Holocene Refreshening and Reoxygenation of a Bothnian Sea Estuary Led to Enhanced Phosphorus Burial     

Nikki Dijkstra  Nadine B. Quintana Krupinski  Masako Yamane  Stephen P. Obrochta  Yosuke Miyairi  Yusuke Yokoyama  Caroline P. Slomp 《Estuaries and Coasts》2018,41(1):139-157

Salinity variations in restricted basins like the Baltic Sea can alter their vulnerability to hypoxia (i.e., bottom water oxygen concentrations <2 mg/l) and can affect the burial of phosphorus (P), a key nutrient for marine organisms. We combine porewater and solid-phase geochemistry, micro-analysis of sieved sediments (including XRD and synchrotron-based XAS), and foraminiferal δ¹⁸O and δ¹³C analyses to reconstruct the bottom water salinity, redox conditions, and P burial in the Ångermanälven estuary, Bothnian Sea. Our sediment records were retrieved during the Integrated Ocean Drilling Program (IODP) Baltic Sea Paleoenvironment Expedition 347 in 2013. We demonstrate that bottom waters in the Ångermanälven estuary became anoxic upon the intrusion of seawater in the early Holocene, like in the central Bothnian Sea. The subsequent refreshening and reoxygenation, which was caused by gradual isostatic uplift, promoted P burial in the sediment in the form of Mn-rich vivianite. Vivianite authigenesis in the surface sediments of the more isolated part of the estuary ultimately ceased, likely due to continued refreshening and an associated decline in productivity and P supply to the sediment. The observed shifts in environmental conditions also created conditions for post-depositional formation of authigenic vivianite, and possibly apatite formation, at ～8 m composite depth. These salinity-related changes in redox conditions and P burial are highly relevant in light of current climate change. The results specifically highlight that increased freshwater input linked to global warming may enhance coastal P retention, thereby contributing to oligotrophication in both coastal and adjacent open waters.  相似文献   

MINERALOGY,PETROGRAPHY AND CHEMISTRY OF THE CHONDRITE,KAMIOMI, SASHIMA-GUN,IBARAKI-KEN,JAPAN     

Akihiko Okada  Masako Shima  Sadao Murayama 《Meteoritics & planetary science》1979,14(2):177-191

The Kamiomi, Sashima-gun (Iwai-shi), Ibaraki-ken, Japan, chondrite (observed to fall in spring, during the period 1913–6), consists of olivine, orthopyroxene, nickel-iron and troilite with minor amount of plagioclase, clinopyroxene, apatite and chromite. The average molar composition of olivine (Fa₁₉) and orthopyroxene (Fs₁₇) indicates that Kamiomi is a typical olivine bronzite chondrite. From the well-recrystallized texture, the presence of poorly-definable chondrules, homogeneous composition of olivine and absence of glass, this chondrite could be classified in petrologic type 5. The bulk chemical composition, especially, total Fe (27.33%) and metallic Fe (17.00%) as well as Fe_total/SiO₂(0.72), Fe_metal/Fe_total (0–633) and SiO₂/MgO (1.59) support the above conclusion. Coexistence of heavily-shocked olivine grains in the matrix composed of olivines and pyroxenes which suffered from light to moderate shock effect suggest that impacting phenomena, small-scaled but locally strong, occurred on the Kamiomi parent body.  相似文献   

BRAZILIAN METEORITES: THE MAFRA,SANTA CATARINA STATE,CHONDRITE     

G. R. Levi-Donati  Masako Shima  G. P. Sighinolfi 《Meteoritics & planetary science》1976,11(1):29-42

A chemical analysis and a mineralogical inspection have been performed on about 50 g of the Mafra, Santa Catarina State, Brazil, meteorite. The stone is an H-4 chondrite. It shows some ambiguous characteristics concerning the iron distribution, which are discussed.  相似文献   

Palaeomagnetism and K-Ar Ages of Neogene Rocks of Northern Taiwan: Tectonics of the Arc Junction of Ryukyu and Luzon Arcs     

Masako Miki  Masahide Furukawa  Yo-Ichiro Otofuji  Shuhjong Tsao  Tunyow Huang 《Geophysical Journal International》1993,114(2):225-235

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Two modes of climatic control in the Holocene stalagmite record from the Japan Sea side of the Japanese islands          下载免费PDF全文

Tomomi Sone  Akihiro Kano  Kenji Kashiwagi  Taiki Mori  Tomoyo Okumura  Chuan‐Chou Shen  Masako Hori 《Island Arc》2015,24(3):342-358

The Holocene stalagmite FG01 collected at the Fukugaguchi Cave in Itoigawa, central Japan provides a unique high‐resolution record of the East Asian winter monsoon. Because of the climate conditions on the Japan Sea side of the Japanese islands, the volume of precipitation during the winter is strongly reflected in the stalagmite δ¹⁸O signal. Examination of the carbon isotopes and the Mg/Ca ratio of FG01 provided additional information on the Holocene climate in Itoigawa, which is characterized by two different modes separated at 6.4 ka. Dripwater composition and the correlation between the δ¹³C and Mg/Ca data of FG01 indicate the importance of prior calcite precipitation (PCP), a process that selectively eliminated ¹²C and calcium ions from infiltrating water from CO₂ degassing and calcite precipitation. In an earlier period (10.0–6.4 ka), an increase in soil pCO₂ associated with warming and wetting climate trends was a critical factor that enhanced PCP, and resulted in an increasing trend in the Mg/Ca and δ¹³C data and a negative correlation between the δ¹³C and δ¹⁸O profiles. A distinct peak in the δ¹³C age profile at 6.8 ka could be a response to an increase of approximately 10% in C4 plants in the recharge area. At 6.4 ka, the climate mode changed to another, and correlation between δ¹⁸O and δ¹³C became positive. In addition, a millennial‐scale variation in δ¹⁸O and pulsed changes in δ¹³C and Mg/Ca became distinct. Assuming that δ¹⁸O and PCP were controlled by moisture in the later period, the volume of precipitation was high during 6.0–5.2, 4.4–4.0, and 3.0–2.0 ka. In contrast, the driest interval in Itoigawa was during 0.2–0.4 ka, and broadly corresponds to the Little Ice Age.  相似文献   

