Characterization of atmospheric surfactants in the bulk precipitation by electrochemical tools     

Palma Orlović-Leko  Zlatica Kozarac  Božena Ćosović  Slađana Strmečki  Marta Plavšić 《Journal of Atmospheric Chemistry》2010,66(1-2):11-26

Characterization of atmospheric surfactants in bulk precipitations was carried out by adsorption study at the mercury electrode/solution interface using phase sensitive AC voltammetry. The structure and permeability of the adsorbed organic films at the mercury electrode was tested using the redox processes of lead and cadmium ions as electrochemical tools. The effects of organic matter from the bulk precipitations (rainwater and melted snow) were compared to those obtained for aqueous solutions of model substances: aromatic hydrocarbon (naphtalene), anionic surfactant (sodium dodecylbenzene sulfonate, NDBS), protein (albumine) and selected model substances suggested to be representative of water soluble organic compounds (WSOC) in atmospheric water (monocarboxylic, dicarboxylic, and polyacidic compounds and levoglucosan). It was found that substances like humic acid and 3-hydroxybutanoic acid may play an important role in atmospheric heterogeneous chemistry because of their surface active potential.  相似文献   

Analytic estimates and topological properties of the weak stability boundary     

Marta Ceccaroni  James Biggs  Luca Biasco 《Celestial Mechanics and Dynamical Astronomy》2012,114(1-2):1-24

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A Minimal Spanning Tree algorithm for source detection in γ-ray images     

Riccardo Campana  Enrico Massaro  Dario Gasparrini †  Sara Cutini †  Andrea Tramacere 《Monthly notices of the Royal Astronomical Society》2008,383(3):1166-1174

We developed a source detection algorithm based on the Minimal Spanning Tree (MST), that is a graph-theoretical method useful for finding clusters in a given set of points. This algorithm is applied to γ-ray bi-dimensional images where the points correspond to the arrival direction of photons, and the possible sources are associated with the regions where they clusterize. Some filters to select these clusters and to reduce the spurious detections are introduced. An empirical study of the statistical properties of MST on random fields is carried out in order to derive some criteria to estimate the best filter values. We also introduce two parameters useful to verify the goodness of candidate sources. To show how the MST algorithm works in practice, we present an application to an EGRET observation of the Virgo field, at high Galactic latitude and with a low and rather uniform background, in which several sources are detected.  相似文献   

Redistribution of archaeological assemblages in plowzones     

Marta Navazo  Carlos Díez 《Geoarchaeology》2008,23(3):323-333

Archaeological surface surveys have located open‐air sites on cropland in the Sierra de Atapuerca (Burgos, Spain). To what degree agricultural disturbances have impacted archaeological site integrity is poorly defined and may greatly affect interpretations of prehistoric land use. This paper presents the results of three experiments concerned with the effects of tillage on artifact distribution, focusing specifically on lateral and vertical artifact displacement. We demonstrate highly variable horizontal displacement of artifacts by plowing and overall downward movement of lithic materials within the soil. This results in an expansion of site boundaries and reduction of surface artifact density, yielding a biased and unrepresentative picture of past human activity. More experimental studies are needed to better define agricultural disturbances to surface archaeological assemblages. © 2008 Wiley Periodicals, Inc.  相似文献   

The 1‐million‐year‐old quartz assemblage from Pont‐de‐Lavaud (Centre,France) in the European context          下载免费PDF全文

Jackie Despriée  Marie‐Hélène Moncel  Marta Arzarello  Gilles Courcimault  Pierre Voinchet  Jean‐Jacques Bahain  Christophe Falguères 《第四纪科学杂志》2018,33(6):639-661

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Climatic vs. tectonic signals in a continental extensional basin (Teruel,NE Spain) from stable isotope (δ18O) and sequence stratigraphical evolution     

Lope Ezquerro  Aránzazu Luzón  Marta Navarro  Carlos L. Liesa  José L. Simón 《地学学报》2014,26(5):337-346

