Origin of ~2.5 Ga potassic granite from the Nellore Schist Belt,SE India: textural,cathodoluminescence, and SHRIMP U–Pb data     

K. Vijaya Kumar  W. G. Ernst  C. Leelanandam  J. L. Wooden  M. J. Grove 《Contributions to Mineralogy and Petrology》2011,162(4):867-888

In a geochemical and geochronological investigation of Archean and Proterozoic magmatism in the Nellore Schist Belt, we conducted SHRIMP U–Pb analyses of zircons from two cospatial granitic bodies at Guramkonda and Vendodu. The former is a Ba- and Sr-rich hornblende-bearing tonalite, whereas the latter is a Rb-, Zr-, Pb-, Th-, U-, and REE-rich biotite-bearing leucogranite. The Guramkonda tonalite displays a restitic texture with remnants of trapped granitic melt, whereas the Vendodu leucogranite contains residual/partially melted plagioclase grains. Both rock types contain two generations of zircon: tonalite contains a group of euhedral zoned zircons enclosed within plagioclase and a group of subhedral patchy zircons associated with trapped melt (quartz + feldspar matrix), and leucogranite also contains a group of doubly terminated euhedral zircons included within orthoclase as well as a group of zircons with visible cores mantled by later rim growth. Cathodoluminescence images also clearly document two distinctly textured varieties of zircon: the tonalite contains a population characterized by narrowly spaced uninterrupted oscillatory zoning and a second population lacking zoning but exhibiting a random distribution of dark (U-rich) and light (U-poor) regions; the leucogranite contains U-rich zoned zircons and U-poor zircon cores mantled by U-rich rims. The REE chemistry of zircon cores from the Vendodu leucogranite is very similar to the REE of zoned zircons from the Guramkonda tonalite. Zircon ages from both plutons exhibit bimodal distributions in U–Pb concordia diagrams. The tonalite defines an age of 2,521 Ma ± 5 Ma for zoned magmatic zircons and 2,485 Ma ± 5 Ma for unzoned newly precipitated zircons, whereas the leucogranite has an age of 2,518 Ma ± 5 Ma for U-poor zircon cores (relics of the tonalite pluton) and 2,483 Ma ± 3 Ma for U-rich zoned magmatic zircons. The trace element geochemistry of the ~2,520 Ma zircons is distinctly different from the ~2,485 Ma zircons, irrespective of the host rock. Our textural, CL image, and SHRIMP U–Pb analyses document the origin of the leucogranite by partial melting of the tonalite. High alkalis (Na₂O + K₂O), Rb, Nb, HREE, FeO^t/MgO and low Ca, Al, Ba, Sr, and large negative Eu anomalies characterize the leucogranite as a thermal minimum melt, whereas the very low K and Rb of the tonalite attests to its residual nature. We suggest that the leucogranite formed by high-T (900–950°C), moderate-pressure (<10 kbar) dehydration partial melting of the tonalite under reducing conditions. The calculated source compositions of the leucogranite melt and the tonalite residue show strong similarities to melts that are considered to have been produced in a subduction-zone environment. The leucogranite probably formed in a post-collisional realm immediately after accretion of the tonalitic crust.  相似文献   

Evidence for Late Riphean granite formation in the Polar Urals     

A. A. Soboleva  A. F. Karchevskii  L. I. Efanova  N. B. Kuznetsov  M. Grove  I. D. Sobolev  M. V. Maurin 《Doklady Earth Sciences》2012,442(2):181-187

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Experiments on liquid immiscibility along tholeiitic liquid lines of descent   总被引：4，自引：2，他引：2  

Bernard Charlier  Timothy L. Grove 《Contributions to Mineralogy and Petrology》2012,164(1):27-44

