Divergent evolution in fluviokarst landscapes of central Kentucky     

Jonathan D. Phillips  Linda L. Martin  Viva G. Nordberg  William A. Andrews 《地球表面变化过程与地形》2004,29(7):799-819

Central Kentucky is characterized by a mixture of karst and ?uvial features, typically manifested as mosaic of karst‐rich/channel‐poor (KRCP) and channel‐rich/karst‐poor (CRKP) environments. At the regional scale the location and distribution of KRCP and CRKP areas are not always systematically related to structural, lithological, topographic, or other controls. This study examines the relationship of KRCP and CRKP zones along the Kentucky River gorge area, where rapid incision in the last 1·5 million years has lowered local base levels and modi?ed slopes on the edge of the inner bluegrass plateau. At the scale of detailed ?eld mapping on foot within a 4 km² area, the development of karst and ?uvial features is controlled by highly localized structural and topographic constraints, and can be related to slope changes associated with retreat of the Kentucky River gorge escarpment. A conceptual model of karst/?uvial transitions is presented, which suggests that minor, localized variations are suf?cient to trigger a karst–?uvial or ?uvial–karst switch when critical slope thresholds are crossed. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Mechanisms of weathering of meteorites recovered from hot and cold deserts and the formation of phyllosilicates     

Martin R. Lee  Philip A. Bland 《Geochimica et cosmochimica acta》2004,68(4):893-916

Petrographic, mineralogical and chemical analysis of naturally weathered equilibrated ordinary chondrites collected from ‘ hot’ deserts and Antarctica has revealed striking similarities and also pronounced differences in weathering between the two environments. Terrestrial weathering in all meteorites studied is dominated by oxidation and hydration of Fe,Ni metal, producing Fe-oxides and oxyhydroxides that have partially replaced the metal grains and have also occluded primary intergranular pores to form veins. Troilite weathers readily in ‘ hot’ desert environments but undergoes very little alteration under Antarctic conditions. Most of the primary porosity of ordinary chondrites has been occluded by the time that ∼ 15 to 25% of the initial Fe⁰ and Fe²⁺ has been oxidised to Fe³⁺ in both environments. Results from modelling the volume changes upon alteration of primary minerals to a range of weathering products demonstrates that the primary porosity of most meteorites is sufficient to accommodate weathering products. Dilation of primary pores and brecciation, which has been observed in parts of some meteorites, will only occur if the meteorite is especially metal-rich, or has a low primary porosity. These weathering products are absent from recent falls but have formed in a fall after ∼ 100 yr of museum storage.Cl-bearing akaganéite and hibbingite are common weathering products in Antarctic finds but occur in abundance in only one ‘ hot’ desert meteorite, Daraj 014. The majority of Fe-rich weathering products in meteorites from both environments contain low, but variable concentrations of Si, Mg and Ca. In most meteorites a proportion of these elements are inferred to be present as a very finely crystalline mineral with a ∼ 1.0-nm lattice fringe spacing; where seen within intragranular fractures this mineral has a topotactic relationship with olivine and orthopyroxene. In the heavily-weathered Antarctic finds ALHA 78045 and 77002, Si is concentrated in cronstedtite, a Fe-rich phyllosilicate. An unidentified hydrous Si-Fe-Ni-Mg mineral or gel has also partially replaced taenite in ALHA 78045. In addition to Fe-rich weathering products, ‘ hot’ desert meteorites contain sulphates, Ca-carbonate and silica, whereas such minerals are largely absent from Antarctic finds. The abundance of silicate weathering products in Antarctic meteorites is unexpected and indicates that olivine and pyroxene undergo significant chemical weathering in these environments. As preterrestrial cronstedtite is abundant in CM2 carbonaceous chondrites, the Antarctic environment may be a powerful analog for aqueous alteration in the asteroidal parent bodies of primitive meteorites.  相似文献   

New constraints on the sources and behavior of neodymium and hafnium in seawater from Pacific Ocean ferromanganese crusts     

Tina van de Flierdt  Martin Frank  Alex N. Halliday  James R. Hein 《Geochimica et cosmochimica acta》2004,68(19):3827-3843

