Effect of hydrocarbon volatility and adsorption on source-rock pyrolysis     

Martha E. Tarafa  John M. Hunt  Inger Ericsson 《Journal of Geochemical Exploration》1983,18(1):75-85

Petroleum source-rock evaluations by pyrolysis are based on the concept that free hydrocarbons in rock samples are volatilized below 300°C while hydrocarbons cracked from kerogen come off at higher temperatures. The pyrolysis of pure hydrocarbons with different mineral matrices shows that free hydrocarbons containing 16 or more carbon atoms may not be evolved eblow 300°C, but at varying higher temperatures. The extent to which this occurs depends on the hydrocarbon volatility, the mineral matrix and the pyrolysis instrument design. Source-rock parameters which use the P₁ (S₁) peak may be not be reproducible between instruments if the rock contains appreciable amounts of high molecular weight hydrocarbons.  相似文献   

Numerical integration errors in calculated tropospheric photodissociation rate coefficients     

Sasha Madronich  Glenn Weller 《Journal of Atmospheric Chemistry》1990,10(3):289-300

Tropospheric photodissociation rate coefficients (J values) were calculated for NO₂, O₃, HNO₂, CH₂O, and CH₃CHO using high spectral resolution (0.1 mm wavelength increments), and compared to the J values obtained with numerically degraded resolution (=1, 2, 4, 6, 8, and 10 nm, and several commonly used nonuniform grids). Depending on the molecule, substantial errors can be introduced by the larger increments. Thus for =10 nm, errors are less than 1% for NO₂, less than 2% for HNO₂, +6.5% to -16% for CH₂O, -6.9% to +24% for CH₃CHO, and -24% to +110% for O₃. The errors for CH₂O arise from the fine structure of its absorption spectrum, and are prevalently negative (underestimate of J). The errors for O₃, and to a lesser extent for CH₃CHO, arise mainly from under-resolving the overlap of the molecular action spectrum and the tropospheric actinic flux in the wavelength region of stratospheric ozone attenuation. The sign of those errors depends on whether the actinic flux is averaged onto the grid before or after the radiative transfer calculation. In all cases studied, grids with 2 nm produced errors no larger than 5%.  相似文献   

Petrographic and petrophysical investigation on carbonate samples (Upper Cretaceous) from the Tushka Area (Egypt) with special focus on the effective pore radius     

Ümit Öner  Andreas Weller  Carl-Diedrich Sattler  Mohamed A. Kassab 《Arabian Journal of Geosciences》2016,9(3):229

Petrographic and petrophysical properties of 42 carbonate rock samples from the Tushka Area, Egypt have been investigated. The samples originate from the Upper Cretaceous taken from seven shallow wells and were subdivided into three microfacies. The petrographic characterization of the glauconite-rich, fossiliferous limestones was carried out over 17 thin sections and an additional measurement of the glauconite content by color differentiation. The facies were characterized as (1) oolithic, low-dolomitic, and low-glauconitic, fossil-rich packstone with a tendency towards floatstone or rudstone; (2) glauconite-rich, low-dolomitic floatstone with a tendency towards rudstone; and (3) glauconite and iron mineral-rich, sparry calcitic cemented, and low-dolomitic rudstone. The petrophysical investigation providing grain density, porosity, electrical conductivity, specific internal surface, permeability, magnetic susceptibility, and the pore throat geometry supports the classification into three facies. A strong relation between permeability and formation factor is observed. The median pore radius derived from mercury porosimetry proves to be a good estimate of the effective hydraulic radius. An increased content of iron oxides was identified in facies 3. The increased iron content is related to higher values of both magnetic susceptibility and specific internal surface.  相似文献   

New structural and U–Pb zircon data from Anafi crystalline basement (Cyclades,Greece): constraints on the evolution of a Late Cretaceous magmatic arc in the Internal Hellenides     

Silviu O. Martha  Wolfgang Dörr  Axel Gerdes  Rainer Petschick  Janina Schastok  Paraskevas Xypolias  Gernold Zulauf 《International Journal of Earth Sciences》2016,105(7):2031-2060

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Assessing the effects of forest biomass reductions on forest health and streamflow     

Ryan R. Bart  Ram L. Ray  Martha H. Conklin  Mohammad Safeeq  Philip C. Saksa  Christina L. Tague  Roger C. Bales 《水文研究》2021,35(3):e14114

