Monitoring of heat transmission from buildings into geological environment and evaluation of soil deformation consequences in foundation engineering     

Işık Yilmaz  Marian Marschalko  David Lamich  Marián Drusa  Jiří Machačík  Silvie Heviánková  Miroslav Kyncl  Eva Lacková  Iva Bestová  David Krčmář  Egon Stutz  Martin Bednárik 《Environmental Earth Sciences》2014,72(8):2947-2955

In engineering geology a number of factors affecting foundation conditions are taken into consideration during engineering-geological investigations. This article deals with the factor of heat sourced from a structure (brick kiln) as a restrictive factor in foundation engineering in clay soils and introduces a documentation of soil deformation observations as an impact of the heat transmission into the geological environment. It was carried out in Southern Moravia in the Czech Republic, where the dominant foundation soils are Neogeneous clays where differential settlements of a tunnel kiln structure occurred as a result of ignoring the boundary conditions of temperature changes in the soil environment. The brick kilns caused heterogeneous spatial changes in the subsoil temperatures. This consequently resulted in differential settlements due to temperature changes originating from the kilns. The differential settlements reached as much as 150 mm. The major objective of the article is to highlight the importance of the heat transmission from buildings into the geological environment as a factor which should be considered in engineering geology and its application in planning. A new procedure for reducing or elimination of ground movements sourced from underlying clayey soils depending on the heat changes was also suggested in this context.  相似文献   

Evolution in sea ice from 1978 to 2012     

Mª E. Pérez González  Mª P. García Rodríguez 《Environmental Earth Sciences》2014,72(9):3467-3477

In this paper, the intra-annual and interannual variability of the sea ice is analysed over the period 1979–2012 from the data and images facilitated by the “National Snow and Ice dates Center”. These data are related to the annual average temperature. The annual average of the marine ice surface area (1979–2012) is very similar in both poles, although its temporary evolution is opposed in both hemispheres. In the Arctic Ocean there is an abrupt reduction of the surface area of the ice during this period. As opposed to it, the marine seas surrounding the Antarctic show an increase of the extension of the ice, especially in the last 15 years, with a maximum value in 2012. With respect to the total of the marine ice over the period 1979–2012, there is an overall deficit balance, because the reduction of the Arctic ice is greater than the increase of the Antarctic ice.  相似文献   

3D alluvial aquifer reconstruction in polluted areas by means of GPR (Sabiñánigo,N Spain)     

Ó. Pueyo Anchuela  J. F. Ipas-Lloréns  H. Gil Garbí  A. M. Casas-Sainz  A. Pocoví Juan  M. L. Garijo  J. G. Fernández-Martos  J. Fernández-Cascán 《Environmental Earth Sciences》2014,72(11):4291-4302

Assumptions of simple geometries for alluvial deposits (related to main rivers) can preclude determination of complexities that are revealed as fundamental controls in underground flow. Although subhorizontal contacts between alluvial and substratum materials are expected, previous sedimentary or erosional processes can result in irregular geometries, only accessible through detailed analysis. The studied case presents the 3D reconstruction of a Quaternary terrace in the proximities of Sabiñánigo (Southern Pyrenees, Northeastern Spain), lying on homogeneous Eocene marls. The studied area is located in an industrialized area supporting strongly pollutant chemical industry (chlorinated pesticides) for the past 50 years. The objective of the study was to constrain the groundwater pathway along the area to subsequently analyze leakage of chemicals to the water table. In order to reveal preferred flow paths, a detailed characterization of the internal structure of the alluvial deposits (0.5–13 m thick) and their relations with the Tertiary substratum was carried out by means of ground penetrating radar (GPR, 50 and 100 MHz antennas). The obtained models permit identifying several topographic highs in the alluvial/substratum contact, determining preferred pathways in water flow, favoring particular conditions associated with low levels of the water table. The presented results support the interest of application of GPR surveys in order to characterize the groundwater pathways in expected homogeneous areas and their importance in order to establish the contaminant surveillance network.  相似文献   

