compared with the typical world values and the average activities
of Chinese soil. The radium equivalent activity, the air absorbed dose rate, the annual effective dose rate, and the external
hazard index were evaluated and compared with the internationally approved values. All the soil samples have Raeq lower than the limit of 370 Bq kg−1 and H
ex less than unity. The overall mean outdoor terrestrial gamma dose rate is 66.3 nGy h−1 and the corresponding outdoor annual effective dose is 0.081 mSv. 相似文献
55.
M. M. Jordán S. Pina F. García-Orenes M. B. Almendro-Candel E. García-Sánchez 《Environmental Geology》2008,55(2):453-462
The ecologic restoration criteria in areas degraded from extraction activities require making use of their mine spoils. These
materials do not meet fertility conditions to guarantee restoration success and therefore, need the incorporation of organic
amendments to obtain efficient substratum. Reducing the deficiencies in the organic material and restoration material nutrients
with the contribution of treated sewage sludge is proposed in this work. This experiment was based on a controlled study using
columns. The work was conducted with two mine spoils, both very rich in calcium carbonate. The first mineral, of poor quality,
came from the formation of aggregates of crushed limestone (Z). The other residual material examined originated in limestone extraction, formed by the levels of interspersed non-limestone
materials and the remains of stripped soils (D). Two treatments were undertaken (30,000 and 90,000 kg/ha of sewage sludge), in addition to a control treatment. The water
contribution was carried out with a device that simulated either short-duration rain or a flooding irrigation system in order
to cover the surface and then percolate through the soil. The collection of leached water took place 24 h after the applications.
Different parameters of the leached water were determined, including pH, electrical conductivity, nitrate anions, ammonium,
phosphates, sulphates and chlorides. The values obtained for each irrigation application are discussed, and the nitrate values
obtained were very elevated. 相似文献
56.
Jos M. Marques Paula M. Carreira Maria Rosrio Carvalho Maria J. Matias Fraser E. Goff Maria J. Basto Rui C. Graa Luís Aires-Barros Luís Rocha 《Applied Geochemistry》2008,23(12):3278-3289
This paper reviews the geochemical, isotopic (2H, 18O, 13C, 3H and 14C) and numerical modelling approaches to evaluate possible geological sources of the high pH (11.5)/Na–Cl/Ca–OH mineral waters from the Cabeço de Vide region (Central-Portugal). Water–rock interaction studies have greatly contributed to a conceptual hydrogeological circulation model of the Cabeço de Vide mineral waters, which was corroborated by numerical modelling approaches. The local shallow groundwaters belong to the Mg–HCO3 type, and are derived by interaction with the local serpentinized rocks. At depth, these type waters evolve into the high pH/Na–Cl/Ca–OH mineral waters of Cabeço de Vide spas, issuing from the intrusive contact between mafic/ultramafic rocks and an older carbonate sequence. The Cabeço de Vide mineral waters are supersaturated with respect to serpentine indicating that they may cause serpentinization. Magnesium silicate phases (brucite and serpentine) seem to control Mg concentrations in Cabeço de Vide mineral waters. Similar δ2H and δ18O suggest a common meteoric origin and that the Mg–HCO3 type waters have evolved towards Cabeço de Vide mineral waters. The reaction path simulations show that the progressive evolution of the Ca–HCO3 to Mg–HCO3 waters can be attributed to the interaction of meteoric waters with serpentinites. The sequential dissolution at CO2 (g) closed system conditions leads to the precipitation of calcite, magnesite, amorphous silica, chrysotile and brucite, indicating that the waters would be responsible for the serpentinization of fresh ultramafic rocks (dunites) present at depth. The apparent age of Cabeço de Vide mineral waters was determined as 2790 ± 40 a BP, on the basis of 14C and 13C values, which is in agreement with the 3H concentrations being below the detection limit. 相似文献
57.
Flood hazard delineation combining geomorphological and hydrological methods: an example in the Northern Iberian Peninsula 总被引:2,自引:1,他引:1
Flood mapping requires the combination and integration of geomorphological and hydrological-hydraulic methods; however, despite
this, there is very little scientific literature that compares and validates both methods. Two types of analysis are addressed
in the present article. On the one hand, maps of flood plains have been elaborated using geomorphological evidence and historical
flood data in the mountainous area of northwestern Spain, covering an area of more then 232 km2 of floodplains. On the other hand, a hydrometeorological model has been developed (Clark semidistributed unit hydrograph)
in the Sarria River basin (155 km2, NW Spain). This basin is not gauged, hence the model was subjected to a goodness-of-fit test of its parameter (curve number)
by means of Monte Carlo simulation. The peak flows obtained by means of the hydrological model were used for hydraulic modeling
(one-phase, one-dimensional and steady flow) in a 4 km2 urban stretch of the river bed. The delineation of surface areas affected by floods since 1918, as well as those analyzed
subsequent to the geomorphological study, reveals a high degree of reliability in the delineation of the flooded areas with
frequent recurrence intervals (<50 years). If we compare these flooded surface areas with the estimate obtained by the hydrological-hydraulic
method we can see that the latter method overestimates the extent of the surface water by 144% for very frequent recurrence
intervals (>10 years) and underestimates it as the recurrence interval increases, by up to 80% less floodplain for exceptional
events (>500 years). Finally, a management map is put forth combining the most reliable results available by integrating both
methods.
Originally presented at the Sixth International Conference on Geomorphology. 相似文献
58.
甲酸和乙酸稳定碳同位素组成(δ^13C)的分析对环境、食品、制药和自然产品等的研究具有重要的应用价值。但目前尚缺乏有效的测定方法。本研究利用最近出现的针式固相微萃取技术(NeedlEX),以吹扫.捕集方式对水溶液中的有机酸进行了萃取,然后利用气相色谱.同位素比值质谱联用仪(GC—IRMS)对所萃取的有机酸分子进行了占δ^13C的测定。结果显示,质谱计的信号强度与水溶液中有机酸的浓度存在显著的线性相关关系(R^2〉0.99,P〈0.05),表明Needl EX对水溶液中有机酸具有稳定的萃取能力。在甲酸与乙酸含量分别不低于300μg/mL与200μg/mL的水溶液中,1000mL的吹扫体积可以使两者δ^13C多次分析结果的相对误差分别保持在3%和1%左右,且整个实验流程没有造成可检测的碳同位素分馏作用。低于这两个浓度界线,则分析误差随浓度的降低迅速增加。本研究虽然是针对水溶液中有机酸δ^13C的测定,其萃取方法对其他水溶性挥发和半挥发有机物δ^13C的分析也同样具有应用价值。 相似文献
59.
60.