Size-segregated characterization of PM10 at the EMEP site Melpitz (Germany) using a five-stage impactor: a six year study     

G. Spindler  T. Gnauk  A. Grüner  Y. Iinuma  K. Müller  S. Scheinhardt  H. Herrmann 《Journal of Atmospheric Chemistry》2012,69(2):127-157

Size-segregated particle samples were collected using a Berner 5-stage impactor (stages 1?C5: 0.05?C0.14?C0.42?C1.2?C3.5?C10???m aerodynamic diameter). The means for all 169?days and for different categories of days were used for a characterization. The sorting criteria were (a) the distinction between winter (Wi, November to April) and summer (Su, May to October), (b) the distinction between air mass inflow from a sector West (W, 210?°?C320?°) and from a sector East (E, 35?°?C140?°). For the assignment of the air mass origin 96-h backward trajectories were used and four categories (WiW, WiE, SuW and SuE) with 48, 18, 42 and 29?days were established. The lowest mean particle mass concentrations were found for SuW and the highest for WiE with relative mass concentration distributions of 5.9, 28.2, 36.5, 18.0, and 11.4?% and 3.5, 22.7, 52.6, 16.7, and 4.5?% for stages 1?C5, respectively. The mass closure for water soluble ions, water, organic material (OM) and elemental carbon (EC) accounts for 81?C99?% of the gravimetric mass in Wi and for 60?C81?% for Su, depending on the stage. The fractions of nitrate were relatively high for WiW while sulphate fractions are high for WiE. The estimated concentrations of secondary organic carbon (SOA) on stage 3 for WiW, WiE, SuW and SuE were 0.32, 1.25, 0.27 and 0.58???gm^?3, respectively. The highest amount of SOA is found for WiE, representing 59?% of organic carbon (OC). The highest difference in the percentages of SOA in OC was found between winter (WiW 55?%, WiE 59?%) and summer (SuW and SuE 74?%) indicating photochemical processes during long-range transport. The mean Carbon Preference Indices (CPI) are highest for SuE (stage 4: 7.57 and stage 5: 9.82) resulting mainly from plant wax abrasion in the surrounding forests. For WiE the mean PAH concentration on stage 3 (9.7?ngm^?3) is about five times higher than for WiW, indicating long range transport following domestic heating and other combustion processes.  相似文献   

Lander radioscience for obtaining the rotation and orientation of Mars     

Veronique Dehant  William Folkner  Etienne Renotte  Daniel Orban  Sami Asmar  Georges Balmino  Jean-Pierre Barriot  Jeremy Benoist  Richard Biancale  Jens Biele  Frank Budnik  Stefaan Burger  Olivier de Viron  Bernd Häusler  Özgur Karatekin  Sébastien Le Maistre  Philippe Lognonné  Michel Menvielle  Michel Mitrovic  Martin Pätzold  Marie Yseboodt 《Planetary and Space Science》2009,57(8-9):1050-1067

The paper presents the concept, the objectives, the approach used, and the expected performances and accuracies of a radioscience experiment based on a radio link between the Earth and the surface of Mars. This experiment involves radioscience equipment installed on a lander at the surface of Mars. The experiment with the generic name lander radioscience (LaRa) consists of an X-band transponder that has been designed to obtain, over at least one Martian year, two-way Doppler measurements from the radio link between the ExoMars lander and the Earth (ExoMars is an ESA mission to Mars due to launch in 2013). These Doppler measurements will be used to obtain Mars’ orientation in space and rotation (precession and nutations, and length-of-day variations). More specifically, the relative position of the lander on the surface of Mars with respect to the Earth ground stations allows reconstructing Mars’ time varying orientation and rotation in space.Precession will be determined with an accuracy better by a factor of 4 (better than the 0.1% level) with respect to the present-day accuracy after only a few months at the Martian surface. This precession determination will, in turn, improve the determination of the moment of inertia of the whole planet (mantle plus core) and the radius of the core: for a specific interior composition or even for a range of possible compositions, the core radius is expected to be determined with a precision decreasing to a few tens of kilometers.A fairly precise measurement of variations in the orientation of Mars’ spin axis will enable, in addition to the determination of the moment of inertia of the core, an even better determination of the size of the core via the core resonance in the nutation amplitudes. When the core is liquid, the free core nutation (FCN) resonance induces a change in the nutation amplitudes, with respect to their values for a solid planet, at the percent level in the large semi-annual prograde nutation amplitude and even more (a few percent, a few tens of percent or more, depending on the FCN period) for the retrograde ter-annual nutation amplitude. The resonance amplification depends on the size, moment of inertia, and flattening of the core. For a large core, the amplification can be very large, ensuring the detection of the FCN, and determination of the core moment of inertia.The measurement of variations in Mars’ rotation also determines variations of the angular momentum due to seasonal mass transfer between the atmosphere and ice caps. Observations even for a short period of 180 days at the surface of Mars will decrease the uncertainty by a factor of two with respect to the present knowledge of these quantities (at the 10% level).The ultimate objectives of the proposed experiment are to obtain information on Mars’ interior and on the sublimation/condensation of CO₂ in Mars’ atmosphere. Improved knowledge of the interior will help us to better understand the formation and evolution of Mars. Improved knowledge of the CO₂ sublimation/condensation cycle will enable better understanding of the circulation and dynamics of Mars’ atmosphere.  相似文献   