Responses of microorganisms and enzymes to soil contamination with metazachlor     

Ma?gorzata?Ba?magaEmail author  Jan?Kucharski  Jadwiga?Wyszkowska  Agata?Borowik  Monika?Tomkiel 《Environmental Earth Sciences》2014,72(7):2251-2262

A greenhouse pot experiment was conducted at the University of Warmia and Mazury in Olsztyn, with the aim of describing the influence of metazachlor on counts and biodiversity of soil microorganisms, soil enzymatic activity, physicochemical properties of soil and yield of spring oilseed rape. The first experimental factor was soil contamination with increasing rates of metazachlor: 0 (soil without the herbicide), 0.333 (recommended by the manufacturer), 6.666, 13.332, 26.665, 53.328, 106.656 and 213.312 mg kg^?1 dm of soil, while the second factor comprised two dates of determination: 30 and 60 days after starting the experiment. The tested herbicide had an adverse effect on reproduction of all analyzed microorganisms: oligotrophic bacteria and their endospore forms, Azotobacter spp. bacteria, organotrophic bacteria, actinomycetes and fungi. The values of the colony development and eco-physiological diversity indices decreased under the influence of excessive doses of the herbicide. Also, significant fluctuation in the enzymatic activity of soil was observed in response to the higher doses of metazachlor and depending on the date of determinations. The herbicide had an invariably negative influence on the activity of soil enzymes, causing the inhibition of dehydrogenases, catalase, urease, acid phosphatase, alkaline phosphatase, arylsulfatase and β-glucosidase. The physicochemical status of soil depended significantly on the degree of soil contamination with the herbicide, same as the yield of spring oilseed rape.  相似文献   

Origin and significance of poikilitic and mosaic peridotite xenoliths in the western Pannonian Basin: geochemical and petrological evidences     

Antal?Embey-IsztinEmail author  Gábor?Dobosi  Jean-Louis?Bodinier  Delphine?Bosch  G.?A.?Jenner  Simone?Pourtales  Olivier?Bruguier 《Contributions to Mineralogy and Petrology》2014,168(3):1054

Peridotite xenoliths erupted by alkali basaltic volcanoes in the western Pannonian Basin can be divided into two fundamentally contrasting groups. Geochemical characteristics of the abundant protogranular, porphyroclastic and equigranular nodules suggest that these samples originate from an old consolidated and moderately depleted lithospheric mantle domain. In contrast, the geochemical features of the worldwide rare, but in the Pannonian Basin relatively abundant, poikilitic xenoliths attest to a more complex evolution. It has been argued that the origin of the peculiar texture and chemistry may be intimately linked to melt/rock reactions at successively decreasing liquid volumes in a porous melt flow system. The most likely site where such reactions can take place is the asthenosphere–lithosphere boundary. In this context, poikilitic xenoliths may provide petrological and geochemical evidence for reactions between magmatic liquids issued from the uprising asthenosphere and the solid mantle rocks of the lithosphere. These reactions are important agents of the thermal erosion of the lithosphere; thus, they could have considerably contributed to the thinning of the lithosphere in the Pannonian region. We suggest that in the Pannonian Basin, there could be a strong relation between the unusual abundance of poikilitic mantle xenoliths and the strongly eroded lithosphere.  相似文献   

Zinc and sulfur isotope variation in sphalerite from carbonate-hosted zinc deposits,Cantabria, Spain   总被引：2，自引：0，他引：2  

Jan Pašava  Fernando Tornos  Vladislav Chrastný 《Mineralium Deposita》2014,49(7):797-807

