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441.
Mid-latitude ice caves are assumed to be highly sensitive to climatic changes and thus represent a potentially interesting environmental archive. Establishing a precise chronology is, however, a prerequisite for the understanding of processes driving the cave-ice mass balance and thus allows a paleoenvironmental interpretation. At St. Livres ice cave (Jura Mountains, Switzerland), subfossil trees and organic material are abundant in the cave-ice deposit, therefore allowing the dating of individual ice layers. The dendrochronological analysis of 45 subfossil samples of Norway spruce (Picea abies (L.) Karst.) from the overhanging front of the ice outcrop as well as the dating of seven wood samples with 14C dating allowed for a reconstruction of the St. Livres cave-ice sequence and for the determination of periods of ice accumulation and ablation. Results suggest a maximal age of 1200 ± 50 14C yr BP for the observed ice sequence and indicate the presence of four major deposition gaps dated to the 14th, 15th, mid-19th and late 19th century, which can be related with periods of positive North Atlantic Oscillation anomalies (NAO+) over the winter half-year and/or anthropogenic cave-ice abstraction. Similarly, there is evidence that periods of cave-ice accumulation as observed between AD 1877-1900 and AD 1393-1415 would correspond with phases of negative NAO indices. Cave ice represents therefore an original climate archive for the winter half-year and is complementary to other continental proxies recording preferentially summer conditions (e.g., tree rings, varves).  相似文献   
442.
The validity of optically stimulated luminescence (OSL) has been tested on known‐age (historical) fluvial deposits along the rivers Danube (Austria) and Ebro (Spain). As partial bleaching of the OSL signal prior to deposition can interfere with correct age estimates, different approaches to extracting the dose accumulated during burial are compared. Using the finite mixture model gave OSL ages that are internally as well as stratigraphically consistent and in agreement with independent age control. According to these results, fluvial deposition at the Danube River study site can be attributed to different periods ranging from Bronze Age to the 18th century A.D. Fluvial deposits of Roman age and of the late 17th or early 18th century A.D. were found at the Ebro River study site. This is consistent with the morphological subdivision of the valleys and encourages further investigation of the fluvial and archaeological history of the study areas using OSL. © 2009 Wiley Periodicals, Inc.  相似文献   
443.
Yu  Yang  Cao  Yiguo  Hou  Dongde  Disse  Markus  Brieden  Andreas  Zhang  Haiyan  Yu  Ruide 《地理学报(英文版)》2022,32(4):717-734
Journal of Geographical Sciences - During the 21st century, artificial intelligence methods have been broadly applied in geosciences to simulate complex dynamic ecosystems, but the use of...  相似文献   
444.
A network of 30 standalone snow monitoring stations was used to investigate the snow cover distribution, snowmelt dynamics, and runoff generation during two rain‐on‐snow (ROS) events in a 40 km2 montane catchment in the Black Forest region of southwestern Germany. A multiple linear regression analysis using elevation, aspect, and land cover as predictors for the snow water equivalent (SWE) distribution within the catchment was applied on an hourly basis for two significant ROS flood events that occurred in December 2012. The available snowmelt water, liquid precipitation, as well as the total retention storage of the snow cover were considered in order to estimate the amount of water potentially available for the runoff generation. The study provides a spatially and temporally distributed picture of how the two observed ROS floods developed in the catchment. It became evident that the retention capacity of the snow cover is a crucial mechanism during ROS. It took several hours before water was released from the snowpack during the first ROS event, while retention storage was exceeded within 1 h from the start of the second event. Elevation was the most important terrain feature. South‐facing terrain contributed more water for runoff than north‐facing slopes, and only slightly more runoff was generated at open compared to forested areas. The results highlight the importance of snowmelt together with liquid precipitation for the generation of flood runoff during ROS and the large temporal and spatial variability of the relevant processes. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
445.
