Broad distribution of crystal-field environments for Nd<Superscript>3+</Superscript> in calcite     

S. H.?Withers  R. E.?PealeEmail author  A. F.?Schulte  G.?Braunstein  K. M.?Beck  W. P.?Hess  R. J.?Reeder 《Physics and Chemistry of Minerals》2003,30(7):440-448

Calcite crystals were grown from solution with single-crystal dimensions up to 3 mm and doped up to 0.1 at% with Nd³⁺ ions. Phase purity was verified by powder X-ray diffraction. The concentration of Nd³⁺ was measured by energy-dispersive spectrometry and Rutherford backscattering spectrometry. Micro X-ray fluorescence mapping of the calcite grains indicates uniform Nd distribution in as-grown crystal grains. X-ray absorption fine structure suggests that Nd³⁺ is substituted for Ca²⁺ with local lattice distortion. Temperature-dependent near-infrared spectroscopy of Nd³⁺ impurities in calcite reveals large inhomogeneous linewidths and smooth line profiles that are characteristic of glassy hosts, though the samples are well crystallized.  相似文献   

Evaluating Models Of The Neutral, Barotropic Planetary Boundary Layer Using Integral Measures: Part Ii. Modelling Observed Conditions     

G. D. Hess  J. R. Garratt 《Boundary-Layer Meteorology》2002,104(3):359-369

The steady-state, horizontally homogeneous, neutral, barotropiccase forms the foundation of our theoretical understanding of the planetary boundary layer (PBL).While simple analytical models and first-order closure models simulate atmospheric observationsof this case well, more sophisticated models, in general, do not. In this paperwe examine how well three higher-order closure models, E - - l, E - l, and LRR - l,which have been especially modified for PBL applications, perform in predicting the behaviour of thecross-isobaric angle ₀, the geostrophic drag coefficient C_g, and the integral of the dissipationrate over the boundary layer, as a function of the surface Rossby number Ro. For comparison we alsoexamine the performance of three first-order closure mixing-length models, two proposed byA. K. Blackadar and one by H. H. Lettau, and the performance of the standard model forsecond-order closure and a modification of it designed to reduce the overprediction of turbulence inthe upper part of the boundary layer.  相似文献   

The atmospheric boundary layer — advances in knowledge and application     

J. R. Garratt  G. D. Hess  W. L. Physick  P. Bougeault 《Boundary-Layer Meteorology》1996,78(1-2):9-37

We summarise major activities and advances in boundary-layer knowledge in the 25 years since 1970, with emphasis on the application of this knowledge to surface and boundary-layer parametrisation schemes in numerical models of the atmosphere. Progress in three areas is discussed: (i) the mesoscale modelling of selected phenomena; (ii) numerical weather prediction; and (iii) climate simulations. Future trends are identified, including the incorporation into models of advanced cloud schemes and interactive canopy schemes, and the nesting of high resolution boundary-layer schemes in global climate models.  相似文献   

Generalized Ground Water Sampling Device Matrix     

K.F. Pohlmann  J. W. Hess 《Ground Water Monitoring & Remediation》1988,8(4):82-84

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Mirages on Mars     

Seymour L. Hess  Jimmy L. Mitchell 《Icarus》1977,30(1):42-48

The possibility of observing mirages on Mars from the Viking lander cameras is examined. A simple model for the production of both inferior and superior mirages is developed. Assuming the atmospheric index of refraction to be a linear function of density (i.e., temperature), ray curvatures are calculated through layers of large, expected thermal gradient.Assuming the Martian morning inversions of Gierasch and Goody (1968), calculations of ray curvature show the superior mirage to be an unlikely occurrence on Mars since the downward curvature of the ray through the inversion layer is less than the downward curvature of the planet. In order to examine the nature of inferior mirages we select a reasonable expression for temperature profile in the surface layer fitted to the midafternoon, midlatitude summer results of Gierasch and Goody. Integration of the expression for ray curvature yields a relation for the minimum distance between the lander cameras and an inferior mirage as a function of the surface superadiabatic lapse rate. Such calculations indicate that the Viking lander cameras will record inferior mirages at horizontal distances of a kilometer or so from the lander. Given the appearance of an inferior mirage at a measured minimum distance from the observer it should be a simple matter to calculate the corresponding mean temperature lapse rate at the surface.  相似文献   

EXAFS study of rare-earth element coordination in calcite     

E.J. ElzingaR.J. Reeder  S.H. WithersR.E. Peale  R.A. MasonK.M. Beck  W.P. Hess 《Geochimica et cosmochimica acta》2002,66(16):2875-2885

