New data on the kinetics of the dissolution of alkali feldspars at 200°C in CO₂ charged water     

Martine Lagache 《Geochimica et cosmochimica acta》1976,40(2):157-161

The kinetics of the dissolution of a (Na. K) sanidine in CO₂-charged water, were studied experimentally at 200°C as a function of the surface area s and of the time t. The molalities of Na⁺ and K⁺ have been plotted against the product st. As for albite and adularia (Lagache, Bull. Soc. Fr. Minéral. Cristallogr. 88, 223–253, 1965), the rates of dissolution of Na² and K⁺ are smooth continuous functions of st, which implies that they are controlled by the composition of the solution.The comparison between the dissolution of pure sodic or potassic feldspars and that of an intermediate feldspar shows that the sanidine dissolves as if it were composed of albite and K-feldspar grains in the proportions corresponding to its composition.Theoretical considerations presented by Helgeson (Geochim. Cosmochim. Acta35, 421–169, 1971; The Feldspars, pp. 184–217, 1972) and Pa?es (Geochim. Cosmochim. Acta37, 2641–2663, 1973) are reviewed: both had suggested, arguing from my first experimental results, that the dissolution could be described by a process of diffusional mass transfer through a surface layer of reaction products.The present experiments do not agree with such an interpretation of the mechanism of dissolution.  相似文献   

Distribution des éléments Na,K, Rb et Cs à l'état de trace entre feldspaths alcalins et solutions hydrothermales à 650° C, 1 kbar: données expérimentales et interpretation thermodynamique     

Martine Lagache  Germain Sabatier 《Geochimica et cosmochimica acta》1973,37(12):2617-2640

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Mechanisms of Mg-phyllosilicate formation in a hydrothermal system at a sedimented ridge (Middle Valley,Juan de Fuca)     

M. D. Buatier  Gretchen L. Früh-Green  A. M. Karpoff 《Contributions to Mineralogy and Petrology》1995,122(1-2):134-151

We present results of a detailed mineralogical and geochemical study of the progressive hydrothermal alteration of clastic sediments recovered at ODP Site 858 in an area of active hydrothermal venting at the sedimented, axial rift valley of Middle Valley (northern Juan de Fuca Ridge). These results allow a characterization of newly formed phyllosilicates and provide constraints on the mechanisms of clay formation and controls of mineral reactions on the chemical and isotopic composition of hydrothermal fluids. Hydrothermal alteration at Site 858 is characterized by a progressive change in phyllosilicate assemblages with depth. In the immediate vent area, at Hole 858B, detrital layers are intercalated with pure hydrothermal precipitates at the top of the section, with a predominance of hydrothermal phases at depth. Sequentially downhole in Hole 858B, the clay fraction of the pure hydrothermal layers changes from smectite to corrensite to swelling chlorite and finally to chlorite. In three pure hydrothermal layers in the deepest part of Hole 858B, the clay minerals coexist with neoformed quartz. Neoformed and detrital components are clearly distinguished on the basis of morphology, as seen by SEM and TEM, and by their chemical and stable isotope compositions. Corrensite is characterized by a 24?Å stacking sequence and high Si- and Mg-contents, with Fe/(Fe+Mg) ratio of ≈0.08. We propose that corrensite is a unique, possibly metastable, mineralogical phase and was precipitated directly from seawater-dominated hydrothermal fluids. Hydrothermal chlorite in Hole 858B has a stacking sequence of 14?Å with Fe/(Fe+Mg) ratios of ≈0.35. The chemistry and structure of swelling chlorite suggest that it is a corrensite/chlorite mixed-layer phase. The mineralogical zonation in Hole 858B is accompanied by a systematic decrease in δ¹⁸O, reflecting both the high thermal gradients that prevail at Site 858 and extensive sediment-fluid interaction. Precipitation of the Mg-phyllosilicates in the vent region directly controls the chemical and isotopic compositions of the pore fluids. This is particularly evident by decreases in Mg and enrichments in deuterium and salinity in the pore fluids at depths at which corrensite and chlorite are formed. Structural formulae calculated from TEM-EDX analyses were used to construct clay-H₂O oxygen isotope fractionation curves based on oxygen bond models. Our results suggest isotopic disequilibrium conditions for corrensite-quartz and swelling chlorite-quartz precipitation, but yield an equilibrium temperature of 300°?C±30° for chlorite-quartz at 32?m below the surface. This estimate is consistent with independent estimates and indicates steep thermal gradients of 10–11°/m in the vent region.  相似文献   