Brominated compounds are ubiquitous in the aquatic environment. The polybrominated diphenyl ether (PBDE) flame retardants are anthropogenic compounds of concern. Studies suggest that PBDEs can be biotransformed to hydroxylated brominated diphenyl ethers (OH-BDE). However, the rate of OH-BDE formation observed has been extremely small. OH-BDEs have also been identified as natural compounds produced by some marine invertebrates. Another class of compounds, the methoxylated BDEs (MeO-BDEs), has also been identified as natural compounds in the marine environment. Both the OH-BDEs and MeO-BDEs bioaccumulate in higher marine organisms. Recent studies have demonstrated that MeO-BDEs can be biotransformed to OH-BDEs and this generates greater amounts of OH-BDEs than could be generated from PBDEs. Consequently, MeO-BDEs likely represent the primary source of metabolically derived OH-BDEs. Given that for some endpoints OH-BDEs often exhibit greater toxicity compared to PBDEs, it is prudent to consider OH-BDEs as chemicals of concern, despite their seemingly "natural" origins.  相似文献   
446.
Climate Dynamics - El Niño-Southern Oscillation (ENSO) is the dominant mode of climate variability, affecting climate conditions over large areas of the globe. There are, however, substantial...  相似文献   
447.
The global rise in atmospheric greenhouse gas concentrations calls for practicable solutions to capture CO2. In this study, a mineral carbonation process was applied in which CO2 reacts with alkaline lignite ash and forms stable carbonate solids. In comparison to previous studies, the assays were conducted at low temperatures and pressures and under semi-dry reaction conditions in an 8 L laboratory mixing device. In order to find optimum process conditions the pCO2 (10-20%), stirring rate (500-3000 rpm) and the liquid to solid ratio (L/S = 0.03-0.36 L kg−1) were varied. In all experiments a considerable CO2 uptake from the gas phase was observed. Concurrently the solid phase contents of Ca and Mg (hydr)oxides decreased and CaCO3 and MgCO3 fractions increased throughout the experiments, showing that CO2 was stabilized as a solid carbonate. The carbonation reaction depends on three factors: Dissolution of CO2 in the liquid phase, mobilization of Ca and Mg from the mineral surface and precipitation of the carbonate solids. Those limitations were found to depend strongly on the variation of the process parameters. Optimum reaction conditions could be found for L/S ratios between 0.12 and 0.18, medium stirring velocities and pCO2 between 10% and 20%.Maximum CO2 uptake by the solid phase was 4.8 mmol g−1 after 120 min, corresponding to a carbonation efficiency for the alkaline material of 53% of the theoretical CO2 binding capacity. In comparison to previous studies both CO2 uptake and carbonation efficiencies were in a similar range, but the reaction times in the semi-dry process were considerably shorter. The proposed method additionally allows for a more simple carbonation setup due to low T and P, and produces an easier to handle product with low water content.  相似文献   
448.
Depth profiles of dissolved zinc were measured monthly over one year in Lake Greifen, a eutrophic lake. The concentrations are in the range 10–40 nM and show systematic variations over time and depth. Due to the increased binding to particles and subsequent settling, concentrations of zinc in the epilimnion decrease during summer stagnation. Clear correlations between Zn and major nutrients (P, Si) are, however, not observed in the water column. No accumulation of Zn occurs in the anoxic hypolimnion. The Zn sedimentation is related to the sedimentation of algae and of manganese oxide. A mass-balance calculation shows that 87% of the Zn input is retained in the sediments of Lake Greifen.  相似文献   
449.
450.
Air circulation due to the urban heat island (UHI) effect can influence the dispersion of air pollutants in a metropolis. This study focusses on the influence of the UHI effect on particulate matter (PM; including PM2.5 and PM2.5–10) between May and September 2010–2012 in the Taipei basin. Meteorological and PM data were obtained from the sites, owned by the governmental authorities. The analysis was carried out using t test, relative indices (RIs), Pearson product–moment correlation and stepwise regression. The results show that the RI values for PM were the highest at moderate UHI intensity (MUI; 2 °C ≤ UHI < 4 °C) rather than at strong UHI intensity (SUI; 4 °C ≤ UHI) during the peak time for anthropogenic emissions (20:00 LST). Neither the accumulation of PM nor the surface convergence occurred in the hot centre, as shown by the case study. At MUI, more than 89 % of the synoptic weather patterns showed that the weather was clear and hot or that the atmosphere was stable. The variation in PM was associated with horizontal and vertical air dispersion. Poor horizontal air dispersion, with subsidence, caused an increase in PM at MUI. However, the updraft motion diluted the PM at SUI. The stepwise regression models show that the cloud index and surface air pressure determined the variation in PM2.5–10, while cloud index, wind speed and mixing height influenced the variation in PM2.5. In conclusion, a direct relationship between UHI effect and PM was not obvious.  相似文献   
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