Optimum design and earthquake-response constrained design of elastic shear buildings     

Tsuneyoshi Nakamura  Takashi Yamane 《地震工程与结构动力学》1986,14(5):797-815

The necessary and sufficient conditions for global optimality and the closed form solution are derived for a problem of minimizing a weighted sum of storey stiffnesses of a shear building subject to a fundamental frequency constraint. A set of higher frequency formulae is derived for optimally designed shear buildings with equal masses. It is shown that, if the weight coefficients are regarded as parameters for adjustment, the distribution of the SRSS estimates of the maximum interstorey drifts can be adjusted so as to coincide with a specified one. The base shear–fundamental period formulae and the base shear–design drift formulae are derived semi-analytically for shear buildings with equal masses on the basis of the optimum design formulae and the SRSS estimates of the maximum interstorey drifts. Some numerical examples are presented in order to illustrate the validity of the proposed method of earthquake-response constrained design.  相似文献   

Noble gas elemental and isotopic abundances in deep-sea trenches in the western Pacific     

George Igarashi  Masako Kodera  Minoru Ozima  Yuji Sano  Hiroshi Wakita  Jacques Boulgue 《Earth and Planetary Science Letters》1987,86(1)

Noble gas elemental and isotopic abundances were measured in seven deep-sea water samples from five different sampling sites in the Nankai Trough, the Japan Trench and the Kuril Trench. The samples were obtained by the manned submersible “Nautile”. Most of the sampling sites are associated with clam colonies and/or fluid venting. Excesses both in³He/⁴He ratio and He concentration are observed in a seawater sample collected a few kilometers off the clam colonies which were found at a depth of 3830 m at the mouth of the Tenryu Canyon. Concentrations of noble gases (Ne, Ar, Kr and Xe) in this sample show progressive depletion from Ne to Xe relative to those in 1°C air-saturated seawater, which can be attributed to mixing of hot water ( 15°C) with cold ambient water ( 1°C). Isotopic compositions of Ne, Ar, Kr and Xe in this sample are atmospheric. These observations may reflect venting of hot pore water around the Tenryu Canyon. All the other samples show a significant excess in concentration of all noble gases relative to 1°C air-saturated seawater and the isotopic compositions are atmospheric. This excess of noble gas concentrations may appear to be air contamination in the samples. However, results of hydrocarbon analyses of the Kaiko samples imply that such large amount of air contamination is improbable. Decomposition of gas hydrate in deep-sea sediments is a more likely explanation for the observed excess of noble gas concentration.  相似文献   

Rb–Sr and Sm–Nd isotopic systematics of the Hayachine–Miyamori ophiolitic complex: Melt generation process in the mantle wedge beneath an Ordovician island arc     

Masako Yoshikawa  Kazuhito Ozawa   《Gondwana Research》2007,11(1-2):234

The Hayachine–Miyamori (HM) ophiolitic complex in the Kitakami Mountains, northeastern Japan consists of ultramafic tectonite and cumulate members. The most fertile lherzolites have mineral and trace element compositions similar to those of abyssal peridotites. They show 350–430 Ma Nd depleted mantle model ages, which are within the range of the K–Ar emplacement ages obtained from intrusive gabbroic rocks, suggesting a partial melting event just before the emplacement. The measured ¹⁴³Nd/¹⁴⁴Nd ratio of clinopyroxene in the tectonite peridotites shows positive correlation with ¹⁴⁷Sm/¹⁴⁴Nd and decreases with increasing refractoriness, which cannot be explained by a simple melting and melt extraction to a various extent followed by radiogenic ingrowth. It clearly suggests influx of a melt/fluid enriched in highly incompatible trace elements during melting. Time corrected isotopic compositions of the HM complex exhibit a clear island arc signature with uniform initial isotopic ratio (⁸⁷Sr/⁸⁶Sr = 0.7035–0.7041, ε_Nd = + 7.8–+ 5.0). Application of an open-system melting model to the observed trace element abundances in clinopyroxene suggests influx of three distinct agents to the HM mantle with the following characteristics: (1) moderate enrichment in highly incompatible elements with negative anomalies of Sr and Zr; (2) extensive enrichment of highly incompatible elements with positive Sr and negative Zr anomalies; and (3) extensive enrichment of highly incompatible elements with positive anomalies of Sr and Zr. These characteristics cover a variety of slab-derived components proposed in the literatures, suggesting the agents responsible for the open-system melting in the HM ophiolite might represent full spectrum of slab-derived components from back-arc to fore-arc regions of the Ordovician island arc system.  相似文献