Unprecedented risk of spring frost damage in Switzerland and Germany in 2017     

Yann Vitasse  Martine Rebetez 《Climatic change》2018,149(2):233-246

Spring frosts are feared by farmers, fruit growers, and wine growers as they can cause significant damage to crops when they occur during the development of the plants. In the second half of April 2017, following a very warm period that had caused premature vegetation growth, a cold air mass from the Arctic penetrated central and western Europe, causing severe damage to natural and cultivated vegetation over broad areas. Here, we analyze how exceptional this event was in Switzerland and Germany in relation to the accumulated growing degree days (GDD), used as a proxy for plant phenology advancement. Although this damaging frost was not the latest on record in terms of calendar days, our results show that it was, in some regions, unprecedented in relation to the accumulated warmth during the preceding period, at least since the beginning of instrumental temperature records (1864). Our results also highlight how global warming has considerably increased the number of days with mean temperature above 5 °C in late winter and early spring, especially since 1970 (+?16.8?±?4.7 °C days decade^?1). However, in spite of earlier spring phenology due to climate warming, our results suggest that the risk of damaging frost events to vegetation has remained unchanged over the last 150 years in lowlands of Switzerland and Germany, due to the concurring earlier occurrence of the last potentially damaging frosts (about ??20 days since 1864). Our analyses reveal therefore that the April 2017 damaging frost was a true outlier in terms of risk of frost damage to plants.  相似文献   

Shorter snow cover duration since 1970 in the Swiss Alps due to earlier snowmelt more than to later snow onset   总被引：1，自引：0，他引：1  

Geoffrey Klein  Yann Vitasse  Christian Rixen  Christoph Marty  Martine Rebetez 《Climatic change》2016,139(3-4):637-649

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The Western Boundary of the Equatorial Pacific Upwelling: Some Consequences of Climatic Variability on Hydrological and Planktonic Properties     

Martine Rodier  Gérard Eldin  Robert Le Borgne 《Journal of Oceanography》2000,56(4):463-471

The longitude of the western limit of the equatorial Pacific upwelling is a key parameter for studies of carbon budget and pelagic fisheries variability. Although it is well defined at the surface on the equator by a salinity front and a sharp variation of the partial pressure of CO₂, data from two equatorial cruises make it clear that this hydrological limit does not necessarily coincide with the boundary of the nitrate and chlorophyll enriched area. In January-February 1991 during a non-El Niño period, when trade winds and the South Equatorial current (SEC) were favorable to upwelling, the two limits were at the same longitude. Conversely, in September-October 1994 during El Niño conditions, when the equatorial upwelling had stopped, the nitrate and chlorophyll enriched zone was found a few degrees of longitude east of the hydrological boundary (5.5° at the surface and 2.5° for the 50 m upper layer), whereas no such offset was observed for zooplankton biomass. A simple model, based on the HNLC (High Nutrient - Low Chlorophyll) ecosystem functioning, was initialized with nitrate uptake measurements and estimates of upwelling break duration. The model results support the hypothesis that zonal separation of the limits arises from biological processes (i.e. nitrate uptake and phytoplankton grazing) achieved during that upwelling break.  相似文献   

Export flux of particles at the equator in the western and central Pacific ocean     

Martine Rodier  Robert Le Borgne 《Deep Sea Research Part II: Topical Studies in Oceanography》1997,44(9-10)

Export of particles was studied at the equator during an El Nin˜o warm event (October 1994) as part of the French ORSTOM/FLUPAC program. Particulate mass, carbon (organic and inorganic) (C), nitrogen (N), and phosphorus (P) export fluxes were measured at the equator in the western and central Pacific during two 6–7 day-long time-series stations located in the warm pool (TS-I at 0°, 167°E) and in the equatorial HNLC situation (TS-II at 0°, 150°W), using drifting sediment traps deployed for 48 h at four depths (between, approximately, 100 and 300 m).The particulate organic carbon (POC) fluxes at the base of the euphotic zone (0.1 % light level), were approximately four times lower at TS-I than at TS-11 (4.1 vs. 17.0 mmol C m^-2 day^-1). Conversely, fluxes measured at 300 m were similar at both sites (3.6vs. 3.7 mmol C m⁻² day⁻¹ at TS-I and TS-11, respectively). This change in export fluxes was in good agreement with food-web dynamics in the euphotic zone characterized by an increase in plankton biomasses and metabolic rates and a shift towards larger size from TS-1 to TS-II. The POC flux profiles indicated high remineralization (up to 78%) of the exported particles at TS-II, between 100 and 200 m in the Equatorial Undercurrent. According to zooplankton ingestion estimates from 100 – 300 m, 60% of this POC loss could be accounted for by zooplankton grazing. At TS-I, no marked increase of flux with depth was observed, and we assume that loss of particles was compensated by in-situ particle production by zooplankton. Fluxes of particulate nitrogen and phosphorus followed the same general patterns as the POC fluxes. The elemental and pigment composition of the exported particles was not very different between the two stations. In particular, the POCYN flux molar ratio at the base of the euphotic zone was low, 6.9 and 6.2 at TS-1 and TS-II, respectively.For particulate inorganic carbon (mainly carbonate) flux, values at the base of the euphotic zone averaged 0.9 mmol C m-2 day-1 at TS-I and 2.3 mmol C m-2 day-1 at TS-11 (corresponding to a 2.6-fold increase) and showed low depth changes at both stations.POC export flux (including active flux associated with the interzonal migrants) at the 0.1 % light level depth represented only 8% of primary production (1°C uptake) measured at TS-1 and 19% at TS-II. For the time and space scales considered in the present study, new primary production, as measured by the 15N method, was in good agreement with the total export flux in the HNLC situation, thus leading to negligible dissolved organic carbon (DOC) or nitrogen (DON) losses from the photic zone. Conversely, export flux was found to be only 50% (C units) and 60% (N) of new production in the oligotrophic system, either because of an overestimation by the 15N method or of a significant export of DOC and DON.Comparison with other oceanic regions shows that export flux in the warm pool was within the same range as in the central gyres. On the other hand, comparison with EgPac data in the central Pacific suggests that there is no straightforward relation between the magnitude of the export and surface nitrate concentrations.  相似文献   

