Aqueous Cr(VI) reduction by pyrite: Speciation and characterisation of the solid phases by X-ray photoelectron, Raman and X-ray absorption spectroscopies     

Martine Mullet  Frédéric Demoisson  Laurent J. Michot 《Geochimica et cosmochimica acta》2007,71(13):3257-3271

Optical microscopy, confocal Raman micro-spectrometry, X-ray photoelectron micro-spectroscopy (XPS) and synchrotron based micro-X-ray fluorescence (XRF), micro-X-ray absorption near edge spectroscopy (XANES) and micro-extended X-ray absorption fine structure (EXAFS) were used to investigate the reduction of aqueous Cr(VI) by pyrite. Special emphasis was placed on the characterisation of the solid phase formed during the reaction process. Cr(III) and Fe(III) species were identified by XPS analyses in addition to non-oxidised pyrite. Optical microscopy images and the corresponding Raman spectra reveal a strong heterogeneity of the samples with three different types of zones. (i) Reflective areas with E_g and A_g Raman wavenumbers relative to non-oxidised pyrite are the most frequently observed. (ii) Orange areas that display a drift of the E_g and A_g pyrite vibration modes of −3 and −6 cm⁻¹, respectively. Such areas are only observed in the presence of Cr(VI) but are not specifically due to this oxidant. (iii) Bluish areas with vibration modes relative to a corundum-like structure that can be assigned to a solid solution Fe_2−xCr_xO₃, x varying between 0.2 and 1.5. The heterogeneity in the spatial distribution of chromium observed by optical microscopy and associated Raman microspectroscopy is confirmed by μ-XRF. In agreement with both solution and XPS analyses, these spectroscopies clearly confirm that chromium is in the trivalent state. XANES spectra in the iron K-edge pre-edge region obtained in rich chromium areas reveal the presence of ferric ion thus revealing a systematic association between Cr(III) and Fe(III). In agreement with Raman analyses, Cr K-edge EXAFS can be interpreted as corresponding to Cr atoms involved in a substituted-type hematite structure Fe_2−xCr_xO₃.  相似文献   

Methods for computing internal flattening, with applications to the Earth's structure and geodynamics     

C. Denis  M. Amalvict  Y. Rogister  & S. Tomecka-Sucho&#; 《Geophysical Journal International》1998,132(3):603-642

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Nutrient fluxes between water column and sediments: Potential influence of the pearl oyster culture   总被引：1，自引：0，他引：1  

Gaertner-Mazouni N  Lacoste E  Bodoy A  Peacock L  Rodier M  Langlade MJ  Orempuller J  Charpy L 《Marine pollution bulletin》2012,65(10-12):500-505

This study quantifies benthic nutrient fluxes and sedimentation rates in the Ahe Atoll lagoon (French Polynesia), in two stations located under pearl oyster frames, and two control stations away from the pearl culture facility. Dissolved inorganic nitrogen fluxes ranged between 2 and 35μmolNm(-2)h(-1) and Soluble Reactive Phosphorus varied between -3 and 8.2μmolPm(-2)h(-1). Particulate sedimentation rates beneath the oysters were approximately five times higher than in the control zone and the percentage of small particles (?63μm) were about the twice. In contrast, sediment composition was similar under and outside the direct influence of oyster frames. In this ecosystem, where primary production is dependent on the available nitrogen, our study revealed that, while highly variable, benthic fluxes could sometimes contribute up to 28% of the nitrogen demand for primary production.  相似文献   

Trace metal pollution and its influence on the community structure of soft bottom molluscs in intertidal areas of the Dar es Salaam coast, Tanzania   总被引：1，自引：0，他引：1  

Rumisha C  Elskens M  Leermakers M  Kochzius M 《Marine pollution bulletin》2012,64(3):521-531

The influence of trace metal pollution on the community structure of soft bottom molluscs was investigated in intertidal areas of the Dar es Salaam coast. Significant enrichment of As, Mn, Mo, Sb, and Zn in sediments was recorded. Redundancy analysis indicated that trace metal pollution contributed 68% of the variation in community structure. Monte Carlo permutation test showed that As and Sb contributed significantly to variation in species composition. T-value biplots and van Dobben circles showed that the gastropods Acteon fortis, Assiminea ovata, and Littoraria aberrans, were negatively affected by As and Sb, while the bivalve Semele radiata and the gastropod Conus litteratus were only negatively affected by As. Bioaccumulation of As, Cd, Cu, Mo and Zn occurred in the bivalve Mactra ovalina and the gastropod Polinices mammilla. This calls for regular monitoring and management measures.  相似文献   

Fluid–rock interactions related to metamorphic reducing fluid flow in meta-sediments: example of the Pic-de-Port-Vieux thrust (Pyrenees,Spain)     

Vincent?TrincalEmail author  Martine?Buatier  Delphine?Charpentier  Brice?Lacroix  Pierre?Lanari  Pierre?Labaume  Abdeltif?Lahfid  Torsten?Vennemann 《Contributions to Mineralogy and Petrology》2017,172(9):78

