Modeling the Acid–Base Surface Properties of Aquatic Sediments     

L. Borgnino  M. G. Garcia  M. V. del Hidalgo  M. Avena  C. P. De Pauli  M. A. Blesa  P. J. Depetris 《Aquatic Geochemistry》2010,16(2):279-291

We propose a model that explains the acid–base surface properties of clastic sediments from two Argentinean reservoir lakes. The model uses potentiometric titration data sets and fixed parameters such as the apparent stability constants and reaction stoichiometries of acid–base equilibriums involving known mineral phases. The model considers that sediments act as a set of independent sorption surfaces, such as organic matter, clay silicate, and iron (hydr)oxides, thus the acid–base equilibrium and the correspondent protolytic constants are represented by a humic acid, a Na-illite, and a poor crystalline Fe-hydr(oxide). In agreement with experimental data, the model predicts that all sediment samples show a similar charging behavior, increasing the negative charge as the pH increases. The net charge of sediments is controlled by the presence of negatively charged minerals and/or organic matter coatings. This reveals the great influence of clays and organic matter functional groups on the acid–base surface properties of sediments, and consequently on the surface reactivity toward contaminant transport.  相似文献   

Long-Term Trends in Intertidal and Subtidal Benthic Communities in Response to Water Quality Improvement Measures     

Paula Chainho  Gilda Silva  Michael F. Lane  José L. Costa  Tadeu Pereira  Carla Azeda  Pedro R. Almeida  Inês Metelo  Maria J. Costa 《Estuaries and Coasts》2010,33(6):1314-1326

Long-term monitoring studies are needed to understand changes in ecosystem status when restoration measures are implemented. A long-term data series (1996–2007) of the Tagus estuary (Portugal) intertidal and subtidal benthic communities was collected in a degraded area where mitigation measures were implemented. Multivariate analysis was used to analyze spatial and temporal patterns in benthic community composition and trends in five benthic community metrics (i.e., taxonomic richness, density, biomass, Shannon–Wiener diversity and the AMBI index) were also examined. The results revealed a clear separation between intertidal and subtidal assemblages, although they had 50% of taxa in common, including the most abundant. Significant positive trends were found for all metrics showing that both intertidal and subtidal communities responded to the restoration measures implemented. Nevertheless, biotic indices need some adaptation before being universally applied to intertidal and subtidal habitats.  相似文献   

Evidence of a partial melt zone beneath Stromboli volcano (Italy) from inversion of teleseismic receiver functions     

Carmen Martinez-Arevalo  Carla Musumeci  Domenico Patanè 《地学学报》2009,21(5):386-392

Teleseismic body waves from broadband seismic stations are used to investigate the crustal and uppermost mantle structure of Stromboli volcano through inversion of the receiver functions (RFs). First, we computed RFs in the frequency domain using a multiple-taper spectral correlation technique. Then, the non-linear neighbourhood algorithm was applied to estimate the seismic shear wave velocity of the crust and uppermost mantle and to define the main seismic velocity discontinuities. The stability of the inversion solution was tested using a range of initial random seeds and model parameterizations. A shallow Moho, present at depth of 14.8 km, is evidence of a thinned crust beneath Stromboli volcano. However, the most intriguing and innovative result is a low S velocity layer in the uppermost mantle, below 32 km. The low S velocity layer suggests a possible partial melt region associated with the volcanism, as also recently supported by tomographic studies and petrological estimations.  相似文献   

Can Jupiters be found by monitoring Galactic bulge microlensing events from northern sites?     

Yiannis Tsapras  Rachel A. Street  Keith Horne  Alan Penny  Fraser Clarke  Hans Deeg  Francisco Garzon  Simon Kemp  Maria Rosa Zapatero Osorio  Alejandro Oscoz Abad  Santiago Madruga Sanchez  Carlos Eiroa  Alcione Mora  Antxon Alberdi  rew Cameron  John K. Davies  Roger Ferlet  Carol Grady  Allan W. Harris  Javier Palacios  reas Quirrenbach  Heike Rauer  Jean Schneider  Dolf de Winter  Bruno Merin  Enrique Solano 《Monthly notices of the Royal Astronomical Society》2001,325(3):1205-1212

In 1998 the EXPORT team monitored microlensing event light curves using a charge-coupled device (CCD) camera on the IAC 0.8-m telescope on Tenerife to evaluate the prospect of using northern telescopes to find microlens anomalies that reveal planets orbiting the lens stars. The high airmass and more limited time available for observations of Galactic bulge sources make a northern site less favourable for microlensing planet searches. However, there are potentially a large number of northern 1-m class telescopes that could devote a few hours per night to monitor ongoing microlensing events. Our IAC observations indicate that accuracies sufficient to detect planets can be achieved despite the higher airmass.  相似文献   

