First health and pollution study on harbor seals (Phoca vitulina) living in the German Elbe estuary     

Antje Kakuschke  Elizabeth Valentine-Thon  Juergen Gandrass  Luis Dominguez Boada  Maira Almeida González  Daniel Pröfrock  Katharina Kramer  Andreas Prange 《Marine pollution bulletin》2010,60(11):2079-2086

The Elbe is one of the major rivers releasing pollutants into the coastal areas of the German North Sea. Its estuary represents the habitat of a small population of harbor seals (Phoca vitulina). Only little is known about the health status and contamination levels of these seals. Therefore, a first-ever seal catch was organized next to the islands of Neuwerk and Scharhörn in the region of the Hamburg Wadden Sea National Park. The investigations included a broad set of health parameters and the analysis of metals and organic pollutants in blood samples. Compared to animals of other Wadden Sea areas, the seals showed higher γ-globulin levels, suggesting higher concentrations of pathogens in this near-urban area, elevated concentrations for several metals in particular for V, Sn, Pb, and Sr, and comparable ranges for chlorinated organic contaminants, except for elevated levels of hexachlorobenzene, which indicates characteristic inputs from the Elbe.  相似文献   

Variability of metal contents in the sea rush Juncus maritimus-estuarine sediment system through one year of plant's life     

Almeida CM  Mucha AP  Vasconcelos MT 《Marine environmental research》2006,61(4):424-438

Metal accumulation by Juncus maritimus and the effect this plant might have on the physico-chemical composition of sediments, from Douro river estuary (NW Portugal), were investigated through one year of plant's life. The contents of Al, Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn were determined (by atomic absorption spectrophotometry) in sediments, rhizosediments (those among plant roots and rhizomes) and different tissues of J. maritimus. Two estuarine sites with different characteristics were studied, one a sandy sediment with relatively low organic matter content, the other a muddy site. The role of the plant seemed to be markedly dependent on the sediment composition. At the sandy site, significant variations throughout the year (a decrease from winter to summer and an increase in autumn) either in rhizosediment and sediment or in J. maritimus roots were only observed in Cd and Cu levels. These variations were the same in both compartments, probably caused by tidal water movements and the activity of the plant. At the muddy site, variations throughout the year were observed for all studied elements but Pb. Changes in the Cd and Zn contents of roots were opposite to those in the rhizosediment (uptake of Cd and Zn by J. maritimus roots in summer may have caused a decrease in rhizosediment levels). Fe and Mn showed similar patterns of variation in both roots and rhizosediment (contents significantly increasing in summer). Higher contents of Fe and Mn in roots in summer could be related to changes in mass, higher availability of the elements, or accumulation at the surface of the root in (hydr)oxides forms. For the remaining elements no significant correlations between rhizosediment and roots variations were observed, indicating that their uptake and release by roots were not based on single exchanges with the sediment. J. maritimus showed capacity to accumulate Cu, Zn and particularly Cd, thus appearing to be useful for the phytostabilization of these metals.  相似文献   

Modelling of shallow landslides with machine learning algorithms     

Zhongqiang Liu  Graham Gilbert  Jose Mauricio Cepeda  Asgeir Olaf Kydland Lysdahl  Luca Piciullo  Heidi Hefre  Suzanne Lacasse 《地学前缘(英文版)》2021,12(1):385-393

This paper introduces three machine learning(ML)algorithms,the‘ensemble'Random Forest(RF),the‘ensemble'Gradient Boosted Regression Tree(GBRT)and the Multi Layer Perceptron neural network(MLP)and applies them to the spatial modelling of shallow landslides near Kvam in Norway.In the development of the ML models,a total of 11 significant landslide controlling factors were selected.The controlling factors relate to the geomorphology,geology,geo-environment and anthropogenic effects:slope angle,aspect,plan curvature,profile curvature,flow accumulation,flow direction,distance to rivers,water content,saturation,rainfall and distance to roads.It is observed that slope angle was the most significant controlling factor in the ML analyses.The performance of the three ML models was evaluated quantitatively based on the Receiver Operating Characteristic(ROC)analysis.The results show that the‘ensemble'GBRT machine learning model yielded the most promising results for the spatial prediction of shallow landslides,with a 95%probability of landslide detection and 87%prediction efficiency.  相似文献   

Resonance tongues in the linear Sitnikov equation     

Mauricio Misquero 《Celestial Mechanics and Dynamical Astronomy》2018,130(4):30

In this paper, we deal with a Hill’s equation, depending on two parameters \(e\in [0,1)\) and \(\varLambda >0\), that has applications to some problems in Celestial Mechanics of the Sitnikov type. Due to the nonlinearity of the eccentricity parameter e and the coexistence problem, the stability diagram in the \((e,\varLambda )\)-plane presents unusual resonance tongues emerging from points \((0,(n/2)^2),\ n=1,2,\ldots \) The tongues bounded by curves of eigenvalues corresponding to \(2\pi \)-periodic solutions collapse into a single curve of coexistence (for which there exist two independent \(2\pi \)-periodic eigenfunctions), whereas the remaining tongues have no pockets and are very thin. Unlike most of the literature related to resonance tongues and Sitnikov-type problems, the study of the tongues is made from a global point of view in the whole range of \(e\in [0,1)\). Indeed, an interesting behavior of the tongues is found: almost all of them concentrate in a small \(\varLambda \)-interval [1, 9 / 8] as \(e\rightarrow 1^-\). We apply the stability diagram of our equation to determine the regions for which the equilibrium of a Sitnikov \((N+1)\)-body problem is stable in the sense of Lyapunov and the regions having symmetric periodic solutions with a given number of zeros. We also study the Lyapunov stability of the equilibrium in the center of mass of a curved Sitnikov problem.  相似文献   