Impact of gamma densitometry on the luminescence signal of quartz grains     

Martine J. J. Couapel  Christopher J. Bowles 《Geo-Marine Letters》2006,26(1):1-5

Most of the marine sediment cores collected in the past 10 years by the ODP and IMAGES programs have been processed using a multi-sensor core logger (MSCL, Geotek). This system estimates the density of sediment using the γ-ray attenuation of a ¹³⁷Cs source. To date, optically stimulated luminescence (OSL) dating has not been applied to sediments from cores treated in this way, because of the possible impact of this exposure on the existing luminescence signal. We have investigated the effect of such γ-ray irradiation by test exposure, measurement and estimation, and conclude that the usual ¹³⁷Cs exposure from γ-ray attenuation densitometry has no impact on the luminescence signal of quartz grains in sediment cores. For longer exposure to the ¹³⁷Cs source, a formula is provided to calculate the received dose. This result will permit the OSL dating technique to be applied to the voluminous body of marine cores already collected and processed by MSCL.  相似文献   

Biogenic hydroxysulfate green rust, a potential electron acceptor for SRB activity     

Asfaw Zegeye  Cédric Carteret  Martine Mullet  Frédéric Jorand 《Geochimica et cosmochimica acta》2007,71(22):5450-5462

Microbiological reduction of a biogenic sulfated green rust , was examined using a sulfate reducing bacterium (Desulfovibrio alaskensis). Experiments investigated whether could serve as a sulfate source for D. alaskensis anaerobic respiration by analyzing mineral transformation. Batch experiments were conducted using lactate as the electron donor and biogenic as the electron acceptor, at circumneutral pH in unbuffered medium. transformation was monitored with time by X-ray diffraction (XRD), Transmission Mössbauer Spectroscopy (TMS), Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS), Transmission Electron Microscopy (TEM) and X-ray Photoelectron Spectroscopy (XPS). The reduction of sulfate anions and the formation of iron sulfur mineral were clearly identified by XPS analyses. TMS showed the formation of additional mineral as green rust (GR) and vivianite. XRD analyses discriminated the type of the newly formed GR as GR1. The formed GR1 was as indicated by DRIFTS analysis. Thus, the results presented in this study indicate that D. alaskensis cells were able to use as an electron acceptor. , vivianite and an iron sulfur compound were formed as a result of reduction by D. alaskensis. Hence, in environments where geochemical conditions promote biogenic formation, this mineral could stimulate the anaerobic respiration of sulfate reducing bacteria.  相似文献   

Links between bacterial communities in marine sediments and trace metal geochemistry as measured by in situ DET/DGT approaches   总被引：1，自引：0，他引：1  

Gillan DC  Baeyens W  Bechara R  Billon G  Denis K  Grosjean P  Leermakers M  Lesven L  Pede A  Sabbe K  Gao Y 《Marine pollution bulletin》2012,64(2):353-362

Our current view about the relationship between metals and bacteria in marine sediments might be biased because most studies only use ex situ approaches to quantify metals. The aim of the present research was to compare ex situ and in situ methods of metal measurement (DET and DGT--diffusive equilibration or diffusive gradients in thin-films) and relate the results with two commonly used microbiological variables (bacterial biomass and bacterial diversity as revealed by DGGE). No previous studies have used such in situ approaches in microbial ecology. For biomass and most of the investigated trace metals (Ag, Cd, Sn, Cr, Ni, Cu, Pb, and Al) no significant correlations were found. The exceptions were Fe, Mn, Co, and As which behave like micronutrients. For bacterial diversity, no relevant relationships were found. We conclude that in situ methods are more adapted tools for microbial ecologists but that ex situ approaches are still necessary.  相似文献