Trace element studies of silicate‐rich inclusions in the Guin (UNGR) and Kodaikanal (IIE) iron meteorites     

Gero Kurat  Ernst Zinner  Maria Eugenia Varela 《Meteoritics & planetary science》2007,42(7-8):1441-1463

Abstract— A devitrified glass inclusion from the Guin (UNGR) iron consists of cryptocrystalline feldspars, pyroxenes, and silica and is rich in SiO₂, Al₂O₃, and Na₂O. It contains a rutile grain and is in contact with a large Cl apatite. The latter is very rich in rare earth elements (REEs) (～80 × CI), which display a flat abundance pattern, except for Eu and Yb, which are underabundant. The devitrified glass is very poor in REEs (<0.1 × CI), except for Eu and Yb, which have positive abundance anomalies. Devitrified glass and Cl apatite are out of chemical equilibrium and their complementary REE patterns indicate a genesis via condensation under reducing conditions. Inclusion 1 in the Kodaikanal (IIE) iron consists of glass only, whereas inclusion 2 consists of clinopyroxene, which is partly overgrown by low‐Ca pyroxene, and apatite embedded in devitrified glass. All minerals are euhedral or have skeletal habits indicating crystallization from the liquid precursor of the glass. Pyroxenes and the apatite are rich in trace elements, indicating crystallization from a liquid that had 10–50 × CI abundances of REEs and refractory lithophile elements (RLEs). The co‐existing glass is poor in REEs (～0.1–1 × CI) and, consequently, a liquid of such chemical composition cannot have crystallized the phenocrysts. Glasses have variable chemical compositions but are rich in SiO₂, Al₂O₃, Na₂O, and K₂O as well as in HFSEs, Be, B, and Rb. The REE abundance patterns are mostly flat, except for the glass‐only inclusion, which has heavy rare earth elements (HREEs) > light rare earth elements (LREEs) and deficits in Eu and Yb—an ultrarefractory pattern. The genetic models suggested so far cannot explain what is observed and, consequently, we offer a new model for silicate inclusion formation in IIE and related irons. Nebular processes and a relationship with E meteorites (Guin) or Ca‐Al‐rich inclusions (CAIs) (Kodaikanal) are indicated. A sequence of condensation (CaS, TiN or refractory pyroxene‐rich liquids) and vapor‐solid elemental exchange can be identified that took place beginning under reducing and ending at oxidizing conditions (phosphate, rutile formation, alkali and Fe²⁺ metasomatism, metasomatic loss of REEs from glass).  相似文献   

Extinction techniques and impact on dust property determination     

D. Froebrich  C. del Burgo 《Monthly notices of the Royal Astronomical Society》2006,369(4):1901-1910

The near-infrared (NIR) extinction power-law index (β) and its uncertainty is derived from three different techniques based on star counts, colour excess and a combination of them. We have applied these methods to Two Micron All Sky Survey (2MASS) data to determine maps of β and NIR extinction of the small cloud IC 1396 W. The combination of star counts and colour excess results in the most reliable method to determine β. It is found that the use of the correct β map to transform colour excess values into extinction is fundamental for column density profile analysis of clouds. We describe how artificial photometric data, based on the model of stellar population synthesis of the Galaxy, can be used to estimate uncertainties and derive systematic effects of the extinction methods presented here. We find that all colour excess based extinction determination methods are subject to small but systematic offsets, which do not affect the star counting technique. These offsets occur since stars seen through a cloud do not represent the same population as stars in an extinction-free control field.  相似文献   

Orientation of Sandhoppers Under Natural Conditions in Repeated Trials: an Analysis Using Longitudinal Directional Data     

A. D'elia  C. Borgioli  F. Scapini   《Estuarine, Coastal and Shelf Science》2001,53(6):839

Zonal recovery is a prompt escape towards the sea performed by sandhoppers under stressful environmental conditions. Differences in habitat features, meteorological conditions during the tests and morphological characteristics of the individuals are all factors affecting orientation. This paper deals with the temporal variation of the orientation of a sandhopper sample, taking into account the effect of some environmental and morphological variables on these changes. The directions chosen by single animals in repeated trials under natural conditions were analysed, using longitudinal circular data. The longitudinal analysis highlights several details about three different kinds of intrapopulation variation due to: sun, wind and eye left/right asymmetry. A clear link between the successive directional responses is demonstrated as well as modulation of behaviour with time: the animals stabilise orientation towards a certain direction in successive trials. The use of longitudinal sets of data in orientation studies produces a good synthesis of directional behaviour, due to several advantages of this kind of analysis. These include the fact that the association between successive behaviours and variability through repeated trials is taken into account; a progressive improvement, due to the integration of information from previous experiences, can be detected; the role of the main cues and factors affecting orientation is more accurately defined; and more parsimonious statistical models can be used to fit the data.  相似文献   