The behavior of dissolved Hf in the marine environment is not well understood due to the lack of direct seawater measurements of Hf isotopes and the limited number of Hf isotope time-series obtained from ferromanganese crusts. In order to place better constraints on input sources and develop further applications, a combined Nd-Hf isotope time-series study of five Pacific ferromanganese crusts was carried out. The samples cover the past 38 Myr and their locations range from sites at the margin of the ocean to remote areas, sites from previously unstudied North and South Pacific areas, and water depths corresponding to deep and bottom waters.For most of the samples a broad coupling of Nd and Hf isotopes is observed. In the Equatorial Pacific ε_Nd and ε_Hf both decrease with water depth. Similarly, ε_Nd and ε_Hf both increase from the South to the North Pacific. These data indicate that the Hf isotopic composition is, in general terms, a suitable tracer for ocean circulation, since inflow and progressive admixture of bottom water is clearly identifiable.The time-series data indicate that inputs and outputs have been balanced throughout much of the late Cenozoic. A simple box model can constrain the relative importance of potential input sources to the North Pacific. Assuming steady state, the model implies significant contributions of radiogenic Nd and Hf from young circum-Pacific arcs and a subordinate role of dust inputs from the Asian continent for the dissolved Nd and Hf budget of the North Pacific.Some changes in ocean circulation that are clearly recognizable in Nd isotopes do not appear to be reflected by Hf isotopic compositions. At two locations within the Pacific Ocean a decoupling of Nd and Hf isotopes is found, indicating limited potential for Hf isotopes as a stand-alone oceanographic tracer and providing evidence of additional local processes that govern the Hf isotopic composition of deep water masses. In the case of the Southwest Pacific there is evidence that decoupling may have been the result of changes in weathering style related to the buildup of Antarctic glaciation.  相似文献   

Socioeconomic GeoComputation and E-Social Science     

David Martin 《Transactions in GIS》2005,9(1):1-3

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Uptake and depuration of PAHs and chlorinated pesticides by semi-permeable membrane devices (SPMDs) and green-lipped mussels (Perna viridis)     

Bruce J. Richardson  Edmund S.-C. Tse  Sharon B. De Luca-Abbott  Michael Martin  Paul K.S. Lam 《Marine pollution bulletin》2005,51(8-12):975

Semi-batch seawater experiments were conducted to follow the uptake and release of selected PAHs (anthracene, fluorathene, pyrene and B[a]P) and organochlorine pesticides (α-HCH, aldrin, dieldrin, p,p′-DDT) in semi-permeable membrane devices (SPMDs) and green-lipped mussels (Perna viridis). Mathematical models were applied to describe the uptake and elimination curves of the contaminants for SPMDs, and kinetic parameters, such as uptake rate constants, and equilibrium triolein/water partitioning coefficients were calculated. SPMD data showed a good fit to estimate rate constant and partition coefficient equations, but only those contaminants which partitioned mainly in the dissolved phase (α-HCH and dieldrin) were well explained for mussels. Poor conformity of the other contaminants indicated mussels uptake by routes other than diffusion, such as ingestion of algae. An apparent equilibrium state was only noted for α-HCH in mussels. Aldrin was not detected in mussels in the first few days of exposure, indicating potential metabolism of this compound. B[a]P was not detected in the triolein of SPMDs, which suggests that the membrane may act as a reservoir. Loss of spiked B[a]P from the triolein was evident in a depuration experiment, which may indicate transfer to the membrane. Rate constants for mussels were higher than those for SPMDs, but the reverse was true for partition coefficients. Overall, mussels and SPMDs had similar uptake rates for all compounds in this study, excluding p,p′-DDT and dieldrin. Contaminant elimination took place more rapidly in mussels, implying that SPMDs are better candidates for detecting episodic discharge of organic contaminants.  相似文献   

Centrifuge modeling of load-deformation behavior of rocking shallow foundations   总被引：4，自引：0，他引：4  

Sivapalan Gajan  Bruce L. Kutter  Justin D. Phalen  Tara C. Hutchinson  Geoff R. Martin 《Soil Dynamics and Earthquake Engineering》2005,25(7-10):773-783

