Decoupling of arsenic and iron release from ferrihydrite suspension under reducing conditions: a biogeochemical model     

André Burnol  Francis Garrido  Philippe Baranger  Catherine Joulian  Marie-Christine Dictor  Françoise Bodénan  Guillaume Morin  Laurent Charlet 《Geochemical transactions》2007,8(1):12

High levels of arsenic in groundwater and drinking water are a major health problem. Although the processes controlling the release of As are still not well known, the reductive dissolution of As-rich Fe oxyhydroxides has so far been a favorite hypothesis. Decoupling between arsenic and iron redox transformations has been experimentally demonstrated, but not quantitatively interpreted. Here, we report on incubation batch experiments run with As(V) sorbed on, or co-precipitated with, 2-line ferrihydrite. The biotic and abiotic processes of As release were investigated by using wet chemistry, X-ray diffraction, X-ray absorption and genomic techniques. The incubation experiments were carried out with a phosphate-rich growth medium and a community of Fe(III)-reducing bacteria under strict anoxic conditions for two months. During the first month, the release of Fe(II) in the aqueous phase amounted to only 3% to 10% of the total initial solid Fe concentration, whilst the total aqueous As remained almost constant after an initial exchange with phosphate ions. During the second month, the aqueous Fe(II) concentration remained constant, or even decreased, whereas the total quantity of As released to the solution accounted for 14% to 45% of the total initial solid As concentration. At the end of the incubation, the aqueous-phase arsenic was present predominately as As(III) whilst X-ray absorption spectroscopy indicated that more than 70% of the solid-phase arsenic was present as As(V). X-ray diffraction revealed vivianite Fe(II)₃(PO₄)₂.8H₂O in some of the experiments. A biogeochemical model was then developed to simulate these aqueous- and solid-phase results. The two main conclusions drawn from the model are that (1) As(V) is not reduced during the first incubation month with high Eh values, but rather re-adsorbed onto the ferrihydrite surface, and this state remains until arsenic reduction is energetically more favorable than iron reduction, and (2) the release of As during the second month is due to its reduction to the more weakly adsorbed As(III) which cannot compete against carbonate ions for sorption onto ferrihydrite. The model was also successfully applied to recent experimental results on the release of arsenic from Bengal delta sediments.  相似文献   

Fracture initiation, growth and effect on stress field: a numerical investigation     

Stephen D. McKinnon  Ivan Garrido de la Barra 《Journal of Structural Geology》1998,20(12):1673-1689

A numerical investigation was made of the relationships between fracture initiation, growth, stress field and boundary conditions. Two-dimensional plane strain continuum models were used in which fractures appeared as zones of strain localization developed through application of a strain softening Mohr–Coulomb constitutive model. R and R′ fractures developed first, followed by Y fractures at larger strains. The models showed that equal development of conjugate R and R′ fractures is easily changed to favor one or the other set by minor variations in model initial conditions. Strength loss in fractures caused stress field rotations in regions bounded by fractures, altering the orientation of subsequent fractures. The amount and sense of stress field rotation is dependent on the strength loss during displacement on the fractures, the orientation of fractures, and on the boundary conditions. Y oriented fractures could be explained on the basis of a Mohr–Coulomb failure criterion provided that stress field rotation is accounted for. Monitoring of fracture slip activity showed that, under conditions of constant boundary velocity, slip was discontinuous in time, alternating on fractures throughout the model.  相似文献   

Relationship between waterfowl and the seagrassRuppia maritima in a Southwestern Atlantic coastal lagoon     

Alejandro Bortolus  Oscar O. Iribarne  Mariano M. Martínez 《Estuaries and Coasts》1998,21(4):710-717

We evaluated the distribution of waterfowl in relation to a seagrass (Ruppia maritima) patch, to infauna, and on its relationship with substrate characteristics. An experiment performed in the Mar Chiquita coastal lagoon (37°46′S, 57°27′W; Argentina) was used to evaluate the effect of herbivory on widgeon grass,R. maritima. Control plots of equal size, located between bird exclosures, were exposed to herbivory. The experiment ran for 31 d, starting on December 1, 1994. Censuses showed that black-necked swan ( $\bar x = 50$ birds ha^?1, SD = 37, n = 10) and coots ( $\bar x = 42$ birds ha^?1, SD = 28, n = 10) were the most important (always present) of the waterfowl seen feeding onR. maritima. The results of the experiment showed greater leaf lengths, lower belowground (rhizomes and roots) biomass, greater aboveground (leaves and shoots) biomass, and greater abundance of the polychaeteHeteromastus similis in exclosure plots. There were no exclosure effects on total biomass (belowground plus aboveground), reproductive parts (fruits and pre- and postpollination flowers), or abundance of most benthic infauna. Topographic surveys showed that sediment surface was higher within theR. maritima patches, but there were no significant differences in granulometric composition. Surveys also showed that bird distribution was strongly associated with the presence ofR. maritima.  相似文献   

Dynamical Properties of a Sample of Ellipticals     

Vladimir Garrido Ortega  Gladys Lopes Vieira  J.A. de Freitas Pacheco 《Astrophysics and Space Science》1998,262(3):271-295

On the basis of Jeans equations we study some dynamical properties of a sample of E galaxies considered as oblate and prolate spheroids. Although the results emphasize the anisotropy as the dominant dynamical factor both for oblate and prolate configurations, the sample contains some oblate galaxies apparently isotropic consistent with full rotational support. Comparisons of the mass-to-luminosity ratios obtained from our models with ratios derived from recent evolutionary synthesis models do not seem to leave room for nonluminous matter within the ranges (of the order of one de Vaucouleurs' radius) of the kinematical observations. Such comparisons suggest that a flatter than the classical Salpeter IMF would lead to better agreement with the dynamical results obtained within the framework of our models.  相似文献   

