Stability at high-pressure,elastic behaviour and pressure-induced structural evolution of CsAlSi<Subscript>5</Subscript>O<Subscript>12</Subscript>, a potential host for nuclear waste     

G. Diego Gatta  Nicola Rotiroti  Martin Fisch  Milen Kadiyski  Thomas Armbruster 《Physics and Chemistry of Minerals》2008,35(9):521-533

The elastic and structural behaviour of the synthetic zeolite CsAlSi₅O₁₂ (a = 16.753(4), b = 13.797(3) and c = 5.0235(17) Å, space group Ama2, Z = 2) were investigated up to 8.5 GPa by in situ single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions. No phase-transition occurs within the P-range investigated. Fitting the volume data with a third-order Birch–Murnaghan equation-of-state gives: V ₀ = 1,155(4) ų, K _T0 = 20(1) GPa and K′ = 6.5(7). The “axial moduli” were calculated with a third-order “linearized” BM-EoS, substituting the cube of the individual lattice parameter (a ³, b ³, c ³) for the volume. The refined axial-EoS parameters are: a ₀ = 16.701(44) Å, K _T0a = 14(2) GPa (β_a = 0.024(3) GPa^?1), K′ _a = 6.2(8) for the a-axis; b ₀ = 13.778(20) Å, K _T0b = 21(3) GPa (β_b = 0.016(2) GPa^?1), K′ _b = 10(2) for the b-axis; c ₀ = 5.018(7) Å, K _T0c = 33(3) GPa (β_c = 0.010(1) GPa^?1), K′ _c = 3.2(8) for the c-axis (K _T0a:K _T0b:K _T0c = 1:1.50:2.36). The HP-crystal structure evolution was studied on the basis of several structural refinements at different pressures: 0.0001 GPa (with crystal in DAC without any pressure medium), 1.58(3), 1.75(4), 1.94(6), 3.25(4), 4.69(5), 7.36(6), 8.45(5) and 0.0001 GPa (after decompression). The main deformation mechanisms at high-pressure are basically driven by tetrahedral tilting, the tetrahedra behaving as rigid-units. A change in the compressional mechanisms was observed at P ≤ 2 GPa. The P-induced structural rearrangement up to 8.5 GPa is completely reversible. The high thermo-elastic stability of CsAlSi₅O_12, the immobility of Cs at HT/HP-conditions, the preservation of crystallinity at least up to 8.5 GPa and 1,000°C in elastic regime and the extremely low leaching rate of Cs from CsAlSi₅O₁₂ allow to consider this open-framework silicate as functional material potentially usable for fixation and deposition of Cs radioisotopes.  相似文献   

The soilmodels.info project   总被引：1，自引：0，他引：1  

Gerd Gudehus  Angelo Amorosi  Antonio Gens  Ivo Herle  Dimitrios Kolymbas  David Mašín  David Muir Wood  Andrzej Niemunis  Roberto Nova  Manuel Pastor  Claudio Tamagnini  Gioacchino Viggiani 《国际地质力学数值与分析法杂志》2008,32(12):1571-1572

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Mineralogy and geochemistry of El Dorado epithermal gold deposit, El Sauce district, central-northern Chile   总被引：1，自引：0，他引：1  

J. Carrillo-Rosúa  S. Morales-Ruano  D. Morata  A. J. Boyce  M. Belmar  A. E. Fallick  P. Fenoll Hach-Alí 《Mineralogy and Petrology》2008,92(3-4):341-360

Summary The El Dorado Au-Cu deposit is located in an extensive intra-caldera zone of hydrothermal alteration affecting Upper Cretaceous andesites of the Los Elquinos Formation at La Serena (≈ 29°47′S Lat., 70°43′W Long., Chile). Quartz-sulfide veins of economic potential are hosted by N25W and N20E fault structures associated with quartz-illite alteration (+supergene kaolinite). The main ore minerals in the deposit are pyrite, chalcopyrite ± fahlore (As/(As + Sb): 0.06−0.98), with electrum, sphalerite, galena, bournonite-seligmanite (As/(As + Sb): 0.21−0.31), marcasite, pyrrhotite being accessory phases. Electrum, with an Ag content between 32 and 37 at.%, occurs interstitial to pyrite aggregates or along pyrite fractures. Pyrite commonly exhibits chemical zonation with some zones up to 1.96 at.% As. Electron probe microanalyses of pyrite indicate that As-rich zones do not exhibit detectable Au values. Fluid inclusion microthermometry shows homogenization temperatures between 130 and 352 °C and salinities between 1.6 and 6.9 wt.% NaCl eq. Isotope data for quartz, ankerite and phyllosilicates and estimated temperatures show that δ¹⁸O and δD for the hydrothermal fluids were between 3 and 10‰ and between −95 and −75‰, respectively. These results suggest the mineralizing fluids were a mixture of meteoric and magmatic waters. An epithermal intermediate-sulfidation model is proposed for the formation of the El Dorado deposit. Author’s present address: J. Carrillo-Rosúa, Dpto. de Didáctica de las Ciencias Experimentales, Universidad de Granada, Campus de Cartuja, 18071, Granada, Spain  相似文献   

