Evaluating climate change at the Croatian Adriatic from observations and regional climate models’ simulations     

Čedo Branković  Ivan Güttler  Marjana Gajić-Čapka 《Climate Dynamics》2013,41(9-10):2353-2373

The 2m temperature (T2m) and precipitation from five regional climate models (RCMs), which participated in the ENSEMBLES project and were integrated at a 25-km horizontal resolution, are compared with observed climatological data from 13 stations located in the Croatian coastal zone. The twentieth century climate was simulated by forcing RCMs with identical boundary conditions from the ERA-40 reanalysis and the ECHAM5/MPI-OM global climate model (GCM); climate change in the twenty-first century is based on the A1B scenario and assessed from the GCM-forced RCMs’ integrations. When forced by ERA-40, most RCMs exhibit cold bias in winter which contributes to an overestimation of the T2m annual cycle amplitude and the errors in interannual variability are in all RCMs smaller than those in the climatological mean. All models underestimate observed warming trends in the period 1951–2010. The largest precipitation biases coincide with locations/seasons with small observed amounts but large precipitation amounts near high orography are relatively well reproduced. When forced by the same GCM all RCMs exhibit a warming in the cold half-year and a cooling (or weak warming) in the warm period, implying a strong impact of GCM boundary forcing. The future eastern Adriatic climate is characterised by a warming, up to +5 °C towards the end of the twenty-first century; for precipitation, no clear signal is evident in the first half of the twenty-first century, but a reduction in precipitation during summer prevails in the second half. It is argued that land-sea contrast and complex coastal configuration of the Croatian coast, i.e. multitude of island and well indented coastline, have a major impact on small-scale variability. Orography plays important role only at small number of coastal locations. We hypothesise that the parameterisations related to land surface processes and soil hydrology have relatively stronger impact on variability than orography at those locations that include a relatively large fraction of land (most coastal stations), but affecting less strongly locations at the Adriatic islands.  相似文献   

Modeling compositional compressible two-phase flow in porous media by the concept of the global pressure     

Brahim Amaziane  Mladen Jurak  Ana Žgaljić Keko 《Computational Geosciences》2014,18(3-4):297-309

We derive a new formulation for the compositional compressible two-phase flow in porous media. We consider a liquid–gas system with two components: water and hydrogen. The formulation considers gravity, capillary effects, and diffusivity of each component. The main feature of this formulation is the introduction of the global pressure variable that partially decouples the system equations. To formulate the final system, and in order to avoid primary unknowns changing between one-phase and two-phase zones, a second persistent variable is introduced: the total hydrogen mass density. The derived system is written in terms of the global pressure and the total hydrogen mass density. The system is capable of modeling the flows in both one and two-phase zones with no changes of the primary unknowns. The mathematical structure is well defined: the system consists of two nonlinear parabolic equations, the global pressure equation, and the total hydrogen mass density equation. The derived formulation is fully equivalent to the original one. Numerical simulations show ability of this new formulation to model efficiently the phase appearance and disappearance.  相似文献   

A geochemical and stable isotope investigation of groundwater/surface-water interactions in the Velenje Basin,Slovenia     

Tjaša Kanduč  Fausto Grassa  Jennifer McIntosh  Vekoslava Stibilj  Marija Ulrich-Supovec  Ivan Supovec  Sergej Jamnikar 《Hydrogeology Journal》2014,22(4):971-984

The geochemical and isotopic composition of surface waters and groundwater in the Velenje Basin, Slovenia, was investigated seasonally to determine the relationship between major aquifers and surface waters, water–rock reactions, relative ages of groundwater, and biogeochemical processes. Groundwater in the Triassic aquifer is dominated by HCO₃ ^–, Ca²⁺, Mg²⁺ and δ¹³C_DIC indicating degradation of soil organic matter and dissolution of carbonate minerals, similar to surface waters. In addition, groundwater in the Triassic aquifer has δ¹⁸O and δD values that plot near surface waters on the local and global meteoric water lines, and detectable tritium, likely reflecting recent (<50 years) recharge. In contrast, groundwater in the Pliocene aquifers is enriched in Mg²⁺, Na⁺, Ca²⁺, K⁺, and Si, and has high alkalinity and δ¹³C_DIC values, with low SO₄ ^2– and NO₃ ^– concentrations. These waters have likely been influenced by sulfate reduction and microbial methanogenesis associated with coal seams and dissolution of feldspars and Mg-rich clay minerals. Pliocene aquifer waters are also depleted in ¹⁸O and ²H, and have ³H concentrations near the detection limit, suggesting these waters are older, had a different recharge source, and have not mixed extensively with groundwater in the Triassic aquifer.  相似文献   