Europium-activated cathodoluminescence in minerals     

A.N Mariano  P.J King 《Geochimica et cosmochimica acta》1975,39(5):649-660

Cathodoluminescence observations give information on the presence of europium in several minerals including apatite, fluorite, strontianite, and scheelite. Information on the oxidation state of the crystallization environment and on the partitioning of europium between coexisting mineral pairs may be obtained.The apatite in carbonatites and genetically related igneous rocks almost always contains europium in the divalent state. Occasionally both divalent and trivalent europium are observed.Europium is preferentially incorporated into strontianite when it crystallizes together with apatite in these same rocks. Similar results are found for fiuorite.  相似文献   

The significance of giant seismites in the Plio‐Pleistocene Baza palaeo‐lake (S Spain)     

Pedro Alfaro  Luis Gibert  Massimo Moretti  Francisco J. García‐Tortosa  Carlos Sanz de Galdeano  Jesús Galindo‐Zaldívar  Ángel C. López‐Garrido 《地学学报》2010,22(3):172-179

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The search for hot spots associated with the Cygnus X-3 relativistic jet     

J. Martí  D. Pérez-Ramírez  P. Luque-Escamilla  J. L. Garrido  J. M. Paredes  A. Muñoz-Arjonilla  J. R. Sánchez-Sutil 《Astrophysics and Space Science》2007,309(1-4):309-313

We report and shortly discuss here the observational work carried out in order to test the possibility that two previously detected radio sources, in the vicinity of the well known microquasar Cygnus X-3, could be hot spot tracers of interaction between its relativistic jet and the interstellar medium (ISM). The motivation behind this search is in part justified considering recent theoretical models of high energy γ-ray emission which strongly rely on the interaction sites of galactic relativistic jets with nearby ISM clouds. The results presented in this paper include an improved radio exploration of the several arc-minute field around Cygnus X-3 using the Very Large Array (VLA), as well as deep near infrared (NIR) imaging with the Calar Alto 3.5 m telescope. We anticipate here that our observations do not appear to support the initial hot spot hypothesis. Instead, the resulting images suggest that the two radio sources, originally believed to be hot spot candidates, are most likely background or foreground objects.  相似文献   

On the heat budget of the Arabian Sea     

Deanna Wilson-Diaz  Arthur J. Mariano  Robert H. Evans 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(2):141-165

This study analyzes the heat budget of the Arabian Sea using satellite-derived sea-surface temperature (SST) from 1985 to 1995 along with other data sets. For a better understanding of air–sea interaction, canonical average monthly fields representing the spatial and temporal structure of the various components of the heat balance of the Arabian Sea are constructed from up to 30 years of monthly atmospheric and oceanic data. The SST over the Arabian Sea is not uniform and continually evolves with time. Cooling occurs over most of the basin during November through January and May through July, with the greatest cooling in June and July. Warming occurs over most of the basin during the remainder of the year, with the greatest warming occurring in March and September. Results indicate that the sign of the net heat flux is strongly dependent on the location and month. The effects of net heat flux and penetrative solar radiation strongly influence the change in SST during February and are less important during August and September. Horizontal advection acts to cool the sea surface during the northeast monsoon months. During the southwest monsoon horizontal advection of surface waters warms the SST over approximately the southern half of the basin, while the advection of upwelled water from the Somalia and Oman coasts substantially cools the northern basin. The central Arabian Sea during the southwest monsoon is the only area where the change in SST is balanced by the entrainment and turbulent diffusion at the base of the mixed layer. Agreement between the temporal change in the satellite-derived SST and the change calculated from the conservation of heat equation is surprisingly good given the errors in the measured variables and the bulk formula parameters. Throughout the year, monthly results over half of the basin agree within 3°. Considering that the SST changes between 8° and 12° over the year, this means that our results explain from 62% to 75% of the change in SST over 56% of the Arabian Sea. Two major processes contribute to the discrepancy in the change in SST calculated according to the heat budget equation and the change in SST derived from satellite observations. The first is the effect of the horizontal advection term. The position of the major eddies and currents during the southwest monsoon greatly affects the change in SST due to the large gradient in temperature between the cold upwelled waters along the Somali coast to the warm waters in the interior of the basin. The second major process is the thermocline effect. In areas of shallow mixed-layer depth, high insolation and wind speeds of either less than 3 m/s or greater than 15 m/s, the bulk formulae parameterization of the surface heat fluxes is inappropriate.  相似文献   

Atmospheric Boundary-Layer Evening Transitions: A Comparison Between Two Different Experimental Sites     

Mariano Sastre  Carlos Yagüe  Carlos Román-Cascón  Gregorio Maqueda 《Boundary-Layer Meteorology》2015,157(3):375-399

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Mode trapping in sdO models     

C. Rodríguez-López  A. Moya  R. Garrido  J. MacDonald  R. Oreiro  A. Ulla 《Astrophysics and Space Science》2010,329(1-2):205-209

Mode trapping of high-radial order gravity modes was found for a particular sdO model. The trapping is caused by the change in composition from the helium radiative shell to the hydrogen burning shell. A non-adiabatic effect of this trapping is the higher tendency to instability of the trapped modes. Low- to intermediate-radial order pressure modes (in sdO models they correspond to mixed modes with most nodes in the P-mode region) are found to be trapped by the chemical transition from the carbon-oxygen core to the He burning shell. As the trapping is produced in the deep interior of the star, where energy interchange is negligible at the p-mode frequencies, it has no particular effect on the driving.  相似文献