Shallow foundations supporting building structures might be loaded well into their nonlinear range during intense earthquake loading. The nonlinearity of the soil may act as an energy dissipation mechanism, potentially reducing shaking demands exerted on the building. This nonlinearity, however, may result in permanent deformations that also cause damage to the building. Five series of tests on a large centrifuge, including 40 models of shear wall footings, were performed to study the nonlinear load-deformation characteristics during cyclic and earthquake loading. Footing dimensions, depth of embedment, wall weight, initial static vertical factor of safety, soil density, and soil type (dry sand and saturated clay) were systematically varied. The moment capacity was not observed to degrade with cycling, but due to the deformed shape of the footing–soil interface and uplift associated with large rotations, stiffness degradation was observed. Permanent deformations beneath the footing continue to accumulate with the number of cycles of loading, though the rate of accumulation of settlement decreases as the footing embeds itself.  相似文献   

Gene Expression Analysis for Exposure to Estrogenic Substances     

Martin Alberti  Ulf Kausch  Stefanie Haindl  Martin Seifert 《洁净——土壤、空气、水》2005,33(1):38-44

Zebrafish (Danio rerio) were exposed with 17β‐estradiol (E2) and nonylphenol (NP) in different concentrations. Gene expression analysis was carried out by two different approaches. First, RT‐PCR experiments were performed for the examination of expression levels of the two marker genes vitellogenin and aromatase. This approach showed a significant increase in the expression of the vitellogenin gene in exposed male fish (500 ng/L 17β‐estradiol and 250 μg/L nonylphenol). This egg yolk protein is usually not synthesized in male vertebrates. A slight decrease of expression of the aromatase gene was observed in exposed female zebrafish. Aromatase is known to catalyze the conversion of androgens to estrogens. Second, DNA microarray experiments were carried out, which allow the simultaneous examination of the expression levels of a great number of marker genes. The microarray experiments resulted in an up‐regulation of vitellogenin up to 850‐fold. In addition, several other genes were identified to be up‐regulated by estrogens, for example the high mobility group box protein ssrp1 (78‐fold) or the chaperonin containing t‐complex polypeptide 1, beta subunit cctb (22‐fold).  相似文献   

The significance of European high mountain lakes in critical load distributions at the EMEP grid scale     

Chris J. Curtis  Max Posch  Pilar Casals-Carrasco  Jordi Catalan  Mike Hughes  Martin Kernan  Marc Ventura 《Aquatic Sciences - Research Across Boundaries》2005,67(3):252-262

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山东莒南后左山恐龙公园早白垩世恐龙足迹化石初步研究   总被引：8，自引：5，他引：8  

李日辉  刘明渭  Lockley Martin R 《地质通报》2005,24(3):277-280

山东省莒南县后左山恐龙公园内保存了数量众多、形态各异的恐龙足迹化石。该足迹化石群产于早白垩世大盛群田家楼组,主要是兽脚类、鸟脚类恐龙的足迹,尤以前者占优质。最大的一个为椭圆形,大小100cm×70cm,可能系鸟脚类恐龙的足迹。鸟脚类足迹大多为椭圆形,长轴一般30～40cm,常呈幻迹保存。最大的兽脚类足迹为三趾型,长49cm,宽35cm,是大型肉食龙类的足迹;最小的一个长8.5cm,宽4.5cm,可能是虚骨龙类的足迹。另外还发现了少量可能是驰龙的足迹,具有2个很长的趾(Ⅲ和Ⅳ趾),趾间角极小,二者几乎平行。鸟脚类恐龙足迹层位分布局限,但密度较大,产出的层面常发育泥裂、波痕,甚至冰晶痕,与泥岩、粉砂质泥岩等层位相关性较强。  相似文献   

Simulation of the development of gypsum maze caves     

Steffen Birk  Rudolf Liedl  Martin Sauter  Georg Teutsch 《Environmental Geology》2005,48(3):296-306

The development of gypsum maze caves under artesian conditions has been simulated. The numerical model simulations show that the evolution of maze caves in this type of setting requires structural preferences such as laterally extended fissure networks in a horizon of the gypsum layer. Without any structural preferences vertical shafts rather than maze caves are predicted to develop. The most important stage for the development of horizontal caves under artesian conditions is found to be the initial karstification period. During this period the structure of the mature conduit system is established. The solutional enlargement of conduits is spatially extended, total dissolution rates are higher than the later ones.  相似文献