We studied zinc and sulfur isotopes and the chemical composition of sphalerite samples from Picos de Europa (Aliva mine) and sphalerite and hydrozincite samples from La Florida mine, two carbonate-hosted Mississippi Valley-type (MVT) deposits located in northern Spain; despite being close, they are hosted in carbonatic rocks of different ages, Lower Carboniferous and Lower Cretaceous, respectively. The two generations of sphalerite at Picos de Europa show different δ⁶⁶Zn values (stage 1 sphalerite +0.24 per mil and stage 2 sphalerite from ?0.75 to +0.08 per mil). Both generations also differ in the sulfur isotope composition (stage 1 has δ³⁴S?=?+6.6 and stage 2 has δ³⁴S?=??0.9 to +2.9 per mil) and the chemical composition (stage 1 sphalerite, compared to stage 2 sphalerite, is significantly enriched in Pb, As, Mn, Sb, slightly enriched in Ag, Ni, and Cu and depleted in Co, Ga, Tl, Te, Ge, and Sn). We suggest that Zn isotope fractionation was controlled predominantly by pH and T changes. High Zn isotope values reflect rapid precipitation of sphalerite from higher-temperature acidic fluids that carried Zn mostly as chloride species after interaction with carbonate rocks while lower Zn isotope values most likely resulted from a longer precipitation process from fluid at higher pH and decreasing T that carried dominantly Zn sulfide species. At La Florida, sphalerite samples show light ⁶⁶Zn-depleted signatures with δ⁶⁶Zn values from ?0.80 to ?0.01 per mil (mostly between ?0.80 and ?0.24 per mil) and δ³⁴S values from +10.7 to +15.7 per mil without any relationship between the δ⁶⁶Zn and δ³⁴S values. Here, the variation in Zn isotope values is interpreted as related to mixing of fluids from two reservoirs. The Zn was carried by a single deep-seated and higher T (~250–320 °C) fluid, and precipitation took place after mixing with a connate S-rich fluid in a system with mH₂S?>?mZn²⁺ as a result of change in pH, T, and Zn predominant species. The light δ⁶⁶Zn accompanied by heavy δ³⁴S values resulted from fractionation of Zn aqueous sulfides at near-neutral pH and decreasing T. Hydrozincite samples show much heavier δ⁶⁶Zn values (+0.21 to +0.33 per mil), consistent with fractionation during supergene processes.  相似文献   

Significance of ancient sulfide PGE and Re–Os signatures in the mantle beneath Calatrava,Central Spain     

José María González-Jiménez  Carlos Villaseca  William L. Griffin  Suzanne Y. O’Reilly  Elena Belousova  Eumenio Ancochea  Norman J. Pearson 《Contributions to Mineralogy and Petrology》2014,168(2):1-24

Spinel lherzolite and wehrlite xenoliths from the Cenozoic Calatrava volcanic field carry the geochemical imprint of metasomatic agents that have affected the subcontinental lithospheric mantle beneath Central Iberia. Some xenoliths (mainly wehrlites) were enriched in REE, Sr, P, and CO₂ by silicic-carbonate-rich metasomatic melts/fluids, while others record the effects of subduction-related hydrous silicate fluids that have precipitated amphibole and induced high Ti/Eu in primary clinopyroxene. The petrographic observations and geochemical data suggest that interstitial glass in the xenoliths represent the quenched products of Si-rich melts that infiltrated the mantle peridotite shortly before the entrainment of the xenoliths in the host magmas that erupted ca 2 million years ago. During their infiltration, the metasomatic melts reacted with peridotite, resulting in silica enrichment, while remobilizing grains of iron-rich monosulfide solid solution (Fe-rich Mss) initially enclosed in, or intergranular to, primary olivine and pyroxenes. In situ laser ablation inductively coupled plasma-mass spectrometry analysis of single sulfide grains reveals that the Fe-rich Mss in glass shows platinum-group element (PGE) patterns and ¹⁸⁷Os/¹⁸⁸Os compositions identical to the Fe-rich Mss occurring as inclusions in, or at grain boundaries of primary silicates. Moreover, independent of its microstructural position, Fe-rich Mss exhibits PGE and ¹⁸⁷Os/¹⁸⁸Os signatures typical of Mss either residual after partial melting or crystallized directly from sulfide melts. Our findings reveal that young metasomatic melt(s)/fluid(s) may carry remobilized sulfides with PGE and Os-isotopic signatures identical to those of texturally older sulfides in the peridotite xenolith. These sulfides thus still provide useful information about the timing and nature of older magmatic events in the subcontinental mantle.  相似文献   

