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341.
Pulse amplitude modulation (PAM) fluorometry is ideally suited to measure the sub-lethal impacts of photosystem II (PSII)-inhibiting herbicides on microalgae, but key relationships between effective quantum yield [Y(II)] and the traditional endpoints growth rate (mu) and biomass increase are unknown. The effects of three PSII-inhibiting herbicides; diuron, hexazinone and atrazine, were examined on two tropical benthic microalgae; Navicula sp. (Heterokontophyta) and Nephroselmis pyriformis (Chlorophyta). The relationships between Y(II), mu and biomass increase were consistent (r(2)0.90) and linear (1:1), validating the utility of PAM fluorometry as a rapid and reliable technique to measure sub-lethal toxicity thresholds of PSII-inhibiting herbicides in these microalgae. The order of toxicity (EC(50) range) was: diuron (16-33nM)>hexazinone (25-110nM)>atrazine (130-620nm) for both algal species. Growth rate and photosynthesis were affected at diuron concentrations that have been detected in coastal areas of the Great Barrier Reef.  相似文献   
342.
Significant improvements in water quality have been observed for several decades throughout much of the Hudson-Raritan Estuary, primarily as a result of regional abatement of municipal and industrial discharges. These improvements include area-wide, order-of-magnitude reductions in ambient coliform concentrations and significant increases in dissolved oxygen (DO) concentrations. In contrast to these improvements, DO in bottom waters of the western Long Island Sound (WLIS) appears to have decreased in the last two decades. Although there is no consensus as to why hypoxia in WLIS may have recently become more severe, several related hypotheses have been suggested, including an increase in eutrophication, increased density stratification, and changes in wastewater loads. To determine if eutrophication has increased in WLIS, trends in several indicators of eutrophication were examined from a long-term water quality data set. Since the mid-1980s surface DO supersaturation has increased, bottom minimum DO has decreased, and vertical DO stratification has increased in WLIS. Other areas of the Hudson-Raritan Estuary, such as Jamaica Bay and Raritan Bay, exhibit similar evidence of declining water quality and may be experiencing increasing eutrophication. Temporal changes in vertical density stratification indicate that surface to bottom temperature differences have increased to a greater extent and have had a more significant impact on bottom DO depletion in WLIS than in the shallower Jamaica Bay and Raritan Bay. Additional factors contributing to the observed decline in water quality include recent changes in wastewater loads and possible increases in upstream and nonpoint source loads.  相似文献   
343.
We present further spectroscopic observations for a sample of galaxies selected in the vacuum ultraviolet (UV) at 2000 Å from the FOCA balloon-borne imaging camera of Milliard et al. This work represents an extension of the initial study by Treyer et al. Our enlarged catalogue contains 433 sources (≃3 times as many as in our earlier study) across two FOCA fields. 273 of these are galaxies, nearly all with redshifts z ≃0–0.4. Nebular emission-line measurements are available for 216 galaxies, allowing us to address issues of excitation, reddening and metallicity. The UV and H α luminosity functions strengthen our earlier assertions that the local volume-averaged star formation rate is higher than indicated from earlier surveys. Moreover, internally within our sample, we do not find a steep rise in the UV luminosity density with redshift over 0< z <0.4. Our data are more consistent with a modest evolutionary trend, as suggested by recent redshift survey results. Investigating the emission-line properties, we find no evidence for a significant number of AGN in our sample; most UV-selected sources to z ≃0.4 are intense star-forming galaxies. We find that the UV flux indicates a consistently higher mean star formation rate than that implied by the H α luminosity for typical constant or declining star formation histories. Following Glazebrook et al., we interpret this discrepancy in terms of a starburst model for our UV-luminous sources. We develop a simple algorithm which explores the scatter in the UV flux–H α relation in the context of various burst scenarios. Whilst we can explain most of our observations in this way, there remains a small population with extreme UV–optical colours which cannot be understood.  相似文献   
344.
