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Matt Rovero Diana Cutt Rachel Griffiths Urszula Filipowicz Katherine Mishkin Brad White Sandra Goodrow Richard T. Wilkin 《Ground Water Monitoring & Remediation》2021,41(4):62-75
Published literature for reported sorption coefficients (Kd) of eight anionic per- and polyfluoroalkyl substances (PFAS) in soil was reviewed. Kd values spanned three to five log units indicating that no single value would be appropriate for use in estimating PFAS impacts to groundwater using existing soil-water partition equations. Regression analysis was used to determine if the soil or solution parameters might be used to predict Kd values. None of the 15 experimental parameters collected could individually explain variability in reported Kd values. Significant associations between Kd and soil calcium and sodium content were found for many of the selected PFAS, suggesting that soil cation content may be critical to PFAS sorption, as previously noted in sources like Higgins and Luthy (2006), while organic carbon content was significant only at elevated levels (>5%). Unexplained discrepancies between the results from studies where PFAS were introduced to soil and desorbed in the laboratory and those that used material from PFAS-impacted sites suggest that laboratory experiments may be overlooking some aspects critical to PFAS sorption. Future studies would benefit from the development and use of standardized analytical methods to improve data quality and the establishment of soil parameters appropriate for collection to produce more complete data sets for predictive analysis. 相似文献
124.
A major seismic swarm occurred near Parícutin volcano between the end of May and early July 2006. More than 700 earthquakes
with magnitude (M
L
) exceeding 2.4 were located. Parícutin, located in the Michoacán–Guanajuato volcanic field in western Mexico, is well known
as the site of the 1943 eruption in which a new 400 m cinder cone was constructed in what had been farmland. The 2006 swarm
exhibits all of the characteristics typically associated with swarms of volcanic origins. The earthquake rate showed the typical
ramp up and ramp down over the course of several days. Magnitudes were evenly distributed in time with a notably high b-value
of 2.45. The earthquake locations cluster around a northeast-striking trend extending approximately 6 km. Over the first two
weeks, hypocenters migrated steadily a few hundred meters per day, rising from 9 to 5 km depth and moving northeast about
5 km. On approximately June 7, the ascent of hypocenters stalled. For the next three weeks, hypocenters held their depth while
migrating laterally back to the southwest. Focal mechanisms during the first part of the swarm reflected the increased stress
caused by dike inflation. Following June 7, the stress orientation changed and became more consistent with the inflation of
horizontal sill-like structures. Though only limited information is available from the seismic swarm preceding the 1943 eruption,
several features, including the swarm duration and magnitude relationships, were comparable to those of the 2006 episode.
The strong indicators of a magmatic origin to the 2006 swarm suggest that at this location there are few, if any, traditional
seismic discriminants that could be used to distinguish which seismic swarms and dike emplacement events might culminate in
eruption. 相似文献
125.
F. Fiore G. Matt M. Cappi M. Elvis K. M. Leighly F. Nicastro L. Piro A. Siemiginowska & B. J. Wilkes 《Monthly notices of the Royal Astronomical Society》1998,298(1):103-113
Steep soft X-ray (0.1–2 keV) quasars share several unusual properties: narrow Balmer lines, strong Fe II emission, large and fast X-ray variability, and a rather steep 2–10 keV spectrum. These intriguing objects have been suggested to be the analogues of Galactic black hole candidates in the high, soft state. We present here results from ASCA observations for two of these quasars: NAB 0205 + 024 and PG 1244 + 026. Both objects show similar variations (factor of ∼ 2 in 10 ks), despite a factor of ∼ 10 difference in the 0.5–10 keV luminosity (7.3 × 1043 erg s−1 for PG 1244 + 026 and 6.4 × 1044 erg s−1 for NAB 0205 + 024, assuming isotropic emission, H 0 = 50.0 and q 0 = 0.0). The X-ray continuum of the two quasars flattens by 0.5–1 going from the 0.1–2 keV band towards higher energies, strengthening recent results on another half-dozen steep soft X-ray active galactic nuclei. PG 1244 + 026 shows a significant feature in the '1-keV' region, which can be described either as a broad emission line centred at 0.95 keV (quasar frame) or as edge or line absorption at 1.17 (1.22) keV. The line emission could be a result of reflection from a highly ionized accretion disc, in line with the view that steep soft X-ray quasars are emitting close to the Eddington luminosity. Photoelectric edge absorption or resonant line absorption could be produced by gas outflowing at a large velocity (0.3–0.6 c ). 相似文献
126.