Shock metamorphism and impact melting in small impact craters on Earth: Evidence from Kamil crater,Egypt     

Agnese Fazio  Luigi Folco  Massimo D'Orazio  Maria Luce Frezzotti  Carole Cordier 《Meteoritics & planetary science》2014,49(12):2175-2200

Kamil is a 45 m diameter impact crater identified in 2008 in southern Egypt. It was generated by the hypervelocity impact of the Gebel Kamil iron meteorite on a sedimentary target, namely layered sandstones with subhorizontal bedding. We have carried out a petrographic study of samples from the crater wall and ejecta deposits collected during our first geophysical campaign (February 2010) in order to investigate shock effects recorded in these rocks. Ejecta samples reveal a wide range of shock features common in quartz‐rich target rocks. They have been divided into two categories, as a function of their abundance at thin section scale: (1) pervasive shock features (the most abundant), including fracturing, planar deformation features, and impact melt lapilli and bombs, and (2) localized shock features (the least abundant) including high‐pressure phases and localized impact melting in the form of intergranular melt, melt veins, and melt films in shatter cones. In particular, Kamil crater is the smallest impact crater where shatter cones, coesite, stishovite, diamond, and melt veins have been reported. Based on experimental calibrations reported in the literature, pervasive shock features suggest that the maximum shock pressure was between 30 and 60 GPa. Using the planar impact approximation, we calculate a vertical component of the impact velocity of at least 3.5 km s^?1. The wide range of shock features and their freshness make Kamil a natural laboratory for studying impact cratering and shock deformation processes in small impact structures.  相似文献   

Frequency of hyperbolic and interstellar meteoroids     

Maria Hajduková Jr.  Leonard Kornoš  Juraj Tóth 《Meteoritics & planetary science》2014,49(1):63-68

Hyperbolic meteor orbits from the catalog of 64,650 meteors observed by the multistation video meteor network located in Japan (SonotaCo 2009) have been investigated with the aim of determining the relation between the frequency of hyperbolic and interstellar meteors. The proportion of hyperbolic meteors in the data decreased significantly (from 11.58% to 3.28%) after a selection of quality orbits, which shows its dependence on the quality of observations. Initially, the hyperbolic orbits were searched for meteors unbound due to planetary perturbation. It was determined that 22 meteors from the 7489 hyperbolic orbits in the catalog (and 2 from the selection of the orbits with the highest quality) had had a close encounter with a planet, none of which, however, produced essential changes in their orbits. Similarly, the fraction of hyperbolic orbits in the data, which could be hyperbolic by reason of a meteor's interstellar origin, was determined to be at most 3.9 × 10^?2. From the statistical point of view, the vast majority of hyperbolic meteors in the database have definitely been caused by inaccuracy in the velocity determination. This fact does not necessarily assume great measurement errors, since, especially near the parabolic limit, a small error in the value of the heliocentric velocity of a meteor can create an artificial hyperbolic orbit that does not really exist. The results show that the remaining 96% of meteoroids with apparent hyperbolic orbits belong to the solar system meteoroid population. This is also supported by their high abundance (about 50%) among the meteor showers.  相似文献   

Is there any long-term memory effect in the tropical cyclones?     

Costas A. Varotsos  Maria N. Efstathiou 《Theoretical and Applied Climatology》2013,114(3-4):643-650

The investigation of the intrinsic properties of the annual tropical cyclone count over Atlantic, during 1870–2006, is herewith attempted. The motivation behind this exploration is to contribute to the current understanding about the dynamics of these disastrous events, as tropical cyclones create destructive impacts for people living around tropical areas. The analytical tool used is the detrended fluctuation analysis, and the exponent obtained reveals that the time series of the annual tropical cyclone count over Atlantic obeys the classical random walk (white noise). In other words, the number of tropical cyclones seems to exhibit neither persistent nor antipersistent behavior. The reliability of the lack of scaling dependence in the time series of the annual tropical cyclone count is confirmed, by applying error bounds statistics and studying the decay of the autocorrelation function (i.e., not rejected exponential decay) and the variability of local slopes (i.e., lack of constancy in a sufficient range). In addition, the fact that the series used is fractional Gaussian noise depicts that the results obtained are reliable, despite the fact that the available data set is still limited. The indication of a nearly white noise signal in the tropical cyclone count fluctuations does not suggest that the climate change phenomenon does not exist.  相似文献