Titanium- and water-rich metamorphic olivine in high-pressure serpentinites from the Voltri Massif (Ligurian Alps,Italy): evidence for deep subduction of high-field strength and fluid-mobile elements     

Jan?C.?M.?De HoogEmail author  Keiko?Hattori  Haemyeong?Jung 《Contributions to Mineralogy and Petrology》2014,167(3):990

Titanium- and water-rich metamorphic olivine (Fo 86–88) is reported from partially dehydrated serpentinites from the Voltri complex, Ligurian Alps. The rocks are composed of mostly antigorite and olivine in addition to magnetite, chlorite, clinopyroxene and Ti-clinohumite. In situ secondary ion mass spectrometry (SIMS) data show that metamorphic olivine has very high and strongly correlated H₂O (up to 0.7 wt%) and TiO₂ contents (up to 0.85 wt%). Ti-rich olivine shows colourless to yellow pleochroism. Olivine associated with Ti-clinohumite contains low Ti, suggesting that Ti-rich olivine is not the breakdown product of Ti-clinohumite. Fourier transform infrared spectroscopy (FTIR) absorption spectra show peaks of serpentine, Ti-clinohumite and OH-related Si vacancies. Combining FTIR and SIMS data, we suggest the presence of clustered planar defects or nanoscale exsolutions of Ti-clinohumite in olivine. These defects or exsolutions contain more H₂O (x ~ 0.1 in the formula 4Mg₂SiO₄·(1?x)Mg(OH,F)₂·xTiO₂) than Ti-clinohumite in the sample matrix (x = 0.34–0.46). In addition to TiO₂ and H₂O, secondary olivine contains significant Li (2–60 ppm), B (10–20 ppm), F (10–130 ppm) and Zr (0.9–2.1 ppm). It is enriched in ¹¹B (δ¹¹B = +17 to +23 ‰). Our data indicate that secondary olivine may play a significant role in transporting water, high-field strength and fluid-mobile elements into the deeper mantle as well as introduce significant B isotope anomalies. Release of hydrogen from H₂O-rich olivine subducted into the deep mantle may result in strongly reduced mantle domains.  相似文献   

New evidence of warm early-Holocene summers in subarctic Finland based on an enhanced regional chironomid-based temperature calibration model     

Tomi P. Luoto  Marjut Kaukolehto  Jan Weckström  Atte Korhola  Minna Väliranta 《Quaternary Research》2014

Paleoclimate reconstructions based on biological proxies present methodological challenges, especially during non-analog conditions, such as the early Holocene. Here, two chironomid-based training sets from Finland were amalgamated to create a more accurate transfer function of summer air temperature. The aim was to reconstruct Holocene paleoclimate in northernmost Lapland, in an area that has been either too warm or too cold for reliable reconstructions using the original calibration models. The results showed that the combined calibration model had improved performance statistics. The temperature trends inferred from the downcore chironomid record using the original and combined models were very similar. However, there were major changes in their absolute values with the combined model showing greatly improved accuracy. The chironomid-based temperature reconstruction showed significant correlation with the previous pollen-based reconstructions from northwestern Finnish Lapland. However, differences were observed in the temperature trends of the early Holocene, when the chironomid-inferred temperatures rapidly increased, but the pollen-based reconstructions lagged behind suggesting that a cool climate continued for much longer. However, similar to the chironomid record, new plant macrofossil evidence from northwestern Finland also showed warmer-than-present early Holocene temperatures. Therefore, we conclude that the early Holocene was probably warm in northern Lapland.  相似文献   

Effects of Shear Rate on Cyclic Loading Shear Behaviour of Rock Joints Under Constant Normal Stiffness Conditions     

Ali Mirzaghorbanali  Jan Nemcik  Naj Aziz 《Rock Mechanics and Rock Engineering》2014,47(5):1931-1938

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