Land-use change in urbanizing areas can significantly alter the hydrology of a watershed and can have serious impacts on wetland water balances, downstream flooding, and groundwater recharge. Most currently available models used in determining the hydrologic impacts of urbanization are not well suited to long-term hydrologic analysis or are too complex and data intensive for widespread practical application. The Long-Term Hydrologic Impact Assessment (LTHIA) model run on a Geographic Information System (GIS) is a relatively simple, user-friendly model that uses the Curve Number method to estimate changes in surface runoff between different stages of development. Application of the model to a large, rapidly urbanizing watershed near Indianapolis, Indiana, suggests that average annual runoff depths increased by more than 60% from 1973 to 1991, with even greater increases for some individual sub-basins. These results are consistent with runoff changes estimated from historical stream flow data in the watershed. A sensitivity analysis to determine minimum data requirements shows that a precipitation record length of 15 years or more is required to produce consistent results with LTHIA and that the highest possible resolution land-use and soils data should be used. The LTHIA model is now available on the Internet at http://www.ecn.purdue.edu/runoff. [Key words: hydrology, urbanization, modeling, GIS.] 相似文献
127.
128.
Charles S. Cockell Matt Balme John C. Bridges Alfonso Davila Susanne P. Schwenzer 《Icarus》2012,217(1):184-193
Investigations of Mars as a potential location for life often make the assumption that where there are habitats, they will contain organisms. However, the observation of the ubiquitous distribution of life in habitable environments on the Earth does not imply the presence of life in martian habitats. Although uninhabited habitats are extremely rare on the Earth, a lack of a productive photosynthetic biosphere on Mars to generate organic carbon and oxygen, thus providing a rapidly available redox couple for energy acquisition by life and/or a lack of connectivity between habitats potentially increases the scope and abundance of uninhabited habitats for much of the geological history of the planet. Uninhabited habitats could have existed on Mars from the Noachian to the present-day in impact hydrothermal systems, megaflood systems, lacustrine environments, transient melted permafrost, gullies and local regions of volcanic activity; and there may be evidence for them in martian meteorites. Uninhabited habitats would provide control habitats to investigate the role of biology in planetary-scale geochemical processes on the Earth and they would provide new constraints on the habitability of Mars. Future robotic craft and samples returned from Mars will be able to directly show if uninhabited habitats exist or existed on Mars. 相似文献
129.
Aeolian processes are probably the dominant ongoing surface process on Mars; Large Dark Dunes (LDDs), particularly common aeolian landforms, were first recognized in the early 1970s. Recent, higher resolution images have revealed another, morphologically distinct, large population of smaller, ripple-like aeolian bedforms that have been termed “Transverse Aeolian Ridges” (TARs) as it is unknown whether they formed as large ripples or small dunes. We have begun a new study of TARs that examines their distribution, orientation, and morphology using > 10,000 high-resolution Mars Orbiter Camera (1.5 to 8 m/pixel resolution) images in a 45° longitude wide, pole-to-pole survey. The aim of this study is to assess whether TARs are active, to identify possible sediment sources and pathways, and to determine the volumes of sediment that they comprise. We present results from the first half of this study, in which we examine the northern hemisphere, and describe a new three-part classification scheme used to aid the survey.Our results show that TARs are abundant but not ubiquitous: preferentially forming proximal to friable, layered terrains such as those found in Terra Meridiani — the location of the ongoing Mars Exploration Rover “Opportunity” mission. TAR distribution in the northern hemisphere shows a strong latitudinal dependence with very few TARs being found north of 30° N. We also find that in most cases TARs are less mobile than LDDs, a conclusion possibly explained by Mars Exploration Rover Opportunity observations that show TAR-like ripples to have a core of fine material armored by a monolayer of granule-sized particles. This could disallow significant bedform movement under the current wind regime. That TARs are essentially inactive is confirmed by superposition relations with slope streaks and LDDs and by observations of superposed impact craters. We suggest that observations made by the Opportunity Rover in Terra Meridiani indicate that the small aeolian bedforms common here are ripples and not small dunes. Farther south, these bedforms transition into larger features indistinguishable from TARs, suggesting that TARs (in the Meridiani area at least) are ripples and not dunes. 相似文献
130.
S. Bianchi A. Corral F. Panessa X. Barcons G. Matt L. Bassani F. J. Carrera E. Jiménez-Bailón 《Monthly notices of the Royal Astronomical Society》2008,385(1):195-199
We report on simultaneous optical and X-ray observations of the Seyfert galaxy, NGC 3147. The XMM–Newton spectrum shows that the source is unabsorbed in the X-rays ( N H < 5 × 1020 cm−2 ) . On the other hand, no broad lines are present in the optical spectrum. The origin of this optical/X-rays misclassification (with respect to the Unification Model) cannot be attributed to variability, since the observations in the two bands are simultaneous. Moreover, a Compton-thick nature of the object can be rejected on the basis of the low-equivalent width of the iron Kα line (≃130 eV) and the large ratio between the 2–10 keV and the [O iii ] fluxes. It seems therefore inescapable to conclude that NGC 3147 intrinsically lacks the Broad-Line Region, making it the first 'true' type 2 Seyfert galaxy. 相似文献