AMS analysis of I in Japanese soil samples collected from background areas far from nuclear facilities     

Yasuyuki Muramatsu  Yukari Takada  Hiroyuki Matsuzaki  Satoshi Yoshida 《Quaternary Geochronology》2008,3(3):291-297

Analytical procedures in the determination of iodine-129 (half-life: 1.6×10⁷ y) have been studied using accelerator mass spectrometry (AMS), with special references to the separation procedures of iodine from soil samples for the AMS measurement. Iodine was successfully volatilized from soil samples by pyrohydrolysis at 1000 °C and collected in a trap solution. Iodine was purified from the matrix by solvent extraction. Finally, it was precipitated as silver iodide to make a target for AMS. In order to obtain information on the ¹²⁹I/¹²⁷I ratio in a chemical blank (or iodine carrier), we have determined the ratios in several iodine reagents and found that the ratios fell in a narrow range around 1.7×10⁻¹³. The detection limit for soil sample (1 g material) by the present method was about 0.01 mBq/kg or 4×10⁻¹¹ as the ratio of stable iodine (¹²⁹I/¹²⁷I ratio), i.e. these values were much better than that by neutron activation analysis (NAA) used in our previous studies. We have applied this method in the analysis of soil samples collected from different places in Japan. We could successfully determine ¹²⁹I in soil samples with low ¹²⁹I concentrations, which could not be detected by NAA. Sample size necessary for the soil analysis by AMS was only about 0.5 g or less, whereas about 100 g of the sample were required for NAA [Muramatsu, Y., Ohmomo, Y., 1986. Iodine-129 and iodine-127 in environmental samples collected from Tokaimura/ Ibaraki, Japan. Sci. Total Environ. 48, 33-43]. Using this method, new data were obtained for the ¹²⁹I levels in 20 soil samples collected from background areas far from nuclear facilities, and the ranges were 1.4×10⁻⁵−4.5×10⁻³ Bq/kg as ¹²⁹I concentrations and 3.9×10⁻¹¹−2.2×10⁻⁸ as ¹²⁹I/¹²⁷I ratios. These values are useful in understanding the ¹²⁹I levels in Japanese environments. Higher ¹²⁹I concentrations were observed in forest soils than those in field and rice paddy soils should be related to the interception effect of atmospheric ¹²⁹I due to tree canopies. Relatively high ¹²⁹I/¹²⁷I ratios found in rice paddy soils could be explained by their low stable iodine concentrations which were caused by the desorption of stable iodine from the rice paddies during the cultivation.  相似文献   

Study on the fate of petroleum-derived polycyclic aromatic hydrocarbons (PAHs) and the effect of chemical dispersant using an enclosed ecosystem,mesocosm     

Yamada M  Takada H  Toyoda K  Yoshida A  Shibata A  Nomura H  Wada M  Nishimura M  Okamoto K  Ohwada K 《Marine pollution bulletin》2003,47(1-6):105-113

Polycyclic Aromatic Hydrocarbons (PAHs) are one of the components found in oil and are of interest because some are toxic. We studied the environmental fate of PAHs and the effects of chemical dispersants using experimental 500 l mesocosm tanks that mimic natural ecosystems. The tanks were filled with seawater spiked with the water-soluble fraction of heavy residual oil. Water samples and settling particles in the tanks were collected periodically and 38 PAH compounds were analyzed by gas chromatography-mass spectrometry (GC-MS). Low molecular weight (LMW) PAHs with less than three benzene rings disappeared rapidly, mostly within 2 days. On the other hand, high molecular weight (HMW) PAHs with more than four benzene rings remained in the water column for a longer time, up to 9 days. Also, significant portions (10-94%) of HMW PAHs settled to the bottom and were caught in the sediment trap. The addition of chemical dispersant accelerated dissolution and biodegradation of PAHs, especially HMW PAHs. The dispersant amplified the amounts of PAHs found in the water column. The amplification was the greater for the more hydrophobic PAHs, with an enrichment factor of up to six times. The increased PAHs resulting from dispersant use overwhelmed the normal degradation and, as a result, higher concentrations of PAHs were observed in water column throughout the experimental period. We conclude that the addition of the dispersant could increase the concentration of water column PAHs and thus increase the exposure and potential toxicity for organisms in the natural environment. By making more hydrocarbon material available to the water column, the application of dispersant reduced the settling of PAHs. For the tank with dispersant, only 6% of chrysene initially introduced was detected in the sediment trap whereas 70% was found in the trap in the tank without dispersant.  相似文献   

Systematic errors in future weak-lensing surveys: requirements and prospects for self-calibration     

Dragan Huterer  Masahiro Takada  Gary Bernstein  Bhuvnesh Jain 《Monthly notices of the Royal Astronomical Society》2006,366(1):101-114

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Polycyclic aromatic hydrocarbon (PAHs) and hopanes in stranded tar-balls on the coasts of Peninsular Malaysia: applications of biomarkers for identifying sources of oil pollution   总被引：1，自引：0，他引：1  

Zakaria MP  Okuda T  Takada H 《Marine pollution bulletin》2001,42(12):1357-1366

Malaysian coasts are subjected to various threats of petroleum pollution including routine and accidental oil spill from tankers, spillage of crude oils from inland and offshore oil fields, and run-off from land-based human activities. Due to its strategic location, the Straits of Malacca serves as a major shipping lane. This paper expands the utility of biomarker compounds, hopanes, in identifying the source of tar-balls stranded on Malaysian coasts. 20 tar-ball samples collected from the east and west coast were analyzed for hopanes and polycyclic aromatic hydrocarbons (PAHs). Four of the 13 tar-ball samples collected from the west coast of Peninsular Malaysia were identified as the Middle East crude oil (MECO) based on their biomarker signatures, suggesting tanker-derived sources significantly contributing the petroleum pollution in the Straits of Malacca. The tar-balls found on the east coast seem to originate from the offshore oil platforms in the South China Sea. The presence of South East Asian crude oil (SEACO) tar-balls on the west coast carry several plausible explanations. Some of the tar-balls could have been transported via sea currents from the east coast. The tankers carrying SEACO to other countries could have accidentally spilt the oil as well. Furthermore, discharge of tank washings and ballast water from the tankers were suggested based on the abundance in higher molecular weight n-alkanes and the absence of unresolved complex mixture (UCM) in the tar-ball samples. The other possibilities are that the tar-balls may have been originated from the Sumatran oil fields and spillage of domestic oil from oil refineries in Port Dickson and Malacca. The results of PAHs analysis suggest that all the tar-ball samples have undergone various extent of weathering through evaporation, dissolution and photo-oxidation.  相似文献