Methodology of hydrogeological characterization of deep carbonate aquifers as potential reservoirs of groundwater. Case of study: the Jurassic aquifer of <Emphasis Type="Italic">El Maestrazgo</Emphasis> (Castellón,Spain)     

M. Mejías  J. Garcia-Orellana  J. L. Plata  M. Marina  E. Garcia-Solsona  B. Ballesteros  P. Masqué  J. López  C. Fernández-Arrojo 《Environmental Geology》2008,54(3):521-536

A methodology for the characterization of deep carbonate aquifers has been developed and applied to El Maestrazgo Jurassic aquifer in Castellón, Spain. Characterization of these aquifer formations, located at more than 300 m deep, consisted of a previous phase of compilation, analysis and synthesis of the existing information about the area, followed by a coordinated combination of different speciality studies: geology, stratigraphy, structural analysis, hydrogeology, hydrochemistry, geophysics and remote sensing. Geological studies included geological mapping, definition of stratigraphical units and facies and structural analysis. The aim of the hydrogeology study was to define aquifer formations, recharge area, aquifer points inventory and groundwater flow directions for the establishment of piezometric and water quality observation nets. Special techniques were applied, like thermal infrared aerial images and the evaluation of submarine groundwater discharge by means of natural radium isotopes. Hydrochemical techniques, including majority elements characterization and stable isotopes (¹⁸O, ²H and ³H) determination, allowed classifying hydrochemical facies and establishing a renewal pattern for water within the system. Geophysics was useful in determining the aquifer geometry, the features of the basement and the petrophysical characteristics of the geological formations. Preliminary results show an important tectonic complexity and the possibilities for groundwater uses in the area of study.  相似文献   

Flexural isostatic response of the Alps to increased Quaternary erosion recorded by foreland basin remnants,SE France     

Jean‐Daniel Champagnac  Peter Van Der Beek  Gaël Diraison  Samuel Dauphin 《地学学报》2008,20(3):213-220

We test the hypothesis that flexural isostatic compensation of the mass removed by enhanced Quaternary erosion is responsible for uplift of the Western European Alps and their forelands. We use two well‐preserved and well‐dated (1.8 Ma) abandonment surfaces of foreland basin remnants in SE France (the Chambaran and Valensole plateaux) as passive benchmarks for tilting of the foreland. Estimating their initial slope from morphometric scaling relationships, we determine bulk post‐depositional tilting of 0.5–0.8% for these surfaces. The calculated isostatic response of the Alpine lithosphere to erosional unloading, using the method recently proposed by Champagnac et al. [Geology 35 (2007) 195–198] , yields a predicted tilting of 0.3–0.4% in the considered areas, explaining approximately half of the determined post‐depositional tilting. Such long‐term deformation being insensitive to cyclic loading/unloading because of glaciations, we suspect the other half to be related to as yet undetermined long‐wavelength and long‐lived tectonic process(es).  相似文献   

On the types and dispersions of whistlers as observed in czechoslovakia     

František Jiříček 《Studia Geophysica et Geodaetica》1962,6(1):98-101

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Zur Frage der Subtropischen Antizyklogenesis     

Vojtěch Vítek 《Studia Geophysica et Geodaetica》1962,6(4):400-406

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Ermittlung der QNH-werte aus dem luftdruckfeld der synoptischen bodenkarte     

Antonín Papež 《Studia Geophysica et Geodaetica》1964,8(2):200-204

Резюме Дабление воздуха, переснитанное иа уровень моря по стандартной атмосфере в Q-коде обозчачается через QNH. Давление воздуха пересчитанное на уровень моря по высотной барометрической формуле обознаеается через QFF. Для целей авиационной службы погоды должны быть известны значения QNH, однако Зе барическое поле на синоптических картах выражается через QFF. С помощью рис. 1 для соответствующей температуры воздуха на станцин и ее высоты н. у. м. можно определить разность значений QFF—QNH при давленин QFF=1000мб. Далее по табл. 2 можно определить поправку для каждого значения QFF отличного от значения QFF при ином давлении, чем 1000мб путем умножения табулированного значения ва разность QFF—1000мб и его алгебраического сложения со значением, полученным по рис. 1.   相似文献   

Space triangulation in the western part of the High Tatras     

Ludvík Hradilek 《Studia Geophysica et Geodaetica》1963,7(4):330-335

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A simple theoretical interpretation of the cloud system in a dying cyclone from the aspect of the boucher-newcomb model     

Pavla Hlachová  Vojtěch Vítek 《Studia Geophysica et Geodaetica》1966,10(4):481-483

Резюме С помощью принятия простых кинематических предположений и на основании ω—уравнения выла определена конфигурация полос облаков в полностью окклюдированном циклоне без фронтов. Облачная система определяется полем скрытой теплоты, выделяемой в процессах конденсации. Полосы облаков теоретически представляют собой в основном листы синусоидальной спирали.

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Address: Boční II, Praha 4-Spořilov.  相似文献