Changes in fish mercury concentrations over 20 years in an acidified lake subject to experimental liming     

Martti Rask  Roger I. Jones  Marko Järvinen  Anna Paloheimo  Maiju Salonen  Jari Syväranta  Matti Verta 《Applied Geochemistry》2007

Lake Iso Valkjärvi (southern Finland, Europe) was divided in two with a plastic curtain in 1991. One half was neutralized with CaCO₃, and the other acted as a control. Mercury concentrations of perch (Perca fluviatilis) and northern pike (Esox lucius) in the limed and control side of the lake were studied both before and after the treatment. Average Hg concentrations of perch and pike were 0.40 and 1.2 μg g⁻¹ (ww) in the early 1980s and 0.25 and 0.72 μg g⁻¹ (ww) a decade later at the time of liming. Ten years after the liming the Hg concentrations of perch in the limed and control sides of the lake were 0.21 and 0.28 μg g⁻¹ (ww) and those of pike were 0.69 and 0.43 μg g⁻¹ (ww), respectively. Nitrogen isotope ratios (δ¹⁵N) for perch in the sampling period 2002–2004 showed wide variation suggesting variable trophic positions for individual fish. Pike formed two groups according to their δ¹⁵N-values, suggesting that zoobenthos dominated the diet of pike around 20 cm in length and fish that of the larger pikes. Because the δ¹⁵N-values of fish were at similar levels in the limed and control sides of L. Iso Valkjärvi, differences in food web structure cannot account for the different fish Hg concentrations. A more likely explanation is water quality induced differences in the dynamics and bioavailability of Hg, leading to decreased formation of methyl Hg.  相似文献   

The deglaciation history of the Lake Superior region and its climatic implications     

Matti Saarnisto 《Quaternary Research》1974,4(3):316-339

A zone of synchronous end moraines has been recognized in the Lake Superior region across northern Ontario and Michigan. The moraines were formed between 11,000 and 10,100 y.a. as cold climate resulted in successive halts in the general ice retreat. The cold climate is also indicated by the presence of tundra near Lake Superior until about 10,000 y.a. This episode is here referred to as the Algonquin Stadial. It was preceded and followed by rapid deglaciation. The Algonquin Stadial is comparable in age with the Younger Dryas Stadial of Europe, and indicates a reversal in the continuous trend toward a warmer climate during Late-Wisconsin (an) time. The apparent conflict between the present result (based on geologic evidence) and earlier pollen stratigraphical studies with no reversal is discussed.Glacial Lake Duluth formed in the western Lake Superior basin before 11,000 BP, followed by a series of Post-Duluth lakes between approximately 11,000 and over 10,100 BP. The Main Lake Algonquin stage in the Huron and Michigan basins terminated approximately 11,000 BP. The subsequent high-level post-Main Algonquin lakes, which were contemporaneous with the Post-Duluth lakes, existed in the southeastern Lake Superior basin. When the ice margin was along the north shore 9500 BP Lake Minong occupied the whole Lake Superior basin. By 9000 BP the ice had retreated north of Lake Superior-Hudson Bay divide.  相似文献   

南极海冰导温系数与孔隙率关系初探          下载免费PDF全文

石立琼  白乙拉  李志军  Cheng Bin 《极地研究》2009,21(2):91-99

利用南极中山站附近固定冰不同季节的温度垂直廓线,冰芯盐度、密度数据,基于Cox等发展的冰内孔隙率计算方法,获得冰内孔隙率的垂直廓线。再通过建立分布参数系统最优控制模型,优化辨识在无热源条件下冰内温度垂直廓线对应的海冰导温系数。通过比较7种冰导温系数同孔隙率的关系,选择出海冰导温系数和孔隙率的最优关系式。用该关系式对同一地点不同年份的海冰进行温度垂直廓线计算,比较辨识的导温系数同孔隙率的关系相对于前人理想海冰模型中的导热系数、比热等公式计算对应条件的海冰垂直温度廓线的优势。两种计算结果说明,辨识得到的关系所引起的偏差在趋势和量级上同理想模式计算的结果相同,但辨识得到的关系更简洁,且更具有物理背景。  相似文献   

Impact of different energies of precipitating particles on NOx generation in the middle and upper atmosphere during geomagnetic storms     

Esa Turunen  Pekka T. Verronen  Annika Seppälä  Craig J. Rodger  Mark A. Clilverd  Johanna Tamminen  Carl-Fredrik Enell  Thomas Ulich 《Journal of Atmospheric and Solar》2009,71(10-11):1176-1189