In orogens, shortening is mainly accommodated by thrusts, which constitute preferential zones for fluid–rock interactions. Fluid flow, mass transfer, and mineralogical reactions taking place along thrusts have been intensely investigated, especially in sedimentary basins for petroleum and uranium research. This study combines petrological investigations, mineralogical quantifications, and geochemical characterizations with a wide range of analytical tools with the aim of defining the fluid properties (nature, origin, temperature, and redox) and fluid–host rock interactions (mass transfers, recrystallization mechanisms, and newly formed synkinematic mineralization) in the Pic-de-Port-Vieux thrust fault zone (Pyrenees, Spain). We demonstrate that two geochemically contrasted rocks have been transformed by fluid flow under low-grade metamorphism conditions during thrusting. The hanging-wall Triassic red pelite was locally bleached, while the footwall Cretaceous dolomitic limestone was mylonitized. The results suggest that thrusting was accompanied by a dynamic calcite recrystallization in the dolomitic limestone as well as by leaching of iron via destabilization of iron oxides and phyllosilicate crystallization in the pelite. Geochemical and physical changes highlighted in this study have strong implications on the understanding of the thrust behavior (tectonic and hydraulic), and improve our knowledge of fluid–rock interactions in open fluid systems in the crust.  相似文献   

A search for Chandler and nearly diurnal free wobbles using Liouville equations   总被引：1，自引：0，他引：1  

Jacques Hinderer  Hilaire Legros  Martine Amalvict 《Geophysical Journal International》1982,71(2):303-332

Summary. The basic equations describing the dynamical effects of the Earth's fluid core (Liouville, Navier-Stokes and elasticity equations) are derived for an ellipsoidal earth model without axial symmetry but with an homogeneous and deformable fluid core and elastic mantle.
We develop the balance of moment of momentum up to the second order and use Love numbers to describe the inertia tensor's variations. The inertial torque takes into account the ellipticity and the volume change of the liquid core. On the core—mantle boundary we locate dissipative, magnetic and viscous torques. In this way we obtain quite a complete formulation for the Liouville equations.
These equations are restricted in order to obtain the usual Chandler and nearly diurnal eigenfrequencies.
Then we propose a method for calculating the perturbations of these eigenfrequencies when considering additional terms in the Liouville equations.  相似文献   

Seasonal effect on vertical positioning by Satellite Laser Ranging and Global Positioning System and on absolute gravity at the OCA geodetic station, Grasse, France     

J. Nicolas  J.-M. Nocquet  M. Van Camp  T. van Dam  J.-P. Boy  J. Hinderer  P. Gegout  E. Calais  M. Amalvict 《Geophysical Journal International》2006,167(3):1127-1137

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Emerging transitions in organic waste infrastructure in Aotearoa New Zealand     

Gradon Diprose  Kelly Dombroski  Emma Sharp  Amanda Yates  Bailey Peryman  Martine Barnes 《New Zealand geographer》2023,79(1):15-26

Aotearoa New Zealand is at a critical juncture in reducing and managing organic waste. Research has highlighted the significant proportion of organic waste sent to landfills and associated adverse effects such as greenhouse gas emissions and loss of valuable organic matter. There is current debate about what practices and infrastructure to invest in to better manage and use organic waste. We highlight the diversity of existing organic waste practices and infrastructures, focusing on Auckland, Wellington and Christchurch. We show how debates about organic waste practices and infrastructure connect across three themes: waste subjectivities, collective action in place and language.  相似文献   

Springtime changes in snow chemistry lead to new insights into mercury methylation in the Arctic     

Catherine Larose  Aurélien Dommergue  Martine De Angelis  Bernard Averty  Nicolas Soumis  Christophe Ferrari 《Geochimica et cosmochimica acta》2010,74(22):6263-6275

Seasonal snow is an active media and an important climate factor that governs nutrient transfer in Arctic ecosystems. Since the snow stores and transforms nutrients and contaminants, it is of crucial importance to gain a better understanding of the dynamics of contaminant cycling within the snowpack and its subsequent release to catchments via meltwater. Over the course of a two-month field study in the spring of 2008, we collected snow and meltwater samples from a seasonal snowpack in Ny-Ålesund, Norway (78°56′N, 11°52′E), which were analyzed for major inorganic ions and some organic acids, as well as total, dissolved, bioavailable mercury (THg, DHg, BioHg, respectively) and monomethylmercury (MMHg) species. We observe a seasonal gradient for ion concentrations, with surface samples becoming less concentrated as the season progressed. A significant negative correlation between BioHg and MMHg was observed in the snowpack. MMHg was positively and significantly correlated to methanesulfonate concentrations. Based on these results, we propose a new model for aerobic methylation of mercury involving species in the dimethylsulfoniopropionate cycle.  相似文献   

Long-term Field Observations on Seasonality in Chlorophyll-<Emphasis Type="Italic">a</Emphasis> Concentrations in a Shallow Coastal Marine Ecosystem,the Wadden Sea     

Catharina Johanna Maria Philippart  Jolanda Martine van Iperen  Gerhard Cornelis Cadée  Alain François Zuur 《Estuaries and Coasts》2010,33(2):286-294

Analyses of long-term field observations (1974–2007) on chlorophyll-a concentrations in the western Wadden Sea showed no long-term trends in the timing of the wax and wane of phytoplankton spring blooms. There is weak evidence, however, that the height of the autumn bloom has decreased since the early 1990s. This fading of the autumn bloom may have had consequences for the carbon transfer to higher trophic levels, currently hampering primary consumer species that mostly rely on food supply during late summer. Current and other findings suggest a shortening of the growing season due to the fading of the autumn bloom in the Wadden Sea and a lengthening of the growing season due to an advancement of the spring bloom in the North Sea. These regionally different changes in seasonality may have contributed to the coinciding decrease in bivalve filtering capacity in the western Wadden Sea and the large-scale offshore shift of juvenile plaice from the Wadden Sea to the adjacent North Sea.  相似文献