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991.
Daily precipitation occurrences and their monthly wet-days' sums of precipitation-measuring stations in Greece are modelled with a Markov chain. The order of the chain is taken to be seasonally varying in accordance with the precipitation station's meteorological conditions and geographical location. The modelling efficiency of the Markov chain is significantly improved when it is conjunctively used with a second-order autoregressive stochastic model fitted on the monthly wet-days' sums.  相似文献   
992.
The Tertiary volcanism of Eastern Macedonia and Western Thrace (Greece) developed in association with the sedimentary basin which formed, from Eocene to Oligocene, along the southern margin of the Rhodope Massif.The volcanic products, ranging in composition from basaltic andesites to rhyolites, show an overall calc-alkaline orogenic affinity, while chemical characteristics identify different groups of rocks, probably reflecting minor differences among parent magmas. The observed evolution within any group of rocks is compatible with fractional crystallization processes acting on relatively shallow magma bodies.The Sr isotopic composition of rhyolitic member shows an initial87Sr/86Sr ratio comparable with that of basaltic andesites, reinforcing the hypothesis of a crystal/liquid line of descent.Geochemical and petrographic evidence, on the whole, suggests that the investigated orogenic association developed on an active continental margin characterized by a relatively thick crust, acting as a density filter for the basic magmas and facilitating their storage and fractionation within the crust itself. Minor contamination by interaction with host materials may also have occurred.Stratigraphic and K/Ar geochronological data indicate that the volcanic activity started in Upper Eocene and reached its maximum development in Upper Oligocene. From Lower Miocene, the volcanism shifted southward in the Central Aegean area and in part of Western Anatolia, coming to an end by Middle Miocene.The southward migration of the volcanic front has been interpreted as a consequence of the increase in the dipping of the Benioff zone, due to the decrease of penetrative strength after the main phase of continental collision.  相似文献   
993.
994.
The easternmost domain of the Borborema Province, northeastern Brazil, presents widespread, extensional-related high-temperature metamorphism during the Brasiliano (=Pan-African) orogeny. This event reached the upper amphibolite to granulite facies and provoked generalized migmatization of Proterozoic metapelitic rocks of the Seridó Group and tonalitic to granodioritic orthogneisses of the Archean to Paleoproterozoic basement. We report new geochronological data based on electron microprobe dating of monazite from metapelitic migmatite and leuconorite within the high-T shear zones that make up the eastern continuation of the huge E–W Patos shear belt. These data were also constrained by using the Sm–Nd isotopic systematic on garnet from a syntectonic alkaline granite and two garnet-bearing leucosomes. The results suggest an age of about 578 to 574 Ma for the peak of the widespread high-T metamorphism. This event is best recorded by Sm–Nd garnet-whole rock ages. The U–Th–Pb isotopes on monazite of the metapelitic migmatite show a younger thermal event at 553 ± 10 Ma. When compared to the Sm–Nd garnet-whole rock ages, the U–Th–Pb electron probe monazite ages seem to record an event of slightly lower temperatures after the peak of the high-T metamorphism. This may reflect the difference in the isotopic behavior of the geochronological methods employed. Otherwise, the U–Th–Pb ages on monazites could indicate an event not yet very well defined. In anyway, this paper reveals the partial or even complete re-opening and resetting of the U–Th–Pb isotopic system produced by the action of low-T Ca-rich fluid.  相似文献   
995.
The H-atom environment in a Tilly Foster chondrodite was analyzed using single-crystal neutron-diffraction data collected at 500, 700 and 900 K and previously published low temperature data collected at 10, 100 and 300 K on the same crystal (Mg4.64Fe0.28Mn0.014Ti0.023(Si1.01O4)2F1.16(OH)0.84; Friedrich et al. in Am Mineral 86:981–989, 2001). The full mean square displacement matrix Σ of the O–H pair was determined from the temperature dependence of the anisotropic displacement parameters, enabling a proper correction of the O–H bond for thermal vibration without assumptions about the correlation of O and H movements. The results show that the perpendicular O–H motions in chondrodite are intermediate between the riding and the independent motion models. The corrected O–H bond lengths do not change with temperature whereas the corrected H···F distances show an increase of ~0.02 Å with temperature, as do the Mg–O distances. This result shows that spectroscopic observations on the strength of the covalent O–H bond cannot be interpreted unambiguously in terms of a corresponding behaviour of the associated H···O/F hydrogen bond.  相似文献   
996.
997.