Energetic particle precipitation couples the solar wind to the Earth's atmosphere and indirectly to Earth's climate. Ionisation and dissociation increases, due to particle precipitation, create odd nitrogen (NO_x) and odd hydrogen (HO_X) in the upper atmosphere, which can affect ozone chemistry. The long-lived NO_x can be transported downwards into the stratosphere, particularly during the polar winter. Thus, the impact of NO_x is determined by both the initial ionisation production, which is a function of the particle flux and energy spectrum, as well as transport rates. In this paper, we use the Sodankylä Ion and Neurtal Chemistry (SIC) model to simulate the production of NO_x from examples of the most representative particle flux and energy spectra available today of solar proton events (SPE), auroral energy electrons, and relativistic electron precipitation (REP). Large SPEs are found to produce higher initial NO_x concentrations than long-lived REP events, which themselves produce higher initial NO_x levels than auroral electron precipitation. Only REP microburst events were found to be insignificant in terms of generating NO_x. We show that the Global Ozone Monitoring by Occultation of Stars (GOMOS) observations from the Arctic winter 2003–2004 are consistent with NO_x generation by a combination of SPE, auroral altitude precipitation, and long-lived REP events.  相似文献   

Mikulino and Valdai palaeoenvironments in the Vologda area, NW Russia     

Valery Gey  Matti Saarnisto  Juha Pekka Lunkka  Igor Demidov 《Global and Planetary Change》2001,31(1-4)

Nine representative sediment sequences and pollen diagrams obtained during the Quaternary mapping programme carried out by the Geological Expedition (St. Petersburg, Russia) between 1960s and 1980s are presented from the Vologda area, NW Russian Plain, covering the time span from the Moscow cold (Saale) stage into the Late Valdai (Weichsel) substage. This work was done in order to shed light on the evolution of palaeoenvironments, vegetation and climate in the area. The results suggest that two major depressions in the Vologda area, namely the Mologa–Sheksnian and Prisukhonian basins, witnessed lake level fluctuations that were most likely closely linked to climatic fluctuations. It is suggested that during the Mikulino (Eem) thermal optimum most of the lowland areas were dry land. However, during the Early and Middle Valdai, the large depressions started to flood as a result of wet and cold climate. This caused the accumulation of lacustrine and also lacustrine–alluvial and lacustrine–bog sediments into the basins. The Valdai forest composition varied between closed spruce–birch forests and treeless tundra. Lakes persisted throughout the Valdai stage including the extremely dry last glacial maximum (LGM)-time when the Scandinavian Ice Sheet dammed the northbound rivers in the Vologda area.  相似文献   

Quantification of Holocene lake-level changes in Finnish Lapland using a cladocera – lake depth transfer model     

Atte?KorholaEmail author  Matti?Tikkanen  Jan?Weckstr?m 《Journal of Paleolimnology》2005,34(2):175-190

During recent years, numerous studies dealing with Holocene lake level fluctuations have been conducted in Finnish Lapland. However, no quantification of lake level variations exists to date. Here, we applied a recently developed modern cladocera – lake depth transfer model to subfossil cladocerans analysed from three small and shallow (< 6 m) kettle-hole lakes in northwestern Finnish Lapland to provide estimates of the amplitudes of long-term lake-level changes in the region. The quantitative inferences were compared to pollen, charcoal and geochemical records from one of the study sites. The lake levels were inferred to be high during the early Holocene; they faced marked reduction up to 4–6 m in the mid-Holocene (≈7000–4000 cal yr BP), and rose again during the latter part of the Holocene. There is some indication of lowered lake levels around 1500 cal yr BP, but interpretation of such small-scale changes is hazardous due to large prediction errors in the initial cladoceran model. The overall pattern of the Holocene lake level variation generally followed the regional changes in climate humidity as reconstructed in previous studies by means of other sedimentary proxy indicators, such as pollen and oxygen isotopic compositions. We postulate that changes in winter precipitation may have had a greater influence on lake-levels than variations in summer precipitation or evaporation.  相似文献   

D. Rossetti, P. Mann de Toledo, A.-M. Góes, New geological framework for Western Amazonia (Brazil) and implications for biogeography and evolution, Quaternary Research 63 (2005) 78-89     

Georg Irion  Matti Räsänen  Carina Hoorn  Frank Wesselingh 《Quaternary Research》2005,64(2):279-280