Crystallization experiments have been conducted on compositions along tholeiitic liquid lines of descent to define the compositional space for the development of silicate liquid immiscibility. Starting materials have 46–56 wt% SiO₂, 11.7–17.7 wt% FeO_tot, and Mg-number between 0.29 and 0.36. These melts fall on the basaltic trends relevant for Mull, Iceland, Snake River Plain lavas and for the Sept Iles layered intrusion, where large-scale liquid immiscibility has been recognized. At one atmosphere under anhydrous conditions, immiscibility develops below 1,000–1,020°C in all of these compositionally diverse lavas. Extreme iron enrichment is not necessary; immiscibility also develops during iron depletion and silica enrichment. Variations in melt composition control the development of silicate liquid immiscibility along the tholeiitic trend. Elevation of Na₂O + K₂O + P₂O₅ + TiO₂ promotes the development of two immiscible liquids. Increasing melt CaO and Al₂O₃ stabilizes a single-liquid field. New data and published phase equilibria show that anhydrous, low-pressure fractional crystallization is the most favorable condition for unmixing during differentiation. Pressure inhibits immiscibility because it expands the stability field of high-Ca clinopyroxene, which reduces the proportion of plagioclase in the crystallizing assemblage, thus enhancing early iron depletion. Magma mixing between primitive basalt and Fe–Ti–P-rich ferrobasalts can serve to elevate phosphorous and alkali contents and thereby promote unmixing. Water might decrease the temperature and size of the two-liquid field, potentially shifting the binodal (solvus) below the liquidus, leading the system to evolve as a single-melt phase.  相似文献   

Amphibole stability in primitive arc magmas: effects of temperature,H<Subscript>2</Subscript>O content,and oxygen fugacity     

Michael J. Krawczynski  Timothy L. Grove  Harald Behrens 《Contributions to Mineralogy and Petrology》2012,164(2):317-339

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Early petrologic processes on the ureilite parent body     

S. J. Singletary  T. L. Grove 《Meteoritics & planetary science》2003,38(1):95-108

Abstract— We present a petrographic and petrologic analysis of 21 olivine‐pigeonite ureilites, along with new experimental results on melt compositions predicted to be in equilibrium with ureilite compositions. We conclude that these ureilites are the residues of a partial melting/smelting event. Textural evidence preserved in olivine and pigeonite record the extent of primary smelting. In pigeonite cores, we observe fine trains of iron metal inclusions that formed by the reduction of olivine to pigeonite and metal during primary smelting. Olivine cores lack metal inclusions but the outer grain boundaries are variably reduced by a late‐stage reduction event. The modal proportion of pigeonite and percentage of olivine affected by late stage reduction are inversely related and provide an estimation of the degree of primary smelting during ureilite petrogenesis. In our sample suite, this correlation holds for 16 of the 21 samples examined. Olivine‐pigeonite‐liquid phase equilibrium constraints are used to obtain temperature estimates for the ureilite samples examined. Inferred smelting temperatures range from ～1150°C to just over 1300°C and span the range of estimates published for ureilites containing two or more pyroxenes. Temperature is also positively correlated with modal percent pigeonite. Smelting temperature is inversely correlated with smelting depth—the hottest olivine‐pigeonite ureilites coming from the shallowest depth in the ureilite parent body. The highest temperature samples also have oxygen isotopic signatures that fall toward the refractory inclusion‐rich end of the carbonaceous chondrite‐anhydrous mineral (CCAM) slope 1 mixing line. These temperature‐depth variations in the ureilite parent body could have been created by a heterogeneous distribution of heat producing elements, which would indicate that isotopic heterogeneities existed in the material from which the ureilite parent body was assembled.  相似文献   

4. Building of a Habitable Planet     

Hervé Martin  Francis Albarède  Philippe Claeys  Muriel Gargaud  Bernard Marty  Alessandro Morbidelli  Daniele L. Pinti 《Earth, Moon, and Planets》2006,98(1-4):97-151