Long-term groundwater resource observatory for Southwestern Madagascar     

Simon D. Carrière  Thomas Health  Pascale F. M. Rakotomandrindra  Chloé Ollivier  Riva E. Rajaomahefasoa  Heritiana A. Rakoto  Jean Lapègue  Yves E. Rakotoarison  Marie Mangin  Jean Kempf  Théodore Razakamanana  Konstantinos Chalikakis 《水文研究》2021,35(3):e14108

Madagascar has one of the highest poverty rates in the world and consequently the long-term monitoring of groundwater resources is not a priority for the authorities. However, groundwater is often the only sustainable resource that has a satisfactory quality to supply the population. This is especially true in the south-west of the country, which is a semi-arid region and a global change hot spot (intense land use and climate changes). In response to the lack of data, the Groundwater Resource Observatory for Southwestern Madagascar (GROSoM) was established to monitor piezometry and meteorology over the longer term as part of a humanitarian response. The first site was setup in 2014 in a catchment located over a carbonate plateau; in 2018, a second site was installed in an alluvial setting within a crystalline basement catchment and a third site will be installed in 2020 to monitor groundwater dynamics in a coastal setting. The three sites, located between Toliara and Taolagnaro cities, are complementary and representative of various hydrogeological systems in Southwestern Madagascar. Each site includes a weather station and between 3 and 6 piezometric probes. The monitoring data indicate a strong inter-annual variability in precipitation, which induces a strong variability in aquifers recharge. One of the driest years in 2016 seems to be consistent with strong El Niño – Southern Oscillation (ENSO) effects observed at the global scale, while years with higher recharge appear to be related to cyclones such as Fundi in 2015 and Eketsang in 2019. Preliminary results of cross-disciplinary studies demonstrated a link between groundwater and health issues (i.e., admissions to basic health centres). This observatory aims to produce long-term data and has two objectives: (i) strengthening the early warning system for humanitarian crises in Madagascar; (ii) contributing to a better understanding of the effects of climate change on groundwater resources in this semi-arid region.  相似文献   

The 1‐million‐year‐old quartz assemblage from Pont‐de‐Lavaud (Centre,France) in the European context          下载免费PDF全文

Jackie Despriée  Marie‐Hélène Moncel  Marta Arzarello  Gilles Courcimault  Pierre Voinchet  Jean‐Jacques Bahain  Christophe Falguères 《第四纪科学杂志》2018,33(6):639-661

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Reducing fugitive methane emissions from the North American oil and gas sector: a proposed science-policy framework     

Kate Konschnik  Sarah Marie Jordaan 《Climate Policy》2018,18(9):1133-1151

The shale gas boom in the United States spurred a shift in electricity generation from coal to natural gas. Natural gas combined cycle units emit half of the CO₂ to produce the same energy as a coal unit; therefore, the market trend is credited for a reduction in GHG emissions from the US power sector. However, methane that escapes the natural gas supply chain may undercut these relative climate benefits. In 2016, Canada, the United States and Mexico pledged to reduce methane emissions from the oil and natural gas sector 40–45% from 2012 levels by 2025. This article reviews the science-policy landscape of methane measurement and mitigation relevant for meeting this pledge, including changes in US policy following the 2016 presidential election. Considerable policy incoherence exists in all three countries. Reliable inventories remain elusive; despite government and private sector research efforts, the magnitude of methane emissions remains in dispute. Meanwhile, mitigation efforts vary significantly. A framework that integrates science and policy would enable actors to more effectively inform, leverage and pursue advances in methane measurement and mitigation. The framework is applied to North America, but could apply to other geographic contexts.

Key policy insights

• The oil and gas sector’s contribution to atmospheric methane concentrations is becoming an increasingly prominent issue in climate policy.

• Efforts to measure and control fugitive methane emissions do not presently proceed within a coherent framework that integrates science and policy.

• In 2016, the governments of Canada, Mexico and the United States pledged to reduce methane emissions from the oil and natural gas sector 40–45% from 2012 levels by 2025.

• The 2016 presidential election in the United States has halted American progress at the federal level, suggesting a heavier reliance on industry and subnational efforts in that country.