The chemical composition of the global ocean is governed by biological, chemical, and physical processes. These processes interact with each other so that the concentrations of carbon, oxygen, nitrogen (mainly from nitrate, nitrite, ammonium), and phosphorous (mainly from phosphate), vary in constant proportions, referred to as the Redfield ratios. We construct here the generalized total least squares estimator of these ratios. The significance of our approach is twofold; it respects the hydrological characteristics of the studied areas, and it can be applied identically in any area where enough data are available. The tests applied to Atlantic Ocean data highlight a variability of the Redfield ratios, both with geographical location and with depth. This variability emphasizes the importance of local and accurate estimates of Redfield ratios.  相似文献   
345.
The present work analyses the spatial and temporal fluctuations of fish communities on Réunion coral reef flats on three different reefs, each comprising three geomorphological zones, over eight seasons within a 6-year period. These three reefs are subjected to different environmental conditions and displayed various percentages of live coral cover. Our objectives were not only to describe the spatio-temporal patterns, but also to organize the factors involved in variation hierarchically, and to quantify the degree of community structuring that could be monitored over various spatial and temporal scales. We also focus on fish guilds to link the spatio-temporal patterns not only to species but also to the roles fish are playing (mainly involving trophic activity). We found that spatial attributes strongly determined fish distribution, with intra-reefal zones (back-reef, inner reef flat and outer reef flat) playing a much more important role than the different reefs. This suggests that the percentage of live coral cover of a given reef was less significant than its morpho-structural organization to explain fish distribution. Seasons had only a weak role in fish distribution, although fish communities were significantly more homogeneous in winter than in summer, possibly due to the arrival of numerous juveniles belonging to various species during summer settlement events. We also identified a marked temporal persistence of the spatial patterns found over the course of the study. This is discussed in relation to the current trend of increased surface seawater temperatures involved in the possible future increase in number/intensity of ENSO events. We consider the average squared Euclidian distance as a candidate for monitoring tools to quantify future changes in fish community structuring.  相似文献   
346.
The application of biomarker climate proxies to lacustrine settings requires a thorough understanding of those processes that give rise to and mediate in the burial and preservation of organic matter in the sediments. This information is to date missing for Lake Baikal in Central Asia. The biogeochemistry of the lake cannot be considered analogous to that in other lacustrine environments given its enormous size, depth, remote location and unique biology. The aim of this paper is to report on the main compound classes in the water column and sediments. As part of an ongoing evaluation of the inputs and fluxes of organic matter in Lake Baikal, we have found that there are significant differences in the inputs and preservation of organic matter between the North and South Basins. Both basins have dominant algal input and a contribution from the terrestrial plants of the lake edges and surrounding environments. However, the concentration of organic material in the sediment traps and sediments of the South Basin is much higher than that of the North Basin. In addition, the South Basin contains much higher proportions of the more labile material than does the North Basin. This is likely due to the South Basin being free of surface ice for a much longer time than the North, and in consequence, primary producers having an overall longer productive season. There is some evidence of microbial activity in the sediment traps and sediments from both the North and South Basins, but it does not appear to be more predominant in one basin than the other. It is probable that the differences in the composition and concentration of biomarkers in sediments between basins is due to the length of and the intensity of the productive season, which is in turn influenced by the climate.  相似文献   
347.
The small scale distribution of the snowpack in mountain areas is highly heterogeneous, and is mainly controlled by the interactions between the atmosphere and local topography. However, the influence of different terrain features in controlling variations in the snow distribution depends on the characteristics of the study area. As this leads to uncertainties in high spatial resolution snowpack simulations, a deeper understanding of the role of terrain features on the small scale distribution of snow depth is required. This study applied random forest algorithms to investigate the temporal evolution of snow depth in complex alpine terrain using as predictors various topographical variables and in situ snow depth observations at a single location. The high spatial resolution (1 m x 1 m) snow depth distribution database used in training and evaluating the random forests was derived from terrestrial laser scanner (TLS) devices at three study sites, in the French Alps (2 sites) and the Spanish Pyrenees (1 site). The results show the major importance of two topographic variables, the topographic position index and the maximum upwind slope parameter. For these variables the search distances and directions depended on the characteristics of each site and the TLS acquisition date, but are consistent across sites and are tightly related to main wind directions. The weight of the different topographic variables on explaining snow distribution evolves while major snow accumulation events still take place and minor changes are observed after reaching the annual snow accumulation peak. Random forests have demonstrated good performance when predicting snow distribution for the sites included in the training set with R2 values ranging from 0.82 to 0.94 and mean absolute errors always below 0.4 m. Oppositely, this algorithm failed when used to predict snow distribution for sites not included in the training set, with mean absolute errors above 0.8 m.  相似文献   
348.