Salt marsh plants (Juncus maritimus and Scirpus maritimus) as sources of strong complexing ligands     

Ana P. Mucha  C. Marisa R. Almeida  Adriano A. Bordalo  M. Teresa S.D. Vasconcelos 《Estuarine, Coastal and Shelf Science》2008

This work aimed to evaluate, in vitro, the capability of roots of salt marsh plants to release strong Cu-complexing ligands and to ascertain whether Cu contamination would stimulate ligands' exudation or not. The sea rush Juncus maritimus and the sea-club rush Scirpus maritimus, both from the lower Douro river estuary (NW Portugal), were used. Plants were collected seasonally, four times a year in 2004, during low tide. After sampling, plant roots were washed for removal of adherent particles and immersed for 2 h in a solution that matched salinity (3) and pH (7.5) of the pore water from the same location and spiked with Cu²⁺ in the range 0–1600 nM to obtain plant exudates. In the final solutions as well as in sediment pore water total dissolved Zn and Cu, Cu-complexing ligand concentrations and the respective conditional stability constants (K_CuL^′) values were determined by voltammetry. This study demonstrated that plants are able to release, in a short period of time, relatively high amounts of strong Cu-complexing ligands (56–265 nmol g_root⁻¹), which differed among plants and sampling site but were independent of the season. Cu contamination did not stimulate exudation of Cu-complexing ligands. On the other hand, in media contaminated with Cu both plants accumulated relatively high amounts (29–83%) of the initially dissolved Cu, indicating that they have alternative internal mechanisms for Cu detoxification. Cu exchange between roots and medium (either accumulation in contaminated medium or release in the absence of Cu) was more intense for S. maritimus than for J. maritimus. It was observed that exudate solutions obtained in the absence of added Cu and sediment pore water (the densities of roots observed inside the salt marsh where comparable to those used in the in vitro experiments), displayed similarities in terms of total dissolved metals, Cu-complexing ligands concentrations, values of K_CuL^′ (12 < log K_CuL^′ < 14), as well as patterns of variation among seasons (only observed for Zn). These results are novel and point out that salt marsh plants may be the source at least partially of the strong organic ligands found in the sediment pore water in shallow marginal areas. The capability of salt marsh plants to release strong organic ligands into the environment, conjugated with their known capacity to oxidize anaerobic sediment around roots, indicate that these plants can play a role in controlling metal speciation in the water/sediment interface.  相似文献   

Sediment dynamics modulated by burrowing crab activities in contrasting SW Atlantic intertidal habitats     

Mauricio Escapa  Gerardo M.E. Perillo  Oscar Iribarne 《Estuarine, Coastal and Shelf Science》2008

Biogenic bottom features, animal burrows and biological activities interact with the hydrodynamics of the sediment–water interface to produce altered patterns of sediment erosion, transport and deposition which have consequences for large-scale geomorphologic features. It has been suggested that depending on the hydrodynamic status of the habitat, the biological activity on the bottom may have a variety of effects. In some cases, different bioturbation activities by the same organism can result in different consequences. The burrowing crab Neohelice granulata is the most important bioturbator at SW Atlantic saltmarshes and tidal plains. Because of the great variety of habitats that this species may inhabit, it is possible to compare its bioturbation effects between zones dominated by different hydrodynamic conditions. Internal marsh microhabitats, tidal creeks bottoms and basins, and open mudflats were selected as contrasting zones for the comparison on a large saltmarsh at Bahía Blanca Estuary (Argentina). Crab burrows act as passive traps of sediment in all zones, because their entrances remain open during inundation periods at high tide. Mounds are generated when crabs remove sediments from the burrows to the surface and become distinctive features in all the zones. Two different mechanisms of sediment transport utilizing mounds as sediment sources were registered. In the first one, parts of fresh mound sediments were transported when exposed to water flow during flooding and ebbing tide, with higher mound erosion where currents were higher as compared to internal marsh habitats and open mudflats. In the second mechanism, mounds exposed to atmospheric influence during low tide became desiccated and cracked forming ellipsoidal blocks, which were then transported by currents in zones of intense water flow in the saltmarsh edge. Sedimentary dynamics varied between zones; crabs were promoting trapping of sediments in the internal saltmarsh (380 g m⁻² day⁻¹) and open mudflats (1.2 kg m⁻² day⁻¹), but were enhancing sediment removal in the saltmarsh edge (between 10 and 500 g m⁻² day⁻¹ in summer). The implication is that biologically mediated sedimentological changes could be different among microhabitats, potentially leading to contrasting geomorphologic effects within a particular ecosystem.  相似文献   