Forest biomass reductions in overgrown forests have the potential to provide hydrologic benefits in the form of improved forest health and increased streamflow production in water-limited systems. Biomass reductions may also alter evaporation. These changes are generated when water that previously would have been transpired or evaporated from the canopy of the removed vegetation is transferred to transpiration of the remaining vegetation, streamflow, and/or non-canopy evaporation. In this study, we combined a new vegetation-change water-balance approach with lumped hydrologic modelling outputs to examine the effects of forest biomass reductions on transpiration of the remaining vegetation and streamflow in California's Sierra Nevada. We found that on average, 102 mm and 263 mm (8.0% and 20.6% of mean annual precipitation [MAP]) of water were made available following 20% and 50% forest biomass-reduction scenarios, respectively. This water was then partitioned to both streamflow and transpiration of the remaining forest, but to varying degrees depending on post-biomass-reduction precipitation levels and forest biomass-reduction intensity. During dry periods, most of the water (approximately 200 mm [15.7% on MAP] for the 50% biomass-reduction scenario) was partitioned to transpiration of the remaining trees, while less than 50 mm (3.9% on MAP) was partitioned to streamflow. This increase in transpiration during dry periods would likely help trees maintain forest productivity and resistance to drought. During wet periods, the hydrologic benefits of forest biomass reductions shifted to streamflow (200 mm [15.7% on MAP]) and away from transpiration (less than 150 mm [11.8% on MAP]) as the remaining trees became less water stressed. We also found that streamflow benefits per unit of forest biomass reduction increased with biomass-reduction intensity, whereas transpiration benefits decreased. By accounting for changes in vegetation, the vegetation-change water balance developed in this study provided an improved assessment of watershed-scale forest health benefits associated with forest biomass reductions.  相似文献   

Vegetation water sources in California's Sierra Nevada (USA) are young and change over time,a multi-isotope (δ18O, δ2H, 3H) tracer approach.     

Melissa Thaw  Ate Visser  Richard Bibby  Amanda Deinhart  Erik Oerter  Martha Conklin 《水文研究》2021,35(6):e14249

Sierra Nevada forests transpire a significant amount of California's water resources, sparking interest in applying forest management to improve California's water supply. Determining the source water of evapotranspiration enables forest managers to make informed decisions. To this end, a significant interest in critical zone science is to develop new methods to work across time scales to predict subsurface water storage and use. In this study, forest vegetation accessed young water and switched sources depending on availability, suggesting that forest drought vulnerability may depend on the range of water sources available (rain, snowmelt and deeply stored water). This finding also suggests that changes in transpiration rates may have immediate effects on water sources in close proximity to vegetation, and delayed effects on storage and runoff. New δ¹⁸O, δ²H and ³H data were used to track precipitation, runoff, evapotranspiration and storage through the critical zone seasonally, including seasons where evapotranspiration and snowmelt were in phase (winter snowmelt) and out of phase (seasonally dry summer). The main source of this headwater catchment's runoff is derived from its meadow saturated zone water, which was dominated by snowmelt. Water that originated as snowmelt contributed to transpiration, unless other sources, such as recent rain, became available. In cases where xylem δ¹⁸O and δ²H signatures matched those of deeper saturated zone water, ³H data showed that xylem water was distinctly younger than the deep saturated zone water. During 2016, which experienced relatively normal snowpack in winter and seasonally dry summer conditions, mean summer saturated zone water and vegetation water were similar in δ¹⁸O, −12.4 ± 0.04 ‰ and − 12.5 ± 0.3 ‰, respectively, but were distinctly different in ³H, 5.5 ± 0.2 pCi/L and 13.7 ± 1.1 pCi/L, respectively. While δ¹⁸O shows that vegetation and meadow saturated zone water have similar origins, ³H shows they have dissimilar ages.  相似文献   

Insights into plant water uptake from xylem‐water isotope measurements in two tropical catchments with contrasting moisture conditions          下载免费PDF全文

Jaivime Evaristo  Jeffrey J. McDonnell  Martha A. Scholl  L. Adrian Bruijnzeel  Kwok P. Chun 《水文研究》2016,30(18):3210-3227

Water transpired by trees has long been assumed to be sourced from the same subsurface water stocks that contribute to groundwater recharge and streamflow. However, recent investigations using dual water stable isotopes have shown an apparent ecohydrological separation between tree‐transpired water and stream water. Here we present evidence for such ecohydrological separation in two tropical environments in Puerto Rico where precipitation seasonality is relatively low and where precipitation is positively correlated with primary productivity. We determined the stable isotope signature of xylem water of 30 mahogany (Swietenia spp.) trees sampled during two periods with contrasting moisture status. Our results suggest that the separation between transpiration water and groundwater recharge/streamflow water might be related less to the temporal phasing of hydrologic inputs and primary productivity, and more to the fundamental processes that drive evaporative isotopic enrichment of residual soil water within the soil matrix. The lack of an evaporative signature of both groundwater and streams in the study area suggests that these water balance components have a water source that is transported quickly to deeper subsurface storage compared to waters that trees use. A Bayesian mixing model used to partition source water proportions of xylem water showed that groundwater contribution was greater for valley‐bottom, riparian trees than for ridge‐top trees. Groundwater contribution was also greater at the xeric site than at the mesic–hydric site. These model results (1) underline the utility of a simple linear mixing model, implemented in a Bayesian inference framework, in quantifying source water contributions at sites with contrasting physiographic characteristics, and (2) highlight the informed judgement that should be made in interpreting mixing model results, of import particularly in surveying groundwater use patterns by vegetation from regional to global scales. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Phase equilibria modelling of blueschist and eclogite from the Sanbagawa metamorphic belt of southwest Japan reveals along‐strike consistency in tectonothermal architecture          下载免费PDF全文