The influence of building materials on salt formation in rural environments     

Vesna Matović  Suzana Erić  Danica Srećković-Batoćanin  Philippe Colomban  Aleksandar Kremenović 《Environmental Earth Sciences》2014,72(6):1939-1951

Blocks of limestone and sandstone used in walls of the Manasija Monastery complex showed damage caused by the efflorescence and subflorescence of different salts in a low-pollution rural environment. In addition to common salts such as thenardite, thermonatrite, trona and gypsum, a small amount of eugsterite and darapskite was also present. Although these sodium and sodium–calcium salts formed where cement mortar was used for repairs, the lithological type and chemical composition of the substrate also had an influence on the development of distinct salts. The interaction between limestone and sandstone (substrates) and a solution rich in sodium (without calcium) was successfully simulated in the laboratory. The presence of gypsum and sodium–calcium sulphate, as experimental products, solely on the limestones indicated that, in addition to the cement-mortar solution, part of the calcium required for the formation of calcium and double sodium–calcium salts could occur from this substrate.  相似文献   

Structure analysis of geopolymers synthesized from clay originated from Serbia     

Snežana S. Nenadović  Ljiljana M. Kljajević  Maja A. Nešić  Marijana Ž. Petković  Katarina V. Trivunac  Vladimir B. Pavlović 《Environmental Earth Sciences》2017,76(2):79

The paper presents chemical and structural analysis of geopolymer materials which are obtained by alkali-activated calcined clay (metakaolin) originated from Serbia under strictly defined conditions. Characterization of the metakaolin and geopolymers molecular structure has been done using X-ray diffraction, scanning electron microscope, Fourier transform infrared spectroscopy and matrix-assisted laser desorption ionization time-of-flight mass spectrometry. The paper presents the possibility of obtaining geopolymer structure and differences in chemical and structural characterization of these materials taking into account the concentration of NaOH as a variable parameter. The results of MALDI analysis of metakaolin and synthesized geopolymer structures using various matrix system: 2,4,6 trihydroxyacetophenone (THAP), α-cyano-4-hydroxycinnamic, 2,6 dihydroxyacetophenone and laser desorption/ionization, have shown that THAP matrix is the most appropriate for analysing these aluminosilicate materials.  相似文献   

Diagenesis of diatomite from the Kolubara Coal Basin,Baroševac,Serbia     

J. Obradović  James R. Hein  J. Djurdjević 《Geological Journal》1994,29(3):209-217

Diatomite associated with the Kolubara Coal Basin was studied to better understand early stage silica diagenesis of shallow water deposits. The Kolubara Basin consists of Neogene siliciclastic rocks, diatomite, marlstone and rare carbonates. Palaeozoic metamorphic and Mesozoic sedimentary and igneous basement rocks are transgressively overlain by Upper Miocene sandstone, siltstone, shale and mudstone. This Upper Miocene section is transgressively overlain by the Pontian section, which contains diatomite and coal beds. White and grey diatomite forms beds 0.7-2.2 m thick that are continuous over an area of about 2 km². Siliceous rocks vary in composition from diatomite (81-89 per cent SiO₂) to diatom-bearing shale (58-60 per cent SiO₂). Siliceous deposits are laminated in places, with the laminae defined by variations in clay minerals, organic matter and diatoms. Diatomite shows only incipient diagenesis characterized by the fragmentation of diatom frustules, the minor to moderate corrosion of frustules and the formation of minor amounts of opal-A' (X-ray amorphous inorganic opal) cement. The low degree of diagenesis results from the young age of the deposits, low burial temperatures and possibly also from the presence of abundant organic matter and the dissolution of kaolinite. The presence of only weak diagenesis is also reflected by the characteristically poor consolidation of the rocks and low rank of the associated coal.  相似文献