ABSTRACT

The temporal nature of humans interaction with Points of Interest (POIs) in cities can differ depending on place type and regional location. Times when many people are likely to visit restaurants (place type) in Italy, may differ from times when many people are likely to visit restaurants in Lebanon (i.e. regional differences). Geosocial data are a powerful resource to model these temporal differences in cities, as traditional methods used to study cross-cultural differences do not scale to a global level. As cities continue to grow in population and economic development, research identifying the social and geophysical (e.g., climate) factors that influence city function remains important and incomplete. In this work, we take a quantitative approach, applying dynamic time warping and hierarchical clustering on temporal signatures to model geosocial temporal patterns for Retail and Restaurant Facebook POIs hours of operation for more than 100 cities in 90 countries around the world. Results show cities’ temporal patterns cluster to reflect the cultural region they represent. Furthermore, temporal patterns are influenced by a mix of social and geophysical factors. Trends in the data suggest social factors influence unique drops in temporal signatures, and geophysical factors influence when daily temporal patterns start and finish.  相似文献   
349.
Alpine areas play a major role in water supply in downstream valleys by releasing water during warm and dry periods. However, the hydrogeology of alpine catchments, which are particularly exposed to the effects of climate change, is currently not well understood. Increasing our knowledge of alpine hydrogeological processes is thus of considerable importance for any forward-looking hydrological investigations in alpine areas. The objectives of this study are to quantify seasonal groundwater storage variations in a small Swiss alpine catchment and to evaluate the capabilities of time-lapse gravimetry in the identification of zones of high groundwater storage fluctuations. Time-lapse gravimetric measurements enable rapid localisation of zones of dynamic groundwater storage changes and help to highlight aquifers with a higher storage decrease. Temperature sensors enable measurement of the temporal trend in stream and spring drying in the post-snowmelt period. Stable isotope measurements allow us to identify the origin of surface water exiting the catchment. The results improve our comprehension of a conceptual schema highlighting two different hydrogeological systems: (a) a shallow, rapidly depleted one fed directly by snowmelt and (b) a deeper one, with a slower recession, fed by main recharge during peak snowmelt and emerging at the lower part of the catchment below the talus and moraine of the catchment where bedrock is exposed. These dynamics confirm the high variability of storage in the talus and moraine aquifers and highlight the dominant role of Quaternary deposits and their connectivity to store water over seasonal and multi-year time-scales. The mechanisms explaining the importance of Quaternary deposits are the combination of moraine and talus with different permeabilities allowing the storage of sufficient quantities of water permitting continuous release during drier periods of the year.  相似文献   
350.
Evaporative flux is a key component of hydrological budgets. Water loss through evapotranspiration reduces volumes available for run‐off. The transition from liquid to water vapour on open water surfaces requires heat. Consequently, evaporation act as a cooling mechanism during summer. Both river discharge and water temperature simulations are thus influenced by the methods used to model evaporation. In this paper, the impact of evapotranspiration estimation methods on simulated discharge is assessed using a semidistributed model on two Canadian watersheds. The impact of evaporation estimation methods on water temperature simulations is also evaluated. Finally, the validity of using the same formulation to simulate both of these processes is verified. Five well‐known evapotranspiration models and five evaporation models with different wind functions were tested. Results show a large disparity (18–22% of mean annual total evapotranspiration) among the evapotranspiration methods, leading to important differences in simulated discharge (3–25% of observed discharge). Larger differences result from evaporation estimation methods with mean annual divergences of 34–48%. This translates into a difference in mean summer water temperature of 1–15%. Results also show that the choice of model parameter has less influence than the choice of evapotranspiration method in discharge simulations. However, the parameter values influence thermal simulations in the same order of magnitude as the choice of evaporation estimation method. Overall, the results of this study suggest that evapotranspiration and open water evaporation should be represented separately in a hydrological modelling framework, especially when water temperature simulations are required.  相似文献   
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