We examined stable carbon isotope fractionation in biosynthesis of fatty acids of a piezophilic bacterium Moritella japonica strain DSK1. The bacterium was grown to stationary phase at pressures of 0.1, 10, 20, and 50 MPa in media prepared using sterile-filtered natural seawater supplied with glucose as the sole carbon source. Strain DSK1 synthesized typical bacterial fatty acids (C14-19 saturated, monounsaturated, and cyclopropane fatty acids) as well as long-chain polyunsaturated fatty acids (PUFA) (20:6ω3). Bacterial cell biomass and individual fatty acids exhibited consistent pressure-dependent carbon isotope fractionations relative to glucose. The observed ΔδFA-glucose (−1.0‰ to −11.9‰) at 0.1 MPa was comparable to or slightly higher than fractionations reported in surface bacteria. However, bulk biomass and fatty acids became more depleted in 13C with pressure. Average carbon isotope fractionation (ΔδFA-glucose) at high pressures was much higher than that for surface bacteria: −15.7‰, −15.3‰, and −18.3‰ at 10, 20, and 50 MPa, respectively. PUFA were more 13C depleted than saturated and monounsaturated fatty acids at all pressures. The observed isotope effects may be ascribed to the kinetics of enzymatic reactions that are affected by hydrostatic pressure and to biosynthetic pathways that are different for short-chain and long-chain fatty acids. A simple quantitative calculation suggests that in situ piezophilic bacterial contribution of polyunsaturated fatty acids to marine sediments is nearly two orders of magnitude higher than that of marine phytoplankton and that the carbon isotope imprint of piezophilic bacteria can override that of surface phytoplankton. Our results have important implications for marine biogeochemistry. Depleted fatty acids reported in marine sediments and the water column may be derived simply from piezophilic bacteria resynthesis of organic matter, not from bacterial utilization of a 13C-depleted carbon source (i.e., methane). The interpretation of carbon isotope signatures of marine lipids must be based on principles derived from piezophilic bacteria.  相似文献   
998.
The coal of the Miocene Bukit Asam deposit in south Sumatra is mostly sub-bituminous in rank, consistent with regional trends due to burial processes. However, effects associated with Plio–Pleistocene igneous intrusions have produced coal with vitrinite reflectance up to at least 4.17% (anthracite) in different parts of the deposit. The un-metamorphosed to slightly metamorphosed coals, with Rvmax values of 0.45–0.65%, contain a mineral assemblage made up almost entirely of well-ordered kaolinite and quartz. The more strongly heat-affected coals, with Rvmax values of more than 1.0%, are dominated by irregularly and regularly interstratified illite/smectite, poorly crystallized kaolinite and paragonite (Na mica), with chlorite in some of the anthracite materials. Kaolinite is abundant in the partings of the lower-rank coals, but is absent from the partings in the higher-rank areas, even at similar horizons in the same coal seam. Regularly interstratified illite/smectite, which is totally absent from the partings in the lower-rank coals, dominates the mineralogy in the partings associated with the higher-rank coal beds. A number of reactions involving the alteration of silicate minerals appear to have occurred in both the coal and the associated non-coal lithologies during the thermal metamorphism generated by the intrusions. The most prominent involve the disappearance of kaolinite, the appearance of irregularly interstratified illite/smectite, and the formation of regular I/S, paragonite and chlorite. Although regular I/S is identified in all of the non-coal partings associated with the higher-rank coals, illite/smectite with an ordered structure is only recognised in the coal samples collected from near the bases of the seams. The I/S in the coal samples adjacent to the floor of the highest rank seam also appears to have a greater proportion of illitic components. The availability of sodium and other non-mineral inorganic elements in the original coal to interact with the kaolinite, under different thermal and geochemical conditions, appears to be the significant factor in the formation of these new minerals, and distinguishes the mineralogical changes at Bukit Asam from those developed more generally with rank increases due to burial, and from the effects of intrusions into coals that were already at higher rank levels.  相似文献   
999.
Rita Raposo 《GeoJournal》2006,66(1-2):43-56
This paper focuses on the commodification processes and the aestheticization practices that shape gated communities and on the way these are connected to their segregational dimension, which is illustrated through the case of the Lisbon Metropolitan Area (LMA). First, I discuss the (increasing) aestheticization of commodities, emphasising some of the more problematic theoretical issues it involves. Following this discussion I present and analyse the ‘Lisbon case’. I provide a brief overview of gated communities in the LMA and then present and analyse the results obtained through a content analysis of LMA gated community advertisements and observation of their site semantics as conveyed through general built form, including physical location, planning, architecture, landscaping, and toponymy. I relate these findings to the LMA gated community market characteristics and to the broader prevailing socio-spatial context regarding their emergence.  相似文献   
1000.
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