Extended X-ray absorption fine-structure (EXAFS) spectroscopy is used to characterize the local coordination of selected rare-earth elements (Nd³⁺, Sm³⁺, Dy³⁺, Yb³⁺) coprecipitated with calcite in minor concentrations from room-temperature aqueous solutions. Fitting results confirm substitution in the Ca site, but first-shell Nd-O and Sm-O distances are longer than the Ca-O distance in calcite and longer than what is consistent with ionic radii sums for sixfold coordination in the octahedral Ca site. In contrast, first-shell Dy-O and Yb-O distances are shorter than the Ca-O distance and are consistent with ionic radii sums for sixfold coordination. Comparison of Nd-O and Sm-O bond lengths with those in lanthanide sesquioxides and with ionic radii trends across the lanthanide series suggests that Nd³⁺ and Sm³⁺ have sevenfold coordination in a modified Ca site in calcite. This would require some disruption of the local structure, with an expected decrease in stability, and possibly a different charge compensation mechanism between Nd and Sm vs. Yb and Dy. A possible explanation for the increased coordination for the larger rare-earth elements involves bidentate ligation from a CO₃ group. Because trivalent actinides such as Am³⁺ and Cm³⁺ have ionic radii similar to Nd³⁺, their incorporation in calcite may result in a similar defect structure.  相似文献   

Cyclocrinus, an enigmatic Jurassic–Cretaceous crinoid     

Hans Hess 《Swiss Journal of Geoscience》2008,101(2):465-481

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Chert provenance analysis at the Mack Canyon Site,Sherman County,Oregon: An evaluative study     

Sean C. Hess 《Geoarchaeology》1996,11(1):51-81

Chert is the most frequent lithic raw material in the Columbia Plateau, but archaeologists have made few attempts to link chert artifacts to their quarries in this area. The Mack Canyon Site in north-central Oregon is near a chert source, providing an opportunity to compare provenance analysis techniques. Macroscopic and microscopic visual attributes and element concentrations were determined for 26 samples from six sources in the Columbia Plateau. Additional concentration data from two other sources were included for comparison. Four artifacts were selected from the Mack Canyon Site for comparison to the nearby outcrop. Although all of the artifacts were macroscopically indistinguishable from the local material, microscopic attributes and element concentrations indicate that only one of the artifacts came from the outcrop. Linking chert artifacts and quarries through statistical analysis of element concentrations holds promise for the Columbia Plateau. © 1996 John Wiley & Sons, Inc.  相似文献   

Chemical erosion of the Lilburn Cave system, Kings Canyon National Park, California     

Abu-Jaber N  Hess JW  Howcroft W 《Ground water》2001,39(2):223-229

Multi-year instrumental records for input, throughflow and output waters of the Lilburn Cave system provide control on denudation rates as they respond to seasonal and spatial variability. Data suggest that maximum denudation is in the late fall and early winter. This is when non-snowmelt discharge is at its maximum. At lower discharge rates the volume of water moving through the cave system is the limiting control on the volume of denudation. During periods of snowmelt the limiting control is the rate at which the calcite dissolves. This is probably the result of water flowing through wider channels during these times. Based on instrumental measurements, there is considerable variation in terms of where denudation occurs inside the cave. The loci of dissolution change from year to year. This is to be expected in the dynamic environment of the cave where materials shift routinely. This variability should be studied over longer periods of time in order to more fully understand its extent. The relatively small area of carbonate exposure relative to the area of the drainage basin gives rise to relatively high denudation rates. The carbonate is being removed at a rate of about 5000 metric tons per year, or at about 830 mm/y. This is about five times the rate reported in the humid karst regions of Malaysia. This information indicates that the relative proportion of carbonate in the drainage basin needs to be considered when trying to estimate denudation in other areas.  相似文献   

Life and death of <Emphasis Type="Italic">Saccocoma tenella</Emphasis> (G<Emphasis Type="SmallCaps">oldfuss</Emphasis>)     

Hans Hess  Walter Etter 《Swiss Journal of Geoscience》2011,104(1):99-106

The morphology of the small stalkless Saccocoma tenella is unique among crinoids. It is characterized by an extremely light skeleton with dish-like lateral wings on the proximal brachials and peculiar paired vertical processes flanking the food grooves of more distal brachials. The arms are heavily branched. The lateral wings obviously were involved in vertical movement. For the vertical processes a “baffle rail” function for arm curling and “snap swimming” has been postulated, with muscles between the processes. However, there is no evidence that the processes were connected by muscles. For food collection a “pulsating funnel” model in the water column is advocated, with the processes serving to collect plankton during upward movement of the arms. The resulting mouth-up position is supported by the biostratinomy. Saccocoma tenella is considered to have been pelagic, a benthic lifestyle is rejected on ecologic and taphonomic grounds. Adorally-curled arms are considered a reaction to hostile environment before death, not a taphonomic artefact.  相似文献