Alluvial fans and shallow carbonate lakes interfered in the Teruel half‐graben during the Late Miocene–Pliocene. Tectonic influence is recorded in alluvial and lacustrine–palustrine successions, with long‐term climate changes being recorded in detail in the isotopic signatures of carbonates. Episodes of tectonic activity induced alluvial fan progradation and lake retraction in the whole basin. Three lacustrine stages have been identified, which support the idea that climate also exerted an important control on sedimentation. The transition between stages 1 and 2 occurred during a tectonically calm episode due to an increase in aridity in the Early Turolian; small fans with source areas next to the lake margin prograded, inducing lake‐shore retraction. The transition from stage 2 to 3 was caused by the superimposition of increasing tectonic activity and aridity effects. Our study demonstrates that discrimination of allogenic factors controlling sedimentation in continental closed basins is possible using sequence stratigraphy in combination with other techniques such as geochemistry of carbonates.  相似文献   

Exploring Chile: Identities and Their Relation with the Environment through the Film Football Stories     

Marta Gallardo  David García-Reyes 《The Journal of geography》2018,117(5):205-215

Cinema can be considered a useful tool for understanding different geographic concepts, showing physical and human factors and the interactions between them. Andres Wood's film Football Stories explores the Chilean territory allowing the observation of the differences between the north and south of the country. Geographic components such as landscapes, architectures, the impact of anthropogenic activities, social inequalities, ways of life, and city and countryside differences are analyzed, as well as the importance of location, the spatial environment, and cinematic narration. The study of geography through films could contribute to understanding of our world and to spatial knowledge.  相似文献   

Applying Fractal Dimensions and Energy-Budget Analysis to Characterize Fracturing Processes During Magma Migration and Eruption: 2011–2012 El Hierro (Canary Islands) Submarine Eruption     

Carmen López  Joan Martí  Rafael Abella  Marta Tarraga 《Surveys in Geophysics》2014,35(4):1023-1044

The impossibility of observing magma migration inside the crust obliges us to rely on geophysical data and mathematical modelling to interpret precursors and to forecast volcanic eruptions. Of the geophysical signals that may be recorded before and during an eruption, deformation and seismicity are two of the most relevant as they are directly related to its dynamic. The final phase of the unrest episode that preceded the 2011–2012 eruption on El Hierro (Canary Islands) was characterized by local and accelerated deformation and seismic energy release indicating an increasing fracturing and a migration of the magma. Application of time varying fractal analysis to the seismic data and the characterization of the seismicity pattern and the strain and the stress rates allow us to identify different stages in the source mechanism and to infer the geometry of the path used by the magma and associated fluids to reach the Earth’s surface. The results obtained illustrate the relevance of such studies to understanding volcanic unrest and the causes that govern the initiation of volcanic eruptions.  相似文献   

Changes in Enzyme Activities and Microbial Community Structure in Heavy Metal‐Contaminated Soil under in Situ Aided Phytostabilization          下载免费PDF全文

Daniel Wasilkowski  Agnieszka Mrozik  Zofia Piotrowska‐Seget  Jacek Krzyżak  Marta Pogrzeba  Grażyna Płaza 《洁净——土壤、空气、水》2014,42(11):1618-1625

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Assimilation and diffusion during xenolith-magma interaction: a case study of the Variscan Karkonosze Granite, Bohemian Massif     

Marta Adamuszek  Timm John  Marcin Dabrowski  Yuri Y. Podladchikov  Ralf Gertisser 《Mineralogy and Petrology》2009,97(3-4):203-222

Magmatic enclaves from the Rudolfov quarry near Liberec (Czech Republic) are interpreted to represent remnants of lamprophyric melt that intruded the Karkonosze granite at a stage at which the granite was not fully solidified. Based on the observation that larger enclaves are generally more circular than the smaller ones, we conclude that bigger blobs of mafic magma became more spherical during flow in the gravity field (sink or float). This flow is also interpreted to be responsible for the incorporation of mineral grains into the enclaves and may have facilitated the assimilation of granitic melt. Linear mixing trends on Harker diagrams for most network-forming and mainly slow-diffusing or fluid-immobile elements indicate such an assimilation process between granite and lamprophyre. In contrast, all fast-diffusing or fluid-mobile elements display scattered element distributions, implying that chemical diffusion also played a role. Pressure and temperature for this late magmatic stage are estimated at around 1 kbar and 500°C. These results suggest that two processes modified the composition of the enclaves in the Karkonosze granite: (1) assimilation (mechanical mixing) of granitic melt during the injection of the lamprophyric melt and the subsequent flow of the forming enclaves in the gravity field (responsible for the linear mixing trends) and (2) diffusion-controlled redistribution of elements between both solidifying rock types at the magmatic stage and/or due to late-stage magmatic fluids (responsible for the scattering and deviation from the linear mixing trends).  相似文献