Except the old Jack Hills zircon crystals, it does not exit direct record of the first 500 Ma of the Earth history. Consequently, the succession of events that took place during this period is only indirectly known through geochemistry, comparison with other telluric planets, and numerical modelling. Just after planetary accretion several episodes were necessary in order to make life apparition and development possible and to make the Earth surface habitable. Among these stages are: the core differentiation, the formation of a magma ocean, the apparition of the first atmosphere, oceans and continents as well as the development of magnetic field and of plate tectonics. In the same time, Earth has been subject to extraterrestrial events such as the Late Heavy Bombardment (LHB) between 3.95 and 3.8 Ga. Since 4.4–4.3 Ga, the conditions for pre-biotic chemistry and appearance of life were already met (liquid water, continental crust, no strong meteoritic bombardment, etc...). This does not mean that life existed as early, but this demonstrates that all necessary conditions assumed for life development were already present on Earth.  相似文献   

Trace elements in native gold by solution ICP-MS and their use in mineral exploration: A British Columbia example     

Marty McInnes  John D. Greenough  Brian J. Fryer  Ron Wells 《Applied Geochemistry》2008

An elegantly simple, aqua regia-based, ICP-MS analytical procedure is used to compare the trace element composition of density-separated alluvial native Au from seven stream silt samples with three samples of geographically-associated Au from a prospective ore deposit in central British Columbia. Not all of the alluvial Au could have come from the ore deposit based on present drainage. The silt sample Au, averaging four alluvial grains and totaling 12–250 μg per sample, generally yielded measurable concentrations for V, Fe, Cu, As, Pd, Ag, Sb, Pt and Bi. The bedrock Au samples represent the three dominant rock types in the showing. Their Au trace element compositions largely bracket the alluvial Au. Multidimensional scaling (exploratory statistics) shows that trace elements in the native Au form lithophile, chalcophile and siderophile groupings. This indicates that a small set of geochemical processes formed all the Au in one geologic environment. Previous work shows that Au from individual deposits has distinct assemblages of detectable elements. Given these observations and that detectable elements are the same in both the deposit and alluvial Au, and that concentrations in the former bracket those of the latter, it is concluded that the source of the alluvial Au has probably been identified. Apparently neither mineral inclusions nor weathering impaired fingerprinting of the Au. The simplicity of the approach indicates that this is a useful exploration tool for determining the bedrock source of alluvial Au. The study also shows that silt sample exploration in glaciated terrains must recognize that paleo-ice movement and paleo-stream directions can yield geographic distributions of alluvial Au that cannot be explained by present-day drainage patterns. Thus this simple analytical/exploration technique is potentially very useful to the exploration industry.  相似文献   

The effect of H<Subscript>2</Subscript>O on the olivine liquidus of basaltic melts: experiments and thermodynamic models   总被引：2，自引：2，他引：0  

Etienne Médard  Timothy L. Grove 《Contributions to Mineralogy and Petrology》2008,155(4):417-432

We designed and carried out experiments to investigate the effect of H₂O on the liquidus temperature of olivine-saturated primitive melts. The effect of H₂O was isolated from other influences by experimentally determining the liquidus temperatures of the same melt composition with various amounts of H₂O added. Experimental data indicate that the effect of H₂O does not depend on pressure or melt composition in the basaltic compositional range. The influence of H₂O on melting point lowering can be described as a polynomial function This expression can be used to account for the effect of H₂O on olivine-melt thermometers, and can be incorporated into fractionation models for primitive basalts. The non-linear effect of H₂O indicates that incorporation of H₂O in silicate melts is non-ideal, and involves interaction between H₂O and other melt components. The simple speciation approach that seems to account for the influence of H₂O in simple systems (albite-H₂O, diopside-H₂O) fails to describe the mixing behavior of H₂O in multi-component silicate melts. However, a non-ideal solution model that treats the effect of H₂O addition as a positive excess free energy can be fitted to describe the effect of melting point lowering.  相似文献   