Metal concentrations in the shell of Bathymodiolus azoricus from contrasting hydrothermal vent fields on the Mid-Atlantic Ridge     

Cravo A  Foster P  Almeida C  Bebianno MJ  Company R 《Marine environmental research》2008,65(4):338-348

Specimens of Bathymodiolus azoricus were sampled along the Mid-Atlantic Ridge at the Menez Gwen, Lucky Strike and Rainbow hydrothermal fields. Individual shells (n = 51), through the weight range 0.62 to 15.70 g, were analyzed for their magnesium, strontium, iron, manganese, copper, zinc and cadmium concentrations. Amongst the marine molluscs the shell of B. azoricus is confirmed as being particularly impoverished in strontium (mean 943 microg g(-1)). Trace metal concentrations in the shells decreased in the order Fe> Mn> Zn> Cu> Cd. Despite originating from trace metal rich environments mean concentrations were low (37.9, 13.2, 10.7, 1.1 and 0.7 microg g(-1), respectively). Irrespective of geographical origin magnesium, strontium and copper concentrations were primarily dictated by shell weight. In contrast cadmium concentrations were elevated in shells from the Rainbow field and ambient seawater chemistry imparted site specific chemical fingerprints to the shells with respect to the iron to manganese ratio.  相似文献   

Multi‐millennial scale climate variability during MIS 3 and MIS 2 inferred from luminescence dating of coastal sand dunes and buried paleosol sequences in central Chile, 32°S     

Juan‐Luis García  Belisario Andrade  Mauricio Caldern  Christopher Lüthgens 《第四纪科学杂志》2019,34(3):203-214

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Suction and time effects in rockfill deformation     

Eduardo E. Alonso  Mauricio A. Tapias 《国际地质力学数值与分析法杂志》2019,43(5):1032-1050

Ambient relative humidity controls the stress-strain-time behaviour of granular media exhibiting particle breakage. Breakage is the result of crack propagation inside loaded particles. The DEM model developed uses the results of subcritical crack propagation in brittle rock to predict breakage and the subsequent structural rearrangement. Two closed-form solutions at grain level, stress distribution under diametrically opposed forces and the mode I crack propagation velocity, were included in the DEM formulation. Crack propagation velocity depends explicitly on relative humidity. The resulting model incorporates comminution and splitting modes of particle breakage as well as arbitrary grain shapes by means of aggregation of spherical microparticles. The model was first validated against a large diameter suction-controlled oedometer test on hard limestone crushed gravel. Direct tests on contact properties (local stiffness and friction) helped to validate the model. The model was then used to predict the response of large diameter suction-controlled triaxial tests on gravels having different (uniform) initial sizes. Time delayed deformations and wetting-induced collapse deformations under maintained load are also a natural outcome of the model. They were shown to follow quite accurately the experimental results.  相似文献   

The transition zone of the Canary Current upwelling region   总被引：2，自引：0，他引：2  

E. D. Barton  J. Arístegui  P. Tett  M. Cantn  J. García-Braun  S. Hernndez-Len  L. Nykjaer  C. Almeida  J. Almunia  S. Ballesteros  G. Basterretxea  J. Escnez  L. García-Weill  A. Hernndez-Guerra  F. Lpez-Laatzen  R. Molina  M. F. Montero  E. Navarro-Prez  J. M. Rodríguez  K. van Lenning  H. Vlez  K. Wild 《Progress in Oceanography》1998,41(4):455-504

Like all the major upwelling regions, the Canary Current is characterised by intense mesoscale structure in the transition zone between the cool, nutrient-rich waters of the coastal upwelling regime and the warmer, oligotrophic waters of the open ocean. The Canary Island archipelago, which straddles the transition, introduces a second source of variability by perturbing the general southwestward flow of both ocean currents and Trade winds. The combined effects of the flow disturbance and the eddying and meandering of the boundary between upwelled and oceanic waters produce a complex pattern of regional variability. On the basis of historical data and a series of interdisciplinary field studies, the principal features of the region are described. These include a prominent upwelling filament originating near 28°N off the African coast, cyclonic and anti-cyclonic eddies downstream of the archipelago, and warm wake regions protected from the Trade winds by the high volcanic peaks of the islands. The filament is shown to be a recurrent feature, apparently arising from the interaction of a topographically trapped cyclonic eddy with the outer edge of the coastal upwelling zone. Its role in the transport and exchange of biogenic material, including fish larvae, is considered. Strong cyclonic eddies, observed throughout the year, drift slowly southwestward from Gran Canaria. One sampled in late summer was characterised by large vertical isopycnal displacements, apparent surface divergence and strong upwelling, producing a fourfold increase in chlorophyll concentrations over background values. Such intense eddies can be responsible for a major contribution to the vertical flux of nitrogen. The lee region of Gran Canaria is shown to be a location of strong pycnocline deformation resulting from Ekman pumping on the wind shear boundaries, which may contribute to the eddy formation process.  相似文献