• Collectively or individually, the countries, individual agencies, or private stakeholders could use the proposed North American Methane Reduction framework to direct research, enhance monitoring and evaluate mitigation efforts, and improve the chances that continental methane reduction targets will be achieved.

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Frontal dynamics boost primary production in the summer stratified Mediterranean sea   总被引：1，自引：1，他引：0  

Antonio Olita  Arthur Capet  Mariona Claret  Amala Mahadevan  Pierre Marie Poulain  Alberto Ribotti  Simón Ruiz  Joaquín Tintoré  Antonio Tovar-Sánchez  Ananda Pascual 《Ocean Dynamics》2017,67(6):767-782

Bio-physical glider measurements from a unique process-oriented experiment in the Eastern Alboran Sea (AlborEx) allowed us to observe the distribution of the deep chlorophyll maximum (DCM) across an intense density front, with a resolution (～ 400 m) suitable for investigating sub-mesoscale dynamics. This front, at the interface between Atlantic and Mediterranean waters, had a sharp density gradient (Δρ ～ 1 kg/m³ in ～ 10 km) and showed imprints of (sub-)mesoscale phenomena on tracer distributions. Specifically, the chlorophyll-a concentration within the DCM showed a disrupted pattern along isopycnal surfaces, with patches bearing a relationship to the stratification (buoyancy frequency) at depths between 30 and 60 m. In order to estimate the primary production (PP) rate within the chlorophyll patches observed at the sub-surface, we applied the Morel and Andrè (J Geophys Res 96:685–698 1991) bio-optical model using the photosynthetic active radiation (PAR) from Argo profiles collected simultaneously with glider data. The highest production was located concurrently with domed isopycnals on the fresh side of the front, suggestive that (sub-)mesoscale upwelling is carrying phytoplankton patches from less to more illuminated levels, with a contemporaneous delivering of nutrients. Integrated estimations of PP (1.3 g C m^?2d^?1) along the glider path are two to four times larger than the estimations obtained from satellite-based algorithms, i.e., derived from the 8-day composite fields extracted over the glider trip path. Despite the differences in spatial and temporal sampling between instruments, the differences in PP estimations are mainly due to the inability of the satellite to measure DCM patches responsible for the high production. The deepest (depth > 60 m) chlorophyll patches are almost unproductive and probably transported passively (subducted) from upper productive layers. Finally, the relationship between primary production and oxygen is also investigated. The logarithm of the primary production in the DCM interior (chlorophyll (Chl) > 0.5 mg/m³) shows a linear negative relationship with the apparent oxygen utilization, confirming that high chlorophyll patches are productive. The slope of this relationship is different for Atlantic, mixed interface waters and Mediterranean waters, suggesting the presence of differences in planktonic communities (whether physiological, population, or community level should be object of further investigation) on the different sides of the front. In addition, the ratio of optical backscatter to Chl is high within the intermediate (mixed) waters, which is suggestive of large phytoplankton cells, and lower within the core of the Atlantic and Mediterranean waters. These observations highlight the relevance of fronts in triggering primary production at DCM level and shaping the characteristic patchiness of the pelagic domain. This gains further relevance considering the inadequacy of optical satellite sensors to observe DCM concentrations at such fine scales.  相似文献   

Enabling affordable omnidirectional subsurface extended image volumes via probing          下载免费PDF全文

Tristan van Leeuwen  Rajiv Kumar  Felix J. Herrmann 《Geophysical Prospecting》2017,65(2):385-406

Image gathers as a function of subsurface offset are an important tool for the inference of rock properties and velocity analysis in areas of complex geology. Traditionally, these gathers are thought of as multidimensional correlations of the source and receiver wavefields. The bottleneck in computing these gathers lies in the fact that one needs to store, compute, and correlate these wavefields for all shots in order to obtain the desired image gathers. Therefore, the image gathers are typically only computed for a limited number of subsurface points and for a limited range of subsurface offsets, which may cause problems in complex geological areas with large geologic dips. We overcome increasing computational and storage costs of extended image volumes by introducing a formulation that avoids explicit storage and removes the customary and expensive loop over shots found in conventional extended imaging. As a result, we end up with a matrix–vector formulation from which different image gathers can be formed and with which amplitude‐versus‐angle and wave‐equation migration velocity analysis can be performed without requiring prior information on the geologic dips. Aside from demonstrating the formation of two‐way extended image gathers for different purposes and at greatly reduced costs, we also present a new approach to conduct automatic wave‐equation‐based migration‐velocity analysis. Instead of focusing in particular offset directions and preselected subsets of subsurface points, our method focuses every subsurface point for all subsurface offset directions using a randomized probing technique. As a consequence, we obtain good velocity models at low cost for complex models without the need to provide information on the geologic dips.  相似文献   