U-Pb zircon geochronology of late Neoproterozoic–Early Cambrian granitoids in Iran: Implications for paleogeography, magmatism, and exhumation history of Iranian basement     

Jamshid Hassanzadeh  Daniel F. Stockli  Brian K. Horton  Gary J. Axen  Lisa D. Stockli  Marty Grove  Axel K. Schmitt  J. Douglas Walker 《Tectonophysics》2008,451(1-4):71-96

Eurasia has largely grown to its present enormous size through episodic addition of crustal blocks by recurring birth and demise of oceans such as Paleotethys and Neotethys. Excluding the Kopet Dagh Mountains in the northeast, crystalline basement rocks of various dimensions are exposed in all continental tectonic zones of Iran. These rocks have traditionally been viewed as continental fragments with Gondwanan affinity and summarily been assigned Precambrian or younger ages, despite the fact that evidence from isotopic dating has largely been lacking. This study presents new ion microprobe and thermal-ionization zircon U-Pb geochronological data from granitoids and orthogneisses from several locations in central Iran and the Sanandaj–Sirjan structural zones to determine crystallization ages and investigate the origin and continental affinity of these various crustal fragments. The resulting U-Pb crystallization ages for the granites and orthogneisses range from late Neoproterozoic to Early Cambrian, matching the mostly juvenile Arabian–Nubian shield and Peri-Gondwanan terranes constructed after the main phase of Pan-African orogenesis. TIMS analyses of zircons with inherited cores from western Iran suggest that the Neoproterozoic crust of Iran might not be entirely juvenile, pointing to the potential presence of inherited older Proterozoic components as is common in the eastern Arabian shield. More importantly, the new zircon U-Pb crystallization ages unequivocally demonstrate that crystalline basement underlying the Sanandaj–Sirjan zone, central Iran, and the Alborz Mountains is composed of continental fragments with Gondwanan affiliation, characterized by wide spread late Neoproterozoic subduction-related magmatism. The exposure of these late Neoproterozoic–Early Cambrian basement rocks in the Iranian regions north of the Zagros is structurally controlled and linked to both large-scale crustal extension and exhumation during Mesozoic and Tertiary time as well as Tertiary collisional tectonics associated with the closure of Neotethys.  相似文献   

Modified passive capillary samplers for collecting samples of snowmelt infiltration for stable isotope analysis in remote,seasonally inaccessible watersheds 1: laboratory evaluation     

Marty D. Frisbee  Fred M. Phillips  Andrew R. Campbell  Jan M. H. Hendrickx 《水文研究》2010,24(7):825-833

Snowmelt is the most significant source of runoff generation and recharge in many of the mountainous watersheds worldwide and this is especially true in the southwestern United States. Yet, the isotopic and geochemical composition of the soil–meltwater endmember remains poorly constrained. Using the isotopic compositions of snow and snowmelt runoff samples taken from the landscape surface as proxies for soil–meltwater endmembers is problematic since they are typically not representative of the actual composition of soil meltwater. Furthermore, the applicability of current methodologies to collect the isotopic composition of meltwater is limited because of the remote and often seasonally inaccessible nature of the terrain where snowpacks develop. Therefore, a robust methodology requiring little maintenance or monitoring is desirable. A lab experiment was conducted to determine the suitability of using a modified passive capillary sampler (M‐PCAPS) design to collect snowmelt infiltration for isotopic analysis. Passive capillary samplers are constructed from fiberglass wicks that can be installed in the soil to sample vadose‐zone waters under a wide range of matric potentials and require little maintenance. Results from this lab experiment indicate that the wicking process associated with M‐PCAPS does not fractionate water but certain precautions are necessary to prevent exchange between the wick and the atmosphere. In this experiment, M‐PCAPS effectively tracked the changing isotopic composition of a soil reservoir undergoing evaporation. Therefore, M‐PCAPS provide a robust methodology to sample the isotopic composition of snowmelt infiltration in remote watersheds and similar applications. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献