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Specific affinity for phosphate uptake and specific alkaline phosphatase activity as diagnostic tools for detecting phosphorus-limited phytoplankton and bacteria     

Tsuneo Tanaka  Peter Henriksen  Risto Lignell  Kalle Olli  Jukka Seppälä  Timo Tamminen  T. Frede Thingstad 《Estuaries and Coasts》2006,29(6):1226-1241

We analyzed responses of soluble reactive phosphorus (SRP), bioavailable phosphate (PO₄), particulate phosphorus, turnover time of orthophosphate (T_t), and alkaline phosphatase activity (APA) to varying degrees of nutrient stress. The nutrient stress was evoked by different treatments in concentration and combination of inorganic nitrogen (N) and phosphorus (P), and labile organic carbon (glucose) to mesocosms in experiments carried out in eutrophic southern (Odense Fjord, Denmark) and northern (Tvärminne Archipelago, Finland) coastal zones of the Baltic Sea. Despite seasonal and geographical differences, similar responses were observed in both experiments. Low SRP (<100 nmol l^?1), shortT _t (<10 h), and increased levels of APA were observed in both N+P balanced and P deficient treatments, while the opposite trend was observed in P replete treatments. The shortestT _t and the highest APA were found when glucose was combined with N treatment. Bioavailable PO₄ was estimated usingT _t and P uptake rates as derived from stoichiometric conversion of carbon based primary and bacterial production. With shorterT _t, the PO₄ pool declined to <1 nmol-P l^?1, whereas the SRP background pool (difference between SRP and PO₄) remained relatively constant (c. 50 nmol l^?1). APA was inversely related to PO₄ but not to SRP. Responses of specific APA and specific affinity for PO₄ uptake, which are APA and PO₄ uptake rates (inverse ofT _t), respectively, normalized to the summed P biomass of phytoplankton and bacteria, responded consistently to the pattern and magnitude of nutrient limitation evoked in our experiments. Our results, together with a literature survey, suggest that both parameters can be useful in examining PO₄ availability for the natural phytoplankton and bacteria community in P starved aquatic systems.  相似文献   

GIS-based DRASTIC model for groundwater vulnerability and pollution risk assessment in the Peshawar District,Pakistan     

Syed Adnan  Javed Iqbal  Matti Maltamo  Rubén Valbuena 《Arabian Journal of Geosciences》2018,11(16):458

Groundwater is the most economic natural source of drinking in urban and rural areas which are degraded due to high population growth and increased industrial development. We applied a GIS-based DRASTIC model in a populated urban area of Pakistan (Peshawar) to assess groundwater vulnerability to pollution. Six input parameters—depth to phreatic/groundwater level, groundwater recharge, aquifer material, soil type, slope, and hydraulic conductivity—were used in the model to generate the groundwater vulnerable zones. Each parameter was divided into different ranges or media types, and ratings R?=?1?–?10 were assigned to each factor where 1 represented the very low impact on pollution potential and 10 represented very high impact. Weight multipliers W?=?1?–?5 were also used to balance and enhance the importance of each factor. The DRASTIC model scores obtained varied from 47 to 147, which were divided into three different zones: low, moderate, and high vulnerability to pollution. The final results indicate that about 31.22, 39.50, and 29.27% of the total area are under low, moderate, and high vulnerable zones, respectively. Our method presents a very simple and robust way to assess groundwater vulnerability to pollution and helps the decision-makers to select appropriate landfill sites for waste disposals, and manage groundwater pollution problems efficiently.  相似文献   

Long-term analysis of hydrography and sea-ice data in Tvärminne,Gulf of Finland,Baltic Sea     

Ioanna Merkouriadi  Matti Leppäranta 《Climatic change》2014,124(4):849-859

We present an analysis of the inter-annual variability of hydrography—temperature and salinity – and ice conditions at the coastal site of Tvärminne, Gulf of Finland, Baltic Sea during the period 1927–2012. The aim is to analyze the natural variability and trends of the hydrographic characteristics, freezing and breakup dates, ice thickness, and the heat content during the last century. The study also includes the inter-connections between the ice season and the surface temperature and salinity in the open water season. The results showed a significant decrease of the ice season length, by almost 30 days. The maximum annual ice thickness decreased by 8 cm in the last 40 years. The surface water temperature increased by almost 1 °C and there was also an increasing trend in the heat content. The thermal memory of the system was 2–2.5 months. The surface salinity increased by 0.5 psu in the last 85 years. The results are discussed and compared to related studies.  相似文献