O. M. Weller  S. R. Wallis  M. Aoya  T. Nagaya 《Journal of Metamorphic Geology》2015,33(6):579-596

The Sanbagawa metamorphic belt of southwest Japan is one of the type localities of subduction‐related high‐P metamorphism. However, variable pressure–temperature (P–T) paths and metabasic assemblages have been reported for eclogite units in the region, leading to uncertainty about the subduction zone paleo‐thermal structure and associated tectonometamorphic conditions. To analyse this variation, phase equilibria modelling was applied to the three main high‐P metabasic rock types documented in the region – glaucophane eclogite, barroisite eclogite and garnet blueschist – with modelling performed over a range of P, T, bulk rock H₂O and bulk rock ferric iron conditions using thermocalc . All samples are calculated to share a common steep prograde P–T path to similar peak conditions of ～16–20 kbar and 560–610 °C. The results establish that regional assemblage variation is systematic, with the alternation in peak amphibole phase due to peak conditions overlapping the glaucophane–barroisite solvus, and bulk composition effects stabilizing blueschist v. eclogite facies assemblages at similar P–T conditions. Furthermore, the results reveal that a steep prograde P–T path is common to all eclogite units in the Sanbagawa belt, indicating that metamorphic conditions were consistent along strike. All localities are compatible with predictions made by a ridge approach model, which attributes eclogite facies metamorphism and exhumation of the Sanbagawa belt to the approach of a spreading ridge.  相似文献   

Oblique surface wave propagation over a small undulation on the bottom of an ocean     

S. C. Martha 《地球物理与天体物理流体动力学》2013,107(2):65-80

The problem of oblique water wave diffraction by small undulation of the bottom of a laterally unbounded ocean is considered using linear water wave theory. A perturbation analysis is employed to obtain the velocity potential, the reflection and the transmission coefficients up to the first order in terms of integrals involving the shape functions c(x) representing the bottom undulation. Finite cosine transform is used to find the first order potential, and this potential is utilised in obtaining the first order reflection and transmission coefficients. Some particular forms of the shape function representing an exponentially damped undulation, a single hump and a patch of sinusoidal ripples are considered and the integrals for the reflection and transmission coefficients are evaluated. For the exponentially damped undulation, it is observed that the reflection ceases much before transmission while for the single hump, reflection and transmission go hand in hand up to a certain value of the wavenumber, after which they vanish. For the patch of sinusoidal ripples having the same wavenumber, the reflection coefficient up to the first order is found to be an oscillatory function in the quotient of twice the component of the wavenumber along x-axis and the ripple wavenumber. When this quotient becomes one, the theory predicts a resonant interaction between the bed and free surface, and the reflection coefficient becomes a multiple of the number of ripples. High reflection of the incident wave energy occurs if this number is large. Also, when a patch of ripples having different wavenumbers is considered the same result follows. Known results for the normal incidence are recovered as special cases for the patch of sinusoidal ripples. The theoretical observations are shown computationally.  相似文献   

Effects of Shoreline Alteration and Other Stressors on Submerged Aquatic Vegetation in Subestuaries of Chesapeake Bay and the Mid-Atlantic Coastal Bays     

Christopher J. Patrick  Donald E. Weller  Xuyong Li  Micah Ryder 《Estuaries and Coasts》2014,37(6):1516-1531

Submerged aquatic vegetation (SAV) provides many important ecosystem functions, but SAV has been significantly reduced in many estuaries. We used spatial–statistical models to identify estuarine shoreline characteristics that explain variations in SAV abundance among subestuaries of the Chesapeake Bay and mid-Atlantic Coastal Bays. We summarized digital spatial data on shoreline construction, shoreline land use, physical characteristics, watershed land cover, and salinity for each subestuary. We related SAV abundance to shoreline characteristics and other stressors using univariate regression and multivariate models. The strongest univariate predictors of SAV abundance were percent shoreline forest, percent shoreline marsh, the percentage of shoreline that is 5–10 m tall, percent riprap, the percentage of subestuary area <2 m deep, percent herbaceous wetland, and percent shrubland. Shoreline marsh, bulkhead, and shoreline forest had different effects on SAV in different salinity zones. Percent riprap shoreline was the most important variable in a regression tree analysis of all the subestuaries, and percent deciduous forest in the watershed was the most important variable in a separate regression tree analysis on the mesohaline subestuaries. Subestuaries with <5.4 % riprap followed a significantly different temporal trajectory than those with >5.4 % riprap. SAV abundance has increased steadily since 1984 in subestuaries with <5.4 % riprap, but has not increased since 1996–1997 in subestuaries with >5.4 % riprap. Some shoreline characteristics interact with larger-scale factors like land cover and salinity zone to affect the distribution of SAV, while the effects of other shoreline characteristics are consistent among subestuaries with different salinities or local watershed land covers. Many shoreline characteristics can be controlled by management decisions, and our results help identify factors that managers should consider in efforts to increase SAV abundance.  相似文献