Assessment of calanchi and rill–interrill erosion susceptibilities using terrain analysis and geostochastics: A case study in the Oltrepo Pavese,Northern Apennines,Italy     

Alberto Bosino  Paolo Giordani  Geraldine Quénéhervé  Michael Maerker 《地球表面变化过程与地形》2020,45(12):3025-3041

Soil erosion is one of the most important environmental problems distributed worldwide. In the last decades, numerous studies have been published on the assessment of soil erosion and the related processes and forms using empirical, conceptual and physically based models. For the prediction of the spatial distribution, more and more sophisticated stochastic modelling approaches have been proposed – especially on smaller spatial scales such as river basins. In this work, we apply a maximum entropy model (MaxEnt) to evaluate badlands (calanchi) and rill–interrill (sheet erosion) areas in the Oltrepo Pavese (Northern Apennines, Italy). The aim of the work is to assess the important environmental predictors that influence calanchi and rill–interrill erosion at the regional scale. We used 13 topographic parameters derived from a 12 m digital elevation model (TanDEM-X) and data on the lithology and land use. Additional information about the vegetation is introduced through the normalized difference vegetation index based on remotely sensed data (ASTER images). The results are presented in the form of susceptibility maps showing the spatial distribution of the occurrence probability for calanchi and rill–interrill erosion. For the validation of the MaxEnt model results, a support vector machine approach was applied. The models show reliable results and highlight several locations of the study area that are potentially prone to future soil erosion. Thus, coping and mitigation strategies may be developed to prevent or fight the soil erosion phenomenon under consideration. © 2020 John Wiley & Sons, Ltd.  相似文献   

Catch Crop Known to Decrease N-leaching also Counteracts Soil CO2 Emissions     

Marie MATTSSON  Marie MAGNHEDEN  Siegfried FLEISCHER 《资源与生态学报(英文版)》2015,6(3):180-185

CO₂ emissions to the atmosphere were studied in a fertilized sandy agricultural soil with and without a catch crop sown into the main crop. The catch crop was grown primarily with the purpose to decrease N-leaching but this study also wanted to find out if the catch crop could have an effect in a climate change perspective. Plots with catch crop showed decreased CO₂ emissions from the soil. Since previous results have shown that catch crops effectively decrease N-leaching we recommend growing catch crops as an effective measure for helping both the climate and the eutrophication issue. Seasonal variations in CO₂ emissions were pronounced with maximum emissions from the fertilized agricultural soil in June and from an adjacent unmanaged grassland in August. From the plot with catch crop emissions decreased in July and August but somewhat increased later in the autumn. Fertilized agricultural soil showed a within-soil CO₂ sink after harvest, i.e. within-soil CO₂ uptake. Availability of NH₄⁺ or NO₃^- in the soil seems to influence the within-soil CO₂ sink, with NH₄⁺ enforcing the sink while the same amount of NO₃^- instead increased CO₂ emissions.  相似文献   

B and Li isotopes as intrinsic tracers for injection tests in aquifer storage and recovery systems     

Wolfram Kloppmann  Haim Chikurel  Géraldine Picot  Joseph Guttman  Marie Pettenati  Avi Aharoni  Catherine Guerrot  Romain Millot  Irina Gaus  Thomas Wintgens 《Applied Geochemistry》2009

Boron and Li isotopes have been tested as environmental tracers of treated sewage injected into a sandy aquifer (Shafdan reclamation project, Israel). During a 38 days injection test in a newly dug injection well, a conservative artificial tracer (Br⁻) was monitored together with δ¹¹B and δ⁷Li in the injectate, in the unsaturated soil zone (porous cup) and an observation well in the aquifer. In spite of B and Li concentrations in the injectate close to background values, significant shifts of the isotope signatures could be observed over the duration of the injection test. Boron isotope ratios show a breakthrough curve delayed with respect to Br⁻ breakthrough due to some reversible sorption on the aquifer material. No isotope fractionation was observed in the unsaturated or the saturated zone so that B isotopes can be considered as conservative in the investigated part of the aquifer system. Lithium isotopes are strongly fractionated, probably due to sorption processes. Lithium concentrations point to a Li sink in the system, δ⁷Li values vary strongly with a tendency of ⁷Li depletion in the liquid phase over the duration of the experiment. This is opposite to the expected preferential sorption of ⁶Li onto clay minerals. Boron isotopes reveals a valuable tracer of artificial recharge of freshwaters derived from treated sewage, both for short term tracer tests and for long-term monitoring of artificial recharge, even if in aquifers with higher clay contents, sorption-linked isotope fractionation cannot be excluded. More data are needed on Li isotope fractionation in natural groundwater systems to assess the potential of this tracer as monitoring tool.  相似文献